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EAST CHEMSOURCES LIMITED

Acrolein diethyl acetal Cas No.:3054-95-3 Molecular Structure: Acrolein diethyl acetal 98% min. Synonyms: 3,3-diethoxy-1-propene EINECS No.: 221-276-0 Molecular Formula: C7H14O2 M.W: 130.18 Properties: 1) Appearance: Colorl

Acrolein diethyl acetal

Cas:3054-95-3

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

High quality Acrolein diethylacetal

Cas:3054-95-3

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Acrolein diethylacetal

Cas:3054-95-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Sinotech Import&Export Corporation

Product Name: Acrolein diethyl acetal Synonyms: ACROLEIN ACETAL;ACROLEIN DEA;ACROLEIN DIETHYL ACETAL;1,1-DIETHOXY-2-PROPENE;3 3-DIETHOXYPROPENE;3,3-DIETHOXY-1-PROPENE;3,3-diethoxy-1-propen;Acrylaldehyde die

Acrolein diethyl acetal CAS: 3054-95-3

Cas:3054-95-3

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3054-95-3

Cas:3054-95-3

Min.Order:0

Negotiable

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Lonwin Chemical Group Limited

Acrolein diethyl acetal CAS:3054-95-3 Specification Acrolein diethyl acetal 98% min. Synonyms: 3,3-diethoxy-1-propene EINECS No.: 221-276-0 Molecular Formula: C7H14O2 M.W: 130.18 Properties: 1) Appearance: Colorless liquid with an agreeable odor

Factory supply Acrolein diethyl acetal CAS 3054-95-3 in China

Cas:3054-95-3

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Acrolein Diethyl Acetal

Cas:3054-95-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Propene, 3,3-diethoxy-

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

3,3-diethoxypropene distributor Order

Cas:3054-95-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Siwei Development Group Ltd.

Product name: 3,3-Diethoxypropene CAS No.:3054-95-3 Molecule Formula:C7H14O2 Molecule Weight:130.18 Purity: 98.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards: Enterprise Standard

High Quality 3,3-Diethoxypropene

Cas:3054-95-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

3,3-diethoxypropene

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Other

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Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 3054-95-3 with competitive price

Cas:3054-95-3

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Acrolein diethyl acetal 3054-95-3

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Propene, 3,3-diethoxy-

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Acrolein Diethyl Acetal

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Other

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Hubei Langyou International Trading Co., Ltd

Acrolein diethyl acetal Application:Acrolein diethyl acetal

Acrolein diethyl acetal

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Other

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SAGECHEM LIMITED

3054-95-3 Application:intermediate

Acraldehydeliethylacetal

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Longxianng Runhui Trading Co.,Ltd

Acrolein diethyl acetalAppearance:liquid Storage:2-8°C Application:Used as a solvent and to make cosmetics. Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for large amou

Acrolein diethyl acetal

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

3,3-diethoxy-1-propene

Cas:3054-95-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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HENAN SUNLAKE ENTERPRISE CORPORATION

1. ISO 9001 approved, GMP producing standard,Proffesional QA system, our quality is guaranteed. 2. Facotory direct sale, most comptive price ensured; 3. Audited Supplier on lookchem, No trick, No Scam! 4. Enough stock can make sure safe deliv

POPULAR ! Raw materials CAS.NO 3054-95-3 C7H14O2 for Multipurpose intermediate

Cas:3054-95-3

Min.Order:100 Gram

FOB Price: $700.0 / 800.0

Type:Trading Company

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Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

3054-95-3

Cas:3054-95-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

ISO 9001 National Research Platform CAS No. 3054-95-3

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art equ

High purity Acrolein Diethyl Acetal

Cas:3054-95-3

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hangzhou KieRay Chem Co.,Ltd.

Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int

Acrolein diethyl acetal

Cas:3054-95-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

3,3-Diethoxypropene

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Other

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ORCHID CHEMICAL SUPPLIES LTD

3,3-diethoxypropene CAS#3054-95-3 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

3,3-diethoxypropene

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

1-Propene, 3,3-diethoxy-

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Nanjing Chemlin Chemical Co., Ltd.

please contact us to confirm the required quantity and quote, we will provide you with COA,NMR,HPLC and other relevant information Storage:Store in a cool place. Keep container tightly closed in a dry and well-ventilated place Package:as your needs A

3,3-diethoxypropene

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Pure Chemistry Scientific Inc.

Acrolein diethyl acetal Application:821916

Acrolein diethyl acetal

Cas:3054-95-3

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Changzhou Ansciep Chemical Co.,Ltd.

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

3054-95-3

Cas:3054-95-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

aminopropane diethyl acetal
41365-75-7

aminopropane diethyl acetal

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With 2-hydroxynitrobenzene; strontium chloride; sodium sulfite In acetonitrile at 135℃; for 9h; Temperature; Time;83%
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

acrolein
107-02-8

acrolein

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With toluene-4-sulfonic acid74%
With perchloric acid In ethanol for 0.5h;60%
With toluene-4-sulfonic acid In ethanol48%
phenylmagnesium bromide

phenylmagnesium bromide

A

styrene
292638-84-7

styrene

B

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

C

α-phenylallyl ethyl ether
14093-65-3

α-phenylallyl ethyl ether

Conditions
ConditionsYield
1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 0℃; for 3h;A 11%
B 55%
C 11%
3-chloro-1,1-diethoxy-propane
35573-93-4

3-chloro-1,1-diethoxy-propane

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With potassium hydroxide
With alkali
With potassium tert-butylate
With alkali Darst.;
3-butoxy-propionaldehyde diethylacetal
856983-92-1

3-butoxy-propionaldehyde diethylacetal

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

1-ethoxy-3-butoxy-propene

1-ethoxy-3-butoxy-propene

Conditions
ConditionsYield
analog der Verbindung /BRN= 1738268/;ensteht ein Gemisch der Stereoisomeren;
2-bromopropionaldehyde diethyl acetal
3400-55-3

2-bromopropionaldehyde diethyl acetal

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With alkaline solution
With potassium tert-butylate In tert-butyl alcohol
ethanol
64-17-5

ethanol

acrolein
107-02-8

acrolein

A

1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

B

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With dichloromethane; ammonium chloride
ethanol
64-17-5

ethanol

acrolein
107-02-8

acrolein

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With aluminum oxide; silica gel; zirconium(IV) oxide
With toluene-4-sulfonic acid; Petroleum ether
With toluene-4-sulfonic acid
ethanol
64-17-5

ethanol

(1R,2R)-1-Bromo-2-ethoxy-cyclopropane
78238-85-4, 78238-86-5

(1R,2R)-1-Bromo-2-ethoxy-cyclopropane

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
With potassium carbonate Heating; Yield given;
2-bromopropionaldehyde diethyl acetal
3400-55-3

2-bromopropionaldehyde diethyl acetal

diluted KOH-solution

diluted KOH-solution

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

2-bromopropionaldehyde diethyl acetal
3400-55-3

2-bromopropionaldehyde diethyl acetal

diluted NaOH-solution

diluted NaOH-solution

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

quinoline
91-22-5

quinoline

1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

cis-1,3-diethoxy-propene

cis-1,3-diethoxy-propene

D

trans-1,3-diethoxy-propene

trans-1,3-diethoxy-propene

Conditions
ConditionsYield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;
quinoline
91-22-5

quinoline

1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

diisopropyl sulfate
2973-10-6

diisopropyl sulfate

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

cis-1,3-diethoxy-propene

cis-1,3-diethoxy-propene

D

trans-1,3-diethoxy-propene

trans-1,3-diethoxy-propene

Conditions
ConditionsYield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;
1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

sulfuric acid
7664-93-9

sulfuric acid

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

cis-1,3-diethoxy-propene

cis-1,3-diethoxy-propene

D

trans-1,3-diethoxy-propene

trans-1,3-diethoxy-propene

pyridine
110-86-1

pyridine

1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

dimethyl sulfate
77-78-1

dimethyl sulfate

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

cis-1,3-diethoxy-propene

cis-1,3-diethoxy-propene

D

trans-1,3-diethoxy-propene

trans-1,3-diethoxy-propene

Conditions
ConditionsYield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;
1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

ammonium sulfate

ammonium sulfate

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

cis-1,3-diethoxy-propene

cis-1,3-diethoxy-propene

D

trans-1,3-diethoxy-propene

trans-1,3-diethoxy-propene

3-chloro-1,1-diethoxy-propane
35573-93-4

3-chloro-1,1-diethoxy-propane

KOH

KOH

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1,1,3-Triethoxy-propane
7789-92-6

1,1,3-Triethoxy-propane

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

1,3-diethoxy-propene

1,3-diethoxy-propene

Conditions
ConditionsYield
With quinoline; diisopropyl sulfate at 350℃;
γ.γ-diethoxybutyrate potassium

γ.γ-diethoxybutyrate potassium

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

1,1,6,6-tetraethoxyhexane
3975-12-0

1,1,6,6-tetraethoxyhexane

Conditions
ConditionsYield
With carbon dioxide Electrolysis;
ethanol
64-17-5

ethanol

3,3-dichloropropene
563-57-5

3,3-dichloropropene

sodium ethanolate
141-52-6

sodium ethanolate

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

3-ethoxy-1-chloro-propene ( mixture of/the/ stereoisomer(ic)/s)

3-ethoxy-1-chloro-propene ( mixture of/the/ stereoisomer(ic)/s)

C

3-ethoxy-propyne(?)

3-ethoxy-propyne(?)

quinoline
91-22-5

quinoline

diisopropyl sulfate
2973-10-6

diisopropyl sulfate

3-butoxy-propionaldehyde diethylacetal
856983-92-1

3-butoxy-propionaldehyde diethylacetal

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

ethanol
64-17-5

ethanol

C

butan-1-ol
71-36-3

butan-1-ol

D

1-ethoxy-3-butoxy-propene

1-ethoxy-3-butoxy-propene

Conditions
ConditionsYield
at 350℃; Pyrolyse des Dampfes.Pyrolysis;
γ.γ-diethoxybutyrate potassium

γ.γ-diethoxybutyrate potassium

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

adipdialdehyde tetraethylacetal

adipdialdehyde tetraethylacetal

Conditions
ConditionsYield
Electrolysis;
2,3-bis-(toluene-4-sulfonyloxy)-propionaldehyde diethylacetal

2,3-bis-(toluene-4-sulfonyloxy)-propionaldehyde diethylacetal

acetone
67-64-1

acetone

sodium iodide

sodium iodide

A

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

B

acrolein
107-02-8

acrolein

1,1-diethoxypropane
4744-08-5

1,1-diethoxypropane

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Br2 / CHCl3
2: KOtBu / 2-methyl-propan-2-ol
View Scheme
orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

SOCl2 (1 mol)

SOCl2 (1 mol)

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: diethyl ether
2: Br2 / CHCl3
3: KOtBu / 2-methyl-propan-2-ol
View Scheme
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

bromobenzene-d5
4165-57-5

bromobenzene-d5

1-ethoxy-3-[2H5]phenylprop-1-ene
253305-55-4

1-ethoxy-3-[2H5]phenylprop-1-ene

Conditions
ConditionsYield
Stage #1: bromobenzene-d5 With iodine; magnesium In tetrahydrofuran for 4h; Heating;
Stage #2: With copper(I) bromide In tetrahydrofuran
Stage #3: acrylaldehyde diethyl acetal In tetrahydrofuran
100%
Stage #1: bromobenzene-d5 With magnesium; copper(I) bromide In tetrahydrofuran
Stage #2: acrylaldehyde diethyl acetal In tetrahydrofuran Further stages.;
100%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

2-benzyl-2-methyl-3-morpholino-3-oxopropanal

2-benzyl-2-methyl-3-morpholino-3-oxopropanal

2-benzyl-6,6-diethoxy-2-methyl-1-morpholinohexane-1,3-dione

2-benzyl-6,6-diethoxy-2-methyl-1-morpholinohexane-1,3-dione

Conditions
ConditionsYield
With [Rh(bis(dicylohexylphosphino)methane)(C6H5F)][BArF4] In acetone at 55℃; for 18h; Inert atmosphere; Sealed tube; regioselective reaction;99%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

allyldibutyltin chloride
64549-05-9

allyldibutyltin chloride

1,5-hexadiene-3-ol
924-41-4

1,5-hexadiene-3-ol

Conditions
ConditionsYield
In water at 20℃; for 0.166667h;98%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

ethyl 3-(4-fluorophenyl)propanoate
7116-38-3

ethyl 3-(4-fluorophenyl)propanoate

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 3h;98%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

tert-butyl 7-(3-oxopropyl)-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

tert-butyl 7-(3-oxopropyl)-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h;
Stage #2: tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate With water; potassium carbonate; tricyclohexylphosphine; palladium diacetate In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Heating;
Stage #3: With hydrogenchloride In Isopropyl acetate; water at 0℃; Further stages.;
97%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-chloro-4-iodo-1,1,2,2,3,3,4,4-octafluorobutane
5848-38-4

1-chloro-4-iodo-1,1,2,2,3,3,4,4-octafluorobutane

1-chloro-7,7-diethoxy-1,1,2,2,3,3,4,4-octafluoro-6-iodo-heptane
281667-73-0

1-chloro-7,7-diethoxy-1,1,2,2,3,3,4,4-octafluoro-6-iodo-heptane

Conditions
ConditionsYield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile at 5 - 10℃; for 2h; Addition;96%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

3-(benzotriazol-1-yl)-3-ethoxy-1-propene
161607-20-1

3-(benzotriazol-1-yl)-3-ethoxy-1-propene

Conditions
ConditionsYield
95%
In various solvent(s) at 82℃; for 2h;95%
In hexane for 6h; Heating;87%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

(1R,2R)-1,2-dicyclohexyl-1,2-ethanediol
120850-92-2

(1R,2R)-1,2-dicyclohexyl-1,2-ethanediol

acrolein (R,R)-1,2-dicyclohexylethylene acetal
257861-22-6

acrolein (R,R)-1,2-dicyclohexylethylene acetal

Conditions
ConditionsYield
With toluene-4-sulfonic acid In dichloromethane at 20℃; for 2h;95%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

4-bromobenzenecarbonitrile
623-00-7

4-bromobenzenecarbonitrile

3-(4-cyano-phenyl)-propionic acid ethyl ester
116460-89-0

3-(4-cyano-phenyl)-propionic acid ethyl ester

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 4-bromobenzenecarbonitrile With N-Methyldicyclohexylamine; tetrabutylammomium bromide In N,N-dimethyl-formamide at 120℃; for 4h; Heck reaction;
Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemospecific reaction;
95%
With N-Methyldicyclohexylamine; tetrabutylammomium bromide; 4-hydroxyacetophenone oxime-derived palladacycle catalyst In N,N-dimethyl acetamide; water at 120℃; for 3h; Heck coupling;86%
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 23h;78%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

dithiocarbonic acid S-(1-acetylamino-2,2,2-trifluoro-ethyl) ester O-ethyl ester
583029-16-7

dithiocarbonic acid S-(1-acetylamino-2,2,2-trifluoro-ethyl) ester O-ethyl ester

dithiocarbonic acid S-(3-acetylamino-1-diethoxymethyl-4,4,4-trifluoro-butyl) ester O-ethyl ester
583029-04-3

dithiocarbonic acid S-(3-acetylamino-1-diethoxymethyl-4,4,4-trifluoro-butyl) ester O-ethyl ester

Conditions
ConditionsYield
With dilauryl peroxide In 1,2-dichloro-ethane for 1.5h; Heating;95%
Stage #1: acrylaldehyde diethyl acetal; dithiocarbonic acid S-(1-acetylamino-2,2,2-trifluoro-ethyl) ester O-ethyl ester In 1,2-dichloro-ethane Reflux; Inert atmosphere;
Stage #2: With dilauryl peroxide In 1,2-dichloro-ethane Reflux; Inert atmosphere;
95%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-bromopyrene
1714-29-0

1-bromopyrene

3-(pyrene-1-yl)propionic acid ethyl ester
83671-44-7

3-(pyrene-1-yl)propionic acid ethyl ester

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 1-bromopyrene With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium acetate In 1-methyl-pyrrolidin-2-one at 140℃; for 6h;
Stage #2: With hydrogenchloride; water In 1-methyl-pyrrolidin-2-one
95%
2-Methylbenzothiazole
120-75-2

2-Methylbenzothiazole

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-(3,3-diethoxypropyl)-2-methylbenzothiazole

1-(3,3-diethoxypropyl)-2-methylbenzothiazole

Conditions
ConditionsYield
With acetic acid In acetonitrile95%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-Chloro-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-6-iodo-hexane
16486-97-8

1-Chloro-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-6-iodo-hexane

1-chloro-9,9-diethoxy-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-8-iodo-nonane
281667-74-1

1-chloro-9,9-diethoxy-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-8-iodo-nonane

Conditions
ConditionsYield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile at 5 - 10℃; for 2h; Addition;94%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-Fluoro-2-iodobenzene
348-52-7

1-Fluoro-2-iodobenzene

ethyl 3-(2-fluorophenyl)propionate
39856-89-8

ethyl 3-(2-fluorophenyl)propionate

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 6.5h;94%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

4-iodobenzoic acid ethyl ester
51934-41-9

4-iodobenzoic acid ethyl ester

ethyl (E)-4-(3-oxoprop-1-en-1-yl)benzoate
145372-96-9

ethyl (E)-4-(3-oxoprop-1-en-1-yl)benzoate

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 4-iodobenzoic acid ethyl ester With potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 0.166667h; microwave irradiation;
Stage #2: With hydrogenchloride In water for 0.166667h; Further stages.;
94%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

3‐bromo‐9H‐fluorene
2038-91-7

3‐bromo‐9H‐fluorene

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

3-(3,3-diethoxy-propyl)-9H-fluorene

3-(3,3-diethoxy-propyl)-9H-fluorene

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h;
Stage #2: 3‐bromo‐9H‐fluorene With 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; palladium diacetate In tetrahydrofuran Suzuki-Miyaura coupling; Heating; Further stages.;
94%
3-bromoquinoline
5332-24-1

3-bromoquinoline

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

3-(3,3-diethoxy-propyl)-quinoline

3-(3,3-diethoxy-propyl)-quinoline

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h;
Stage #2: 3-bromoquinoline With water; potassium carbonate; tricyclohexylphosphine; palladium diacetate In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Heating; Further stages.;
93%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

bis-(phenylthio)-dibutylstannane
14365-16-3

bis-(phenylthio)-dibutylstannane

1-ethoxy-3-phenylthio-1-propene
53963-18-1

1-ethoxy-3-phenylthio-1-propene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In toluene at -78℃;92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

(3R,5S)-5-hydroxy-3-methyl-oct-7-enoic acid N,N-dimethylamide
379269-69-9

(3R,5S)-5-hydroxy-3-methyl-oct-7-enoic acid N,N-dimethylamide

(3R,5S)-5-[(1RS)-1-ethoxy-allyloxy]-3-methyl-oct-7-enoic acid N,N-dimethylamide
379269-70-2

(3R,5S)-5-[(1RS)-1-ethoxy-allyloxy]-3-methyl-oct-7-enoic acid N,N-dimethylamide

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 40℃; under 60.0048 Torr;92%
toluene-4-sulfonic acid In toluene at 40℃; under 60.006 Torr;92%
1-Chloro-4-iodobenzene
637-87-6

1-Chloro-4-iodobenzene

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

ethyl 3-(4-chlorophenyl)propanoate
7116-36-1

ethyl 3-(4-chlorophenyl)propanoate

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 2.5h;92%
With N-Methyldicyclohexylamine; 4-hydroxyacetophenone oxime-derived palladacycle catalyst In N,N-dimethyl acetamide; water at 90℃; for 4h; Heck coupling;79%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

2-iodo-1-methyl-4-nitrobenzene
7745-92-8

2-iodo-1-methyl-4-nitrobenzene

3-(2-methyl-5-nitro-phenyl)-propionic acid ethyl ester

3-(2-methyl-5-nitro-phenyl)-propionic acid ethyl ester

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 1h;92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

1-Fluoro-3-iodobenzene
1121-86-4

1-Fluoro-3-iodobenzene

ethyl 3-(3-fluorophenyl)propanoate
7116-37-2

ethyl 3-(3-fluorophenyl)propanoate

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 2.5h;92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

2-(2-Ethoxycarbonyl-ethyl)-benzoic acid methyl ester
105986-52-5

2-(2-Ethoxycarbonyl-ethyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 5h;92%
tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex

tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex

tricarbonylcyclopentadienyltungsten(II) hydride
12128-26-6

tricarbonylcyclopentadienyltungsten(II) hydride

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

(C5H5)(CO)3WC2H5OCHCHCH3(1+)*B(C6H3(CF3)2)4(1-)=[(C5H5)(CO)3WC2H5OCHCHCH3]B(C6H3(CF3)2)4
184370-78-3

(C5H5)(CO)3WC2H5OCHCHCH3(1+)*B(C6H3(CF3)2)4(1-)=[(C5H5)(CO)3WC2H5OCHCHCH3]B(C6H3(CF3)2)4

Conditions
ConditionsYield
In toluene (Ar); stirring (-15°C, 30 min), removal of the solvent, dissolution in CH2Cl2; addn. of hexane, filtration, recrystn. (-78°C, CH2Cl2/hexane); elem. anal.;92%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

4-methoxycinnamaldehyde
1963-36-6

4-methoxycinnamaldehyde

Conditions
ConditionsYield
Stage #1: 1-bromo-4-methoxy-benzene; acrylaldehyde diethyl acetal With potassium chloride; tetrabutylammonium acetate; potassium carbonate In N,N-dimethyl acetamide at 120℃; for 3h; Heck reaction;
Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemospecific reaction;
92%
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine at 100℃; for 2h;
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

A

3-(4-nitrophenyl)-2-propenal
1734-79-8

3-(4-nitrophenyl)-2-propenal

B

ethyl 3-(4-nitrophenyl)propanoate
7116-34-9

ethyl 3-(4-nitrophenyl)propanoate

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; para-nitrophenyl bromide With N-Methyldicyclohexylamine; tetrabutylammomium bromide In N,N-dimethyl-formamide at 120℃; for 6h; Heck reaction;
Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemoselective reaction;
A n/a
B 92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

2-(tert-butyl)phenyl trifluoromethanesulfonate
198206-03-0

2-(tert-butyl)phenyl trifluoromethanesulfonate

2-(p-tert-butylphenyl)acrolein diethyl acetal
1393539-70-2

2-(p-tert-butylphenyl)acrolein diethyl acetal

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; lithium carbonate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl acetamide at 80℃; for 41h; Mizoroki-Heck reaction; Inert atmosphere;92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

phenylmethanethiol
100-53-8

phenylmethanethiol

3-benzylthiopropanal diethyl acetal
32380-88-4

3-benzylthiopropanal diethyl acetal

Conditions
ConditionsYield
With benzo[de]benzo[4,5]imidazo[2,1-a]isoquinolin-7-one In cyclohexane at 20℃; for 1h; Inert atmosphere; Sealed tube; Irradiation;92%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane
23235-61-2

3,3,7,7-tetra(hydroxymethyl)-5-oxanonane

di[(5-ethyl-2-vinyl-[1,3]dioxan-5-yl)methyl] ether

di[(5-ethyl-2-vinyl-[1,3]dioxan-5-yl)methyl] ether

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; 3,3,7,7-tetra(hydroxymethyl)-5-oxanonane With pyridinium p-toluenesulfonate In toluene for 4h; Heating / reflux;
Stage #2: With potassium tert-butylate In toluene at 20℃;
91%
acrylaldehyde diethyl acetal
3054-95-3

acrylaldehyde diethyl acetal

N,N-dibenzyl-3-(2-bromophenyl)propan-1-amine

N,N-dibenzyl-3-(2-bromophenyl)propan-1-amine

(E)-3-(2-(3-(dibenzylamino)propyl)phenyl)acrylaldehyde

(E)-3-(2-(3-(dibenzylamino)propyl)phenyl)acrylaldehyde

Conditions
ConditionsYield
Stage #1: acrylaldehyde diethyl acetal; N,N-dibenzyl-3-(2-bromophenyl)propan-1-amine With potassium chloride; tetrabutylammonium acetate; palladium diacetate; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 18h;
Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 0℃; for 2h;
91%

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