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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New CAS 1544-53-2 with best price

Cas:1544-53-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:1 Gram

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Qingdao Beluga Import and Export Co., LTD

2,2,2-TRIFLUOROETHANETHIOLCAS:1544-53-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

2,2,2-TRIFLUOROETHANETHIOLCAS:1544-53-2

Cas:1544-53-2

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0 Metric Ton

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Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best Offer2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:1 Gram

Negotiable

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:1 Kilogram

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Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

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Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Manufacturers

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Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Trading Company

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Antimex Chemical Limied

factory?direct?sale Application:healing drugs

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

2,2,2-Trifluoroethanethiol Application:2,2,2-Trifluoroethanethiol

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Other

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DB BIOTECH CO., LTD

best seller Application:API

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Trading Company

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,2,2-TRIFLUOROETHANETHIOL

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

Ethanethiol,2,2,2-trifluoro-

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

2,2,2-Trifluoroethanethiol

Cas:1544-53-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

2,2,2-trifluoroethylthiomethylbenzene
77745-03-0

2,2,2-trifluoroethylthiomethylbenzene

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

Conditions
ConditionsYield
With phosphorus pentoxide at 150 - 180℃;95%
With methanesulfonic acid at 180℃; for 0.75h;
S-(2,2,2-trifluoroethyl) ethanethioate
14897-48-4

S-(2,2,2-trifluoroethyl) ethanethioate

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

Conditions
ConditionsYield
With sodium; ethylene glycol for 2h; Inert atmosphere; Reflux;72%
With benzylamine at 150℃;58%
2,2,2-Trifluoroacetaldehyde
75-90-1

2,2,2-Trifluoroacetaldehyde

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

Conditions
ConditionsYield
With hydrogen sulfide at 200℃;
S-(2,2,2-trifluoroethyl) ethanethioate
14897-48-4

S-(2,2,2-trifluoroethyl) ethanethioate

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
With water at 25℃; Equilibrium constant;
Pyridine 1-oxide; compound with 2,2,2-trifluoro-ethanethiol

Pyridine 1-oxide; compound with 2,2,2-trifluoro-ethanethiol

A

pyridine N-oxide
694-59-7

pyridine N-oxide

B

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

Conditions
ConditionsYield
In cyclohexane at 23.3℃; Equilibrium constant;
3,4-Dinitro-phenol; compound with 2,2,2-trifluoro-ethanethiol

3,4-Dinitro-phenol; compound with 2,2,2-trifluoro-ethanethiol

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

3,4-dinitophenol
577-71-9

3,4-dinitophenol

Conditions
ConditionsYield
In cyclohexane at 23.3℃; Equilibrium constant;
2-(morpholin-4-yl)ethanol
622-40-2

2-(morpholin-4-yl)ethanol

2-(6-Methoxy-naphthalen-2-yl)-thiopropionic acid S-(2,2,2-trifluoro-ethyl) ester

2-(6-Methoxy-naphthalen-2-yl)-thiopropionic acid S-(2,2,2-trifluoro-ethyl) ester

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

(2S)-2-(6-methoxy(2-naphthyl))propanoic acid
22204-53-1

(2S)-2-(6-methoxy(2-naphthyl))propanoic acid

C

(R)-2-(6-methoxy-2-naphthyl)propionic acid
23979-41-1

(R)-2-(6-methoxy-2-naphthyl)propionic acid

D

(S)-2-(6-Methoxy-naphthalen-2-yl)-propionic acid 2-morpholin-4-yl-ethyl ester

(S)-2-(6-Methoxy-naphthalen-2-yl)-propionic acid 2-morpholin-4-yl-ethyl ester

E

(R)-2-(6-Methoxy-naphthalen-2-yl)-propionic acid 2-morpholin-4-yl-ethyl ester

(R)-2-(6-Methoxy-naphthalen-2-yl)-propionic acid 2-morpholin-4-yl-ethyl ester

Conditions
ConditionsYield
With Lipase MY In 2,2,4-trimethylpentane at 37℃; for 105h; Product distribution; Mechanism; other naproxen and ibuprofen thioesters; also Candida rugosa lipase as catalyst; var. solvents and time;
2,2,2-Trifluoro-ethanethiol; compound with iodine

2,2,2-Trifluoro-ethanethiol; compound with iodine

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

I2

I2

Conditions
ConditionsYield
In cyclohexane at 25℃; Equilibrium constant;
2,2,2-Trifluoroethyl p-toluenesulfonate
433-06-7

2,2,2-Trifluoroethyl p-toluenesulfonate

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

bis(2,2,2-trifluoroethyl) disulfide
674-63-5

bis(2,2,2-trifluoroethyl) disulfide

C

Bis-(2,2,2-trifluorethyl)sulfid
674-62-4

Bis-(2,2,2-trifluorethyl)sulfid

Conditions
ConditionsYield
With sodium hydrogen sulfide In 1-methyl-pyrrolidin-2-one at 80℃; under 966.916 Torr; for 3h;
With sodium hydrogen sulfide In 1-methyl-pyrrolidin-2-one at 90℃; for 3h; Reagent/catalyst; Solvent; Temperature; Pressure;
1,1,1-trifluoro-2-chloroethane
75-88-7

1,1,1-trifluoro-2-chloroethane

A

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

B

bis(2,2,2-trifluoroethyl) disulfide
674-63-5

bis(2,2,2-trifluoroethyl) disulfide

C

Bis-(2,2,2-trifluorethyl)sulfid
674-62-4

Bis-(2,2,2-trifluorethyl)sulfid

Conditions
ConditionsYield
With sodium hydrogen sulfide In 1-methyl-pyrrolidin-2-one at 90℃; under 1328.93 Torr; for 3h;
With sodium hydrogen sulfide In 1-methyl-pyrrolidin-2-one at 90℃; under 1328.93 Torr; for 3h; Solvent; Reagent/catalyst; Temperature;
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

heptakis-(6-chloro-6-deoxy)-β-cyclodextrin
155953-27-8

heptakis-(6-chloro-6-deoxy)-β-cyclodextrin

heptakis-6-deoxy-6-((2,2,2-trifluoroethyl)thio)-β-cyclodextrin
1237753-74-0

heptakis-6-deoxy-6-((2,2,2-trifluoroethyl)thio)-β-cyclodextrin

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 75℃; for 120h;100%
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h;
Stage #2: heptakis-(6-chloro-6-deoxy)-β-cyclodextrin In N,N-dimethyl-formamide; mineral oil at 70℃;
88%
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h;
Stage #2: heptakis-(6-chloro-6-deoxy)-β-cyclodextrin In N,N-dimethyl-formamide; mineral oil at 70℃; for 120h;
88%
2-fluoro-5-(methylsulfonyl)benzoic acid
247569-56-8

2-fluoro-5-(methylsulfonyl)benzoic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

5-Methanesulfonyl-2-(2,2,2-trifluoro-ethylsulfanyl)-benzoic acid

5-Methanesulfonyl-2-(2,2,2-trifluoro-ethylsulfanyl)-benzoic acid

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 90℃; for 0.5h;99%
With caesium carbonate In N,N-dimethyl-formamide at 90℃; for 0.5h;99%
With caesium carbonate In N,N-dimethyl acetamide at 90℃; for 0.5h;99%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

2-Bromo-4'-methoxyacetophenone
2632-13-5

2-Bromo-4'-methoxyacetophenone

C11H11F3O2S
948837-90-9

C11H11F3O2S

Conditions
ConditionsYield
With potassium carbonate In ethanol at 20℃; for 20h;99%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

3-phenyl-5-chloroisoxazole
3356-89-6

3-phenyl-5-chloroisoxazole

3-phenyl-5-[(2,2,2-trifluoroethyl)sulfanyl]isoxazole

3-phenyl-5-[(2,2,2-trifluoroethyl)sulfanyl]isoxazole

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 36h;99%
N-(5-bromopentyl)phthalimide
954-81-4

N-(5-bromopentyl)phthalimide

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

5-N-phthalimido-1-pentyl 2’,2’,2’-trifluoroethyl sulfide
1584658-29-6

5-N-phthalimido-1-pentyl 2’,2’,2’-trifluoroethyl sulfide

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium methylate In methanol at 20℃; for 15h;
Stage #2: N-(5-bromopentyl)phthalimide In methanol at 20℃; for 48h;
98%
Stage #1: 2,2,2-trifluoroethanethiol With sodium methylate In methanol at 0 - 20℃; for 0.25h; Inert atmosphere;
Stage #2: N-(5-bromopentyl)phthalimide In 1,2-dimethoxyethane at 0 - 20℃; Inert atmosphere;
89%
4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-2,5-difluorobenzonitrile
958031-87-3

4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-2,5-difluorobenzonitrile

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-5-fluoro-2-[(2,2,2-trifluoroethyl)thio]benzonitrile
958031-88-4

4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-5-fluoro-2-[(2,2,2-trifluoroethyl)thio]benzonitrile

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 0 - 20℃; for 2h;97%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

hexakis(2,3,6-tri-O-allyl)-α-cyclodextrin

hexakis(2,3,6-tri-O-allyl)-α-cyclodextrin

hexakis{2,3,6-tri-O-[(2,2,2-trifluoroethyl)thio]propyl}-α-cyclodextrin

hexakis{2,3,6-tri-O-[(2,2,2-trifluoroethyl)thio]propyl}-α-cyclodextrin

Conditions
ConditionsYield
With 2,2-dimethoxy-2-phenylacetophenone In N,N-dimethyl-formamide UV-irradiation;95%
1,3-dithiane-2-carboxylic acid
20461-89-6

1,3-dithiane-2-carboxylic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

2,2,2-trifluoroethyl 2-[(1,3-dithian)-2-yl]-ethanthioate

2,2,2-trifluoroethyl 2-[(1,3-dithian)-2-yl]-ethanthioate

Conditions
ConditionsYield
Stage #1: 1,3-dithiane-2-carboxylic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃;
95%
Stage #1: 1,3-dithiane-2-carboxylic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃;
95%
para-dinitrobenzene
100-25-4

para-dinitrobenzene

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

(4-nitrophenyl)(2,2,2-trifluoroethyl)sulfane

(4-nitrophenyl)(2,2,2-trifluoroethyl)sulfane

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 20℃; for 2h;92%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-tolyl iodide
624-31-7

4-tolyl iodide

(2,2,2-trifluoroethyl) (4-methylphenyl) sulfide
62158-92-3

(2,2,2-trifluoroethyl) (4-methylphenyl) sulfide

Conditions
ConditionsYield
With pyridine; (1,2-dimethoxyethane)dichloronickel(II); Ir[dF(CF3)ppy]2(dtbbpy)PF6; 4,4′-di-(tert-butyl)-2,2′-bipyridyl In acetonitrile at 23 - 25℃; for 24h; Irradiation; chemoselective reaction;92%
(triethylphosphine)chlorogold(I)
15529-90-5

(triethylphosphine)chlorogold(I)

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

(2,2,2-trifluoroethanethiolato)(triethylphosphine) gold(I)

(2,2,2-trifluoroethanethiolato)(triethylphosphine) gold(I)

Conditions
ConditionsYield
With sodium methylate In methanol at 20℃;92%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

methyl 2-(2,2,2-trifluoroethylthio)acetate
675-81-0

methyl 2-(2,2,2-trifluoroethylthio)acetate

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.45h; Inert atmosphere;
Stage #2: bromoacetic acid methyl ester In N,N-dimethyl-formamide; mineral oil at 0 - 20℃;
91%
4-trifluoromethyl-nicotinic acid 3-bromopropylamide
750592-58-6

4-trifluoromethyl-nicotinic acid 3-bromopropylamide

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-trifluoromethyl-nicotinic acid 3-bromopropylamide

4-trifluoromethyl-nicotinic acid 3-bromopropylamide

Conditions
ConditionsYield
With sodium methylate In methanol at 20 - 50℃; for 6h;90.1%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

(7-methylimidazo<1,2-a>pyridin-3-yl)methanol
29096-61-5

(7-methylimidazo<1,2-a>pyridin-3-yl)methanol

7-methyl-3-(2,2,2-trifluoro-ethylsulfanylmethyl)-imidazo[1,2-a]pyridine

7-methyl-3-(2,2,2-trifluoro-ethylsulfanylmethyl)-imidazo[1,2-a]pyridine

Conditions
ConditionsYield
With acetic acid at 80℃; for 2h;90%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

(tetramethylammonium)2[Fe4S4(methanethiolato)4]

(tetramethylammonium)2[Fe4S4(methanethiolato)4]

(tetramethylammonium)2[Fe4S4(2,2,2-trifluoroethanethiolato)4]

(tetramethylammonium)2[Fe4S4(2,2,2-trifluoroethanethiolato)4]

Conditions
ConditionsYield
In tetrahydrofuran for 16h; Schlenk technique; Glovebox; Inert atmosphere; Reflux;89%
N'-(2,5-dichloro-4-nitrophenyl)-N,N-diethyl-2,2,2-trifluoroethaneimideamide

N'-(2,5-dichloro-4-nitrophenyl)-N,N-diethyl-2,2,2-trifluoroethaneimideamide

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

N'-{2-chloro-4-nitro-5-[(2,2,2-trifluoroethyl)thio]phenyl}-N,N-diethyl-2,2,2-trifluoroethaneimideamide

N'-{2-chloro-4-nitro-5-[(2,2,2-trifluoroethyl)thio]phenyl}-N,N-diethyl-2,2,2-trifluoroethaneimideamide

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 15h;87%
3-chloropivalic acid
13511-38-1

3-chloropivalic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

2,2-dimethyl-3-((2,2,2-trifluoroethyl)thio)propanoic acid

2,2-dimethyl-3-((2,2,2-trifluoroethyl)thio)propanoic acid

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃;
Stage #2: 3-chloropivalic acid In N,N-dimethyl-formamide; mineral oil at 20 - 24℃;
87%
2-(4-bromobutyl)isoindoline-1,3-dione
5394-18-3

2-(4-bromobutyl)isoindoline-1,3-dione

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-N-phthalimido-1-butyl 2’,2’,2’-trifluoroethyl sulfide
1584658-28-5

4-N-phthalimido-1-butyl 2’,2’,2’-trifluoroethyl sulfide

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium methylate In methanol at 0℃; for 0.25h; Inert atmosphere;
Stage #2: 2-(4-bromobutyl)isoindoline-1,3-dione In methanol at 0 - 20℃; Inert atmosphere;
86%
Stage #1: 2,2,2-trifluoroethanethiol With sodium methylate In methanol at 0 - 20℃; for 0.25h; Inert atmosphere;
Stage #2: 2-(4-bromobutyl)isoindoline-1,3-dione In 1,2-dimethoxyethane at 0 - 20℃; Inert atmosphere;
86%
2-bromohexanoic acid
616-05-7

2-bromohexanoic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

S-2,2,2-trifluoroethyl 2-bromohexanethioate
1309379-79-0

S-2,2,2-trifluoroethyl 2-bromohexanethioate

Conditions
ConditionsYield
Stage #1: 2-bromohexanoic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃; Inert atmosphere;
85%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

octakis(6-chloro-6-deoxy)-γ-cyclodextrin
173094-60-5

octakis(6-chloro-6-deoxy)-γ-cyclodextrin

octakis[6-deoxy-6-(2,2,2-trifluoroethyl)thio]-γ-cyclodextrin
1237753-77-3

octakis[6-deoxy-6-(2,2,2-trifluoroethyl)thio]-γ-cyclodextrin

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h;
Stage #2: octakis(6-chloro-6-deoxy)-γ-cyclodextrin In N,N-dimethyl-formamide; mineral oil at 70℃; for 120h;
84%
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h;
Stage #2: octakis(6-chloro-6-deoxy)-γ-cyclodextrin In N,N-dimethyl-formamide; mineral oil at 70℃;
82%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-Cyanophenacyl bromide
20099-89-2

4-Cyanophenacyl bromide

4-(2,2,2-trifluoroethylthiomethylcarbonyl)-benzonitrile
928650-41-3

4-(2,2,2-trifluoroethylthiomethylcarbonyl)-benzonitrile

Conditions
ConditionsYield
Stage #1: 2,2,2-trifluoroethanethiol With sodium hydride In tetrahydrofuran at 0℃; for 0.25h;
Stage #2: 4-Cyanophenacyl bromide In tetrahydrofuran at 20℃;
84%
(3,4-Dimethoxyphenyl)acetic acid
93-40-3

(3,4-Dimethoxyphenyl)acetic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

S-2,2,2-trifluoroethyl 3,4-dimethoxyphenylthioacetate
1309379-76-7

S-2,2,2-trifluoroethyl 3,4-dimethoxyphenylthioacetate

Conditions
ConditionsYield
Stage #1: (3,4-Dimethoxyphenyl)acetic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃; Inert atmosphere;
84%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

3-chloro-N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylpropanamide
1374315-14-6

3-chloro-N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethylpropanamide

N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((2,2,2-trifluoroethyl)thio)propanamide
1393662-58-2

N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-N-ethyl-3-((2,2,2-trifluoroethyl)thio)propanamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; sodium iodide In tetrahydrofuran at 50℃;83%
With N-ethyl-N,N-diisopropylamine; sodium iodide In tetrahydrofuran at 50℃;83%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

copper(l) chloride

copper(l) chloride

[(1,10-phenanthroline)Cu(μ-SCH2CF3)]2

[(1,10-phenanthroline)Cu(μ-SCH2CF3)]2

Conditions
ConditionsYield
Stage #1: copper(l) chloride With sodium t-butanolate In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1,10-Phenanthroline In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere;
Stage #3: 2,2,2-trifluoroethanethiol In tetrahydrofuran at 20℃; for 0.333333h; Inert atmosphere;
83%
bis(cyclopentadienyl)tin(II)
26078-96-6

bis(cyclopentadienyl)tin(II)

disulfiram
97-77-8

disulfiram

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

((C2H5)2NCS2)2Sn(CF3CH2S)2

((C2H5)2NCS2)2Sn(CF3CH2S)2

Conditions
ConditionsYield
In diethyl ether CF3CH2SH was added to (C5H5)2Sn in Et2O, stirred at room temp. for 1 h, ligand was added, refluxed for 5 min, stirred at room temp. for 1 h; solvent was removed in vacuo, recrystd. from THF at -30°C;82%
tetrakis(dimethylamido)titanium(IV)

tetrakis(dimethylamido)titanium(IV)

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

2(CH3)2NH2(1+)*Ti(SCH2CF3)6(2-)=((CH3)2NH2)2Ti(SCH2CF3)6

2(CH3)2NH2(1+)*Ti(SCH2CF3)6(2-)=((CH3)2NH2)2Ti(SCH2CF3)6

Conditions
ConditionsYield
In hexane N2 atm.; thiol was added to a soln. of Ti-compound in hexane, stirred for 3 h; ppt. was filtered, ppt. was washed with hexanes and dried in vac.; elem.anal.;82%
2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

4-bromo-6-fluorobenzonitrile
105942-08-3

4-bromo-6-fluorobenzonitrile

4-bromo-2-[(2,2,2-trifluoroethyl)sulphanyl]benzonitrile

4-bromo-2-[(2,2,2-trifluoroethyl)sulphanyl]benzonitrile

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃;82%
With sodium hydride In N,N-dimethyl acetamide; mineral oil at 0 - 20℃;82%
With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃;82%
2-(2,4-dichloro-5-fluorophenyl)-1H-isoindol-1,3(2H)-dione
958031-89-5

2-(2,4-dichloro-5-fluorophenyl)-1H-isoindol-1,3(2H)-dione

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

2-{2,4-dichloro-5-[(2,2,2-trifluoroethyl)thio]phenyl}-1H-isoindol-1,3(2H)-dione
958031-90-8

2-{2,4-dichloro-5-[(2,2,2-trifluoroethyl)thio]phenyl}-1H-isoindol-1,3(2H)-dione

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 0 - 20℃; for 12h;80%
phenylacetic acid
103-82-2

phenylacetic acid

2,2,2-trifluoroethanethiol
1544-53-2

2,2,2-trifluoroethanethiol

S-2,2,2-trifluoroethyl phenylthioacetate
1041425-65-3

S-2,2,2-trifluoroethyl phenylthioacetate

Conditions
ConditionsYield
Stage #1: phenylacetic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃; Inert atmosphere;
80%
Stage #1: phenylacetic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.666667h;
Stage #2: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃;
Stage #1: phenylacetic acid With benzotriazol-1-ol In dichloromethane at 0℃; for 0.166667h;
Stage #2: With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.5h;
Stage #3: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃;
Stage #1: phenylacetic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 0℃; for 0.666667h; Inert atmosphere;
Stage #2: 2,2,2-trifluoroethanethiol In dichloromethane at 0 - 20℃; Inert atmosphere;

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