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Synthetic route

calcium permanganate

calcium permanganate

sodium sulfate
7757-82-6

sodium sulfate

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In not given evapn. of filtrated soln.;
calcium hypochlorite
7778-54-3

calcium hypochlorite

sodium hydroxide
1310-73-2

sodium hydroxide

manganese(ll) chloride

manganese(ll) chloride

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In water heating;;
In water heating;;
silver(I) permanganate
7783-98-4

silver(I) permanganate

sodium chloride
7647-14-5

sodium chloride

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In not given evapn.of filtrated soln.;
manganese
7439-96-5

manganese

sodium hydroxide
1310-73-2

sodium hydroxide

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In further solvent(s) Electrolysis; in 5-20 w.-% NaOH soln.;
In not given Electrolysis; in dild. NaOH soln.;
manganese
7439-96-5

manganese

sodium carbonate
497-19-8

sodium carbonate

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In not given Electrolysis;
barium manganate

barium manganate

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

A

barium permanganate

barium permanganate

B

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In water byproducts: Na2CO3; stirring (1 h), refluxing (30 min); filtration, crystn.; IR spectroccopy, X-ray diffractometry;
sodium hypochlorite
7681-52-9

sodium hypochlorite

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
With Mn(II)-silicate In water alk. soln.;;
With Mn(II)-silicate In water alk. soln.;;
hydroxide

hydroxide

2Na(1+)*MnO4(2-)*10H2O=Na2MnO4*10H2O

2Na(1+)*MnO4(2-)*10H2O=Na2MnO4*10H2O

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In water Kinetics; Na2MnO4*10H2O was reacted with aq. OH(1-) at 0; 25 and 45°C; reaction was study at 45°C with varied pressure (0-180 MPa);
sodium permanganate trihydrate

sodium permanganate trihydrate

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
dehydratation at 160°C or quicker at 180°C;
dehydratation at 70°C in vac. over P2O5;
dehydratation at 160°C or quicker at 180°C;
dehydratation at 70°C in vac. over P2O5;
dehydratation in vac. at 70-80°C;
barium permanganate

barium permanganate

sodium sulfate
7757-82-6

sodium sulfate

sodium permanganate
10101-50-5

sodium permanganate

Conditions
ConditionsYield
In water
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

boric acid
11113-50-1

boric acid

magnesium oxide

magnesium oxide

sodium silicate solution of Ludox 30

sodium silicate solution of Ludox 30

A

sodium permanganate
10101-50-5

sodium permanganate

B

Mg6MnO8

Mg6MnO8

3Mg(2+)*2BO3(3-)

3Mg(2+)*2BO3(3-)

Conditions
ConditionsYield
Stage #1: manganese(IV) oxide; boric acid; magnesium oxide; sodium silicate solution of Ludox 30 With lithium hydroxide In water at 110℃; for 12h;
Stage #2: at 900℃; for 12h; Calcination;
sodium permanganate
10101-50-5

sodium permanganate

cadmium sulfate octahydrate

cadmium sulfate octahydrate

ammonia
7664-41-7

ammonia

tetraamminecadmium(II) bis(permanganate)

tetraamminecadmium(II) bis(permanganate)

Conditions
ConditionsYield
In ammonia aq. NH3; Cd sulfate dissolved in aq. NH3, cooled to 5°C, then aq. NaMnO4 cooled to 5°C added; cooled to 0°C;86%
manganese sulfate pentahydrate

manganese sulfate pentahydrate

sodium permanganate
10101-50-5

sodium permanganate

manganese (IV) dioxide

manganese (IV) dioxide

Conditions
ConditionsYield
In water at 159.84℃; for 12h; Autoclave; High pressure;83%
sodium permanganate
10101-50-5

sodium permanganate

silver nitrate

silver nitrate

silver(I) permanganate
7783-98-4

silver(I) permanganate

Conditions
ConditionsYield
In water63%
In water
sodium permanganate
10101-50-5

sodium permanganate

malonic acid
141-82-2

malonic acid

{(sodium)2{Mn(III)(malonate)2}{Mn(III)(malonate)2(methanol)}*methanol}n

{(sodium)2{Mn(III)(malonate)2}{Mn(III)(malonate)2(methanol)}*methanol}n

Conditions
ConditionsYield
With CH3OH In acetonitrile to a soln. of malonic acid in actonitrile was added NaMnO4 under N2, stirred for 20-30 min, methanol was added; evapn.; elem. anal.;38%
sodium permanganate
10101-50-5

sodium permanganate

N-(3-chloro-2-methylphenyl)acetamide
7463-35-6

N-(3-chloro-2-methylphenyl)acetamide

2-(acetylamino)-6-chlorobenzoic acid
19407-42-2

2-(acetylamino)-6-chlorobenzoic acid

Conditions
ConditionsYield
In water
sodium metabisulfite

sodium metabisulfite

sodium permanganate
10101-50-5

sodium permanganate

sulfuric acid
7664-93-9

sulfuric acid

(5R,6R)-6-amino-2,2-dimethyl-1,1-dioxopenam-3-carboxylic acid
36091-15-3

(5R,6R)-6-amino-2,2-dimethyl-1,1-dioxopenam-3-carboxylic acid

Conditions
ConditionsYield
With phosphoric acid; ammonia In water; acetonitrile
sodium permanganate
10101-50-5

sodium permanganate

potassium chloride

potassium chloride

potassium permanganate
7722-64-7

potassium permanganate

Conditions
ConditionsYield
In not given first treating of NaMnO4 soln. with chlorine or air then pptg. with KCl;
sodium permanganate
10101-50-5

sodium permanganate

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

Conditions
ConditionsYield
With dihydrogen peroxide In not given dropwise addn. of H2O2 at 70 °C to NaMnO4-soln. (contg. NaOH or KOH);; MnO1.99-MnO2;;
With hydrogenchloride In hydrogenchloride redn. of NaMnO4 with HCl;; drying at 120 °C in O2-atmosphere yields Na0.22MnO1.97;;
In neat (no solvent) thermal decompn.;;
With HCl In hydrogenchloride redn. of NaMnO4 with HCl;; drying at 120 °C in O2-atmosphere yields Na0.22MnO1.97;;
sodium permanganate
10101-50-5

sodium permanganate

Eisenharnstoffnitrat

Eisenharnstoffnitrat

Eisen(III)-harnstoffpermanganat

Eisen(III)-harnstoffpermanganat

Conditions
ConditionsYield
In not given excess of soln. of NaMnO4 used;
In not given excess of soln. of NaMnO4 used;
sodium permanganate
10101-50-5

sodium permanganate

sodium paramolybdate

sodium paramolybdate

water
7732-18-5

water

oxalic acid
144-62-7

oxalic acid

3K2O*MnO2*8MoO3*15H2O

3K2O*MnO2*8MoO3*15H2O

Conditions
ConditionsYield
With ethanol In not given redn. of a soln. of sodium paramolybdate and NaMnO4 by alcohol; addn. of KCl;;
With alcohol In not given redn. of a soln. of sodium paramolybdate and NaMnO4 by alcohol; addn. of KCl;;
sodium permanganate
10101-50-5

sodium permanganate

disodium pentacyanonitrosylferrate(II) dihydrate

disodium pentacyanonitrosylferrate(II) dihydrate

sodium iron(III) nitritopentacyanide*2H2O

sodium iron(III) nitritopentacyanide*2H2O

Conditions
ConditionsYield
With NaOH; H2O dissolved 20g of Na2{Fe(CN)5NO}*2H2O, 10g of NaMnO4, 2.5g of NaOH in 100cm^3 water; stayed (often shaked); added 30 cm^3 of ethanol; filtered; mixed with acetic acid, then with alcohol-ether; washed 5 times in water, pptd. with alcohol;
manganese(IV) oxide
1313-13-9

manganese(IV) oxide

sodium permanganate
10101-50-5

sodium permanganate

sodium hydroxide
1310-73-2

sodium hydroxide

sodium manganate(VI)

sodium manganate(VI)

Conditions
ConditionsYield
In sodium hydroxide byproducts: H2O; aq. NaOH; in 30-40 % NaOH soln., heating, mixing;
In sodium hydroxide byproducts: H2O; in 30-40 % NaOH soln., heating, mixing;
sodium permanganate
10101-50-5

sodium permanganate

sodium hydroxide
1310-73-2

sodium hydroxide

sodium manganate(VI)

sodium manganate(VI)

Conditions
ConditionsYield
excess of NaOH used, at 125°C;
In neat (no solvent) N2 atmosphere; molar ratio Na-compd. : Mn-compd. = 1 : 1, heating (150°C, 10 h); detd. by X-ray powder diffraction and IR-spectroscopy;
In not given
excess of NaOH used, at 125°C;
sodium permanganate
10101-50-5

sodium permanganate

bismuth oxide perchlorate
44584-78-3

bismuth oxide perchlorate

2BiO(1+)*OH(1-)*MnO4(1-)*1.5H2O={Bi2O2(OH)}MnO4*1.5H2O

2BiO(1+)*OH(1-)*MnO4(1-)*1.5H2O={Bi2O2(OH)}MnO4*1.5H2O

Conditions
ConditionsYield
In not given in soln. of perchloric acid;
sodium permanganate
10101-50-5

sodium permanganate

bismuth oxide perchlorate
44584-78-3

bismuth oxide perchlorate

6BiO(1+)*3OH(1-)*3MnO4(1-)={Bi6O6}(OH)3(MnO4)3

6BiO(1+)*3OH(1-)*3MnO4(1-)={Bi6O6}(OH)3(MnO4)3

Conditions
ConditionsYield
In not given in soln. of perchloric acid;
sodium permanganate
10101-50-5

sodium permanganate

bismuth oxide perchlorate
44584-78-3

bismuth oxide perchlorate

6Bi(OH)2(1+)*2OH(1-)*4MnO4(1-)=Bi6(OH)12(OH)2(MnO4)4

6Bi(OH)2(1+)*2OH(1-)*4MnO4(1-)=Bi6(OH)12(OH)2(MnO4)4

Conditions
ConditionsYield
In not given in soln. of perchloric acid;
sodium permanganate
10101-50-5

sodium permanganate

A

manganese(IV) oxide
1313-13-9

manganese(IV) oxide

B

sodium manganate(VI)

sodium manganate(VI)

Conditions
ConditionsYield
In neat (no solvent) byproducts: O2; heating to 120 - 180°C; reaction followed by X-ray powder diffraction and IR-spectroscopy;
byproducts: O2; thermal decompn. at 330°C;
sodium permanganate
10101-50-5

sodium permanganate

Phosphate
14265-44-2

Phosphate

Conditions
ConditionsYield
With phosphorous In water byproducts: hypophosphate, triphosphate, tetraphosphate; phosphorus dissolved in CS2; further byproduct: MnO2-hydrate; detn. of products by paper chromatography;
With white phosphorus In water byproducts: hypophosphate, triphosphate, tetraphosphate; phosphorus dissolved in CS2; further byproduct: MnO2-hydrate; detn. of products by paper chromatography;
sodium permanganate
10101-50-5

sodium permanganate

manganese oxide

manganese oxide

Conditions
ConditionsYield
With LiI In not given redox reaction between NaMnO4 and LiI in 6-fold excess at room temp. according to A. Ibarra-Palos et al., Solid State Ionics 138 (2001) 203-212 and A. Ibarra-Palos, et al., J. Power Sources 146 (2005)294-299; washed with distd. H2O, filtered, dried under vac. at >=150 °C; small contents of I (2-4%);
barium sulfate

barium sulfate

sodium permanganate
10101-50-5

sodium permanganate

Ba(2+)*SO4(2-)=BaSO4#Na(1+)*MnO4(1-)=NaMnO4

Ba(2+)*SO4(2-)=BaSO4#Na(1+)*MnO4(1-)=NaMnO4

Conditions
ConditionsYield
In neat (no solvent) formation of a diadochous compound between BaSO4 and NaMnO4;;
In neat (no solvent) formation of a diadochous compound between BaSO4 and NaMnO4;;
In not given satd soln. used;
manganese(III) oxide

manganese(III) oxide

sodium permanganate
10101-50-5

sodium permanganate

sodium manganese oxide

sodium manganese oxide

Conditions
ConditionsYield
In neat (no solvent) heating in air (800°C, 8 h);
sodium permanganate
10101-50-5

sodium permanganate

sodium hydroxide
1310-73-2

sodium hydroxide

2Na(1+)*MnO4(2-)*6H2O=Na2MnO4*6H2O

2Na(1+)*MnO4(2-)*6H2O=Na2MnO4*6H2O

Conditions
ConditionsYield
excess of NaOH used, at 125°C; recrystn from heavy basic soln.;
excess of NaOH used, at 125°C; recrystn from heavy basic soln.;
sodium permanganate
10101-50-5

sodium permanganate

sodium hydroxide
1310-73-2

sodium hydroxide

2Na(1+)*MnO4(2-)*10H2O=Na2MnO4*10H2O

2Na(1+)*MnO4(2-)*10H2O=Na2MnO4*10H2O

Conditions
ConditionsYield
excess of NaOH used, at 125°C, cooling in mixture of ice and NaCl;
excess of NaOH used, at 125°C, cooling in mixture of ice and NaCl;

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