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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. Near 20 years DayangChem has provided dif

High purity 4-Fluorothiophenol 98% TOP1 supplier in China

Cas:371-42-6

Min.Order:100 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Fluorothiophenol with high purity

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 371-42-6 4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:Colorless transparent liquid Storage:Cool dry place Package:25kg/drum,200kg/drum Application:phar

4-Fluorothiophenol Cas 371-42-6

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Fluorothiophenol CAS number 371-42-6 Assay ≥99% Appearance Colorless transparent to yellowish liquid Capacity 200mt/year Application Pharm

4-Fluorothiophenol

Cas:371-42-6

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hangzhou Think Chemical Co. Ltd

4-Fluorothiophenol CAS No.:371-42-6 Name: 4-Fluorothiophenol Synonyms: 4-Fluorobenzenethiol; 4-Mercaptofluorobenzene Molecular Structure Molecular Formula: C6H5FS Molecular Weight: 128.16 CAS Regi

High purity 4-Fluorothiophenol CAS No.:371-42-6

Cas:371-42-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply P-Fluorothiophenol

Cas:371-42-6

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

371-42-6Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, i

4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

4-Fluorothiophenol -- CHemwill

Cas:371-42-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-Fluorothiophenol Basic information Product Name: 4-Fluorothiophenol Synonyms: P-FLUOROTHIOPHENOL;P-FLUOROPHENYL MERCAPTAN;4-FLUOROTHIOPHENOL;4-FLUOROBENZENETHIOL;4-MERCAPTOFLUOROBENZEN

4-Fluorothiophenol 371-42-6

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 371-42-6 with fast shipping

Cas:371-42-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: 4-Fluorothiophenol Appearance: Colorless and transparent to light yellow liquid M.F.:C6H5FS M.W.:128.17 CAS NO.: 371-42-6 EINECS NO.:206-737-6 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Pa

4-Fluorothiophenol CAS: 371-42-6

Cas:371-42-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenethiol,4-fluoro- 371-42-6

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Kilogram

FOB Price: $85.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Fluorothiophenol CAS:371-42-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermed

4-Fluorothiophenol CAS:371-42-6

Cas:371-42-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenethiol,4-fluoro-

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:371-42-6

Cas:371-42-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

4-Fluoro thiophenol CAS371-42-6

Cas:371-42-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:clear colorless to light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermed

4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Fluoro thiophenol

Cas:371-42-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

4-FLUOROTHIOPHENOL

Cas:371-42-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Fluorothiophenol

Cas:371-42-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-Fluorothiophenol/High quality/Best price

Cas:371-42-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality P-Fluorothiophenol

Cas:371-42-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

4-Fluoro thiophenol

Cas:371-42-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Hebei yanxi chemical co.,LTD.

4-Fluorothiophenol is primarily used in wet chemistry as a capping ligand for various metal nanostructures so that they don’t aggregate in solution. 4-Fluorothiophenol is also capable of creating a self-assembled monolayer, which is used to imp

371-42-6 4-Fluorothiophenol

Cas:371-42-6

Min.Order:25 Kilogram

FOB Price: $120.0 / 150.0

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity 4-Fluorothiophenol

Cas:371-42-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Fluorothiophenol Synonyms: P-FLUOROTHIOPHENOL;P-FLUOROPHENYL MERCAPTAN;4-FLUOROTHIOPHENOL;4-FLUOROBENZENETHIOL;4-MERCAPTOFLUOROBENZENE;4-FLUOROBENZENE-1-THIOL;Fluorothiophenol2;4-FLUOROBENZENETHIOL,98% CAS: 371-42-6 MF: C

4-Fluorothiophenol 371-42-6 C6H5FS

Cas:371-42-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-Fluoro thiophenol

Cas:371-42-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Synthetic route

bis(4-fluorophenyl)disulfide
405-31-2

bis(4-fluorophenyl)disulfide

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
In water; isopropyl alcohol98.5%
98.5%
With sodium tetrahydroborate In water; isopropyl alcohol96.5%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With copper(l) iodide; thiourea; L-proline; sodium t-butanolate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;97%
Stage #1: 4-fluoro-1-iodobenzene With copper(l) iodide; potassium carbonate; sulfur In N,N-dimethyl-formamide at 90℃; for 8h; Inert atmosphere;
Stage #2: With sodium tetrahydroborate In N,N-dimethyl-formamide at 40℃; Inert atmosphere; Cooling with ice;
88%
p-Fluorophenylsulfenyl methyl thiocarbonate
72050-06-7

p-Fluorophenylsulfenyl methyl thiocarbonate

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

C

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
With triphenylphosphine In benzene Mechanism; Ambient temperature;A 90%
B 6%
C 94%
4-fluorobenzenesulfonic acid
368-88-7

4-fluorobenzenesulfonic acid

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With 6% Pd/C; iodine; triphenylphosphine; isopropyl alcohol for 10h; Reflux;92%
4-Fluorobenzenesulfonyl chloride
349-88-2

4-Fluorobenzenesulfonyl chloride

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With formic acid; 6% Pd/C; triphenylphosphine at 60℃; for 8h;90%
With potassium formate at 200℃; for 7h; neat (no solvent);80%
With sulfuric acid; zinc
With phosphorus; iodine
4-fluorophenylsulphonamide
402-46-0

4-fluorophenylsulphonamide

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With ammonium formate at 100 - 200℃; for 7h; neat (no solvent);82%
sodium 4-fluorobenzenesulfinate
824-80-6

sodium 4-fluorobenzenesulfinate

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With hydrogenchloride; tin In water for 24h; Heating;78%
1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
Stage #1: 1-Bromo-4-fluorobenzene With water; caesium carbonate; sodium thiosulfate; bis(dibenzylideneacetone)-palladium(0); XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere;
Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice;
73%
With diethyl ether; sulfur; magnesium Kochen des Reaktionsprodukts mit Zink und wss. HCl;
(i) Mg, (ii) sulfur, (iii) Zn, aq. HCl; Multistep reaction;
1-Chloro-4-fluorobenzene
352-33-0

1-Chloro-4-fluorobenzene

A

fluorobenzene
462-06-6

fluorobenzene

B

5-fluorobenzo[b]thiophene
70060-12-7

5-fluorobenzo[b]thiophene

C

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

D

4,4'-difluorodiphenyl sulfide
404-38-6

4,4'-difluorodiphenyl sulfide

Conditions
ConditionsYield
With hydrogen sulfide at 700℃; for 1.5h; Product distribution; Kinetics; Further Variations:; Temperatures; Reagents; Substitution; Reduction;A n/a
B n/a
C 18%
D 28%
[Dimethylamino-(4-fluoro-phenylsulfanyl)-methylene]-dimethyl-ammonium; iodide

[Dimethylamino-(4-fluoro-phenylsulfanyl)-methylene]-dimethyl-ammonium; iodide

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

tetramethylurea
632-22-4

tetramethylurea

Conditions
ConditionsYield
at 20℃; Rate constant; pH=11;
(4-fluorophenylthio)acetic acid
332-51-4

(4-fluorophenylthio)acetic acid

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

Glyoxilic acid
298-12-4

Glyoxilic acid

Conditions
ConditionsYield
With perchloric acid; sodium perborate; acetic acid at 24.9℃; Rate constant; Thermodynamic data; Mechanism; var. temp., ΔH(excit.), ΔS(excit.);
fluorobenzene
462-06-6

fluorobenzene

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
(i) ClSO3H, (ii) Zn, aq. H2SO4; Multistep reaction;
4-fluoroaniline
371-40-4

4-fluoroaniline

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
(i) NaNO2, aq. HCl, NaOAc, (ii) aq. EtOCS2K, (iii) KOH, glucose; Multistep reaction;
(4-fluorophenylthio)acetic acid
332-51-4

(4-fluorophenylthio)acetic acid

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
With perchloric acid; pyridinium chlorochromate In water; acetic acid at 24.85 - 44.85℃; Kinetics; Oxidation;
biphenyl
92-52-4

biphenyl

bis(4-fluorophenyl)disulfide
405-31-2

bis(4-fluorophenyl)disulfide

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

4-fluoro-3'-phenyldiphenyl sulfide

4-fluoro-3'-phenyldiphenyl sulfide

C

biphenyl-4-yl(4-fluorophenyl)sulfane

biphenyl-4-yl(4-fluorophenyl)sulfane

Conditions
ConditionsYield
With aluminium trichloride In hexane at 25℃; for 3h; Product distribution; Kinetics; Disproportionation; substitution;A 3.7 % Chromat.
B 6.8 % Chromat.
C 69 % Chromat.
ethylbenzene
100-41-4

ethylbenzene

bis(4-fluorophenyl)disulfide
405-31-2

bis(4-fluorophenyl)disulfide

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

4-fluorophenyl 2-ethylphenyl sulfide

4-fluorophenyl 2-ethylphenyl sulfide

C

4-fluorophenyl 4-ethylphenyl sulfide

4-fluorophenyl 4-ethylphenyl sulfide

D

4-fluorophenyl 3-ethylphenyl sulfide

4-fluorophenyl 3-ethylphenyl sulfide

Conditions
ConditionsYield
With aluminium trichloride at 25℃; for 6h; Product distribution; Kinetics; Disproportionation; substitution;A 20 % Chromat.
B 7.0 % Chromat.
C 54 % Chromat.
D 9.0 % Chromat.
bis(4-fluorophenyl)disulfide
405-31-2

bis(4-fluorophenyl)disulfide

toluene
108-88-3

toluene

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

4-fluorophenyl-4'-methylphenyl sulfide
42917-47-5

4-fluorophenyl-4'-methylphenyl sulfide

C

(4-fluorophenyl)(o-tolyl)sulfide

(4-fluorophenyl)(o-tolyl)sulfide

D

4-fluorophenyl 3-tolyl sulfide

4-fluorophenyl 3-tolyl sulfide

Conditions
ConditionsYield
With aluminium trichloride at 25℃; for 3h; Product distribution; Kinetics; Disproportionation; substitution;A 2.2 % Chromat.
B 57 % Chromat.
C 18 % Chromat.
D 9.3 % Chromat.
methanol
67-56-1

methanol

thiophosphoric acid O,O'-diethyl ester S-(4-fluorophenyl) ester
333-42-6

thiophosphoric acid O,O'-diethyl ester S-(4-fluorophenyl) ester

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

diethyl methyl phosphate
867-17-4

diethyl methyl phosphate

Conditions
ConditionsYield
With 1,5,9-triazacyclododecane Zn(2+)-OCH3(1-) at 25℃; pH=9.1; Kinetics; Further Variations:; Reagents;
methyl-phosphonothioic acid O-ethyl ester S-(4-fluoro-phenyl) ester
886227-41-4

methyl-phosphonothioic acid O-ethyl ester S-(4-fluoro-phenyl) ester

sodium methylate
124-41-4

sodium methylate

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

O-ethyl O-methyl methylphosphonate
18755-36-7

O-ethyl O-methyl methylphosphonate

Conditions
ConditionsYield
With N-ethylmorpholine;; perchloric acid; sodium methylate; La(OTf) In methanol Title compound not separated from byproducts;
lanthanum(lll) triflate In methanol Kinetics; Further Variations:; Catalysts;
C7H7ClFOPS

C7H7ClFOPS

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Na2CO3 / tetrahydrofuran / 0.5 h
2: La(OTf)3 / methanol
View Scheme
methanol
67-56-1

methanol

C7H8FO2PS
1284189-31-6

C7H8FO2PS

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

methyl hydrogen methylphosphonate
1066-53-1

methyl hydrogen methylphosphonate

Conditions
ConditionsYield
With lanthanum(lll) triflate at 25℃; pH=8.4; Kinetics; Mechanism; pH-value; aq. buffer;
C13H11F2OPS2

C13H11F2OPS2

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium hydroxide / 1,4-dioxane; water / 8 h / 50 °C
2: lanthanum(lll) triflate / 25 °C / pH 8.4 / aq. buffer
View Scheme
4-(4-fluorophenylthio)-7-nitrobenzo[c][1,2,5]oxadiazole
882289-35-2

4-(4-fluorophenylthio)-7-nitrobenzo[c][1,2,5]oxadiazole

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

7-nitrobenzo[c][1,2,5]oxadiazole-4-thiol
16597-09-4

7-nitrobenzo[c][1,2,5]oxadiazole-4-thiol

Conditions
ConditionsYield
With sodium hydrogen sulfide In aq. buffer pH=7.4;
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

bis(4-fluorophenyl)disulfide
405-31-2

bis(4-fluorophenyl)disulfide

Conditions
ConditionsYield
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 20℃; for 0.0166667h;100%
With (S)-tetrahydrotellurophen-3-amine hydrochloride; dihydrogen peroxide In dichloromethane at 25℃; pH=7.5; Flow reactor;100%
With melamine hydrogen peroxide In acetonitrile for 0.25h; Reflux;99%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

4-fluorophenyl 4′-nitrophenyl sulfide
2438-85-9

4-fluorophenyl 4′-nitrophenyl sulfide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20 - 25℃; for 16h;100%
With potassium carbonate In N,N-dimethyl-formamide at 100℃;98%
With potassium hydroxide
(i) Na, EtOH, (ii) /BRN= 508691/; Multistep reaction;
With potassium carbonate In acetonitrile at 20℃; for 48h; Inert atmosphere;
2-iodo-propane
75-30-9

2-iodo-propane

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

1-Fluoro-4-(isopropylthio)benzene
702-13-6

1-Fluoro-4-(isopropylthio)benzene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃;100%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

4-fluorobenzenesulfinic acid lithium salt

4-fluorobenzenesulfinic acid lithium salt

Conditions
ConditionsYield
With methyllithium; N-(benzenesulfonyl)-3-phenyloxaziridine In tetrahydrofuran; diethyl ether at -78 - -10℃;100%
With methyllithium; N-(benzenesulfonyl)-3-phenyloxaziridine In tetrahydrofuran; diethyl ether at -78 - -40℃;
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

1-(tert-butoxycarbonyl)piperidin-4-yl methanesulfonate
141699-59-4

1-(tert-butoxycarbonyl)piperidin-4-yl methanesulfonate

tert-butyl 4-[(4-fluorophenyl)sulfanyl]piperidine-1-carboxylate
226398-48-7

tert-butyl 4-[(4-fluorophenyl)sulfanyl]piperidine-1-carboxylate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 18h; Heating / reflux;100%
With potassium carbonate In acetonitrile at 85℃;95%
With potassium carbonate In acetonitrile at 85℃;95%
With potassium carbonate In acetonitrile at 85℃;95%
With potassium carbonate In N,N-dimethyl-formamide at 70℃; for 7h;86%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

bromoacetic acid tert-butyl ester
5292-43-3

bromoacetic acid tert-butyl ester

2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester
212770-40-6

2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester

Conditions
ConditionsYield
100%
100%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

4-fluorophenyl-4-nitrophenyl sulfide

4-fluorophenyl-4-nitrophenyl sulfide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20 - 25℃; for 16h;100%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

tert-Butyl chloroacetate
107-59-5

tert-Butyl chloroacetate

2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester
212770-40-6

2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester

Conditions
ConditionsYield
With dmap; potassium carbonate In DMF (N,N-dimethyl-formamide) at 20℃;100%
8-chloro-3-iodo-quinoline
847727-21-3

8-chloro-3-iodo-quinoline

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

8-chloro-3-[(4-fluorophenyl)sulfanyl]quinoline
870301-30-7

8-chloro-3-[(4-fluorophenyl)sulfanyl]quinoline

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide In ethylene glycol at 20 - 80℃; for 18h;100%
With potassium phosphate; copper(l) iodide In ethylene glycol at 20 - 80℃; for 18h;100%
With copper(l) iodide; caesium carbonate In N,N-dimethyl-formamide at 100℃;94%
With potassium phosphate; copper(l) iodide In ethylene glycol at 20 - 80℃; for 18h;
2,2-dimethyl-3(2H)-furanone
35298-48-7

2,2-dimethyl-3(2H)-furanone

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

4-[(4-Fluorophenyl)sulfonyl]methyl-2,2-dimethyl-3(2H)-furanone

4-[(4-Fluorophenyl)sulfonyl]methyl-2,2-dimethyl-3(2H)-furanone

Conditions
ConditionsYield
With formaldehyd; triethylamine In ethanol100%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

2-bromo-5-[chloro(2,5-difluorophenyl)methyl]-4-methylpyridine
913091-70-0

2-bromo-5-[chloro(2,5-difluorophenyl)methyl]-4-methylpyridine

2-bromo-5-[(2,5-difluorophenyl)[(4-fluorophenyl)thio]methyl]-4-methylpyridine
913091-71-1

2-bromo-5-[(2,5-difluorophenyl)[(4-fluorophenyl)thio]methyl]-4-methylpyridine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 0 - 20℃; for 1h;100%
2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester
212770-40-6

2-(4-fluoro-benzenesulfanyl)-acetic acid tert-butyl ester

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

bromoacetic acid tert-butyl ester
5292-43-3

bromoacetic acid tert-butyl ester

2-(4-Fluoro-benzenesulfonyl)-2-pyridin-3-ylmethyl-hex-4-ynoic acid hydroxyamide

2-(4-Fluoro-benzenesulfonyl)-2-pyridin-3-ylmethyl-hex-4-ynoic acid hydroxyamide

Conditions
ConditionsYield
100%
4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

(2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide
206193-17-1

(2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide

(R)-Thiobicalutamide

(R)-Thiobicalutamide

Conditions
ConditionsYield
Stage #1: 4-Fluorothiophenol With sodium hydride In tetrahydrofuran; mineral oil
Stage #2: (2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide In tetrahydrofuran; mineral oil at 20℃; for 20h;
100%
Stage #1: 4-Fluorothiophenol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃;
Stage #2: (2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide In tetrahydrofuran; mineral oil at 0 - 20℃;
88%
Stage #1: 4-Fluorothiophenol With sodium hydride In tetrahydrofuran; mineral oil Inert atmosphere;
Stage #2: (2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide In tetrahydrofuran; mineral oil at 20℃; for 24h; Inert atmosphere;
60%
Stage #1: 4-Fluorothiophenol With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 0.5h; Inert atmosphere;
Stage #2: (2R)-3-bromo-N-[4-cyano-3-(trifluoromethyl)phenyl]-2-hydroxy-2-methylpropanamide In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;

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