Acrolein diethyl acetal supplier

Name
Acrolein diethyl acetal
EINECS 221-276-0
CAS No. 3054-95-3
Article Data37
CAS DataBase
Density 0.854 g/cm³
Solubility Soluble in water
Melting Point 120-125°C
Formula C₇H₁₄O₂
Boiling Point 123.5 °C at 760 mmHg
Molecular Weight 130.187
Flash Point 22.3 °C
Transport Information UN 2374 3/PG 2
Appearance clear colorless liquid
Safety 9-16-26-33-29-7/9
Risk Codes 11-36
Molecular Structure
Hazard Symbols F,Xi
Synonyms Acrolein,diethyl acetal (7CI,8CI);Propene, 3,3-diethoxy- (8CI);1,1-Diethoxy-2-propene;3,3-Diethoxy-1-propene;3,3-Diethoxypropene;Acrylylaldehyde diethyl acetal;Propenal diethyl acetal;
PSA 18.46000
LogP 1.57150

Synthetic route

: 41365-75-7
aminopropane diethyl acetal

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With 2-hydroxynitrobenzene; strontium chloride; sodium sulfite In acetonitrile at 135℃; for 9h; Temperature; Time;	83%

: 122-51-0
orthoformic acid triethyl ester

: 107-02-8
acrolein

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With toluene-4-sulfonic acid	74%
With perchloric acid In ethanol for 0.5h;	60%
With toluene-4-sulfonic acid In ethanol	48%

: phenylmagnesium bromide

A: 292638-84-7
styrene

B: 3054-95-3
acrylaldehyde diethyl acetal

C: 14093-65-3
α-phenylallyl ethyl ether

Conditions

Conditions	Yield
1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 0℃; for 3h;	A 11% B 55% C 11%

...Expand

: 35573-93-4
3-chloro-1,1-diethoxy-propane

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With potassium hydroxide
With alkali
With potassium tert-butylate
With alkali Darst.;

: 856983-92-1
3-butoxy-propionaldehyde diethylacetal

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 1-ethoxy-3-butoxy-propene

Conditions

Conditions	Yield
analog der Verbindung /BRN= 1738268/;ensteht ein Gemisch der Stereoisomeren;

: 3400-55-3
2-bromopropionaldehyde diethyl acetal

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With alkaline solution
With potassium tert-butylate In tert-butyl alcohol

: 64-17-5
ethanol

: 107-02-8
acrolein

A: 7789-92-6
1,1,3-Triethoxy-propane

B: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With dichloromethane; ammonium chloride

...Expand

: 64-17-5
ethanol

: 107-02-8
acrolein

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With aluminum oxide; silica gel; zirconium(IV) oxide
With toluene-4-sulfonic acid; Petroleum ether
With toluene-4-sulfonic acid

: 64-17-5
ethanol

: 78238-85-4, 78238-86-5
(1R,2R)-1-Bromo-2-ethoxy-cyclopropane

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
With potassium carbonate Heating; Yield given;

: 3400-55-3
2-bromopropionaldehyde diethyl acetal

diluted KOH-solution: diluted KOH-solution

: 3054-95-3
acrylaldehyde diethyl acetal

: 3400-55-3
2-bromopropionaldehyde diethyl acetal

diluted NaOH-solution: diluted NaOH-solution

: 3054-95-3
acrylaldehyde diethyl acetal

: 91-22-5
quinoline

: 7789-92-6
1,1,3-Triethoxy-propane

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C cis-1,3-diethoxy-propene: cis-1,3-diethoxy-propene

D trans-1,3-diethoxy-propene: trans-1,3-diethoxy-propene

Conditions

Conditions	Yield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;

...Expand

: 91-22-5
quinoline

: 7789-92-6
1,1,3-Triethoxy-propane

: 2973-10-6
diisopropyl sulfate

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C cis-1,3-diethoxy-propene: cis-1,3-diethoxy-propene

D trans-1,3-diethoxy-propene: trans-1,3-diethoxy-propene

Conditions

Conditions	Yield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;

...Expand

: 7789-92-6
1,1,3-Triethoxy-propane

: 7664-93-9
sulfuric acid

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C cis-1,3-diethoxy-propene: cis-1,3-diethoxy-propene

D trans-1,3-diethoxy-propene: trans-1,3-diethoxy-propene

...Expand

: 110-86-1
pyridine

: 7789-92-6
1,1,3-Triethoxy-propane

: 77-78-1
dimethyl sulfate

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C cis-1,3-diethoxy-propene: cis-1,3-diethoxy-propene

D trans-1,3-diethoxy-propene: trans-1,3-diethoxy-propene

Conditions

Conditions	Yield
at 260 - 450℃; Pyrolyse des Dampfes.Pyrolysis;

...Expand

: 7789-92-6
1,1,3-Triethoxy-propane

ammonium sulfate: ammonium sulfate

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C cis-1,3-diethoxy-propene: cis-1,3-diethoxy-propene

D trans-1,3-diethoxy-propene: trans-1,3-diethoxy-propene

...Expand

: 35573-93-4
3-chloro-1,1-diethoxy-propane

KOH: KOH

: 3054-95-3
acrylaldehyde diethyl acetal

: 7789-92-6
1,1,3-Triethoxy-propane

A: 3054-95-3
acrylaldehyde diethyl acetal

B 1,3-diethoxy-propene: 1,3-diethoxy-propene

Conditions

Conditions	Yield
With quinoline; diisopropyl sulfate at 350℃;

γ.γ-diethoxybutyrate potassium: γ.γ-diethoxybutyrate potassium

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 3975-12-0
1,1,6,6-tetraethoxyhexane

Conditions

Conditions	Yield
With carbon dioxide Electrolysis;

: 64-17-5
ethanol

: 563-57-5
3,3-dichloropropene

: 141-52-6
sodium ethanolate

A: 3054-95-3
acrylaldehyde diethyl acetal

B 3-ethoxy-1-chloro-propene ( mixture of/the/ stereoisomer(ic)/s): 3-ethoxy-1-chloro-propene ( mixture of/the/ stereoisomer(ic)/s)

C 3-ethoxy-propyne(?): 3-ethoxy-propyne(?)

...Expand

: 91-22-5
quinoline

: 2973-10-6
diisopropyl sulfate

: 856983-92-1
3-butoxy-propionaldehyde diethylacetal

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 64-17-5
ethanol

C: 71-36-3
butan-1-ol

D 1-ethoxy-3-butoxy-propene: 1-ethoxy-3-butoxy-propene

Conditions

Conditions	Yield
at 350℃; Pyrolyse des Dampfes.Pyrolysis;

...Expand

γ.γ-diethoxybutyrate potassium: γ.γ-diethoxybutyrate potassium

A: 3054-95-3
acrylaldehyde diethyl acetal

B adipdialdehyde tetraethylacetal: adipdialdehyde tetraethylacetal

Conditions

Conditions	Yield
Electrolysis;

: 2,3-bis-(toluene-4-sulfonyloxy)-propionaldehyde diethylacetal

: 67-64-1
acetone

sodium iodide: sodium iodide

A: 3054-95-3
acrylaldehyde diethyl acetal

B: 107-02-8
acrolein

...Expand

: 4744-08-5
1,1-diethoxypropane

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Br2 / CHCl3 2: KOtBu / 2-methyl-propan-2-ol View Scheme

: 122-51-0
orthoformic acid triethyl ester

SOCl2 (1 mol): SOCl2 (1 mol)

: 3054-95-3
acrylaldehyde diethyl acetal

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: diethyl ether 2: Br2 / CHCl3 3: KOtBu / 2-methyl-propan-2-ol View Scheme

: 3054-95-3
acrylaldehyde diethyl acetal

: 4165-57-5
bromobenzene-d5

: 253305-55-4
1-ethoxy-3-[2H5]phenylprop-1-ene

Conditions

Conditions	Yield
Stage #1: bromobenzene-d5 With iodine; magnesium In tetrahydrofuran for 4h; Heating; Stage #2: With copper(I) bromide In tetrahydrofuran Stage #3: acrylaldehyde diethyl acetal In tetrahydrofuran	100%
Stage #1: bromobenzene-d5 With magnesium; copper(I) bromide In tetrahydrofuran Stage #2: acrylaldehyde diethyl acetal In tetrahydrofuran Further stages.;	100%

: 3054-95-3
acrylaldehyde diethyl acetal

: 2-benzyl-2-methyl-3-morpholino-3-oxopropanal

: 2-benzyl-6,6-diethoxy-2-methyl-1-morpholinohexane-1,3-dione

Conditions

Conditions	Yield
With [Rh(bis(dicylohexylphosphino)methane)(C6H5F)][BArF4] In acetone at 55℃; for 18h; Inert atmosphere; Sealed tube; regioselective reaction;	99%

: 3054-95-3
acrylaldehyde diethyl acetal

: 64549-05-9
allyldibutyltin chloride

: 924-41-4
1,5-hexadiene-3-ol

Conditions

Conditions	Yield
In water at 20℃; for 0.166667h;	98%

: 3054-95-3
acrylaldehyde diethyl acetal

: 352-34-1
4-fluoro-1-iodobenzene

: 7116-38-3
ethyl 3-(4-fluorophenyl)propanoate

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 3h;	98%

: 3054-95-3
acrylaldehyde diethyl acetal

: 280-64-8
9-bora-bicyclo[3.3.1]nonane

: tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

: tert-butyl 7-(3-oxopropyl)-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h; Stage #2: tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate With water; potassium carbonate; tricyclohexylphosphine; palladium diacetate In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Heating; Stage #3: With hydrogenchloride In Isopropyl acetate; water at 0℃; Further stages.;	97%

Yield

Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h;
Stage #2: tert-butyl 7-chloro-3,4-dihydro-1,8-naphthyridine-1(2H)-carboxylate With water; potassium carbonate; tricyclohexylphosphine; palladium diacetate In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Heating;
Stage #3: With hydrogenchloride In Isopropyl acetate; water at 0℃; Further stages.;

97%

...Expand

: 3054-95-3
acrylaldehyde diethyl acetal

: 5848-38-4
1-chloro-4-iodo-1,1,2,2,3,3,4,4-octafluorobutane

: 281667-73-0
1-chloro-7,7-diethoxy-1,1,2,2,3,3,4,4-octafluoro-6-iodo-heptane

Conditions

Conditions	Yield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile at 5 - 10℃; for 2h; Addition;	96%

: 95-14-7
1,2,3-Benzotriazole

: 3054-95-3
acrylaldehyde diethyl acetal

: 161607-20-1
3-(benzotriazol-1-yl)-3-ethoxy-1-propene

Conditions

Conditions	Yield
	95%
In various solvent(s) at 82℃; for 2h;	95%
In hexane for 6h; Heating;	87%

: 3054-95-3
acrylaldehyde diethyl acetal

: 120850-92-2
(1R,2R)-1,2-dicyclohexyl-1,2-ethanediol

: 257861-22-6
acrolein (R,R)-1,2-dicyclohexylethylene acetal

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In dichloromethane at 20℃; for 2h;	95%

: 3054-95-3
acrylaldehyde diethyl acetal

: 623-00-7
4-bromobenzenecarbonitrile

: 116460-89-0
3-(4-cyano-phenyl)-propionic acid ethyl ester

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 4-bromobenzenecarbonitrile With N-Methyldicyclohexylamine; tetrabutylammomium bromide In N,N-dimethyl-formamide at 120℃; for 4h; Heck reaction; Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemospecific reaction;	95%
With N-Methyldicyclohexylamine; tetrabutylammomium bromide; 4-hydroxyacetophenone oxime-derived palladacycle catalyst In N,N-dimethyl acetamide; water at 120℃; for 3h; Heck coupling;	86%
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 23h;	78%

: 3054-95-3
acrylaldehyde diethyl acetal

: 583029-16-7
dithiocarbonic acid S-(1-acetylamino-2,2,2-trifluoro-ethyl) ester O-ethyl ester

: 583029-04-3
dithiocarbonic acid S-(3-acetylamino-1-diethoxymethyl-4,4,4-trifluoro-butyl) ester O-ethyl ester

Conditions

Conditions	Yield
With dilauryl peroxide In 1,2-dichloro-ethane for 1.5h; Heating;	95%
Stage #1: acrylaldehyde diethyl acetal; dithiocarbonic acid S-(1-acetylamino-2,2,2-trifluoro-ethyl) ester O-ethyl ester In 1,2-dichloro-ethane Reflux; Inert atmosphere; Stage #2: With dilauryl peroxide In 1,2-dichloro-ethane Reflux; Inert atmosphere;	95%

: 3054-95-3
acrylaldehyde diethyl acetal

: 1714-29-0
1-bromopyrene

: 83671-44-7
3-(pyrene-1-yl)propionic acid ethyl ester

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 1-bromopyrene With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium acetate In 1-methyl-pyrrolidin-2-one at 140℃; for 6h; Stage #2: With hydrogenchloride; water In 1-methyl-pyrrolidin-2-one	95%

: 120-75-2
2-Methylbenzothiazole

: 3054-95-3
acrylaldehyde diethyl acetal

: 1-(3,3-diethoxypropyl)-2-methylbenzothiazole

Conditions

Conditions	Yield
With acetic acid In acetonitrile	95%

: 3054-95-3
acrylaldehyde diethyl acetal

: 16486-97-8
1-Chloro-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-6-iodo-hexane

: 281667-74-1
1-chloro-9,9-diethoxy-1,1,2,2,3,3,4,4,5,5,6,6-dodecafluoro-8-iodo-nonane

Conditions

Conditions	Yield
With sodium dithionite; sodium hydrogencarbonate In water; acetonitrile at 5 - 10℃; for 2h; Addition;	94%

: 3054-95-3
acrylaldehyde diethyl acetal

: 348-52-7
1-Fluoro-2-iodobenzene

: 39856-89-8
ethyl 3-(2-fluorophenyl)propionate

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 6.5h;	94%

: 3054-95-3
acrylaldehyde diethyl acetal

: 51934-41-9
4-iodobenzoic acid ethyl ester

: 145372-96-9
ethyl (E)-4-(3-oxoprop-1-en-1-yl)benzoate

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 4-iodobenzoic acid ethyl ester With potassium carbonate; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 0.166667h; microwave irradiation; Stage #2: With hydrogenchloride In water for 0.166667h; Further stages.;	94%

: 3054-95-3
acrylaldehyde diethyl acetal

: 2038-91-7
3‐bromo‐9H‐fluorene

: 280-64-8
9-bora-bicyclo[3.3.1]nonane

: 3-(3,3-diethoxy-propyl)-9H-fluorene

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h; Stage #2: 3‐bromo‐9H‐fluorene With 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate; palladium diacetate In tetrahydrofuran Suzuki-Miyaura coupling; Heating; Further stages.;	94%

...Expand

: 5332-24-1
3-bromoquinoline

: 3054-95-3
acrylaldehyde diethyl acetal

: 280-64-8
9-bora-bicyclo[3.3.1]nonane

: 3-(3,3-diethoxy-propyl)-quinoline

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran at 20℃; for 12h; Stage #2: 3-bromoquinoline With water; potassium carbonate; tricyclohexylphosphine; palladium diacetate In tetrahydrofuran for 13h; Suzuki-Miyaura coupling; Heating; Further stages.;	93%

...Expand

: 3054-95-3
acrylaldehyde diethyl acetal

: 14365-16-3
bis-(phenylthio)-dibutylstannane

: 53963-18-1
1-ethoxy-3-phenylthio-1-propene

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In toluene at -78℃;	92%

: 3054-95-3
acrylaldehyde diethyl acetal

: 379269-69-9
(3R,5S)-5-hydroxy-3-methyl-oct-7-enoic acid N,N-dimethylamide

: 379269-70-2
(3R,5S)-5-[(1RS)-1-ethoxy-allyloxy]-3-methyl-oct-7-enoic acid N,N-dimethylamide

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In toluene at 40℃; under 60.0048 Torr;	92%
toluene-4-sulfonic acid In toluene at 40℃; under 60.006 Torr;	92%

: 637-87-6
1-Chloro-4-iodobenzene

: 3054-95-3
acrylaldehyde diethyl acetal

: 7116-36-1
ethyl 3-(4-chlorophenyl)propanoate

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 2.5h;	92%
With N-Methyldicyclohexylamine; 4-hydroxyacetophenone oxime-derived palladacycle catalyst In N,N-dimethyl acetamide; water at 90℃; for 4h; Heck coupling;	79%

: 3054-95-3
acrylaldehyde diethyl acetal

: 7745-92-8
2-iodo-1-methyl-4-nitrobenzene

: 3-(2-methyl-5-nitro-phenyl)-propionic acid ethyl ester

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 1h;	92%

: 3054-95-3
acrylaldehyde diethyl acetal

: 1121-86-4
1-Fluoro-3-iodobenzene

: 7116-37-2
ethyl 3-(3-fluorophenyl)propanoate

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 2.5h;	92%

: 3054-95-3
acrylaldehyde diethyl acetal

: 610-97-9
o-iodo-methyl-benzoic acid

: 105986-52-5
2-(2-Ethoxycarbonyl-ethyl)-benzoic acid methyl ester

Conditions

Conditions	Yield
With tributyl-amine; tetrabutyl-ammonium chloride; palladium diacetate In N,N-dimethyl-formamide at 90℃; for 5h;	92%

: tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex

: 12128-26-6
tricarbonylcyclopentadienyltungsten(II) hydride

: 3054-95-3
acrylaldehyde diethyl acetal

: 184370-78-3
(C5H5)(CO)3WC2H5OCHCHCH3(1+)*B(C6H3(CF3)2)4(1-)=[(C5H5)(CO)3WC2H5OCHCHCH3]B(C6H3(CF3)2)4

Conditions

Conditions	Yield
In toluene (Ar); stirring (-15°C, 30 min), removal of the solvent, dissolution in CH2Cl2; addn. of hexane, filtration, recrystn. (-78°C, CH2Cl2/hexane); elem. anal.;	92%

...Expand

: 104-92-7
1-bromo-4-methoxy-benzene

: 3054-95-3
acrylaldehyde diethyl acetal

: 1963-36-6
4-methoxycinnamaldehyde

Conditions

Conditions	Yield
Stage #1: 1-bromo-4-methoxy-benzene; acrylaldehyde diethyl acetal With potassium chloride; tetrabutylammonium acetate; potassium carbonate In N,N-dimethyl acetamide at 120℃; for 3h; Heck reaction; Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemospecific reaction;	92%
With palladium diacetate; triethylamine; tris-(o-tolyl)phosphine at 100℃; for 2h;

: 3054-95-3
acrylaldehyde diethyl acetal

: 586-78-7
para-nitrophenyl bromide

A: 1734-79-8
3-(4-nitrophenyl)-2-propenal

B: 7116-34-9
ethyl 3-(4-nitrophenyl)propanoate

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; para-nitrophenyl bromide With N-Methyldicyclohexylamine; tetrabutylammomium bromide In N,N-dimethyl-formamide at 120℃; for 6h; Heck reaction; Stage #2: With hydrogenchloride In water; ethyl acetate at 20℃; chemoselective reaction;	A n/a B 92%

...Expand

: 3054-95-3
acrylaldehyde diethyl acetal

: 198206-03-0
2-(tert-butyl)phenyl trifluoromethanesulfonate

: 1393539-70-2
2-(p-tert-butylphenyl)acrolein diethyl acetal

Conditions

Conditions	Yield
With 1,1'-bis-(diphenylphosphino)ferrocene; lithium carbonate; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl acetamide at 80℃; for 41h; Mizoroki-Heck reaction; Inert atmosphere;	92%

: 3054-95-3
acrylaldehyde diethyl acetal

: 100-53-8
phenylmethanethiol

: 32380-88-4
3-benzylthiopropanal diethyl acetal

Conditions

Conditions	Yield
With benzo[de]benzo[4,5]imidazo[2,1-a]isoquinolin-7-one In cyclohexane at 20℃; for 1h; Inert atmosphere; Sealed tube; Irradiation;	92%

: 3054-95-3
acrylaldehyde diethyl acetal

: 23235-61-2
3,3,7,7-tetra(hydroxymethyl)-5-oxanonane

: di[(5-ethyl-2-vinyl-[1,3]dioxan-5-yl)methyl] ether

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; 3,3,7,7-tetra(hydroxymethyl)-5-oxanonane With pyridinium p-toluenesulfonate In toluene for 4h; Heating / reflux; Stage #2: With potassium tert-butylate In toluene at 20℃;	91%

: 3054-95-3
acrylaldehyde diethyl acetal

: N,N-dibenzyl-3-(2-bromophenyl)propan-1-amine

: (E)-3-(2-(3-(dibenzylamino)propyl)phenyl)acrylaldehyde

Conditions

Conditions	Yield
Stage #1: acrylaldehyde diethyl acetal; N,N-dibenzyl-3-(2-bromophenyl)propan-1-amine With potassium chloride; tetrabutylammonium acetate; palladium diacetate; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 18h; Stage #2: With hydrogenchloride In water; N,N-dimethyl-formamide at 0℃; for 2h;	91%

Acrolein diethyl acetal Chemical Properties

IUPAC Name: 3,3-Diethoxyprop-1-ene
Synonyms of Acrolein diethyl acetal (CAS NO.3054-95-3): 1,1-Diethoxy-2-propene ; 1,1-Diethoxy-2-propene ; 3,3-Diethoxy-1-propene ; 3,3-Diethoxypropene ; Acrolein diethyl acetal ; Acrylaldehyde diethyl acetal ; Propenal diethyl acetal ; 1-Propene, 3,3-diethoxy- ; 1-Propene, 3,3-diethoxy- (9CI) ; Acrolein, diethyl acetal (8CI)
CAS NO: 3054-95-3
Molecular Formula: C₇H₁₄O₂
Molecular Weight: 130.18
Molecular Structure:
EINECS: 221-276-0
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 5
Polar Surface Area: 18.46 Å²
Index of Refraction: 1.409
Molar Refractivity: 37.65 cm³
Molar Volume: 152.2 cm³
Surface Tension: 23.8 dyne/cm
Density: 0.854 g/cm³
Flash Point: 22.3 °C
Enthalpy of Vaporization: 34.65 kJ/mol
Boiling Point: 123.5 °C at 760 mmHg
Vapour Pressure: 16 mmHg at 25°C
Storage temp: 2-8°C
Appearance: clear colorless liquid
SMILES: C=CC(OCC)OCC
Product Categories of Acrolein diethyl acetal (CAS NO.3054-95-3): Pharmaceutical Intermediates;pharmacetical

Acrolein diethyl acetal Uses

Acrolein diethyl acetal (CAS NO.3054-95-3) is used as an important intermediate in the pharmaceutical, dyes and organic synthesis industry.

Acrolein diethyl acetal Toxicity Data With Reference

mma-sat 5 µg/plate

TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. 1 (1980),259.

Acrolein diethyl acetal Safety Profile

Safty informations about Acrolein diethyl acetal (CAS NO.3054-95-3):
Hazard Codes: Irritant XiF
Risk Statements:11-36
11: Highly Flammable
36: Irritating to the eyes
Safety Statements: 9-16-26-33-29-7/9
9: Keep container in a well-ventilated place
16: Keep away from sources of ignition-No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
33: Take precautionary measures against static discharges
29: Do not empty into drains
7/9: Keep container tightly closed and in a well-ventilated place
RIDADR: UN 2374 3/PG 2
WGK Germany: 3
RTECS: AS1370000
F: 8-13
HazardClass: 3
Mutation data reported. A flammable liquid. A dangerous fire hazard when exposed to heat, flame, or oxidizers. When heated to decomposition it emits acrid smoke and fumes.

Acrolein diethyl acetal Standards and Recommendations

DOT Classification: 3; Label: Flammable Liquid

Acrolein diethyl acetal Specification

Handling and Storage:
Storage: Keep Acrolein diethyl acetal in a cool, dry, dark location in a tightly sealed container or cylinder. Keep it away from incompatible materials, ignition sources and untrained individuals. Protect containers/cylinders from physical damage.
Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Product Name

Acrolein diethyl acetal

Synthetic route

Acrolein diethyl acetal Chemical Properties

Acrolein diethyl acetal Uses

Acrolein diethyl acetal Toxicity Data With Reference

Acrolein diethyl acetal Safety Profile

Acrolein diethyl acetal Standards and Recommendations

Acrolein diethyl acetal Specification

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