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Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Manufacturers
inquiryDayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
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Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
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Cas:3878-45-3
Min.Order:10 Gram
FOB Price: $146.0 / 176.0
Type:Trading Company
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryTRIPHENYLPHOSPHINE SULFIDE CAS:3878-45-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic
Cas:3878-45-3
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:3878-45-3
Min.Order:0
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Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:3878-45-3
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Cas:3878-45-3
Min.Order:0
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Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:3878-45-3
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:3878-45-3
Min.Order:1 Kilogram
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Type:Lab/Research institutions
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Cas:3878-45-3
Min.Order:1 Metric Ton
FOB Price: $7.0 / 8.0
Type:Trading Company
inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
Cas:3878-45-3
Min.Order:0
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Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Cas:3878-45-3
Min.Order:100 Gram
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Type:Lab/Research institutions
inquiryR & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Cas:3878-45-3
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirySupply top quality products with a reasonable price Application:api
Triphenylphosphine sulfide cas 3878-45-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:3878-45-3
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta
Cas:3878-45-3
Min.Order:0
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Type:Lab/Research institutions
inquirygood quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:5g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port
Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen
bulk?production Application:Pharmaceutical intermediates
Cas:3878-45-3
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Keywords Triphenylphosphine sulfide 99% Triphenylphosphine sulfide supplier High quality Triphenylphosphine sulfide Quick Details ProName: High quality Triphenylphosphine sulfid... CasNo: 3878-45-3 Molecular Formula: C18H15PS Appearance:
Cas:3878-45-3
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryConditions | Yield |
---|---|
With N,N-dimethyl-N'-(5-sulfanylidene-1,2,4-dithiazol-3-yl)methanimidamide In perdeuteriopyridine for 0.0833333h; | 99.9% |
With sulfur In chloroform-d1 at 15 - 25℃; for 12h; Inert atmosphere; Sealed tube; | 99% |
With (Et4N)2[MoVIO(S)(S2C2(COOMe)2)2] In acetonitrile at -40 - -25℃; for 5h; Kinetics; Activation energy; Equilibrium constant; Temperature; | 96% |
phenylsulfenyl methyl thiocarbonate
A
thiophenol
B
triphenylphosphine sulfide
C
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triphenylphosphine In benzene Mechanism; Ambient temperature; reaction of var. sulfenyl thiocarbonates with triphenylphosphine; | A 99% B 1% C 99% |
Conditions | Yield |
---|---|
In acetonitrile a suspension of (PPh3Et)2Mo3S7Br6 and SePPh3 in MeCN was boiled for 1 h under Ar;; toluene was added to the filtrate, filtn., washed with toluene, dried in vac.;; | A n/a B 99% |
iodobenzene
(hydroxymethyl)diphenylphosphine sulfide
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 40℃; for 3h; | 99% |
iodobenzene
(benzoyloxymethyl)diphenylphosphine sulfide
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium ethanolate In tetrahydrofuran at 70℃; for 2h; Inert atmosphere; | 99% |
iodobenzene
(t-butyldimethylsilyloxymethyl)diphenylphosphine sulfide
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; cesium fluoride In tetrahydrofuran at 70℃; for 12h; Inert atmosphere; | 99% |
ethanol
triphenylphosphine
3-tert-butyl-5-phenyl-3H-[1,2,4]dithiazole
A
triphenylphosphine sulfide
Conditions | Yield |
---|---|
at 20℃; for 1h; | A 72% B 98% |
Conditions | Yield |
---|---|
With triphenylphosphine In xylene for 2h; Heating; | 97% |
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With PPh3 In tetrahydrofuran (N2), stirred for 0.5 h; evapd. in high vac., triturated with diethyl ether, NMR; | A 96% B 60% |
5-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetrathiagermolane
triphenylphosphine
A
[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](2,4,6-triisopropylphenyl)germanethione
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
In hexane refluxing (2 h),; filtration, concentration (Ar); | A 96% B 4% |
bromobenzene
(hydroxymethyl)diphenylphosphine sulfide
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 60℃; for 4h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; | 96% |
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With PPh3 In toluene addn. of PPh3 to suspn. of Cu-complex , dissolution, pptn.; treatment with light petroleum (b.p. 30-50°C), washing of PPH3S off (diethyl ether), recrystn. (CS2, ether); elem. anal.; | A 95% B n/a |
{(η5-C5H5)Re(NO)(PPh3)(η2-H2C=S)}(+)PF6(-)
A
{(η5-C5H5)Re(NO)(PPh3)(CH2PPh3)}(+)PF6(-)
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With triphenylphosphine In acetone stirred for 2 h under N2 atmosphere; CH2Cl2 was added, ether was slowly introduced by vapor diffusion, crystals of the Re-complex were collected after 2 d by filtration, PPh3S was isolated from the filtrate; | A 95% B 88% |
p-Fluorophenylsulfenyl methyl thiocarbonate
A
4-Fluorothiophenol
B
triphenylphosphine sulfide
C
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triphenylphosphine In benzene Mechanism; Ambient temperature; | A 90% B 6% C 94% |
sulfur
trans-{PtCOPh(Cl)(PPh3)2}
carbon monoxide
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
In chlorobenzene; benzene Kinetics; N2 atmosphere; addn. of solvents to mixt. of Pt-complex and S8 (room temp.), introduction of CO (10 atm, (31)P((1)H)-NMR monitoring), standing (room temp., 10 days); evapn. to dryness (vac.), mixt. of three complex isomers (60:27:13) not sepd.; | A n/a B 94% |
Phenyl triflate
(hydroxymethyl)diphenylphosphine sulfide
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With 1,1'-bis(diisopropylphosphino)ferrocene; tetrabutylammomium bromide; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 60℃; for 3h; Reagent/catalyst; Inert atmosphere; | 94% |
tris(2,6-dimethoxyphenyl)phosphibe sulfide
triphenylphosphine
A
Tris-(2,6-dimethoxy-phenyl)-phosphane; hydrochloride
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With hydrogenchloride In acetone at 50℃; for 3h; | A n/a B 92% |
5-phenyl-3H-1,2-dithiol-3-one
ethanol
A
ethyl ester of β-(mercapto)cinnamic acid
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With triphenylphosphine In chloroform for 2h; Heating; | A 50% B 91% |
triphenylphosphine
A
P,P,P-triphenylphosphine imide hydrochloride
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With S4N3Cl In acetonitrile at 30℃; for 24h; Product distribution; Mechanism; other cyclic sulphur-nitrogen chlorides; also in the presence of Et3N, pyridine or Na2CO3; var. solvents; | A 91% B 1.09 g |
With S4N3Cl In acetonitrile for 24h; Ambient temperature; | A 91% B 0.35 g |
morpholine
methyl (triphenylphosphoranylidene)acetate
A
methyl 2-morpholino-2-thioxoacetate
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With sulfur In toluene for 12h; Heating; | A 75% B 90% |
diisopropoxyphosphinothionyl tert-butylamino trisulfide
triphenylphosphine
A
diisopropoxyphosphinothionyl tert-butylamino disulfide
B
triphenylphosphine sulfide
Conditions | Yield |
---|---|
In diethyl ether at 0℃; for 0.25h; | A 81.5% B 90% |
Conditions | Yield |
---|---|
With perchloric acid; (s-tetrathiane-3,6-diylidene)bis(dimethylammonium) diperchlorate In acetonitrile at 60℃; | A 40% B 90% |
Conditions | Yield |
---|---|
With oct-1-ene; sulfur In tetrahydrofuran for 24h; Heating; | 90% |
Conditions | Yield |
---|---|
In acetonitrile a suspension of (NEt4)2Mo3S7Br6 and SePPh3 in MeCN was boiled for 1 h under Ar;; toluene was added dropwise to the filtrate, soln. was allowed to stay at -5°C for 12 h, filtn., washed with toluene, dried in vac., elem. anal.;; | A 90% B >99 |
Conditions | Yield |
---|---|
With perchloric acid In acetonitrile for 0.0166667h; Heating; | A 0.35 g B 89% |
Conditions | Yield |
---|---|
With perchloric acid; (s-tetrathiane-3,6-diylidene)bis(diethylammonium) diperchlorate In acetonitrile for 0.0166667h; Heating; | A 0.35 g B 89% |
Dithiooxalsaeure-O,O'-dimethylester
1-triphenylphosphoranylidene-2-propanone
A
(2E)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester
B
(2Z)-3-Acetyl-2-methoxythioacrylsaeure-O-methylester
C
triphenylphosphine sulfide
Conditions | Yield |
---|---|
In benzene for 130h; Heating; | A 23% B 23% C 89% |
C
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With triphenylphosphane In dichloromethane (Ar), refluxed (40°C) for 40 min; column chromatography on silica gel (pentane/CH2Cl2 (2:1), pentane/CH2Cl2 (1:2), CH2Cl2), recrystallization from CHCl3/pentane at -25°C; | A 9.4% B 88.5% C n/a |
methylthiotriphenylphosphonium methylsulfate
A
methylthiol
B
dimethylsulfide
C
triphenylphosphine
D
triphenylphosphine sulfide
Conditions | Yield |
---|---|
With lithium chloride In methanol electrolysis; Further byproducts given; | A n/a B n/a C 86% D n/a |
cyanomethylene triphenylphosphorane
A
triphenylphosphine sulfide
B
1,2-Dicyanoethylene
Conditions | Yield |
---|---|
With sulfur In toluene for 3h; Heating; | A 86% B 60% |
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 20h; Mechanism; other thiophosphoramides are also investigated; | 100% |
With 3,3-dimethyldioxirane In dichloromethane; acetone for 0.0833333h; Ambient temperature; | 100% |
With pyridine; trifluoroacetic anhydride for 3h; | 100% |
triphenylphosphine sulfide
[Rh(1,5-cyclooctadiene)Cl(triphenylphosphinesulfide)]
Conditions | Yield |
---|---|
In dichloromethane under refluxing condition for 30 min; elem. anal.; | 99% |
Conditions | Yield |
---|---|
In dichloromethane for 3h; | 97% |
Conditions | Yield |
---|---|
With 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane In toluene at 80℃; for 1h; Product distribution; Further Variations:; Reaction partners; reaction times; | 96% |
With n In tetrahydrofuran at 60℃; for 3h; | 95% |
Stage #1: triphenylphosphine sulfide With oxalyl dichloride In toluene at 20℃; for 0.166667h; Inert atmosphere; Stage #2: With lithium aluminium tetrahydride In tetrahydrofuran; toluene at 20℃; for 0.5h; Inert atmosphere; | 88% |
triphenylphosphine sulfide
triphenylphosphine sulfide diiodine
Conditions | Yield |
---|---|
With iodine In dichloromethane for 4h; | 96% |
With iodine In carbon disulfide at 20.3℃; Equilibrium constant; |
Conditions | Yield |
---|---|
In methanol; dichloromethane PPh3S in CH2Cl2 added to (Ru(CO)2Cl2)n dissolved in CH3OH (1:1), reaction mixture stirred at room temp. for 2 h; solvent evapd. under vacuum, washed with Et2O, recrystallized from CH2Cl2, elem. anal.; | 96% |
Conditions | Yield |
---|---|
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; 2,2′‐(1,4‐butanediyl)bis‐1,3‐benzoxazole In dichloromethane at 20℃; for 1h; Inert atmosphere; Stage #2: triphenylphosphine sulfide In dichloromethane at 20℃; for 4h; Inert atmosphere; | 94% |
chloro(dimethylsulfide) gold(I)
triphenylphosphine sulfide
chloro(triphenylphosphine sulfide)gold(I)
Conditions | Yield |
---|---|
In dichloromethane excess Ph3PS; concn. (vac.), Et2O addn., crystn. on cooling (refrigerator, overnight),filtration, washing (Et2O), drying (vac.); second crop from filtrate; e lem. anal.; | 93% |
triphenylphosphine sulfide
Conditions | Yield |
---|---|
In toluene byproducts: (C5Me5)2, PPh3; (Ar or N2); 3 days, solid PPh3 filtn. off; solvent removing (vac.), product washing (hexane), recrystn. (THF), solvent evapn. gave (C5Me5)2; | 93% |
MoI2(CO)3(MeCN)2
triphenylphosphine sulfide
iodo(tricarbonyl)tris(triphenylphosphinesulfide)molybdenum(II) iodide
Conditions | Yield |
---|---|
In dichloromethane addn. of the ligand to Mo compd. in CH2Cl2 with stirring under N2, stirring for 2 h, addn. of further ligand and stirring for 18 h; filtn., removing of solvent (vac.) and recrystn. from CH2Cl2; elem. anal.; | 91% |
silver(I) hexafluorophosphate
chloro(dicyclohexylamine)gold(I)
triphenylphosphine sulfide
Au(P(C6H5)3S)2(1+)*PF6(1-)=[Au(P(C6H5)3S)2]PF6
Conditions | Yield |
---|---|
In dichloromethane byproducts: AgCl; stoich. amts. of Au-complex and ligand, 10 % excess of AgPF6; filtration off of AgCl, concn. (vac.), crystn. on Et2O addn. (refrigerator); elem. anal.; | 91% |
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