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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4,4'-BIS(BROMOMETHYL)-2,2'-BIPYRIDINE

Cas:134457-14-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:white powder Storage:Sealed, dry, microtherm ,

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:1

Negotiable

Type:Other

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 134457-14-0 with competitive price

Cas:134457-14-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 4,4'-bis(bromomethyl)-2,2'-bipyridine Structural formula CAS No. 134457-14-0 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Applicat

4,4'-bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Qingdao Beluga Import and Export Co., LTD

4,4'-Bis(bromomethyl)-2,2'-bipyridine CAS:134457-14-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in

4,4'-Bis(bromomethyl)-2,2'-bipyridine CAS:134457-14-0

Cas:134457-14-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Bis-4,4'-bromomethyl-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Manufacturers

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Zhengzhou Yuanli Biological Technology Co., Ltd.

ProName: 6813-38-3 98% YL CasNo: 134457-14-0 Molecular Formula: C12H8N2O4 Appearance: White or almost white crystalline powder Application: Intermediates. DeliveryTime:Have stock. PackAge: 500g/bottle. Port: Beijing, Shanghai, Qingdao, Tian

134457-14-0 98% YL

Cas:134457-14-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bis-4,4'-bromomethyl-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

4,4'-Bis(bromomethyl)-2,2'-bipyridine Chemical Properties Melting point 135-137 °C(Solv: hexane (110-54-3); dichloromethane (75-09-2)) Boiling point 425.2±40.0 °C(Predicted) density 1.708 storage temp. Inert atm

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Shanghai Massive Chemical Technology Co., Ltd. is engaged in development, production and marketing Specialty Chemicals to satisfy the changing needs of the chemical industry. We specialize in manufacturing high quality of Advanced Intermediates, Sp

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

4,4'-bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4,4'-Bis(bromomethyl)-2,2'-bipyridine cas no. 134457-14-0 98%

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

4,4'-bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Bis-4,4'-Bromomethyl-2,2'-BipyridineAppearance:White crystalline powder Storage:Keep away of light,cool place Package:25kg/drum;200kg/drum Application:Fine Chemical Transportation:Sea/air/courier

Bis-4,4'-Bromomethyl-2,2'-Bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

4,4'-Bis(broMoMethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

134457-14-0

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

4,4'-Bis(bromomethyl)-2,2'-bipyridine

Cas:134457-14-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

4,4’-bis[(trimethylsilyl)methyl]-2,2’-bipyridine
199282-52-5

4,4’-bis[(trimethylsilyl)methyl]-2,2’-bipyridine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
With 1,2-dibromo-1,1,2,2-tetrafluoroethane; cesium fluoride In N,N-dimethyl-formamide at 25℃; for 2h;97%
With hexabromoethane; cesium fluoride97%
With 1,2-dibromo-1,1,2,2-tetrafluoroethane; cesium fluoride In N,N-dimethyl-formamide at 20℃; for 3h;94.8%
With 1,2-dibromo-1,1,2,2-tetrafluoroethane; tetrabutyl ammonium fluoride; silica gel In tetrahydrofuran at -78℃;
With 1,2-dibromo-1,1,2,2-tetrafluoroethane; cesium fluoride In N,N-dimethyl-formamide at 25℃; for 2h; Bromination;
4,4'-bis(hydroxymethyl)-2,2'-bipyridine
109073-77-0

4,4'-bis(hydroxymethyl)-2,2'-bipyridine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
With sulfuric acid; hydrogen bromide for 6h; Substitution; Heating;88%
With sulfuric acid; hydrogen bromide at 110℃; for 6h;88%
With sulfuric acid; hydrogen bromide at 110℃; for 6h;88%
4,4'-dimethyl-2,2'-bipyridines
1134-35-6

4,4'-dimethyl-2,2'-bipyridines

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
With sulfuric acid; hydrogen bromide for 6h; Reflux;85%
With N-Bromosuccinimide30%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane for 3h; Heating;10.1%
4,4'-bis(hydroxymethyl)-2,2'-bipyridine
109073-77-0

4,4'-bis(hydroxymethyl)-2,2'-bipyridine

A

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

B

(4'-Bromomethyl-[2,2']bipyridinyl-4-yl)-methanol

(4'-Bromomethyl-[2,2']bipyridinyl-4-yl)-methanol

Conditions
ConditionsYield
With hydrogen bromide In water for 3h; Heating;A 75%
B 18%
2,2'-Bipyridine-4,4'-dicarboxylic acid
6813-38-3

2,2'-Bipyridine-4,4'-dicarboxylic acid

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 99 percent / conc. H2SO4 / 60 h / Heating
2: 30 percent / NaBH4 / methanol / 60 h / Heating
3: 30 percent / aq. HBr / 3.5 h / Heating
View Scheme
Multi-step reaction with 3 steps
1: sulfuric acid / 4 h / Reflux
2: sodium tetrahydroborate / ethanol / 3 h / Reflux
3: sulfuric acid; hydrogen bromide / 6 h / Reflux
View Scheme
Multi-step reaction with 3 steps
1: sulfuric acid
2: sodium tetrahydroborate / ethanol
3: hydrogen bromide / sulfuric acid
View Scheme
4,4'-bis(carbomethoxy)-2,2'-bipyridine
71071-46-0

4,4'-bis(carbomethoxy)-2,2'-bipyridine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 30 percent / NaBH4 / methanol / 60 h / Heating
2: 30 percent / aq. HBr / 3.5 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: NaBH4 / ethanol
2: 48percent HBr, drops of conc. H2SO4
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / ethanol
2: hydrogen bromide / sulfuric acid
View Scheme
4,4’-dimethyl-2,2’-bipyridine N,N’-dioxide
87855-83-2

4,4’-dimethyl-2,2’-bipyridine N,N’-dioxide

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 43.5 percent / acetic acid / 4 h / Heating
2: 44 percent / NaOH; water / methanol / 3 h / Heating
3: 72.3 percent / hydrobromic acid / 5 h / Heating
View Scheme
4,4'-bis(acetoxymethyl)-2,2'-bipyridine
279681-06-0

4,4'-bis(acetoxymethyl)-2,2'-bipyridine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 44 percent / NaOH; water / methanol / 3 h / Heating
2: 72.3 percent / hydrobromic acid / 5 h / Heating
View Scheme
[2,2']bipyridinyl-4,4'-dicarbaldehyde
99970-84-0

[2,2']bipyridinyl-4,4'-dicarbaldehyde

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: NaBH4; aq. NaOH / methanol / 1 h / 20 °C
2: aq. HBr; H2SO4 / Heating
View Scheme
Multi-step reaction with 4 steps
1: nitric acid / 2 h / Reflux
2: thionyl chloride / 20 h / Reflux
3: sodium tetrahydroborate / ethanol / 3 h / Reflux
4: hydrogen bromide / water / 3 h / Reflux
View Scheme
4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine
1762-42-1

4,4'-bis(ethoxycarbonyl)-2,2'-bipyridine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 89 percent / NaBH4 / ethanol / 3 h / 20 °C
2: 88 percent / HBr; H2SO4 / 6 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / ethanol / 3 h / Reflux
2: sulfuric acid; hydrogen bromide / 6 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / ethanol / 12 h / 80 °C
2: hydrogen bromide; sulfuric acid / 12 h / Reflux
View Scheme
2,2'-bipyridyl-4,4'-dicarboxylic acid chloride
72460-28-7

2,2'-bipyridyl-4,4'-dicarboxylic acid chloride

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 12 h / Reflux
2: sodium tetrahydroborate / ethanol / 3 h / Reflux
3: hydrogen bromide; sulfuric acid; sodium hydroxide / 6 h / pH 7.0 / Reflux
View Scheme
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

trimethylamine
75-50-3

trimethylamine

4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine

4,4’‐bis(trimethylammoniummethyl)‐2,2’‐bipyridine

Conditions
ConditionsYield
In dichloromethane; water at 20℃; for 24h;100%
In ethanol; water at 20℃; for 1h; Inert atmosphere;100%
In ethanol; water at 20℃; for 1h;
In dichloromethane; water at 20℃; for 24h;
In dichloromethane at 20℃; for 24h;
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis(azidomethylene)-2,2-bipyridine

4,4'-bis(azidomethylene)-2,2-bipyridine

Conditions
ConditionsYield
With sodium azide In dimethyl sulfoxide at 20℃; Inert atmosphere;99%
With sodium azide In dimethyl sulfoxide; acetonitrile at 20℃; for 120h;94%
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

triethyl phosphite
122-52-1

triethyl phosphite

4,4'-bis(diethylphosphonomethyl)-2,2'-bipyridine
176220-38-5

4,4'-bis(diethylphosphonomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
at 80℃; for 12h; Inert atmosphere;98%
at 80℃; for 6h; Inert atmosphere;95%
In chloroform95%
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis(aminomethyl)-2,2'-bipyridine
727380-18-9

4,4'-bis(aminomethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Stage #1: 4,4'-bis(bromomethyl)-2,2'-bipyridine With potassium phtalimide In N,N-dimethyl-formamide
Stage #2: With hydrazine hydrate In ethanol
98%
Stage #1: 4,4'-bis(bromomethyl)-2,2'-bipyridine With potassium phtalimide In N,N-dimethyl-formamide at 50℃; for 15h; Inert atmosphere;
Stage #2: With hydrazine In ethanol; water at 100℃; for 18h;
71%
Multi-step reaction with 2 steps
1: sodium azide / dimethyl sulfoxide / 20 °C / Inert atmosphere
2: triethylamine; palladium 10% on activated carbon; hydrogen / tetrahydrofuran / 48 h / Inert atmosphere
View Scheme
3-aminopropyltriethoxysilane
919-30-2

3-aminopropyltriethoxysilane

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis[3-(triethoxysilyl)propylaminomethyl]-2,2'-bipyridine

4,4'-bis[3-(triethoxysilyl)propylaminomethyl]-2,2'-bipyridine

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 50℃; for 6h;96%
With triethylamine In tetrahydrofuran at 50℃; for 6h; Inert atmosphere;92%
With triethylamine In tetrahydrofuran at 50℃; for 6h; Inert atmosphere;92%
With triethylamine In tetrahydrofuran at 50℃; for 6h;
bis[dimethyl(μ-dimethylsulfide)platinum(II)]

bis[dimethyl(μ-dimethylsulfide)platinum(II)]

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

(CH2C5H3NC5H3N(CH2Br))Pt(Br)(CH3)2((CH2C5H3N)2)[Pt(Br)(CH3)2((BrCH2C5H3N)2)]Pt(Br)(CH3)2(CH2C5H3NC5H3NCH2Br)Pt(Br)(CH3)2

(CH2C5H3NC5H3N(CH2Br))Pt(Br)(CH3)2((CH2C5H3N)2)[Pt(Br)(CH3)2((BrCH2C5H3N)2)]Pt(Br)(CH3)2(CH2C5H3NC5H3NCH2Br)Pt(Br)(CH3)2

Conditions
ConditionsYield
In acetone washing (ether); elem. anal.;95%
[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C34H26Br2IrN4(1+)*Cl(1-)

C34H26Br2IrN4(1+)*Cl(1-)

Conditions
ConditionsYield
In methanol; dichloromethane for 12h; Reflux; Inert atmosphere;95%
In methanol; dichloromethane Reflux;
dimethyl amine
124-40-3

dimethyl amine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C16H22N4
1036649-23-6

C16H22N4

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 50℃; for 20h;95%
triethylamine
121-44-8

triethylamine

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C24H40N4(2+)*F6P(1-)

C24H40N4(2+)*F6P(1-)

Conditions
ConditionsYield
Stage #1: triethylamine; 4,4'-bis(bromomethyl)-2,2'-bipyridine In dichloromethane; water at 20℃; for 24h;
Stage #2: With ammonium hexafluorophosphate In dichloromethane; water
92.1%
1-hexylimidazole
33529-01-0

1-hexylimidazole

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C30H42N6(2+)*2Br(1-)

C30H42N6(2+)*2Br(1-)

Conditions
ConditionsYield
In chloroform92%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C20H22N6(2+)*2Br(1-)

C20H22N6(2+)*2Br(1-)

Conditions
ConditionsYield
In toluene for 12h; Reflux; Inert atmosphere;92%
1‐(naphthalen‐2‐ylmethyl)imidazole
98318-77-5

1‐(naphthalen‐2‐ylmethyl)imidazole

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C40H34N6(2+)*2Br(1-)

C40H34N6(2+)*2Br(1-)

Conditions
ConditionsYield
In acetonitrile Reflux;92%
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

salicylic acid
69-72-7

salicylic acid

[2,2'-bipyridine]-4,4'-diylbis(methylene) bis(2-hydroxybenzoate)

[2,2'-bipyridine]-4,4'-diylbis(methylene) bis(2-hydroxybenzoate)

Conditions
ConditionsYield
Stage #1: salicylic acid With potassium hydrogencarbonate In N,N-dimethyl-formamide at 20℃;
Stage #2: 4,4'-bis(bromomethyl)-2,2'-bipyridine In N,N-dimethyl-formamide at 20℃; for 6h;
91%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

Ammonium iron sulfate

Ammonium iron sulfate

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

{Fe(4,4`-bis(bromomethyl)-2,2`-bipyridine)3}(PF6)2

{Fe(4,4`-bis(bromomethyl)-2,2`-bipyridine)3}(PF6)2

Conditions
ConditionsYield
In methanol Ar; stirred for 1 h;; pptd. from NH4PF6 in H2O; elem. anal.;;90%
(4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II)

(4,4'-di-tert-butyl-2,2'-bipyridine)dimethylplatinum(II)

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)

[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)

Conditions
ConditionsYield
In acetone filtering, washing (ether); elem. anal.;90%
In not given
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4-(4-[4-(1,1-diallyl-but-3-enyl)-phenoxy]-1,1-bis-{3-[4-(1,1-diallyl-but-3-enyl)-phenoxy]-propyl}-butyl)-phenol
224191-95-1

4-(4-[4-(1,1-diallyl-but-3-enyl)-phenoxy]-1,1-bis-{3-[4-(1,1-diallyl-but-3-enyl)-phenoxy]-propyl}-butyl)-phenol

(C5H3NCH2OC6H4C((CH2)3OC6H4C(CH2CHCH2)3)3)2
1144500-85-5

(C5H3NCH2OC6H4C((CH2)3OC6H4C(CH2CHCH2)3)3)2

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 80℃; for 24h;90%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III)

tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III)

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C42H30Br2IrN4(1+)*F6P(1-)

C42H30Br2IrN4(1+)*F6P(1-)

Conditions
ConditionsYield
Stage #1: tetrakis(2-phenylquinoline-C2,N')(μ-dichloro)diiridium(III); 4,4'-bis(bromomethyl)-2,2'-bipyridine In methanol; dichloromethane at 40℃; for 4h;
Stage #2: potassium hexafluorophosphate In methanol; dichloromethane at 20℃;
90%
sodium methylate
124-41-4

sodium methylate

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-Bis(methoxymethyl)-2,2'-bipyridin

4,4'-Bis(methoxymethyl)-2,2'-bipyridin

Conditions
ConditionsYield
In toluene for 12h; Heating;89%
HOC6H4(C((CH2)3OC6H4C((CH2)3Si(CH3)2(C5H4))3)3)(9-)*9Fe(2+)*9C5H5(1-)=HOC6H4C(C3H6OC6H4C(C3H6Si(CH3)2C5H4FeC5H5)3)3

HOC6H4(C((CH2)3OC6H4C((CH2)3Si(CH3)2(C5H4))3)3)(9-)*9Fe(2+)*9C5H5(1-)=HOC6H4C(C3H6OC6H4C(C3H6Si(CH3)2C5H4FeC5H5)3)3

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

(C5H3NCH2OC6H4C((CH2)3OC6H4C((CH2)3Si(CH3)2(C5H4)Fe(C5H5))3)3)2

(C5H3NCH2OC6H4C((CH2)3OC6H4C((CH2)3Si(CH3)2(C5H4)Fe(C5H5))3)3)2

Conditions
ConditionsYield
With potassium carbonate In tetrahydrofuran; acetonitrile treatment of 1 equiv. of 4,4'-bis(bromomethyl)-2,2'-bipy with 2 equiv. of nonaferrocenyl dendrone in the presence of K2CO3 in mixt. of MeCN and THF (v/v 1:1); heating at 80°C for 24 h with stirring; removal of solvent under vac.; extn. with Et2O; drying over Na2SO4; evapn. of solvent; chromy. (silica gel, pentane/diethyl ether 8:2; then diethyl ether); elem. anal.;89%
[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)Pt(CH3)2
155761-57-2

[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)Pt(CH3)2

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

[[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)Pt(Br)(CH3)2]2((CH2C5H3N)2)

[[Pt(Br)(CH3)2(((CH3)3CC5H3N)2)]2((CH2C5H3N)2)Pt(Br)(CH3)2]2((CH2C5H3N)2)

Conditions
ConditionsYield
In acetone; benzene evapn., washing (ether), drying (vac.); elem. anal.;88%
In not given
2,2,3,3,4,4,4-heptafluorobutanol
375-01-9

2,2,3,3,4,4,4-heptafluorobutanol

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis(n-C3F7CH2OH2)-2,2'-bpy
949116-85-2

4,4'-bis(n-C3F7CH2OH2)-2,2'-bpy

Conditions
ConditionsYield
Stage #1: 2,2,3,3,4,4,4-heptafluorobutanol With methanol; sodium methylate at 80℃; for 4h; Inert atmosphere;
Stage #2: 4,4'-bis(bromomethyl)-2,2'-bipyridine In tetrahydrofuran Reflux;
86.2%
Stage #1: 2,2,3,3,4,4,4-heptafluorobutanol With sodium methylate In methanol
Stage #2: 4,4'-bis(bromomethyl)-2,2'-bipyridine
2,2,2-trifluoroethanol
75-89-8

2,2,2-trifluoroethanol

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis(2,2,2-trifluoroethoxymethyl)-2,2'-bipyridine
1289642-74-5

4,4'-bis(2,2,2-trifluoroethoxymethyl)-2,2'-bipyridine

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanol With methanol; sodium methylate at 80℃; for 4h; Inert atmosphere;
Stage #2: 4,4'-bis(bromomethyl)-2,2'-bipyridine In tetrahydrofuran Reflux;
86%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

[iridium(III)(μ-chloro)(2-phenylpyridine)2]2

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

[Ir(ppy)2-bpy-Br]+PF6-

[Ir(ppy)2-bpy-Br]+PF6-

Conditions
ConditionsYield
In methanol; dichloromethane for 24h; Inert atmosphere; Reflux;86%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

pq2Ir(μ-Cl)2Irpq2
632327-37-8, 337526-84-8

pq2Ir(μ-Cl)2Irpq2

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

C42H32Br2IrN4(1+)*F6P(1-)

C42H32Br2IrN4(1+)*F6P(1-)

Conditions
ConditionsYield
In methanol; dichloromethane at 45℃; for 24h; Inert atmosphere;86%
1H,1H,9H-hexadecafluoro-1-nonanol
376-18-1

1H,1H,9H-hexadecafluoro-1-nonanol

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4,4'-bis(HCF2(CF2)7CH2OCH2)-2,2'-bipyridine

4,4'-bis(HCF2(CF2)7CH2OCH2)-2,2'-bipyridine

Conditions
ConditionsYield
With sodium methylate In acetonitrile at 65℃; for 4h;85%
4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

4-triallylmethylphenol
224191-80-4

4-triallylmethylphenol

(C5H3NCH2OC6H4C(CH2CHCH2)3)2
1144500-84-4

(C5H3NCH2OC6H4C(CH2CHCH2)3)2

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 80℃; for 24h;85%
tert-butyl (R)-(+)-(1-(4-hydroxyphenyl)ethyl)carbamate
931093-11-7

tert-butyl (R)-(+)-(1-(4-hydroxyphenyl)ethyl)carbamate

4,4'-bis(bromomethyl)-2,2'-bipyridine
134457-14-0

4,4'-bis(bromomethyl)-2,2'-bipyridine

di-tert-butyl ((1R,1'R)-((([2,2'-bipyridine]-4,4'-diylbis(methylene))bis(oxy))bis(4,1-phenylene))bis(ethane-1,1-diyl))dicarbamate

di-tert-butyl ((1R,1'R)-((([2,2'-bipyridine]-4,4'-diylbis(methylene))bis(oxy))bis(4,1-phenylene))bis(ethane-1,1-diyl))dicarbamate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 65℃; for 20h; Inert atmosphere;85%

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