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Synthetic route

: 10102-43-9
nitrogen(II) oxide

: 1310-65-2
lithium hydroxide

A: 13568-33-7
lithium nitrite

B: 7727-37-9
nitrogen

C: lithium nitrate

D: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
byproducts: H2O; at room temp.;

...Expand

: 10102-43-9
nitrogen(II) oxide

: 1310-65-2
lithium hydroxide

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
In neat (no solvent) byproducts: N2O, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2O and H2O;;
In neat (no solvent) byproducts: N2, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2 and H2O;;
In neat (no solvent) byproducts: N2, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2 and H2O;;
In neat (no solvent) byproducts: N2O, H2O; slowly reaction with gaseous NO, at 280°C and 90 hours, formation of LiNO2, N2O and H2O;;

: 10102-44-0
Nitrogen dioxide

: 1310-65-2
lithium hydroxide

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
With NO In water reaction with nitrous gases, formation of LiNO2;;

: 7782-77-6
cis-nitrous acid

: 1310-65-2
lithium hydroxide

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
In water neutralization of aq. LiOH with aq. HNO2;;

: lithium nitrate

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
byproducts: O2; thermal decompn.;
In neat (no solvent) byproducts: O2; on heating LiNO3 above the melting point, decomposition in LiNO2 and O2;;
In neat (no solvent) byproducts: O2; thermal dissociation of LiNO3 above 420°C;;

: lithium nitrate

A: 13568-33-7
lithium nitrite

B: 80937-33-3
oxygen

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; temp. 580-620 °C;

: lithium nitrate

: 7440-22-4
silver

A: 13568-33-7
lithium nitrite

B: silver(I) chloride

Conditions

Conditions	Yield
With KCl In melt 1 h, 400°C;	A n/a B 0%

...Expand

: 554-13-2
lithium carbonate

A: 13568-33-7
lithium nitrite

B: lithium nitrate

Conditions

Conditions	Yield
With nitrous gases In not given reaction with nitrous gases, formation of nitrite, no formation of nitrate;;	A n/a B 0%

: indium chloride

: lithium nitrate

: 7732-18-5
water

A: 13568-33-7
lithium nitrite

B: indium(III) hydroxide

C: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;

...Expand

: 13453-77-5
lithium nitrite monohydrate

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O; dehydration on heating at 160°C;;
In neat (no solvent) byproducts: H2O; dehydration in vac. over P2O5;;
In neat (no solvent) byproducts: H2O; dehydration in vac.;;

: lithium nitrate trihydrate

A: 13568-33-7
lithium nitrite

B: 1310-65-2
lithium hydroxide

Conditions

Conditions	Yield
With hydrogen In neat (no solvent) byproducts: H2O, NH3; reduction of LiNO3*3H2O with H2 by silent electrical discharge;;
With hydrogen In not given byproducts: NH3, NO2; reduction with atomic hydrogen leds to LiNO2, LiOH, NH3 and NO2;;
With H2
With atomic hydrogen

: lithium sulfate

: 7758-09-0
potassium nitrite

: 13568-33-7
lithium nitrite

Conditions

Conditions	Yield
In water equimolar amts.; filtration, evapn., extn. into EtOH, evapn., heating in vac. up to 110°C (16 h); elem. anal.;

: 13568-33-7
lithium nitrite

: [VO((O2CCH2)2NCH(CH3)C5H4N)(H2O)]*2H2O

: Li(1+)*[V(O)2((O2CCH2)2NCH(CH3)C5H4N)](1-)*2CH3OH*5H2O=Li[V(O)2((O2CCH2)2NCH(CH3)C5H4N)]*2CH3OH*5H2O

Conditions

Conditions	Yield
With methanol In methanol suspn. of V complex in methanol contg. LiNO2 stirred for 3 h at room temp.; mixed with Et2O, left in refrigerator overnight; elem. anal.;	89%

: 13568-33-7
lithium nitrite

: trans(*)-{Pt(en)(NH3)(ClNO2)(*)}(NO3)2

: trans(*)-{Pt(NOen-H)(NH3)(ClNO2)(*)}NO3

Conditions

Conditions	Yield
In water byproducts: N2; heating (H2O bath, 15-20 min); slow cooling and evapn. (air), filtn., washing (EtOHand Et2O), recrystn. (H2O); elem. anal.;	76%

: 13568-33-7
lithium nitrite

: 32547-71-0
5-amino-3-benzylthio-4-phenoxybenzoic acid

A: 3-benzyl thio-5-chlorosulfonyl-4-phenoxybenzoic acid

B: 52399-13-0
3-Benzylthio-5-chlorosulfonyl-4-phenoxybenzoic acid

Conditions

Conditions	Yield
With hydrogenchloride; acetic acid In lithium hydroxide

...Expand

: 13568-33-7
lithium nitrite

: 7758-09-0
potassium nitrite

: 10361-79-2
praseodymium(III) chloride

: praseodymium oxide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl(1-), NO2, NO; PrCl3 was added to LiNO2-KNO2 eutectic at 120°C, 1 h at 160°C; then heating to 245°C;; ppt. was washed and dried ; elem. anal.;

...Expand

: trisodium hexanitrocobaltate(III)

: 13568-33-7
lithium nitrite

: 7758-09-0
potassium nitrite

: cobalt(II,III) oxide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: NO, NO2; in (Na/K)NO2 eutectic melt, 230°C, 5 min (pptn.); elem. anal.;

...Expand

: 13568-33-7
lithium nitrite

: 7758-09-0
potassium nitrite

: hexammine cobalt(III) chloride

: cobalt(II,III) oxide

Conditions

Conditions	Yield
In neat (no solvent) byproducts: NO, NO2; in (Na/K)NO2 eutectic melt, 230°C (pptn.); powder X-ray diffraction;

...Expand

: 13568-33-7
lithium nitrite

: hydroxyammonium sulfate

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In not given Kinetics; byproducts: H2O;
In not given Kinetics; byproducts: H2O;

: 13568-33-7
lithium nitrite

: Hg(I)-nitrate

: 7732-18-5
water

A: Li(1+)*Hg(2+)*3NO2(1-)*H2O=LiNO2*Hg(NO2)2*H2O

B: 4Li(1+)*Hg(2+)*6NO2(1-)*4H2O=4LiNO2*Hg(NO2)2*4H2O

Conditions

Conditions	Yield
In water prepn. a paste from Hg(I) nitrite, LiNO2 and H2O; addn. more H2O, filtration, concentrating of the filtrate over H2SO4 in vac.; from the mother liquor;
In water prepn. a paste from Hg(I) nitrite, LiNO2 and H2O; addn. more water, filtration, concentrating of the filtrate over H2SO4 in vac.;
In water prepn. a paste from Hg(I) nitrite, LiNO2 and H2O; addn. more H2O, filtration, concentrating of the filtrate over H2SO4 in vac.; from the mother liquor;
In water prepn. a paste from Hg(I) nitrite, LiNO2 and H2O; addn. more water, filtration, concentrating of the filtrate over H2SO4 in vac.;

...Expand

: bismuth(III) nitrate

: 13568-33-7
lithium nitrite

: ammonium nitrate

: lithium ammonium bismuth nitrite

Conditions

Conditions	Yield
In water 50 % LiNO2 soln., addn. of NH4NO3 soln. to mixt. of educts, 0°C; drying (between filter papers);
In water 50 % LiNO2 soln., addn. of NH4NO3 soln. to mixt. of educts, 0°C; drying (between filter papers);

...Expand

: 13568-33-7
lithium nitrite

: 13465-08-2
hydroxylamine nitrate

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In not given Kinetics; byproducts: water;
In not given Kinetics; byproducts: water;

: 13568-33-7
lithium nitrite

: 5470-11-1
hydroxylamine hydrochloride

: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In not given Kinetics; byproducts: H2O;
In not given Kinetics; byproducts: H2O;

: 13568-33-7
lithium nitrite

: lead nitrite

: lithium lead(II) nitrite

Conditions

Conditions	Yield
In not given equimolar amts.;
In not given equimolar amts.;

: 13568-33-7
lithium nitrite

: 10102-44-0
Nitrogen dioxide

Conditions

Conditions	Yield
With methanol In solid matrix Kinetics; other Radiation; 77°C; solvent - CH3OH; γ-irradn.; EPR;

: 13568-33-7
lithium nitrite

: 7782-77-6
cis-nitrous acid

Conditions

Conditions	Yield
With silicic acid In melt molten LiNO2 reacts with the silicic acid of the glass, formation of HNO2;;
With silicic acid

: 13568-33-7
lithium nitrite

: 7758-09-0
potassium nitrite

: lithium potassium bismuth(III) nitrite

Conditions

Conditions	Yield
With nitric acidic Bi(NO3)3-soln. In not given 10 ml of nitric acidic Bi(NO3)3 soln.(obtained by dissoln. of 25 g Bi2O3 in 35 ml concd. HNO3 + 10 ml H2O and and filling up with H2O to 100 ml) mixed with 25 ml of 20% LiNO3 soln. and 50 ml 50%KNO2-soln.; ppt. sucked after 1 h, pressed between filter paper;

: 13568-33-7
lithium nitrite

: 7758-09-0
potassium nitrite

: 7646-79-9
cobalt(II) chloride

: potassium hexakis(nitrito)cobaltate(III)

Conditions

Conditions	Yield
In neat (no solvent) byproducts: KCl, K2O, NO; in (Li/K)NO2 eutectic melt, 120°C (pptn.);

...Expand

: caesium nitrate

: 13568-33-7
lithium nitrite

: 1304-76-3
bismuth(III) oxide

: caesium lithium nitrobismuthate(III)

Conditions

Conditions	Yield
With nitric acid In water a nitric acid soln. of Bi(NO3)3 (prepared by dissolution of Bi2O3 in concd. HNO3 under heating, then dilution with water) and an aq. soln. of CsNO3 were added to a soln. of LiNO2 (15%);; LiCs2(Bi(NO2)6) crystals were sucked off after 1 hour and pressed between filter paper;;
With HNO3 In water a nitric acid soln. of Bi(NO3)3 (prepared by dissolution of Bi2O3 in concd. HNO3 under heating, then dilution with water) and an aq. soln. of CsNO3 were added to a soln. of LiNO2 (15%);; LiCs2(Bi(NO2)6) crystals were sucked off after 1 hour and pressed between filter paper;;

...Expand

: 13568-33-7
lithium nitrite

: 13826-63-6
thallium nitrite

: 1304-76-3
bismuth(III) oxide

: lithium thallium(I) bismuth(III) nitrite

Conditions

Conditions	Yield
With HNO3 In water Bi2O3 is dissolved in aq. HNO3; the soln. is mixed with TlNO2 soln. and 50% LiNO2 soln. at 0 °C;;

...Expand

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Triumph International Development Limilted

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