Conditions | Yield |
---|---|
In not given evapn. of filtrated soln.; |
Conditions | Yield |
---|---|
In water heating;; | |
In water heating;; |
Conditions | Yield |
---|---|
In not given evapn.of filtrated soln.; |
Conditions | Yield |
---|---|
In further solvent(s) Electrolysis; in 5-20 w.-% NaOH soln.; | |
In not given Electrolysis; in dild. NaOH soln.; |
Conditions | Yield |
---|---|
In not given Electrolysis; |
sodium hydrogencarbonate
B
sodium permanganate
Conditions | Yield |
---|---|
In water byproducts: Na2CO3; stirring (1 h), refluxing (30 min); filtration, crystn.; IR spectroccopy, X-ray diffractometry; |
sodium hypochlorite
sodium permanganate
Conditions | Yield |
---|---|
With Mn(II)-silicate In water alk. soln.;; | |
With Mn(II)-silicate In water alk. soln.;; |
Conditions | Yield |
---|---|
In water Kinetics; Na2MnO4*10H2O was reacted with aq. OH(1-) at 0; 25 and 45°C; reaction was study at 45°C with varied pressure (0-180 MPa); |
sodium permanganate
Conditions | Yield |
---|---|
dehydratation at 160°C or quicker at 180°C; | |
dehydratation at 70°C in vac. over P2O5; | |
dehydratation at 160°C or quicker at 180°C; | |
dehydratation at 70°C in vac. over P2O5; | |
dehydratation in vac. at 70-80°C; |
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
Stage #1: manganese(IV) oxide; boric acid; magnesium oxide; sodium silicate solution of Ludox 30 With lithium hydroxide In water at 110℃; for 12h; Stage #2: at 900℃; for 12h; Calcination; |
sodium permanganate
ammonia
Conditions | Yield |
---|---|
In ammonia aq. NH3; Cd sulfate dissolved in aq. NH3, cooled to 5°C, then aq. NaMnO4 cooled to 5°C added; cooled to 0°C; | 86% |
Conditions | Yield |
---|---|
In water at 159.84℃; for 12h; Autoclave; High pressure; | 83% |
Conditions | Yield |
---|---|
In water | 63% |
In water |
sodium permanganate
malonic acid
Conditions | Yield |
---|---|
With CH3OH In acetonitrile to a soln. of malonic acid in actonitrile was added NaMnO4 under N2, stirred for 20-30 min, methanol was added; evapn.; elem. anal.; | 38% |
sodium permanganate
N-(3-chloro-2-methylphenyl)acetamide
2-(acetylamino)-6-chlorobenzoic acid
Conditions | Yield |
---|---|
In water |
sodium permanganate
sulfuric acid
6-aminopenicillanic acid
(5R,6R)-6-amino-2,2-dimethyl-1,1-dioxopenam-3-carboxylic acid
Conditions | Yield |
---|---|
With phosphoric acid; ammonia In water; acetonitrile |
Conditions | Yield |
---|---|
In not given first treating of NaMnO4 soln. with chlorine or air then pptg. with KCl; |
sodium permanganate
manganese(IV) oxide
Conditions | Yield |
---|---|
With dihydrogen peroxide In not given dropwise addn. of H2O2 at 70 °C to NaMnO4-soln. (contg. NaOH or KOH);; MnO1.99-MnO2;; | |
With hydrogenchloride In hydrogenchloride redn. of NaMnO4 with HCl;; drying at 120 °C in O2-atmosphere yields Na0.22MnO1.97;; | |
In neat (no solvent) thermal decompn.;; | |
With HCl In hydrogenchloride redn. of NaMnO4 with HCl;; drying at 120 °C in O2-atmosphere yields Na0.22MnO1.97;; |
Conditions | Yield |
---|---|
In not given excess of soln. of NaMnO4 used; | |
In not given excess of soln. of NaMnO4 used; |
Conditions | Yield |
---|---|
With ethanol In not given redn. of a soln. of sodium paramolybdate and NaMnO4 by alcohol; addn. of KCl;; | |
With alcohol In not given redn. of a soln. of sodium paramolybdate and NaMnO4 by alcohol; addn. of KCl;; |
sodium permanganate
Conditions | Yield |
---|---|
With NaOH; H2O dissolved 20g of Na2{Fe(CN)5NO}*2H2O, 10g of NaMnO4, 2.5g of NaOH in 100cm^3 water; stayed (often shaked); added 30 cm^3 of ethanol; filtered; mixed with acetic acid, then with alcohol-ether; washed 5 times in water, pptd. with alcohol; |
Conditions | Yield |
---|---|
In sodium hydroxide byproducts: H2O; aq. NaOH; in 30-40 % NaOH soln., heating, mixing; | |
In sodium hydroxide byproducts: H2O; in 30-40 % NaOH soln., heating, mixing; |
Conditions | Yield |
---|---|
excess of NaOH used, at 125°C; | |
In neat (no solvent) N2 atmosphere; molar ratio Na-compd. : Mn-compd. = 1 : 1, heating (150°C, 10 h); detd. by X-ray powder diffraction and IR-spectroscopy; | |
In not given | |
excess of NaOH used, at 125°C; |
sodium permanganate
bismuth oxide perchlorate
Conditions | Yield |
---|---|
In not given in soln. of perchloric acid; |
sodium permanganate
bismuth oxide perchlorate
Conditions | Yield |
---|---|
In not given in soln. of perchloric acid; |
sodium permanganate
bismuth oxide perchlorate
Conditions | Yield |
---|---|
In not given in soln. of perchloric acid; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: O2; heating to 120 - 180°C; reaction followed by X-ray powder diffraction and IR-spectroscopy; | |
byproducts: O2; thermal decompn. at 330°C; |
sodium permanganate
Phosphate
Conditions | Yield |
---|---|
With phosphorous In water byproducts: hypophosphate, triphosphate, tetraphosphate; phosphorus dissolved in CS2; further byproduct: MnO2-hydrate; detn. of products by paper chromatography; | |
With white phosphorus In water byproducts: hypophosphate, triphosphate, tetraphosphate; phosphorus dissolved in CS2; further byproduct: MnO2-hydrate; detn. of products by paper chromatography; |
sodium permanganate
Conditions | Yield |
---|---|
With LiI In not given redox reaction between NaMnO4 and LiI in 6-fold excess at room temp. according to A. Ibarra-Palos et al., Solid State Ionics 138 (2001) 203-212 and A. Ibarra-Palos, et al., J. Power Sources 146 (2005)294-299; washed with distd. H2O, filtered, dried under vac. at >=150 °C; small contents of I (2-4%); |
sodium permanganate
Conditions | Yield |
---|---|
In neat (no solvent) formation of a diadochous compound between BaSO4 and NaMnO4;; | |
In neat (no solvent) formation of a diadochous compound between BaSO4 and NaMnO4;; | |
In not given satd soln. used; |
Conditions | Yield |
---|---|
In neat (no solvent) heating in air (800°C, 8 h); |
Conditions | Yield |
---|---|
excess of NaOH used, at 125°C; recrystn from heavy basic soln.; | |
excess of NaOH used, at 125°C; recrystn from heavy basic soln.; |
Conditions | Yield |
---|---|
excess of NaOH used, at 125°C, cooling in mixture of ice and NaCl; | |
excess of NaOH used, at 125°C, cooling in mixture of ice and NaCl; |
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