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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

3-Fluorobenzoic acid 455-38-9 Manufacturer/High quality/Best price/In stock

Cas:455-38-9

Min.Order:1 Kilogram

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Nanyang Junhao Chemical Co.,Ltd

3-Fluorobenzoic acidProduct name: 3-Fluorobenzoic acidCAS: 455-38-9Structural formula:Quality specification:Appearance: White powderContent: 98.0%(HPLC)minMelting point: 122-124℃Appearance:White powder Storage:Sealed and preserved Package:200/Kilogra

3-Fluorobenzoic acid99%

Cas:455-38-9

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-Fluorobenzoic acid Manufacturer/High quality/Best price/In stock

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3-Fluorobenzoicacid with high purity

Cas:455-38-9

Min.Order:1 Kilogram

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Gram

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EAST CHEMSOURCES LIMITED

3-Fluorobenzoic acid Product name: 3-Fluorobenzoic acid CAS: 455-38-9 Structural formula: Quality specification: Appearance: White powder Content: 98.0%(HPLC)min Melting point: 122-124℃ Our Server 1. Competitive offers with standa

3-Fluorobenzoic acid manufacturers

Cas:455-38-9

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Kilogram

FOB Price: $5.0

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--455-38-9--3-Fluorobenzoic acid factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business re

TIANFUCHEM--455-38-9--3-Fluorobenzoic acid factory price

Cas:455-38-9

Min.Order:1 Metric Ton

FOB Price: $2000.0

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 3-Fluorobenzoic acid CAS No. 455-38-9

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top CAS 455-38-9 with best quality

Cas:455-38-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 3-Fluorobenzoic acid Synonyms: 3-fluorobenzoate CAS:455-38-9 MF: C7H4FO2 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Organic Synthesis Transportation:By sea or b

3-Fluorobenzoic acid CAS:455-38-9

Cas:455-38-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3-Fluorobenzoic acid 455-38-9

Cas:455-38-9

Min.Order:1 Kilogram

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

3-Fluorobenzoic acid cas:455-38-9

Cas:455-38-9

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:10 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:0

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:100 Gram

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS455-38-9 3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Kilogram

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:0 Metric Ton

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

3-FLUOROBENZOIC ACID

Cas:455-38-9

Min.Order:1 Gram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:0

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:0 Metric Ton

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Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:off white crystalline powder Storage:In Room Temperature Package:25kg/drum, or as per your request. Application:For medicine , pesticide intermediates Transportation: as per your

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Kilogram

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Siwei Development Group Ltd.

Product name: 3-Fluorobenzoic Acid CAS No.: 455-38-9 Molecule Formula:C7H4FO2 Molecule Weight:139.10 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

Lower Price 3-Fluorobenzoic Acid

Cas:455-38-9

Min.Order:1 Kilogram

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Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

3-Fluorobenzoic acid Chemical Properties Melting point 122-124 °C (lit.) Boiling point 226.1°C (rough estimate) density 1.474 storage temp. Refrigerator solubility 1.5g/l pka 3.86(at 25℃) form Powder color White

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Gram

FOB Price: $65.0

Type:Lab/Research institutions

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

hot sale 3-Fluorbenzoesaeure

Cas:455-38-9

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3-Fluorobenzoic acid

Cas:455-38-9

Min.Order:1 Metric Ton

FOB Price: $1.5

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Synthetic route

3-Fluorobenzaldehyde
456-48-4

3-Fluorobenzaldehyde

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With potassium ferrate(VI) In neat (no solvent) for 2h; Milling;98.9%
With oxygen; copper(II) acetate monohydrate; cobalt(II) diacetate tetrahydrate In water at 70℃; under 760.051 Torr; for 12h;98%
With oxygen; Langlois reagent In acetonitrile at 25℃; under 760.051 Torr; for 12h; Irradiation; Green chemistry;95%
m-Fluorotoluene
352-70-5

m-Fluorotoluene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With oxygen; pyridinium chlorochromate In water at 120℃; under 45004.5 Torr; for 2h;95%
With copper(l) iodide; oxygen; nitric acid at 160℃; under 11251.1 - 18751.9 Torr; for 4.7h; Autoclave;84.7%
With cerium(III) chloride; 1,1,1-trichloroethanol; oxygen In acetonitrile at 60℃; Irradiation;83%
meta-aminobenzoic acid
99-05-8

meta-aminobenzoic acid

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With pyridine hydrogenfluoride; sodium nitrite 1.) O deg C, 20 min, 2.) 80 deg C, 1 h;95%
With hydrogen fluoride; sodium nitrite
Ueberfuehrung in die Diazoaminoverbindung und Zersetzung mit rauchender Fluorwasserstoffsaeure;
With pyridine; hydrogen fluoride; sodium nitrite 1.) room temperature, 2.) 0 deg C, 3.) 80 deg C; Yield given. Multistep reaction;
Stage #1: meta-aminobenzoic acid With sodium nitrite at 70℃; for 1.5h; Schiemann Aromatic Fluorination;
Stage #2: With hydrogen fluoride; boric acid
Stage #3: In toluene at 110℃;
3-fluoro-benzenemethanol
456-47-3

3-fluoro-benzenemethanol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With dichloro(1,5-cyclooctadiene)ruthenium(II); C30H30N3P2(1+)*Cl(1-); potassium hydroxide In toluene at 120℃; for 24h; Inert atmosphere; Schlenk technique;94%
With lithium hydroxide monohydrate; oxygen In water at 25℃; for 12h;93%
With picoline; tert.-butylhydroperoxide; chlorophyllin coppered trisodium salt In water at 80℃; for 15h; Temperature; chemoselective reaction;93%
3-Fluoro-benzoic acid benzyl ester

3-Fluoro-benzoic acid benzyl ester

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With palladium diacetate; sodium hydride In N,N-dimethyl acetamide at 60℃; for 3h; Inert atmosphere;94%
With palladium diacetate; sodium hydride In N,N-dimethyl acetamide at 50℃; for 5h; Inert atmosphere;94%
3-fluoro(nitromethyl)benzene

3-fluoro(nitromethyl)benzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With water; tetra-(n-butyl)ammonium iodide at 80℃; for 15h; Reagent/catalyst;91%
With zinc diacetate; water; tetra-(n-butyl)ammonium iodide at 80℃; for 24h;90%
With tetra-(n-butyl)ammonium iodide; acetic acid In water at 80℃; for 15h; Reagent/catalyst;84%
1-(3-fluorophenyl)ethane-1,2-diol
1041469-36-6

1-(3-fluorophenyl)ethane-1,2-diol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With tert.-butylhydroperoxide; potassium tert-butylate In water at 80℃; for 8h;87%
carbon dioxide
124-38-9

carbon dioxide

3-fluorophenyl sulfofluoridate

3-fluorophenyl sulfofluoridate

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With manganese; bis(triphenylphosphine)nickel(II) chloride; 2.9-dimethyl-1,10-phenanthroline In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 20h; Schlenk technique; Inert atmosphere; Glovebox;87%
3-fluorophthalic acid
1583-67-1

3-fluorophthalic acid

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With acetic acid; silver carbonate In dimethyl sulfoxide at 120℃; for 16h; regioselective reaction;86%
With [Au(1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene)(O2CAd)] In toluene at 120℃; regioselective reaction;
methanol
67-56-1

methanol

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

carbon monoxide
201230-82-2

carbon monoxide

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

methyl 3-fluorobenzoate
455-68-5

methyl 3-fluorobenzoate

Conditions
ConditionsYield
With tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 7h; Irradiation;A 8%
B 85%
2,4-dimethylthiosemicarbazide
6621-75-6

2,4-dimethylthiosemicarbazide

3-fluorobenzoyl chloride
1711-07-5

3-fluorobenzoyl chloride

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

5-(3-fluorophenyl)-2,4-dihydro-2,4-dimethyl-3H-1,2,4-triazole-3-thione
110623-33-1

5-(3-fluorophenyl)-2,4-dihydro-2,4-dimethyl-3H-1,2,4-triazole-3-thione

Conditions
ConditionsYield
With sodium hydroxide In water; toluene at 50 - 84℃; for 1.75h; Kinetics; Temperature; Large scale;A n/a
B 85%
1-ethyl-3-fluorobenzene
696-39-9

1-ethyl-3-fluorobenzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With 1-hydroxy-pyrrolidine-2,5-dione; oxygen; nitric acid at 90℃; under 1500.15 - 6000.6 Torr; for 30h; Autoclave; Green chemistry;84.13%
1-ethynyl-3-fluoro-benzene
2561-17-3

1-ethynyl-3-fluoro-benzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
Stage #1: 1-ethynyl-3-fluoro-benzene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h;
Stage #2: With hydrogenchloride In water at 20℃;
83%
With hydroxylamine hydrochloride; iodine In dimethyl sulfoxide at 100℃; for 8h;60%
1-Fluoro-3-iodobenzene
1121-86-4

1-Fluoro-3-iodobenzene

H2O*CHLiO2

H2O*CHLiO2

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With formic acid; 1,3-bis-(diphenylphosphino)propane; nickel(II) acetate tetrahydrate; acetic anhydride In tetrahydrofuran at 100℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;81%
1-Fluoro-3-iodobenzene
1121-86-4

1-Fluoro-3-iodobenzene

lithium formate monohydrate
6108-23-2

lithium formate monohydrate

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel(0); formic acid; 1,3-bis-(diphenylphosphino)propane; acetic anhydride In tetrahydrofuran at 100℃; for 24h; Schlenk technique; Inert atmosphere;81%
3-fluorobenzamide
455-37-8

3-fluorobenzamide

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With niobium(V) oxide; water In neat (no solvent) for 24h; Reflux; Inert atmosphere;80%
With hydrogenchloride In 1,4-dioxane at 90℃; for 3h; Rate constant;
2-(3-fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

2-(3-fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

carbon dioxide
124-38-9

carbon dioxide

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
Stage #1: 2-(3-fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane; carbon dioxide With [Ni(N,N'-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazole-2-ylidene)(allyl)Cl]; potassium tert-butylate In toluene at 100℃; under 760.051 Torr; for 15h; Schlenk technique; Inert atmosphere;
Stage #2: With hydrogenchloride In water; ethyl acetate; toluene at 20℃;
78%
diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

3-Fluorobenzaldehyde
456-48-4

3-Fluorobenzaldehyde

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

3-(3-Fluorophenyl)acrylic acid ethyl ester
351-46-2

3-(3-Fluorophenyl)acrylic acid ethyl ester

Conditions
ConditionsYield
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester; 3-Fluorobenzaldehyde With potassium carbonate for 6h; Horner-Wadsworth-Emmons olefination; Neat (no solvent); high-speed ball milling;
Stage #2: With Oxone for 12h; Neat (no solvent); high-speed ball milling; optical yield given as %de; diastereoselective reaction;
A n/a
B 77%
carbon dioxide
124-38-9

carbon dioxide

3-fluorophenol
372-20-3

3-fluorophenol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
Stage #1: 3-fluorophenol With fluorosulfonyl fluoride; sodium hydride In N,N-dimethyl-formamide for 0.5h;
Stage #2: carbon dioxide With manganese; bis(triphenylphosphine)nickel(II) chloride; 2.9-dimethyl-1,10-phenanthroline In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 20h; Schlenk technique; Inert atmosphere; Glovebox;
73%
carbon dioxide
124-38-9

carbon dioxide

3-chlorofluorobenzene
625-98-9

3-chlorofluorobenzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With manganese; 2,9-dibutyl-4,7-dimethyl-1,10-phenanthroline; tetraethylammonium iodide; lithium acetate; cobalt(II) bromide In N,N-dimethyl acetamide at 100℃; under 760.051 Torr; for 12h; Inert atmosphere; Schlenk technique;71%
Stage #1: 3-chlorofluorobenzene With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide In tetrahydrofuran at 40℃; for 6h; Inert atmosphere; Schlenk technique;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; Schlenk technique;
60%
1-(3-fluorophenyl)cyclohexanol
1496-35-1

1-(3-fluorophenyl)cyclohexanol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With iron(III) chloride; cerium(III) chloride; tetrabutyl-ammonium chloride; oxygen In acetonitrile at 20℃; under 760.051 Torr; for 24h; Schlenk technique; Irradiation;71%
1-(3-fluorophenyl)ethanone
455-36-7

1-(3-fluorophenyl)ethanone

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With copper(l) iodide; hydroxylamine hydrochloride; oxygen In dimethyl sulfoxide at 100℃; for 10h;65%
With hydroxylamine hydrochloride; iodine In dimethyl sulfoxide at 100℃; for 5h;64%
With sodium hydroxide; potassium chloride; potassium hexacyanoferrate(III) In methanol; water at 30℃; Kinetics; further temperature;
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

carbon dioxide
124-38-9

carbon dioxide

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With manganese; 2.9-dimethyl-1,10-phenanthroline; lithium acetate; cobalt(II) bromide In N,N-dimethyl acetamide at 20℃; under 760.051 Torr; for 12h; Inert atmosphere; Schlenk technique;64%
4-bromo-2-chloro-5-fluorobenzoic acid
177480-81-8

4-bromo-2-chloro-5-fluorobenzoic acid

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

2-chloro-5-fluoro-benzoic acid
2252-50-8

2-chloro-5-fluoro-benzoic acid

Conditions
ConditionsYield
With triethanolamine; C33H21IrN3O9S3(3-) In water for 6h; Alkaline conditions; Inert atmosphere; Irradiation;A 60%
B n/a
3-fluoro-benzenemethanol
456-47-3

3-fluoro-benzenemethanol

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

3-Fluorobenzaldehyde
456-48-4

3-Fluorobenzaldehyde

Conditions
ConditionsYield
With picoline; tert.-butylhydroperoxide; chlorophyllin coppered trisodium salt In water at 60℃; for 12h; Temperature; chemoselective reaction;A 35%
B 56%
carbon dioxide
124-38-9

carbon dioxide

1-Fluoro-3-iodobenzene
1121-86-4

1-Fluoro-3-iodobenzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With copper(l) iodide; N,N,N,N,-tetramethylethylenediamine; diethylzinc In N,N-dimethyl acetamide at 70℃; under 760.051 Torr;55%
Stage #1: 1-Fluoro-3-iodobenzene With copper In tetrahydrofuran at 25℃; for 0.5h;
Stage #2: carbon dioxide In tetrahydrofuran for 24h;
31%
Stage #1: carbon dioxide; 1-Fluoro-3-iodobenzene With tert.-butyl lithium In pentane at -70℃; Inert atmosphere;
Stage #2: With sulfuric acid; water In pentane at 20℃; Inert atmosphere;
17%
potassium cyanide

potassium cyanide

4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With ethanol In water at 85℃; for 50h; von Richter Aromatic Carboxylation; Ionic liquid;52%
carbon dioxide
124-38-9

carbon dioxide

3-fluorophenyl 4-methylbenzenesulfonate
57606-64-1

3-fluorophenyl 4-methylbenzenesulfonate

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With manganese; (2,2'-bipyridine)nickel(II) dibromide In N,N-dimethyl-formamide at 60℃; under 760.051 Torr;51%
tris[2-perfluorohexylethyl]tin-3-benzoic acid

tris[2-perfluorohexylethyl]tin-3-benzoic acid

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Conditions
ConditionsYield
With fluorine In FC-72 at -85℃; for 0.583333h;24%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

carbon monoxide
201230-82-2

carbon monoxide

A

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

B

methyl 3-fluorobenzoate
455-68-5

methyl 3-fluorobenzoate

Conditions
ConditionsYield
With methanol; tert-Amyl alcohol; sodium hydride; cobalt(II) acetate In tetrahydrofuran at 40℃; under 760 Torr; for 7h; Irradiation;A 8%
B 8%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

3-fluorobenzoyl chloride
1711-07-5

3-fluorobenzoyl chloride

Conditions
ConditionsYield
Stage #1: 3-fluorobenzoic acid With N,N-dimethyl-formamide In dichloromethane at 0℃; for 0.0833333h;
Stage #2: With oxalyl dichloride In dichloromethane at 20℃; for 12h;
100%
With thionyl chloride Heating;87%
With phosphorus pentachloride
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

methyl 2-(4-(1H-pyrazol-1-yl)phenyl)-2-aminoacetate hydrochloride

methyl 2-(4-(1H-pyrazol-1-yl)phenyl)-2-aminoacetate hydrochloride

methyl 2-(4-(1H-pyrazol-1-yl)phenyl)-2-(3-fluorobenzamido)-acetate

methyl 2-(4-(1H-pyrazol-1-yl)phenyl)-2-(3-fluorobenzamido)-acetate

Conditions
ConditionsYield
With 6-chloro-3-((dimethylamino)(dimethyliminio)methyl)-1H-benzo[d][1,2,3]triazol-3-ium-1-olatehexafluorophosphate(V); N-ethyl-N,N-diisopropylamine In dichloromethane; N,N-dimethyl-formamide at 20℃; for 2.25h;100%
para-iodoanisole
696-62-8

para-iodoanisole

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

4'-fluoro-4,4''-dimethoxy-[1,1':3',1''-terphenyl]-2'-carboxylic acid

4'-fluoro-4,4''-dimethoxy-[1,1':3',1''-terphenyl]-2'-carboxylic acid

Conditions
ConditionsYield
With C30H54N6Ru(2+)*2BF4(1-); potassium perfluoro-tert-butoxide; potassium carbonate at 140℃; for 24h; Glovebox; Inert atmosphere;99%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

L-leucine ethyl ester hydrochloride
2743-40-0

L-leucine ethyl ester hydrochloride

ethyl (3-fluorobenzoyl)-L-leucinate

ethyl (3-fluorobenzoyl)-L-leucinate

Conditions
ConditionsYield
Stage #1: 3-fluorobenzoic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0℃;
Stage #2: L-leucine ethyl ester hydrochloride In N,N-dimethyl-formamide at 0 - 20℃;
99%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

benzylamine
100-46-9

benzylamine

N-benzyl-3-fluorobenzamide
671-01-2

N-benzyl-3-fluorobenzamide

Conditions
ConditionsYield
With borane-ammonia complex In 5,5-dimethyl-1,3-cyclohexadiene for 6h; Reflux;99%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

3-chlorodibenzo[b,d]bromol-5-ium methanesulfonate

3-chlorodibenzo[b,d]bromol-5-ium methanesulfonate

2'-bromo-4-chloro-[1,1'-biphenyl]-2-yl 3-fluorobenzoate

2'-bromo-4-chloro-[1,1'-biphenyl]-2-yl 3-fluorobenzoate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 16h; Inert atmosphere; Schlenk technique;99%
propan-1-ol
71-23-8

propan-1-ol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

propyl 3-fluorobenzoate

propyl 3-fluorobenzoate

Conditions
ConditionsYield
With sulfated zirconia at 130℃; for 1h; Catalytic behavior; Temperature; Time; Microwave irradiation;98.5%
bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)osmium(III)
120752-10-5, 214534-64-2

bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)osmium(III)

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

Os(SC6F5)2(FC6H4COO)(P(CH3)2C6H5)2

Os(SC6F5)2(FC6H4COO)(P(CH3)2C6H5)2

Conditions
ConditionsYield
In acetone (air); shaking (room temp., 48 h); solvent removal (vac.), washing (EtOH), crystn. (acetone-EtOH); elem. anal.;98%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

N-biphenyl-4-yl-3-oxo-3-piperazin-1-yl-propionamide hydrochloride
1187890-09-0

N-biphenyl-4-yl-3-oxo-3-piperazin-1-yl-propionamide hydrochloride

N-biphenyl-4-yl-3-[4-(3-fluoro-benzoyl)-piperazin-1-yl]-3-oxo-propionamide
1187889-62-8

N-biphenyl-4-yl-3-[4-(3-fluoro-benzoyl)-piperazin-1-yl]-3-oxo-propionamide

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 10 - 20℃;98%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

N-methoxy-2-(prop-1-en-2-yl)benzamide

N-methoxy-2-(prop-1-en-2-yl)benzamide

(2-methoxy-1-methyl-3-oxoisoindolin-1-yl)methyl 3-fluorobenzoate

(2-methoxy-1-methyl-3-oxoisoindolin-1-yl)methyl 3-fluorobenzoate

Conditions
ConditionsYield
With [2,2]bipyridinyl; oxygen; palladium diacetate In tetrahydrofuran at 60℃; under 760.051 Torr; for 12h; Schlenk technique; Molecular sieve;98%
Cyclohexyl isocyanide
931-53-3

Cyclohexyl isocyanide

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

4-[2,2-bis(trimethylsilyl)ethenyl]benzaldehyde
1268519-27-2

4-[2,2-bis(trimethylsilyl)ethenyl]benzaldehyde

(cyclohexylcarbamoyl)(4-(2,2-bis(trimethylsilyl)vinyl)phenyl)methyl 3-fluorobenzoate

(cyclohexylcarbamoyl)(4-(2,2-bis(trimethylsilyl)vinyl)phenyl)methyl 3-fluorobenzoate

Conditions
ConditionsYield
In water at 20℃; for 1.5h; Passerini Condensation;98%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

5-fluoro-2-nitrobenzoic acid
320-98-9

5-fluoro-2-nitrobenzoic acid

Conditions
ConditionsYield
With sulfuric acid; nitric acid97%
With sulfuric acid; nitric acid; phosphorus pentoxide at 0℃; for 3h;95%
With sulfuric acid; nitric acid at 0 - 20℃; for 1h;93%
dichloromethane
75-09-2

dichloromethane

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

bis(3-fluorobenzoyloxy)methane

bis(3-fluorobenzoyloxy)methane

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 60℃; for 3h;97%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

(S)-methyl 2-(tert-butoxy)-2-(6-(p-tolyl)-4,7-bis(trifluoromethyl)isoindolin-5-yl)acetate

(S)-methyl 2-(tert-butoxy)-2-(6-(p-tolyl)-4,7-bis(trifluoromethyl)isoindolin-5-yl)acetate

(S)-methyl 2-(tert-butoxy)-2-(2-(3-fluorobenzoyl)-6-(p-tolyl)-4,7-bis(trifluoromethyl)isoindolin-5-yl)acetate

(S)-methyl 2-(tert-butoxy)-2-(2-(3-fluorobenzoyl)-6-(p-tolyl)-4,7-bis(trifluoromethyl)isoindolin-5-yl)acetate

Conditions
ConditionsYield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine In ethyl acetate for 1h;97%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

(2S)-ethyl 2-(tert-butoxy)-2-((M)-8-(8-fluoro-5-methylchroman-6-yl)-6,9-dimethyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)acetate

(2S)-ethyl 2-(tert-butoxy)-2-((M)-8-(8-fluoro-5-methylchroman-6-yl)-6,9-dimethyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)acetate

(S)-ethyl 2-(tert-butoxy)-2-((M)-8-(8-fluoro-5-methylchroman-6-yl)-3-(3-fluorobenzoyl)-6,9-dimethyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)acetate

(S)-ethyl 2-(tert-butoxy)-2-((M)-8-(8-fluoro-5-methylchroman-6-yl)-3-(3-fluorobenzoyl)-6,9-dimethyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)acetate

Conditions
ConditionsYield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine In ethyl acetate at 20℃; for 1.16667h;96%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

N-isocyaniminotriphenylphosphorane
73789-56-7

N-isocyaniminotriphenylphosphorane

dimethylglyoxal
431-03-8

dimethylglyoxal

3-[5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl]-3-hydroxybutan-2-one
1278591-63-1

3-[5-(3-fluorophenyl)-1,3,4-oxadiazol-2-yl]-3-hydroxybutan-2-one

Conditions
ConditionsYield
In water at 20 - 26℃; for 12h; Green chemistry;95%
In dichloromethane at 20℃; for 12.25h; tandem Passerini/intramolecular aza-Wittig reaction;90%
ethyl 2,3,4-tri-O-benzyl-1-thio-α-D-glucopyranoside
39483-51-7

ethyl 2,3,4-tri-O-benzyl-1-thio-α-D-glucopyranoside

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

ethyl 2,3,4-tri-O-benzyl-6-O-(3-fluorobenzoyl)-1-thio-α-D-glucopyranoside

ethyl 2,3,4-tri-O-benzyl-6-O-(3-fluorobenzoyl)-1-thio-α-D-glucopyranoside

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 18h;95%
1-methylindole
603-76-9

1-methylindole

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

C25H19FN2O2

C25H19FN2O2

Conditions
ConditionsYield
With silver carbonate; palladium dichloride In dimethyl sulfoxide; N,N-dimethyl-formamide at 80℃; for 7h;95%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

1-(2-methyl-6-amino-4-phenylquinolin-3-yl)ethanone

1-(2-methyl-6-amino-4-phenylquinolin-3-yl)ethanone

N‑(3‑acetyl‑2‑methyl‑4‑phenylquinolin‑6‑yl)‑3‑fluorobenzamide

N‑(3‑acetyl‑2‑methyl‑4‑phenylquinolin‑6‑yl)‑3‑fluorobenzamide

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 20℃; for 1h;95%
p-hydroxyphenethyl alcohol
501-94-0

p-hydroxyphenethyl alcohol

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

4-hydroxyphenethyl 3-fluorobenzoate

4-hydroxyphenethyl 3-fluorobenzoate

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃; for 48h; Schlenk technique; Inert atmosphere;95%
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 20℃; for 24h;
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

dibenzo[b,d]bromol-5-ium methanesulfonate

dibenzo[b,d]bromol-5-ium methanesulfonate

2'-bromo-[1,1'-biphenyl]-3-yl 3-fluorobenzoate

2'-bromo-[1,1'-biphenyl]-3-yl 3-fluorobenzoate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 16h; Inert atmosphere; Schlenk technique;95%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

22-(2-aminoethylsulfanyl)-22-deoxypleuromutilin

22-(2-aminoethylsulfanyl)-22-deoxypleuromutilin

22-(2-(3-fluorobenzoylamino)ethylsulfanyl)-22-deoxypleuromutilin

22-(2-(3-fluorobenzoylamino)ethylsulfanyl)-22-deoxypleuromutilin

Conditions
ConditionsYield
With O‑(6‑chlorobezotriazol‑1‑yl)‑N,N,N,N‑tetramethyluronium hexafluorophosphate; triethylamine In ethyl acetate at 70℃; for 1h;94.15%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

aniline
62-53-3

aniline

3-fluoro-N-phenylbenzamide
1629-09-0

3-fluoro-N-phenylbenzamide

Conditions
ConditionsYield
With oxygen; lithium hydroxide In water at 20℃; for 14h; Sonication;94%
3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

1-(3-fluoro-4-(piperazine-1-yl)phenyl)butane-1-one

1-(3-fluoro-4-(piperazine-1-yl)phenyl)butane-1-one

1-(3-fluoro-4-(4-(3-fluorobenzoyl)piperazine-1-yl)phenyl)butane-1-one

1-(3-fluoro-4-(4-(3-fluorobenzoyl)piperazine-1-yl)phenyl)butane-1-one

Conditions
ConditionsYield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 22h;94%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

3-fluorobenzoic acid
455-38-9

3-fluorobenzoic acid

1-(3-fluorobenzoyl)benzotriazole
670231-03-5

1-(3-fluorobenzoyl)benzotriazole

Conditions
ConditionsYield
With thionyl chloride In dichloromethane for 2h; Inert atmosphere;93%
With thionyl chloride In dichloromethane at 20℃;80%

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