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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Triphenylphosphine?sulfide with high purity

Cas:3878-45-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Triphenylphosphine sulfide

Cas:3878-45-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

3878-45-3 TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top qualityCAS 3878-45-3 with competitive price

Cas:3878-45-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phosphine sulfide,triphenyl- 3878-45-3

Cas:3878-45-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

TRIPHENYLPHOSPHINE SULFIDE CAS:3878-45-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

TRIPHENYLPHOSPHINE SULFIDE CAS:3878-45-3

Cas:3878-45-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Triphenylphosphine?sulfide

Cas:3878-45-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply Triphenylphosphine sulfide

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Other

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Triphenylphosphine sulfide

Cas:3878-45-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3878-45-3 CAS NO.3878-45-3

Cas:3878-45-3

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Triphenylphosphine Sulfide

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Triphenylphosphine sulfide

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Triphenylphosphine?Sulfide

Cas:3878-45-3

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Triphenylphosphine Sulfide

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

3878-45-3

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Triphenylphosphine sulfide cas 3878-45-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Triphenylphosphine sulfide cas 3878-45-3

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:5g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

Triphenylphosphine Sulfide

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

3878-45-3

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TRIPHENYLPHOSPHINE SULFIDE

Cas:3878-45-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

shanxiyuhong

Keywords Triphenylphosphine sulfide 99% Triphenylphosphine sulfide supplier High quality Triphenylphosphine sulfide Quick Details ProName: High quality Triphenylphosphine sulfid... CasNo: 3878-45-3 Molecular Formula: C18H15PS Appearance:

Phosphine sulfide,triphenyl-

Cas:3878-45-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

triphenylphosphine
603-35-0

triphenylphosphine

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With N,N-dimethyl-N'-(5-sulfanylidene-1,2,4-dithiazol-3-yl)methanimidamide In perdeuteriopyridine for 0.0833333h;99.9%
With sulfur In chloroform-d1 at 15 - 25℃; for 12h; Inert atmosphere; Sealed tube;99%
With (Et4N)2[MoVIO(S)(S2C2(COOMe)2)2] In acetonitrile at -40 - -25℃; for 5h; Kinetics; Activation energy; Equilibrium constant; Temperature;96%
phenylsulfenyl methyl thiocarbonate
61775-35-7

phenylsulfenyl methyl thiocarbonate

A

thiophenol
108-98-5

thiophenol

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

C

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
With triphenylphosphine In benzene Mechanism; Ambient temperature; reaction of var. sulfenyl thiocarbonates with triphenylphosphine;A 99%
B 1%
C 99%
2P(C6H5)3(C2H5)(1+)*Mo3S7Br6(2-)=(P(C6H5)3(C2H5))2Mo3S7Br6

2P(C6H5)3(C2H5)(1+)*Mo3S7Br6(2-)=(P(C6H5)3(C2H5))2Mo3S7Br6

Triphenylphosphine selenide
3878-44-2

Triphenylphosphine selenide

A

2P(C6H5)3(C2H5)(1+)*Mo3S4Se3Br6(2-)=(P(C6H5)3(C2H5))2Mo3S4Se3Br6

2P(C6H5)3(C2H5)(1+)*Mo3S4Se3Br6(2-)=(P(C6H5)3(C2H5))2Mo3S4Se3Br6

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In acetonitrile a suspension of (PPh3Et)2Mo3S7Br6 and SePPh3 in MeCN was boiled for 1 h under Ar;; toluene was added to the filtrate, filtn., washed with toluene, dried in vac.;;A n/a
B 99%
iodobenzene
591-50-4

iodobenzene

(hydroxymethyl)diphenylphosphine sulfide
96620-51-8

(hydroxymethyl)diphenylphosphine sulfide

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 40℃; for 3h;99%
iodobenzene
591-50-4

iodobenzene

(benzoyloxymethyl)diphenylphosphine sulfide
1420040-32-9

(benzoyloxymethyl)diphenylphosphine sulfide

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate In tetrahydrofuran at 70℃; for 2h; Inert atmosphere;99%
iodobenzene
591-50-4

iodobenzene

(t-butyldimethylsilyloxymethyl)diphenylphosphine sulfide
1420040-31-8

(t-butyldimethylsilyloxymethyl)diphenylphosphine sulfide

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; cesium fluoride In tetrahydrofuran at 70℃; for 12h; Inert atmosphere;99%
ethanol
64-17-5

ethanol

triphenylphosphine
603-35-0

triphenylphosphine

3-tert-butyl-5-phenyl-3H-[1,2,4]dithiazole
343783-49-3

3-tert-butyl-5-phenyl-3H-[1,2,4]dithiazole

A

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

B

N-(1-ethoxy-2,2-dimethyl-propyl)-thiobenzamide

N-(1-ethoxy-2,2-dimethyl-propyl)-thiobenzamide

Conditions
ConditionsYield
at 20℃; for 1h;A 72%
B 98%
5-phenyl-3H-1,2-dithiole-3-thione
3445-76-9

5-phenyl-3H-1,2-dithiole-3-thione

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With triphenylphosphine In xylene for 2h; Heating;97%
MoO(S2CNEt2)2(S2O)

MoO(S2CNEt2)2(S2O)

A

μ-oxobis[oxobis(N,N-diethyldithiocarbamato)molybdenum(V)]

μ-oxobis[oxobis(N,N-diethyldithiocarbamato)molybdenum(V)]

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With PPh3 In tetrahydrofuran (N2), stirred for 0.5 h; evapd. in high vac., triturated with diethyl ether, NMR;A 96%
B 60%
5-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetrathiagermolane
152291-64-0

5-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetrathiagermolane

triphenylphosphine
603-35-0

triphenylphosphine

A

[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germanethione
152291-63-9

[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germanethione

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In hexane refluxing (2 h),; filtration, concentration (Ar);A 96%
B 4%
bromobenzene
108-86-1

bromobenzene

(hydroxymethyl)diphenylphosphine sulfide
96620-51-8

(hydroxymethyl)diphenylphosphine sulfide

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 60℃; for 4h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere;96%
copper(I) trithioperoxy-p-toluate

copper(I) trithioperoxy-p-toluate

A

1,2,3;1,2,4;1,3,4;2,3,4-tetrakis(μ3-dithio-p-toluato-S,μ-S')-1,2-bis(triphenylphosphine)tetracopper(I)

1,2,3;1,2,4;1,3,4;2,3,4-tetrakis(μ3-dithio-p-toluato-S,μ-S')-1,2-bis(triphenylphosphine)tetracopper(I)

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With PPh3 In toluene addn. of PPh3 to suspn. of Cu-complex , dissolution, pptn.; treatment with light petroleum (b.p. 30-50°C), washing of PPH3S off (diethyl ether), recrystn. (CS2, ether); elem. anal.;A 95%
B n/a
{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)
84369-18-6

{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)

A

{(η5-C5H5)Re(NO)(PPh3)(CH2PPh3)}(+)PF6(-)
71763-25-2

{(η5-C5H5)Re(NO)(PPh3)(CH2PPh3)}(+)PF6(-)

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With triphenylphosphine In acetone stirred for 2 h under N2 atmosphere; CH2Cl2 was added, ether was slowly introduced by vapor diffusion, crystals of the Re-complex were collected after 2 d by filtration, PPh3S was isolated from the filtrate;A 95%
B 88%
p-Fluorophenylsulfenyl methyl thiocarbonate
72050-06-7

p-Fluorophenylsulfenyl methyl thiocarbonate

A

4-Fluorothiophenol
371-42-6

4-Fluorothiophenol

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

C

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
With triphenylphosphine In benzene Mechanism; Ambient temperature;A 90%
B 6%
C 94%
sulfur
10544-50-0

sulfur

trans-{PtCOPh(Cl)(PPh3)2}
18421-48-2

trans-{PtCOPh(Cl)(PPh3)2}

carbon monoxide
201230-82-2

carbon monoxide

A

PtCl(C6H5CO)(P(C6H5)3)(CO)

PtCl(C6H5CO)(P(C6H5)3)(CO)

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In chlorobenzene; benzene Kinetics; N2 atmosphere; addn. of solvents to mixt. of Pt-complex and S8 (room temp.), introduction of CO (10 atm, (31)P((1)H)-NMR monitoring), standing (room temp., 10 days); evapn. to dryness (vac.), mixt. of three complex isomers (60:27:13) not sepd.;A n/a
B 94%
Phenyl triflate
17763-67-6

Phenyl triflate

(hydroxymethyl)diphenylphosphine sulfide
96620-51-8

(hydroxymethyl)diphenylphosphine sulfide

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With 1,1'-bis(diisopropylphosphino)ferrocene; tetrabutylammomium bromide; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 60℃; for 3h; Reagent/catalyst; Inert atmosphere;94%
tris(2,6-dimethoxyphenyl)phosphibe sulfide
123317-05-5

tris(2,6-dimethoxyphenyl)phosphibe sulfide

triphenylphosphine
603-35-0

triphenylphosphine

A

Tris-(2,6-dimethoxy-phenyl)-phosphane; hydrochloride
123317-07-7

Tris-(2,6-dimethoxy-phenyl)-phosphane; hydrochloride

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With hydrogenchloride In acetone at 50℃; for 3h;A n/a
B 92%
5-phenyl-3H-1,2-dithiol-3-one
827-42-9

5-phenyl-3H-1,2-dithiol-3-one

ethanol
64-17-5

ethanol

A

ethyl ester of β-(mercapto)cinnamic acid
36367-20-1

ethyl ester of β-(mercapto)cinnamic acid

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With triphenylphosphine In chloroform for 2h; Heating;A 50%
B 91%
triphenylphosphine
603-35-0

triphenylphosphine

A

P,P,P-triphenylphosphine imide hydrochloride
21612-82-8

P,P,P-triphenylphosphine imide hydrochloride

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With S4N3Cl In acetonitrile at 30℃; for 24h; Product distribution; Mechanism; other cyclic sulphur-nitrogen chlorides; also in the presence of Et3N, pyridine or Na2CO3; var. solvents;A 91%
B 1.09 g
With S4N3Cl In acetonitrile for 24h; Ambient temperature;A 91%
B 0.35 g
morpholine
110-91-8

morpholine

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

A

methyl 2-morpholino-2-thioxoacetate
117081-21-7

methyl 2-morpholino-2-thioxoacetate

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With sulfur In toluene for 12h; Heating;A 75%
B 90%
diisopropoxyphosphinothionyl tert-butylamino trisulfide
76289-06-0

diisopropoxyphosphinothionyl tert-butylamino trisulfide

triphenylphosphine
603-35-0

triphenylphosphine

A

diisopropoxyphosphinothionyl tert-butylamino disulfide
76276-34-1

diisopropoxyphosphinothionyl tert-butylamino disulfide

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In diethyl ether at 0℃; for 0.25h;A 81.5%
B 90%
triphenylphosphine
603-35-0

triphenylphosphine

A

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

B

(dimethylthiocarbamoyl)triphenylphosphonium perchlorate

(dimethylthiocarbamoyl)triphenylphosphonium perchlorate

Conditions
ConditionsYield
With perchloric acid; (s-tetrathiane-3,6-diylidene)bis(dimethylammonium) diperchlorate In acetonitrile at 60℃;A 40%
B 90%
triphenylphosphine borane
2049-55-0

triphenylphosphine borane

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With oct-1-ene; sulfur In tetrahydrofuran for 24h; Heating;90%
bis(tetraethylammonium) tri-μ2-disulfido-μ3-thio-hexabromo-triangular-trimolybdenum(IV)

bis(tetraethylammonium) tri-μ2-disulfido-μ3-thio-hexabromo-triangular-trimolybdenum(IV)

Triphenylphosphine selenide
3878-44-2

Triphenylphosphine selenide

A

2N(C2H5)4(1+)*Mo3S4Se3Br6(2-)=(N(C2H5)4)2Mo3S4Se3Br6

2N(C2H5)4(1+)*Mo3S4Se3Br6(2-)=(N(C2H5)4)2Mo3S4Se3Br6

B

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In acetonitrile a suspension of (NEt4)2Mo3S7Br6 and SePPh3 in MeCN was boiled for 1 h under Ar;; toluene was added dropwise to the filtrate, soln. was allowed to stay at -5°C for 12 h, filtn., washed with toluene, dried in vac., elem. anal.;;A 90%
B >99
(s-tetrathiane-3,6-diylidene)bis(diethylammonium) diperchlorate

(s-tetrathiane-3,6-diylidene)bis(diethylammonium) diperchlorate

triphenylphosphine
603-35-0

triphenylphosphine

A

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

B

(diethylthiocarbamoyl)triphenylphosphonium perchlorate

(diethylthiocarbamoyl)triphenylphosphonium perchlorate

Conditions
ConditionsYield
With perchloric acid In acetonitrile for 0.0166667h; Heating;A 0.35 g
B 89%
triphenylphosphine
603-35-0

triphenylphosphine

A

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

B

(diethylthiocarbamoyl)triphenylphosphonium perchlorate

(diethylthiocarbamoyl)triphenylphosphonium perchlorate

Conditions
ConditionsYield
With perchloric acid; (s-tetrathiane-3,6-diylidene)bis(diethylammonium) diperchlorate In acetonitrile for 0.0166667h; Heating;A 0.35 g
B 89%
Dithiooxalsaeure-O,O'-dimethylester
54129-78-1

Dithiooxalsaeure-O,O'-dimethylester

1-triphenylphosphoranylidene-2-propanone
1439-36-7

1-triphenylphosphoranylidene-2-propanone

A

(2E)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester
85477-45-8

(2E)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester

B

(2Z)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester
85477-44-7

(2Z)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester

C

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
In benzene for 130h; Heating;A 23%
B 23%
C 89%
(pentamethylcyclopentadienyl)(cyclo-hexasulfido)(trimethylphosphane)iridium

(pentamethylcyclopentadienyl)(cyclo-hexasulfido)(trimethylphosphane)iridium

A

(pentamethylcyclopentadienyl)(cyclo-tetrasulfido)(trimethylphosphane)iridium

(pentamethylcyclopentadienyl)(cyclo-tetrasulfido)(trimethylphosphane)iridium

B

(pentamethylcyclopentadienyl)(cyclo-pentasulfido)(trimethylphosphane)iridium

(pentamethylcyclopentadienyl)(cyclo-pentasulfido)(trimethylphosphane)iridium

C

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With triphenylphosphane In dichloromethane (Ar), refluxed (40°C) for 40 min; column chromatography on silica gel (pentane/CH2Cl2 (2:1), pentane/CH2Cl2 (1:2), CH2Cl2), recrystallization from CHCl3/pentane at -25°C;A 9.4%
B 88.5%
C n/a
methylthiotriphenylphosphonium methylsulfate
113270-33-0

methylthiotriphenylphosphonium methylsulfate

A

methylthiol
74-93-1

methylthiol

B

dimethylsulfide
75-18-3

dimethylsulfide

C

triphenylphosphine
603-35-0

triphenylphosphine

D

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Conditions
ConditionsYield
With lithium chloride In methanol electrolysis; Further byproducts given;A n/a
B n/a
C 86%
D n/a
cyanomethylene triphenylphosphorane
16640-68-9

cyanomethylene triphenylphosphorane

A

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

B

1,2-Dicyanoethylene
764-42-1

1,2-Dicyanoethylene

Conditions
ConditionsYield
With sulfur In toluene for 3h; Heating;A 86%
B 60%
triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 20h; Mechanism; other thiophosphoramides are also investigated;100%
With 3,3-dimethyldioxirane In dichloromethane; acetone for 0.0833333h; Ambient temperature;100%
With pyridine; trifluoroacetic anhydride for 3h;100%
chloro(1,5-cyclooctadiene)rhodium(I) dimer

chloro(1,5-cyclooctadiene)rhodium(I) dimer

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

[Rh(1,5-cyclooctadiene)Cl(triphenylphosphinesulfide)]
460095-62-9

[Rh(1,5-cyclooctadiene)Cl(triphenylphosphinesulfide)]

Conditions
ConditionsYield
In dichloromethane under refluxing condition for 30 min; elem. anal.;99%
trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

(methylthio)triphenylphosphonium tetrafluoroborate

(methylthio)triphenylphosphonium tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane for 3h;97%
triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

triphenylphosphine
603-35-0

triphenylphosphine

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane In toluene at 80℃; for 1h; Product distribution; Further Variations:; Reaction partners; reaction times;96%
With n In tetrahydrofuran at 60℃; for 3h;95%
Stage #1: triphenylphosphine sulfide With oxalyl dichloride In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: With lithium aluminium tetrahydride In tetrahydrofuran; toluene at 20℃; for 0.5h; Inert atmosphere;
88%
triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

triphenylphosphine sulfide diiodine
55344-99-5

triphenylphosphine sulfide diiodine

Conditions
ConditionsYield
With iodine In dichloromethane for 4h;96%
With iodine In carbon disulfide at 20.3℃; Equilibrium constant;
dicarbonyldichlororuthenium

dicarbonyldichlororuthenium

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Ru(CO)2Cl2(P(C6H5)3S)
724703-32-6

Ru(CO)2Cl2(P(C6H5)3S)

Conditions
ConditionsYield
In methanol; dichloromethane PPh3S in CH2Cl2 added to (Ru(CO)2Cl2)n dissolved in CH3OH (1:1), reaction mixture stirred at room temp. for 2 h; solvent evapd. under vacuum, washed with Et2O, recrystallized from CH2Cl2, elem. anal.;96%
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

2,2′‐(1,4‐butanediyl)bis‐1,3‐benzoxazole
2008-10-8

2,2′‐(1,4‐butanediyl)bis‐1,3‐benzoxazole

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Cu(1+)*2C18H16N2O2*BF4(1-)*C18H15PS

Cu(1+)*2C18H16N2O2*BF4(1-)*C18H15PS

Conditions
ConditionsYield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; 2,2′‐(1,4‐butanediyl)bis‐1,3‐benzoxazole In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #2: triphenylphosphine sulfide In dichloromethane at 20℃; for 4h; Inert atmosphere;
94%
chloro(dimethylsulfide) gold(I)
29892-37-3

chloro(dimethylsulfide) gold(I)

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

chloro(triphenylphosphine sulfide)gold(I)
15279-72-8

chloro(triphenylphosphine sulfide)gold(I)

Conditions
ConditionsYield
In dichloromethane excess Ph3PS; concn. (vac.), Et2O addn., crystn. on cooling (refrigerator, overnight),filtration, washing (Et2O), drying (vac.); second crop from filtrate; e lem. anal.;93%
tris(η5-pentamethylcyclopentadienyl)samarium

tris(η5-pentamethylcyclopentadienyl)samarium

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

[(Sm(η5-C5Me5)2(tetrahydrofuran))2(μ-S)]

[(Sm(η5-C5Me5)2(tetrahydrofuran))2(μ-S)]

Conditions
ConditionsYield
In toluene byproducts: (C5Me5)2, PPh3; (Ar or N2); 3 days, solid PPh3 filtn. off; solvent removing (vac.), product washing (hexane), recrystn. (THF), solvent evapn. gave (C5Me5)2;93%
MoI2(CO)3(MeCN)2
102349-56-4

MoI2(CO)3(MeCN)2

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

iodo(tricarbonyl)tris(triphenylphosphinesulfide)molybdenum(II) iodide
131054-48-3

iodo(tricarbonyl)tris(triphenylphosphinesulfide)molybdenum(II) iodide

Conditions
ConditionsYield
In dichloromethane addn. of the ligand to Mo compd. in CH2Cl2 with stirring under N2, stirring for 2 h, addn. of further ligand and stirring for 18 h; filtn., removing of solvent (vac.) and recrystn. from CH2Cl2; elem. anal.;91%
silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

chloro(dicyclohexylamine)gold(I)
64704-71-8

chloro(dicyclohexylamine)gold(I)

triphenylphosphine sulfide
3878-45-3

triphenylphosphine sulfide

Au(P(C6H5)3S)2(1+)*PF6(1-)=[Au(P(C6H5)3S)2]PF6
64736-29-4

Au(P(C6H5)3S)2(1+)*PF6(1-)=[Au(P(C6H5)3S)2]PF6

Conditions
ConditionsYield
In dichloromethane byproducts: AgCl; stoich. amts. of Au-complex and ligand, 10 % excess of AgPF6; filtration off of AgCl, concn. (vac.), crystn. on Et2O addn. (refrigerator); elem. anal.;91%

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