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Cas:18649-64-4
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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Cas:18649-64-4
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:18649-64-4
Min.Order:1 Metric Ton
FOB Price: $7.0 / 8.0
Type:Trading Company
inquiryR & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
Cas:18649-64-4
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white to yellow crystal powder Storage:Room temperature with sealed well Package:according to the clients requirement Applicatio
Supply top quality products with a reasonable price Application:api
3-ETHYNYL-2-HYDROXY-PHENOLAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:18649-64-4
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryGood Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen
home-produced Application:medicine
Cas:18649-64-4
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP
Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right
Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom
Furan,2-ethynyl-Appearance:Off white to slight yellow solid Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courier like
Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen
(furan-2-ylethynyl)-trimethylsilane
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium carbonate In methanol at 20℃; for 18h; Cooling with ice; Inert atmosphere; | 98.9% |
With potassium carbonate In methanol at 20℃; for 18h; Inert atmosphere; |
2,2-dibromovinyl-2-furan
2-ethynylfuran
Conditions | Yield |
---|---|
Stage #1: 2,2-dibromovinyl-2-furan With methyllithium In diethyl ether at -78 - 20℃; Stage #2: With water; ammonium chloride In diethyl ether | 47% |
With methyllithium; hydrogen cation 1.) ether, a.) -78 deg C, 1 h; b.) up to RT; c.) RT, 1 h; 2.) ether; Yield given. Multistep reaction; | |
With n-butyllithium In hexane at -78 - 20℃; for 5h; |
α-(2-furoyl)-α-(ethoxycarbonyl)methylenetriphenylphosphorane
2-ethynylfuran
Conditions | Yield |
---|---|
at 750℃; under 0.1 - 1 Torr; | 40% |
(furan-2-yl)ethylene
2-ethynylfuran
Conditions | Yield |
---|---|
With diethyl ether; bromine at -20℃; Behandeln des Reaktionsprodukts mit aethanol. Kalilauge; |
3-(fur-2-yl)crotonic acid
2-ethynylfuran
Conditions | Yield |
---|---|
With bromine Erwaermen der erhaltenen 2,3-Dibrom-3-<2>furyl-propionsaeure mit wss. Alkalilauge; |
furfural
dimethyl diazomethylphosphonate
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium tert-butylate 1.) THF, -78 deg C, 5 min, 2.) 8 h; Yield given. Multistep reaction; |
4-Furan-2-yl-2-methyl-but-3-yn-2-ol
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium hydroxide In paraffin under 1 Torr; for 0.5h; Heating; Yield given; |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); zinc dibromide In tetrahydrofuran at 22 - 23℃; for 1h; | 92 % Chromat. |
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium hydroxide |
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium hydroxide |
2-furancarbonyl chloride
2-ethynylfuran
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 82 percent / Et3N / toluene / 3 h / Ambient temperature 2: 40 percent / 750 °C / 0.1 - 1 Torr View Scheme |
furfural
2-ethynylfuran
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1.) triphenylphosphine (PPh3), Zn dust / 1.) CH2Cl2, RT, 38 h; 2.) CH2Cl2, a.) 0 deg C; b.) RT, 6 h 2: 1.) 2.3M methyllithium, 2.) H(1+) / 1.) ether, a.) -78 deg C, 1 h; b.) up to RT; c.) RT, 1 h; 2.) ether View Scheme | |
Multi-step reaction with 2 steps 1.1: triphenylphosphine; zinc / dichloromethane / 24 h / 20 °C / Inert atmosphere 1.2: 18 h / 20 °C / Inert atmosphere 2.1: tert.-butyl lithium / diethyl ether; pentane / 1 h / -78 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1.1: triphenylphosphine; zinc / dichloromethane / 41 h / 20 °C 1.2: 6 h / 20 °C 2.1: methyllithium / diethyl ether / -78 - 20 °C View Scheme |
Conditions | Yield |
---|---|
With caesium carbonate In ethanol at 0℃; |
2-(2-bromovinyl)furan
A
2-ethynylfuran
B
(E)-2-(2-bromoethenyl)furan
Conditions | Yield |
---|---|
With sodium hydroxide In isopropyl alcohol for 1.5h; Reflux; | A n/a B 2.51 g |
Conditions | Yield |
---|---|
With piperidine; (1R,2R)-3-(tert-butyldimethylsilyloxy)-2-(N-pyrrolidinyl)-1-nitrophenyl-1-propanol; zinc(II) tosylate In n-heptane; benzene at 25℃; Reflux; | 95% |
Conditions | Yield |
---|---|
With copper(l) iodide; 1,1,1,3',3',3'-hexafluoro-propanol at 25 - 60℃; for 14h; Molecular sieve; regioselective reaction; | 93% |
2-ethynylfuran
N-tosyl-2-benzylaziridine
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran With sulfur; copper diacetate; sodium L-ascorbate In water; tert-butyl alcohol at 25℃; for 0.5h; Stage #2: N-tosyl-2-benzylaziridine In water; tert-butyl alcohol at 80℃; for 22h; regioselective reaction; | 92% |
2-ethynylfuran
1,4-di(furan-2-yl)buta-1,3-diyne
Conditions | Yield |
---|---|
With triethylamine; chloroacetone; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene Ambient temperature; | 90% |
With 1,10-Phenanthroline; tetrabutylammonium dichloroaurate(I); [bis(acetoxy)iodo]benzene In acetonitrile at 50℃; | 90% |
With oxygen; copper(l) chloride In pyridine at 20 - 40℃; | |
With N,N,N,N,-tetramethylethylenediamine; oxygen; copper(l) chloride In acetone |
Conditions | Yield |
---|---|
With copper(l) iodide; triethylamine at 50℃; for 6h; Inert atmosphere; Schlenk technique; | 90% |
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran; carbon dioxide With ethyl bromide; caesium carbonate; silver(l) oxide In N,N-dimethyl-formamide at 50℃; for 12h; Schlenk technique; Stage #2: pyridine-2-acetonitrile In N,N-dimethyl-formamide at 100℃; for 4h; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran With N-ethyl-N,N-diisopropylamine; silver(I) iodide In N,N-dimethyl-formamide at 25℃; for 0.5h; Schlenk technique; Molecular sieve; Inert atmosphere; Stage #2: carbon disulfide; N-tosyl-2-benzylaziridine In N,N-dimethyl-formamide at 70℃; for 16h; Schlenk technique; Molecular sieve; Inert atmosphere; | 90% |
Conditions | Yield |
---|---|
With copper(l) iodide at 20℃; for 0.5h; | 90% |
Conditions | Yield |
---|---|
With copper(l) iodide; sodium azide at 20℃; for 0.5h; | 90% |
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran; diisopropyl-carbodiimide With copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene; tetra-n-butylphosphonium acetate In acetonitrile at 25℃; for 0.5h; Molecular sieve; Inert atmosphere; Stage #2: malononitrile In acetonitrile at 80℃; for 16h; Inert atmosphere; Molecular sieve; | 89% |
2-ethynylfuran
dimethyl acetylenedicarboxylate
diisopropyl-carbodiimide
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran; diisopropyl-carbodiimide With copper(l) iodide; tetra-n-butylphosphonium acetate In tetrahydrofuran at 20℃; for 1h; Schlenk technique; Inert atmosphere; Stage #2: dimethyl acetylenedicarboxylate In tetrahydrofuran at 25℃; for 16h; Schlenk technique; Inert atmosphere; | 89% |
2-ethynylfuran
2-benzenesulfonylamino-3-iodo-5-methylthiopyridine
Conditions | Yield |
---|---|
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In 1,4-dioxane at 60℃; for 1h; | 85% |
Conditions | Yield |
---|---|
Stage #1: 2-ethynylfuran; Phenyl glycidyl ether With silver carbonate In 1,4-dioxane at 25℃; for 0.5h; Stage #2: phenyl isothiocyanate In 1,4-dioxane at 55℃; for 18h; regioselective reaction; | 84% |
2-ethynylfuran
Conditions | Yield |
---|---|
With copper(ll) sulfate pentahydrate; sodium L-ascorbate; tris[(1-benzyl-1H-1,2,3-triazol-4yl)methyl]amine In water; tert-butyl alcohol at 20℃; | 81% |
Conditions | Yield |
---|---|
With N-methylcyclohexylamine; potassium tert-butylate; sulfur; copper(l) chloride In N,N-dimethyl-formamide at 55℃; for 16h; Molecular sieve; Inert atmosphere; | 81% |
2-ethynylfuran
1-(2-furyl)-1-ethanone
Conditions | Yield |
---|---|
With Perfluorooctanesulfonic acid; C8AgF17O3S*H2O In water at 100℃; for 8h; Darkness; regioselective reaction; | 80% |
With silver tetrafluoroborate; water In acetic acid at 110℃; for 10h; regioselective reaction; | 76% |
2-ethynylfuran
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; potassium iodide In acetonitrile at 60℃; for 16h; Inert atmosphere; | 79% |
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate; carbonyl(pentamethylcyclopentadienyl)cobalt diiodide; silver(I) triflimide at 120℃; for 8h; regioselective reaction; | 79% |
Conditions | Yield |
---|---|
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide Ambient temperature; | 78% |
Conditions | Yield |
---|---|
With copper(l) iodide; ammonium acetate In neat (no solvent) at 120℃; for 4h; | 77% |
2-ethynylfuran
1-(2-furyl)-2-bromoethanone
Conditions | Yield |
---|---|
With N,N'-ethylenethiourea; 1,3-dibromo-5,5-dimethylhydantoin; water In acetone at 45℃; | 77% |
2-ethynylfuran
tricarbonyl(η6-chlorobenzene)chromium
tricarbonyl[η(6)-(2-furylethynyl)benzene]chromium(0)
Conditions | Yield |
---|---|
With NEt3; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran (argon); addn. of the alkyne in THF to the Cr complex, NEt3 and the catalysts at room temp. over 1 h, reflux (4 h); addn. of Et2O, filtration, evapn., chromy. (basic alumina; Et2O/pentane), recrystn. (Et2O/pentane); elem. anal.; | 76% |
2-ethynylfuran
2,2‐dibromo‐1‐(furan‐2‐yl)ethan‐1‐one
Conditions | Yield |
---|---|
With N,N'-ethylenethiourea; 1,3-dibromo-5,5-dimethylhydantoin; water at 20℃; | 76% |
Conditions | Yield |
---|---|
With copper(l) iodide; tert.-butylnitrite; acetic acid; zinc dibromide In chloroform at 20℃; for 24h; Schlenk technique; Inert atmosphere; | 76% |
Conditions | Yield |
---|---|
With triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide heteroarylation; Heating; | 75% |
2-ethynylfuran
ethyl 2-oxocyclohexane carboxylate
Conditions | Yield |
---|---|
With (Re(CO)3(THF)Br)2 In toluene at 80℃; for 24h; Molecular sieve; | 74% |
2-ethynylfuran
C10H10O2S2
2-(furan-2-yl)-4-methyl-5-(phenylsulfonylmethyl)thiophene
Conditions | Yield |
---|---|
With 1,8-diazabicyclo[5.4.0]undec-7-ene; copper(l) chloride In toluene at 50℃; for 12h; Inert atmosphere; | 73% |
Conditions | Yield |
---|---|
With copper diacetate; sodium L-ascorbate; N-ethyl-N,N-diisopropylamine In water; tert-butyl alcohol at 0 - 23℃; for 8h; | 73% |
2-ethynylfuran
triethyloxonium fluoroborate
chromium(0) hexacarbonyl
Conditions | Yield |
---|---|
With n-BuLi In diethyl ether; hexane n-BuLi in hexane was added to soln. 2-ethynylfuran in Et2O at -78°C, 50 min at -78°C, warmed for 15 min, added at 0°C to Cr(CO)6 in Et2O, warmed to r.t., 1 h, THF was added, overnight, cooled to -78°C, Et3OBF4, 1 h at r.t.; soln. was concd., filtered, and evapd. in vacuo, residue was purified bychromy. on silica; elem. anal.; | 72% |
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