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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methoxyacetophenone

Cas:4079-52-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 4079-52-1 with best quality

Cas:4079-52-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethanone,2-methoxy-1-phenyl- 4079-52-1

Cas:4079-52-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-METHOXYACETOPHENONE CAS:4079-52-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

2-METHOXYACETOPHENONE CAS:4079-52-1

Cas:4079-52-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methoxyacetophenone

Cas:4079-52-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

N-(3-aminopropyl)Acetamide

Cas:4079-52-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Methoxyacetophenone

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

N-(3-aminopropyl)Acetamide

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethanone, 2-Methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

Ethanone,2-methoxy-1-phenyl- cas 4079-52-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Ethanone,2-methoxy-1-phenyl- cas 4079-52-1

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-Methoxyacetophenone

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-METHOXYACETOPHENONE

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

4079-52-1

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-METHOXYACETOPHENONE

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei youze Biotechnology Co.,Ltd

Our Advantage 1.Best quality with competitive price. 2.Quick shipping,delivery on time. 3.We have a pharmaceutical raw material production plant and a reagent R&D center. 4.Support multiple trading methods and payment.We support wire transfer

2-Methoxyacetophenone CAS 4079-52-1 Phenyl methoxymethyl ketone

Cas:4079-52-1

Min.Order:1 Kilogram

FOB Price: $6.8 / 8.6

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Ethanone,2-methoxy-1-phenyl- CAS NO.4079-52-1

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Shuokang Biological Technology Co.,Ltd

Company Profile ShuoKang biotechnology co., LTD. Is located in wuhan, China, is a collection research and development, production, sales for the integration of medicine and chemical industry leader, the company has been to high-quality product

Superior quality 2-METHOXYACETOPHENONE

Cas:4079-52-1

Min.Order:5 Gram

FOB Price: $50.0

Type:Trading Company

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Nanjing Chemlin Chemical Co., Ltd.

Compound sourcing ServicesAgency of testing serviceFactory audit serviceFounded in Dec. 1999, Nanjing Chemlin Chemical Industrial Co.,Ltd(CHEMLIN) has been covering the business scope from trading of chemicals to custom-synthesis & Manufacturing. Co

4079-52-1

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-METHOXYACETOPHENONE, CAS:4079-52-1 with the most competitive price and the best qua

2-METHOXYACETOPHENONE

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Ethanone,2-methoxy-1-phenyl- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Ethanone,2-methoxy-1-phenyl-

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

4079-52-1

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

2-Methoxyacetophenone

Cas:4079-52-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1-phenyl-1,1,2-trimethoxyethane
143191-51-9

1-phenyl-1,1,2-trimethoxyethane

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With hydrogenchloride100%
1-acetoxy-1-fluoro-1-phenyl-2-methoxyethane
143191-50-8

1-acetoxy-1-fluoro-1-phenyl-2-methoxyethane

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With base100%
methanol
67-56-1

methanol

acetophenone
98-86-2

acetophenone

A

iodoacetophenone
4636-16-2

iodoacetophenone

B

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With ammonium iodide; Oxone for 2.3h; Reflux;A 92%
B 6%
N-methoxy-N-methylbenzamide
6919-61-5

N-methoxy-N-methylbenzamide

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With 4,4'-di-tert-butylbiphenyl; lithium In tetrahydrofuran; mineral oil at -78℃; for 2.5h; Inert atmosphere; Schlenk technique;91%
methanol
67-56-1

methanol

2-diazo-acetophenone
3282-32-4

2-diazo-acetophenone

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
In(OSO2CF3)3 at 20℃; for 0.0333333h;90%
With montmorillonite K-1087%
at 25℃; for 1h; Green chemistry;87%
methanol
67-56-1

methanol

1-styrenyloxytrimethylsilane
13735-81-4

1-styrenyloxytrimethylsilane

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With Ph[I(OH)OTf] 18-crown-6 complex monohydrate at -78 - 20℃; for 7h;87%
With C6H6BF4IO*C12H24O6 In dichloromethane at -70 - 20℃; for 4.5h; Reagent/catalyst; Inert atmosphere;87%
With iodosylbenzene; boron trifluoride diethyl etherate at -70 - 25℃; for 3.5h; Mechanism; var. silyl enol ethers;78%
methoxydimethyl((1-phenylvinyl)oxy)silane
1638623-53-6

methoxydimethyl((1-phenylvinyl)oxy)silane

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene In dichloromethane at 25℃; Inert atmosphere; Schlenk technique;86%
1-styrenyloxytrimethylsilane
13735-81-4

1-styrenyloxytrimethylsilane

methyl hypofluorite
36336-08-0

methyl hypofluorite

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
In chloroform; acetonitrile at -40 - 20℃;85%
2-methoxy-1-phenylethanol
3587-84-6

2-methoxy-1-phenylethanol

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; butanedial; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; for 1h;83%
With chlorine-triphenylphosphine; dimethyl sulfoxide; triethylamine In dichloromethane at -78 - 20℃; for 3.25h;70%
With bromopentacarbonylmanganese(I); N-methyl-N,N-di(2-pyridylmethyl)amine; acetone; sodium t-butanolate In toluene at 90℃; for 24h; Inert atmosphere; Schlenk technique; Darkness;35 %Chromat.
methanol
67-56-1

methanol

acetophenone
98-86-2

acetophenone

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide; toluene-4-sulfonic acid hydrazide In water at 20℃; for 16h; Mechanism; Temperature; Reagent/catalyst; Schlenk technique;83%
2-methoxy-1-phenylethanol
3587-84-6

2-methoxy-1-phenylethanol

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; butanedial; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; for 1h;A 83%
B n/a
2-methoxyacetonitrile
1738-36-9

2-methoxyacetonitrile

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
Stage #1: 2-methoxyacetonitrile; phenylmagnesium chloride With copper(l) iodide In tetrahydrofuran for 0.5h; Reflux; Inert atmosphere;
Stage #2: With sulfuric acid In tetrahydrofuran; water at 0 - 20℃; for 18h; Inert atmosphere;
82%
Stage #1: 2-methoxyacetonitrile; phenylmagnesium chloride With copper(l) iodide In tetrahydrofuran for 0.5h; Reflux;
Stage #2: With sulfuric acid In tetrahydrofuran; water at 20℃;
15%
(methoxymethyl)triphenylphosphonium chloride
4009-98-7

(methoxymethyl)triphenylphosphonium chloride

benzonitrile
100-47-0

benzonitrile

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
Stage #1: (methoxymethyl)triphenylphosphonium chloride With phenyllithium In tetrahydrofuran at 0℃; for 0.166667h; Dehydrochlorination;
Stage #2: benzonitrile In tetrahydrofuran at 20℃; for 2h; Alkylation;
Stage #3: With water In tetrahydrofuran Hydrolysis;
81%
methanol
67-56-1

methanol

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

2,2-dimethoxy-1-phenylethanone
6956-56-5

2,2-dimethoxy-1-phenylethanone

C

methyl 2-methoxy-2-phenylacetate
3558-61-0

methyl 2-methoxy-2-phenylacetate

Conditions
ConditionsYield
With perchloric acid; thallium(III) nitrate at 20℃; for 5h;A 8%
B 80%
C 11%
benzonitrile
100-47-0

benzonitrile

(methoxymethyl)diphenylphosphine oxide
4455-77-0

(methoxymethyl)diphenylphosphine oxide

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With phenyllithium In tetrahydrofuran Alkylation;80%
bromobenzene
108-86-1

bromobenzene

2-methoxyacetonitrile
1738-36-9

2-methoxyacetonitrile

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
Stage #1: bromobenzene With iodine; magnesium In tetrahydrofuran at 40 - 70℃; for 3h; Inert atmosphere;
Stage #2: 2-methoxyacetonitrile In tetrahydrofuran for 48h; Inert atmosphere;
80%
sodium methylate
124-41-4

sodium methylate

1-chloroacetophenone
532-27-4

1-chloroacetophenone

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

1-phenyl-2-hydroxyethanone
582-24-1

1-phenyl-2-hydroxyethanone

Conditions
ConditionsYield
In methanol at 25℃; Kinetics; Concentration;A 27.3%
B 73.8%
1-benzoyl-1,3-dimethoxyacetone
130895-63-5

1-benzoyl-1,3-dimethoxyacetone

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With hydrogenchloride In methanol at 50℃; for 20h;71%
methanol
67-56-1

methanol

acetophenone
98-86-2

acetophenone

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

C

2,2-dimethoxy-1-phenylethanone
6956-56-5

2,2-dimethoxy-1-phenylethanone

D

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With perchloric acid; thallium(III) nitrate at 20℃; for 5h; Product distribution; Mechanism; effect of the presence of HClO4;A 2%
B 8%
C 2%
D 71%
3-(methoxymethyl)-3-phenyldioxetane
161925-21-9

3-(methoxymethyl)-3-phenyldioxetane

A

2-amino-1,9-dihydro-6H-purin-6-one
73-40-5

2-amino-1,9-dihydro-6H-purin-6-one

B

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

C

3-methoxy-2-phenylpropane-1,2-diol

3-methoxy-2-phenylpropane-1,2-diol

D

2',3',5'-tri-O-acetyl-8-methoxyguanosine

2',3',5'-tri-O-acetyl-8-methoxyguanosine

Conditions
ConditionsYield
With 2',3',5'-triacetylguanosine In methanol at 0℃; for 36h; Further byproducts given;A n/a
B 70%
C 12%
D n/a
sodium methylate
124-41-4

sodium methylate

α-bromoacetophenone
70-11-1

α-bromoacetophenone

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

1-phenyl-2-hydroxyethanone
582-24-1

1-phenyl-2-hydroxyethanone

Conditions
ConditionsYield
In methanol at 25℃; Kinetics; Concentration;A 36.3%
B 67.2%
ethyl 2-methoxyacetate
3938-96-3

ethyl 2-methoxyacetate

phenylmagnesium bromide

phenylmagnesium bromide

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

1-hydroxy-2-methoxy-1,1-diphenylethane
14704-09-7

1-hydroxy-2-methoxy-1,1-diphenylethane

Conditions
ConditionsYield
In diethyl ether at -78 - 20℃;A 29%
B 67%
methanol
67-56-1

methanol

para-methylacetophenone
122-00-9

para-methylacetophenone

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

methyl p-tolylacetate
23786-13-2

methyl p-tolylacetate

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; hydrogen cation at 60℃; for 1h; oxidative rearrangement;A 11%
B 67%
methanol
67-56-1

methanol

[bis(acetoxy)iodo]benzene
3240-34-4

[bis(acetoxy)iodo]benzene

phenylacetylene
536-74-3

phenylacetylene

A

2-acetoxyacetophenone
2243-35-8

2-acetoxyacetophenone

B

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

C

2-methoxy-1-phenylvinyl acetate
1191256-36-6

2-methoxy-1-phenylvinyl acetate

Conditions
ConditionsYield
at 70℃; for 12h;A 66%
B 13%
C 6%
methanol
67-56-1

methanol

C17H14F3O3Tl
112481-60-4

C17H14F3O3Tl

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Conditions
ConditionsYield
With iodosylbenzene; boron trifluoride diethyl etherate Product distribution; other α-metallo ketones; other alcohol;65%
methanol
67-56-1

methanol

1-phenylbutan-1,3-dione
93-91-4

1-phenylbutan-1,3-dione

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With iodosylbenzene; boron trifluoride diethyl etherate for 8h; Mechanism; Ambient temperature;A 63%
B 24%
With iodosylbenzene; boron trifluoride diethyl etherate for 8h; Ambient temperature;A 63%
B 24%
styrene
292638-84-7

styrene

methanol
67-56-1

methanol

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

2-methoxy-1-phenylethyl hydroperoxide

2-methoxy-1-phenylethyl hydroperoxide

C

benzaldehyde
100-52-7

benzaldehyde

Conditions
ConditionsYield
With oxygen; magnesium oxide; 9-(2-mesityl)-10-methylacridinium perchlorate In ethyl acetate at 20℃; for 10h; Reagent/catalyst; Time; Solvent; Irradiation; Green chemistry;A 6 %Spectr.
B 63%
C 8 %Spectr.
morpholine
110-91-8

morpholine

3-(methoxymethyl)-3-phenyldioxetane
161925-21-9

3-(methoxymethyl)-3-phenyldioxetane

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

N-(2-Hydroxy-3-methoxy-2-phenylpropoxy)morpholine

N-(2-Hydroxy-3-methoxy-2-phenylpropoxy)morpholine

Conditions
ConditionsYield
In dichloromethane at 0℃; for 0.2h;A 1%
B 62%
3-(methoxymethyl)-3-phenyldioxetane
161925-21-9

3-(methoxymethyl)-3-phenyldioxetane

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

N-(2-Hydroxy-3-methoxy-2-phenylpropoxy)morpholine

N-(2-Hydroxy-3-methoxy-2-phenylpropoxy)morpholine

Conditions
ConditionsYield
With morpholine In dichloromethane at 0℃; for 0.2h;A 1%
B 62%
methanol
67-56-1

methanol

acetophenone
98-86-2

acetophenone

A

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

B

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene at 60℃; for 1h;A 17%
B 59%
With [hydroxy(tosyloxy)]iodobenzene for 36h; Mechanism; Ambient temperature; var. p-substituted acetophenones, other reagents;A 10%
B 57%
With [hydroxy(tosyloxy)]iodobenzene for 36h; Ambient temperature;A 10%
B 57%
With [bis(acetoxy)iodo]benzene; sulfuric acid at 60℃; for 1h;A 21%
B 56%
With [bis(acetoxy)iodo]benzene; hydrogen cation at 60℃; for 1h; oxidative rearrangement;A 21%
B 56%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

(R)-Phenylglycinol
56613-80-0

(R)-Phenylglycinol

(R)-2,4-diphenyl-2-(methoxymethyl)-1,3-oxazolidine
103621-11-0, 103621-12-1

(R)-2,4-diphenyl-2-(methoxymethyl)-1,3-oxazolidine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 72h; Heating;100%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

allyltributylstanane
24850-33-7

allyltributylstanane

1-methoxy-2-phenylpent-4-en-2-ol

1-methoxy-2-phenylpent-4-en-2-ol

Conditions
ConditionsYield
With tin(ll) chloride In acetonitrile for 1h;100%
5-iodoisatin
20780-76-1

5-iodoisatin

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

6-iodo-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

6-iodo-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; potassium hydroxide In ethanol for 72h; Heating;100%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

allylmagnesium bromide
2622-05-1

allylmagnesium bromide

1-methoxy-2-phenylpent-4-en-2-ol

1-methoxy-2-phenylpent-4-en-2-ol

Conditions
ConditionsYield
Stage #1: methoxymethyl phenyl ketone; allylmagnesium bromide In tetrahydrofuran at 20℃; for 3h;
Stage #2: With water; ammonium chloride In tetrahydrofuran
100%
In tetrahydrofuran at -78℃; Inert atmosphere;100%
Stage #1: methoxymethyl phenyl ketone; allylmagnesium bromide In tetrahydrofuran at 20℃; for 3h;
Stage #2: With water; ammonium chloride In tetrahydrofuran
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

3-methoxy-2-phenyl-2-(trimethylsilyloxy)propionitrile
137057-20-6

3-methoxy-2-phenyl-2-(trimethylsilyloxy)propionitrile

Conditions
ConditionsYield
indium(III) bromide In dichloromethane at 20℃; for 0.5h;99%
With indium(III) bromide In dichloromethane at 20℃; for 0.5h;99%
With zinc(II) iodide In dichloromethane for 24h; Ambient temperature;
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

(E)-cinnamyl(tributyl)tin
74785-32-3

(E)-cinnamyl(tributyl)tin

(2S,3R)-1-methoxy-2,3-diphenyl-4-penten-2-ol

(2S,3R)-1-methoxy-2,3-diphenyl-4-penten-2-ol

Conditions
ConditionsYield
With tin(ll) chloride In acetonitrile at 20℃; for 3h;99%
4-bromo-trans-crotonic acid ethyl ester
37746-78-4

4-bromo-trans-crotonic acid ethyl ester

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

ethyl (E)-5-hydroxy-6-methoxy-5-phenylhex-2-enoate

ethyl (E)-5-hydroxy-6-methoxy-5-phenylhex-2-enoate

Conditions
ConditionsYield
With indium In tetrahydrofuran at 20℃; for 20h;99%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

benzaldehyde
100-52-7

benzaldehyde

(l,u,l,l)-3,5-dimethoxy-2,4,6-triphenyltetrahydro-2H-pyran-2,4-diol

(l,u,l,l)-3,5-dimethoxy-2,4,6-triphenyltetrahydro-2H-pyran-2,4-diol

Conditions
ConditionsYield
Stage #1: methoxymethyl phenyl ketone With lithium diisopropyl amide In tetrahydrofuran; hexane at -40℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: With indium(III) chloride In tetrahydrofuran; hexane at -40 - 25℃; for 1.5h; Inert atmosphere; Schlenk technique;
Stage #3: benzaldehyde In tetrahydrofuran; hexane at 67℃; for 1h; Reagent/catalyst; Temperature; Aldol Addition; Inert atmosphere; Schlenk technique;
99%
2-aminopyridine
504-29-0

2-aminopyridine

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

3-Methoxy-2-phenylimidazo<1,2-a>pyridine
89192-94-9

3-Methoxy-2-phenylimidazo<1,2-a>pyridine

Conditions
ConditionsYield
With iodine In 1,2-dichloro-ethane at 100℃; for 0.5h;96%
With copper(l) iodide; oxygen In 1,2-dichloro-ethane at 100℃; under 760.051 Torr; Sealed tube;71%
With copper(l) iodide; oxygen In 1,2-dichloro-ethane at 100℃; for 16h;71%
3-chloro-cyclohexene
2441-97-6

3-chloro-cyclohexene

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

C15H20O2

C15H20O2

Conditions
ConditionsYield
With indium In tetrahydrofuran at 20℃; for 5h;95%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

Cinnamyl bromide
4392-24-9

Cinnamyl bromide

C18H20O2

C18H20O2

Conditions
ConditionsYield
With indium In tetrahydrofuran; water at 20℃; for 16h;95%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

(R)-3-methoxy-2-phenyl-2-trimethylsilyloxypropanenitrile
1402458-64-3

(R)-3-methoxy-2-phenyl-2-trimethylsilyloxypropanenitrile

Conditions
ConditionsYield
With tert-butyl methyl ether; Ru[t-leu]2[(S)-binap]; lithium phenolate at -40℃; for 2h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;95%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

C6H5COCH2OCH(2)H2

C6H5COCH2OCH(2)H2

Conditions
ConditionsYield
With [D]-sodium hydroxide; deuteromethanol; water-d2 for 21h; Reflux;95%
iodobenzene
591-50-4

iodobenzene

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

benzoin monomethyl ether
3524-62-7

benzoin monomethyl ether

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 60℃; for 13h; Inert atmosphere; Schlenk technique;94%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With ammonium chloride; zinc In ethanol for 0.5h; Heating;93%
With 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine cobalt(II)dichloride; bis(pinacol)diborane; sodium t-butanolate In tetrahydrofuran; methanol at 65℃; for 24h; Schlenk technique; Inert atmosphere;30%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

2-methoxy-1-phenylethanol
3587-84-6

2-methoxy-1-phenylethanol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0 - 20℃; for 3.5h;92%
With sodium tetrahydroborate In methanol at 0 - 20℃; Inert atmosphere;86%
84%
methanol
67-56-1

methanol

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

methyl 2-oxo-2-phenylacetate
15206-55-0

methyl 2-oxo-2-phenylacetate

Conditions
ConditionsYield
With bromine for 1h; Heating;92%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

tributyl(cyclohex-2-en-1-yl)stannane
112520-99-7, 1177092-71-5

tributyl(cyclohex-2-en-1-yl)stannane

(S)-1-((R)-cyclohex-2-enyl)-2-methoxy-1-phenylethanol

(S)-1-((R)-cyclohex-2-enyl)-2-methoxy-1-phenylethanol

Conditions
ConditionsYield
With tin(ll) chloride In acetonitrile at 20℃; for 3h;92%
2-methoxyacetophene

2-methoxyacetophene

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

isopropyl alcohol
67-63-0

isopropyl alcohol

(R)-2-methoxy-1-phenyl-ethanol
109459-34-9

(R)-2-methoxy-1-phenyl-ethanol

Conditions
ConditionsYield
With potassium tert-butylate In tert-butyl alcohol92%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

methyl 2-oxo-2-phenylacetate
15206-55-0

methyl 2-oxo-2-phenylacetate

Conditions
ConditionsYield
With iodine; sodium carbonate In 1,2-dichloro-ethane at 60℃; for 3h; Time;92%
6-fluoroisatin
324-03-8

6-fluoroisatin

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

7-fluoro-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

7-fluoro-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; potassium hydroxide In ethanol for 72h; Heating;90%
7-iodoisatin
20780-78-3

7-iodoisatin

methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

8-iodo-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

8-iodo-3-methoxy-2-phenylquinoline-4-carboxylic acid hydrochloride

Conditions
ConditionsYield
With hydrogenchloride; potassium hydroxide In ethanol for 72h; Heating;90%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

2-bromobutyric acid ethyl ester
533-68-6

2-bromobutyric acid ethyl ester

ethyl 3-hydroxy-4-methoxy-2-methyl-3-phenylbutyrate

ethyl 3-hydroxy-4-methoxy-2-methyl-3-phenylbutyrate

Conditions
ConditionsYield
With indium In tetrahydrofuran Reformatsky-type reaction; Heating;90%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

C15H22O2
1046828-28-7

C15H22O2

Conditions
ConditionsYield
Stage #1: 2,3-dimethyl-buta-1,3-diene With dichloroindium hydride In tetrahydrofuran at 20℃; for 5h;
Stage #2: methoxymethyl phenyl ketone With water In tetrahydrofuran at 20℃; for 14h; regioselective reaction;
90%
methoxymethyl phenyl ketone
4079-52-1

methoxymethyl phenyl ketone

tetraphenylethane-1,2-diol
464-72-2

tetraphenylethane-1,2-diol

A

benzophenone
119-61-9

benzophenone

B

C22H22O3

C22H22O3

Conditions
ConditionsYield
With titanium(IV) tetrabutoxide; triethylsilyl chloride In dichloromethane at 20℃;A n/a
B 90%

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