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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1,3,5-Tri(4-carboxyphenyl)benzene Manufacturer/High quality/Best price/In stock

Cas:50446-44-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3,5-Tris-(4-carboxyphenyl)-benzene

Cas:50446-44-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Pure CAS 50446-44-1 with competitive price

Cas:50446-44-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: 1,3,5-Tri(4-carboxyphenyl)benzene Synonyms: 4-[3,5-bis(4-carboxyphenyl)phenyl]benzoic acid;1,3,5-Tri(4-carboxyphenyl)benzene;1,3,5-Tris(4-carboxyphenyl)benzene >=98%, <=20 wt. % solvent;H3BTB;4',4'',4''&#

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

1,3,5-Tri(4-carboxyphenyl)benzene CAS:50446-44-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

1,3,5-Tri(4-carboxyphenyl)benzene CAS:50446-44-1

Cas:50446-44-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:50446-44-1

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Shanghai Massive Chemical Technology Co., Ltd. is engaged in development, production and marketing Specialty Chemicals to satisfy the changing needs of the chemical industry. We specialize in manufacturing high quality of Advanced Intermediates, Sp

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:1 Gram

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Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

1,3,5-Tris(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

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Type:Lab/Research institutions

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as:

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:1 Gram

Negotiable

Type:Manufacturers

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,3,5-tris(4-Carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

4-[3,5-bis(4-carboxyphenyl)phenyl]benzoic acid

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1,3,5-Tri(4-carboxyphenyl)benzene 25g

Cas:50446-44-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,3,5-Tris(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Fandachem Co.,Ltd

1,3,5-Tri(4-carboxyphenyl)benzene cas 50446-44-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,3,5-Tri(4-carboxyphenyl)benzene cas 50446-44-1

Cas:50446-44-1

Min.Order:0

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Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

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Type:Lab/Research institutions

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 797 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Organic catalyst

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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Hunan Longxianng Runhui Trading Co.,Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

1,3,5-Tris(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

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Type:Lab/Research institutions

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Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:250mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any po

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Other

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Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

50446-44-1

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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Shanghai Puhao Chemical Technology Co. Ltd.

Our company's tenet is to treat every customer sincerely and be responsible for every product. The production of products according to customer demand for customized, in strict accordance with strict requirements, the production of products always wi

Buy High purity of 1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

1,3,5-Tri(4-carboxyphenyl)benzene

Cas:50446-44-1

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

1,3,5-tris(4-methyl-phenyl)-benzene
50446-43-0

1,3,5-tris(4-methyl-phenyl)-benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
With pyridine; ammonium cerium (IV) nitrate; dihydrogen peroxide; sodium carbonate; cobalt(II) nitrate at 110℃; under 15001.5 Torr; for 6h; Reagent/catalyst; Temperature; Pressure; Green chemistry;97%
With 2-aminoisonicotinic acid; oxygen; antimony(III) acetate; acetic anhydride; acetic acid; potassium nitrate; 1-aza-adamantane-1-oxide; Dimethyl succinate In 1,2-dichloro-benzene at 180℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Solvent; Temperature; Pressure;92%
With dihydrogen peroxide; sodium carbonate at 100℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Solvent;90%
With nitric acid at 160 - 180℃; im geschlossenen Rohr;
With nitric acid at 170℃;
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate
117100-41-1

dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
With methanol; sodium hydroxide In tetrahydrofuran92%
With water; sodium hydroxide In tetrahydrofuran; methanol92%
With water; sodium hydroxide In tetrahydrofuran; methanol92%
carbon dioxide
124-38-9

carbon dioxide

1,3,5-tris(4-hydroxyphenyl)benzene
15797-52-1

1,3,5-tris(4-hydroxyphenyl)benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 90℃; electrochemical reaction;75%
1-[4-[3,5-bis(4-acetylphenyl)phenyl]phenyl]ethanone

1-[4-[3,5-bis(4-acetylphenyl)phenyl]phenyl]ethanone

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
With bromine; sodium hydroxide In 1,4-dioxane; water at 60℃; for 2h;75%
With sodium hypobromide In 1,4-dioxane at 60℃; for 2h;
carbon dioxide
124-38-9

carbon dioxide

1,3,5-tris(4-bromophenyl)benzene
7511-49-1

1,3,5-tris(4-bromophenyl)benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -60℃;60%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -60℃;
Stage #2: carbon dioxide In tetrahydrofuran; hexane at -60 - 20℃;
57%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -60℃; Inert atmosphere;
Stage #2: carbon dioxide at -60℃;
33%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -65 - -60℃; for 1h; Inert atmosphere;
Stage #2: carbon dioxide With hydrogenchloride In tetrahydrofuran; hexane; water at -65 - -60℃; for 1h; Inert atmosphere;
0.29 g
carbon dioxide
124-38-9

carbon dioxide

1,3,5-tris(4-hydroxyphenyl)benzene
15797-52-1

1,3,5-tris(4-hydroxyphenyl)benzene

A

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

B

1,3-bis(4-carboxyphenyl)-5-(4-hydroxyphenyl)benzene

1,3-bis(4-carboxyphenyl)-5-(4-hydroxyphenyl)benzene

Conditions
ConditionsYield
bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 90℃; electrochemical reaction;A 43%
B 34%
4-Ethynyl-benzoic acid
10602-00-3

4-Ethynyl-benzoic acid

A

poly((4-carboxyphenyl)acetylene), Mn (GPC): ca. 2000 g/mol

poly((4-carboxyphenyl)acetylene), Mn (GPC): ca. 2000 g/mol

B

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
at 125℃; for 72h; Title compound not separated from byproducts.;
4-acetophenyl triflate
109613-00-5

4-acetophenyl triflate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo
2: 67 percent / dimethylformamide / Ambient temperature; electrolysis
3: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
Multi-step reaction with 3 steps
1: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo
2: 67 percent / dimethylformamide / Ambient temperature; electrolysis
3: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
4-Hydroxyacetophenone
99-93-4

4-Hydroxyacetophenone

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: triethylamine / CH2Cl2 / -50 deg C (1 h) to r.t (8 h)
2: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo
3: 67 percent / dimethylformamide / Ambient temperature; electrolysis
4: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
Multi-step reaction with 4 steps
1: triethylamine / CH2Cl2 / -50 deg C (1 h) to r.t (8 h)
2: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo
3: 67 percent / dimethylformamide / Ambient temperature; electrolysis
4: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
1,3,5-tris[4-[(trifluoromethanesulfonyl)oxy]phenyl]benzene
214049-70-4

1,3,5-tris[4-[(trifluoromethanesulfonyl)oxy]phenyl]benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 67 percent / dimethylformamide / Ambient temperature; electrolysis
2: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
Multi-step reaction with 2 steps
1: 67 percent / dimethylformamide / Ambient temperature; electrolysis
2: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction
View Scheme
para-bromoacetophenone
99-90-1

para-bromoacetophenone

HNO3+H2SO4

HNO3+H2SO4

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 41 percent / triethyl orthoformate
2: 60 percent / 1.6 M n-BuLi / tetrahydrofuran; hexane / -60 °C
View Scheme
methyl 4-acetylbenzoate
3609-53-8

methyl 4-acetylbenzoate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene-4-sulfonic acid; toluene
View Scheme
Multi-step reaction with 2 steps
1: toluene
View Scheme
toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene
View Scheme
para-methylacetophenone
122-00-9

para-methylacetophenone

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrogen chloride
2: nitric acid / 160 - 180 °C / im geschlossenen Rohr
View Scheme
para-methylacetophenone
122-00-9

para-methylacetophenone

W2(OCH2-t-Bu)6(O)(CMe2)(py)

W2(OCH2-t-Bu)6(O)(CMe2)(py)

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: AlCl3 / 210 °C
2: aq. HNO3 / 170 °C
View Scheme
C33H30O6
50446-45-2

C33H30O6

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
With water; sodium hydroxide1.18 g
carbon dioxide
124-38-9

carbon dioxide

para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Stage #1: para-bromoacetophenone
Stage #2: With n-butyllithium
Stage #3: carbon dioxide
para-bromoacetophenone
99-90-1

para-bromoacetophenone

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sulfuric acid; potassium hydrogensulfate / 18 h / 180 °C
1.2: 7 h / Reflux
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -65 - -60 °C / Inert atmosphere
2.2: 1 h / -65 - -60 °C / Inert atmosphere
View Scheme
1,3,5-trisbromobenzene
626-39-1

1,3,5-trisbromobenzene

4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: cesium fluoride; tetrakis(triphenylphosphine) palladium(0) / 1,2-dimethoxyethane / 48 h / Schlenk technique; Inert atmosphere; Reflux
2: methanol; sodium hydroxide / tetrahydrofuran
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); cesium fluoride / 1,2-dimethoxyethane / 48 h / Schlenk technique; Inert atmosphere; Reflux
2: water; sodium hydroxide / tetrahydrofuran; methanol
View Scheme
4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 4 h / 110 °C / 6000.6 Torr / Inert atmosphere; Microwave irradiation
2: sodium hydroxide / tetrahydrofuran; methanol / 16 h / 20 °C
View Scheme
4-carboxyphenylboronic acid
14047-29-1

4-carboxyphenylboronic acid

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: thionyl chloride / 2.5 h / 50 °C / Inert atmosphere
2: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 4 h / 110 °C / 6000.6 Torr / Inert atmosphere; Microwave irradiation
3: sodium hydroxide / tetrahydrofuran; methanol / 16 h / 20 °C
View Scheme
4,4'-bipyridine
553-26-4

4,4'-bipyridine

2NO3(1-)*Co(1+)*6H2O

2NO3(1-)*Co(1+)*6H2O

2NO3(1-)*Ni(1+)*6H2O

2NO3(1-)*Ni(1+)*6H2O

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

3C10H8N2*4C27H15O6(3-)*0.7Ni(2+)*5.3Co(2+)*43C3H7NO*67H2O

3C10H8N2*4C27H15O6(3-)*0.7Ni(2+)*5.3Co(2+)*43C3H7NO*67H2O

Conditions
ConditionsYield
at 100℃; for 72h;95.2%
1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

C24H12O24S8(4-)*4Na(1+)

C24H12O24S8(4-)*4Na(1+)

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

6C24H8O24S8(8-)*8C27H15O6(3-)*24Co(2+)*6HO(1-)

6C24H8O24S8(8-)*8C27H15O6(3-)*24Co(2+)*6HO(1-)

Conditions
ConditionsYield
In methanol at 85℃; for 12h;95%
europium(III) nitrate hexahydrate

europium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

[Eu(1,3,5-benzenetrisbenzoate)(H2O)]

[Eu(1,3,5-benzenetrisbenzoate)(H2O)]

Conditions
ConditionsYield
Stage #1: europium(III) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene With 3-ethyl-1-methyl-1H-imidazol-3-ium bromide at 100℃; Heating;
Stage #2: water In N,N-dimethyl-formamide at 160℃; for 72h; Reagent/catalyst; Solvent; Autoclave;
94%
In N,N-dimethyl-formamide at 150℃; for 72h; High pressure; Autoclave;44%
terbium(III) nitrate hexahydrate

terbium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

[Eu(1,3,5-benzenetrisbenzoate)(H2O)]

[Eu(1,3,5-benzenetrisbenzoate)(H2O)]

Conditions
ConditionsYield
Stage #1: terbium(III) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene With 3-ethyl-1-methyl-1H-imidazol-3-ium bromide at 100℃; Heating;
Stage #2: water In N,N-dimethyl-formamide at 160℃; for 72h; Reagent/catalyst; Solvent; Autoclave;
94%
1,4-dioxane
123-91-1

1,4-dioxane

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

copper(II) nitrate

copper(II) nitrate

catena-[triaquatris(1,4-dioxane)tetrakis{4,4',4"-benzene-1,3,5-triyltris(benzoate)}hexacopper(II)] 1,4-dioxane tetrasolvate decahydrate

catena-[triaquatris(1,4-dioxane)tetrakis{4,4',4"-benzene-1,3,5-triyltris(benzoate)}hexacopper(II)] 1,4-dioxane tetrasolvate decahydrate

Conditions
ConditionsYield
With (S)-Malic acid at 100℃;94%
4,4'-bipyridine
553-26-4

4,4'-bipyridine

2NO3(1-)*Ni(1+)*6H2O

2NO3(1-)*Ni(1+)*6H2O

2NO3(1-)*Zn(1+)*6H2O

2NO3(1-)*Zn(1+)*6H2O

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

3C10H8N2*4C27H15O6(3-)*1.2Ni(2+)*4.8Zn(2+)*47C3H7NO*47H2O

3C10H8N2*4C27H15O6(3-)*1.2Ni(2+)*4.8Zn(2+)*47C3H7NO*47H2O

Conditions
ConditionsYield
at 100℃; for 72h;93.5%
1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

1,4-bis(4-pyridyl)benzene
113682-56-7

1,4-bis(4-pyridyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

C27H15O6(3-)*1.5Co(2+)*H2O*C3H7NO*C16H12N2

C27H15O6(3-)*1.5Co(2+)*H2O*C3H7NO*C16H12N2

Conditions
ConditionsYield
at 120℃; for 72h; pH=5; Autoclave; High pressure;92%
1,4-diaza-bicyclo[2.2.2]octane
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

copper(II) nitrate trihydrate

copper(II) nitrate trihydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[Cu3([1,1':3',1''-terphenyl]-4,4'',5'-tricarboxylate)2(1,4-diazabicylo[2.2.2]octane)(H2O)]*15H2O*9DMF

[Cu3([1,1':3',1''-terphenyl]-4,4'',5'-tricarboxylate)2(1,4-diazabicylo[2.2.2]octane)(H2O)]*15H2O*9DMF

Conditions
ConditionsYield
With HCl In 1,4-dioxane; water; N,N-dimethyl-formamide High Pressure; mixt. Cu(NO3)2*3H2O, (1,1':3',1''-terphenyl)-4,4'',5'-tricarboxylic acid, DABCO, concd. HCl, DMF, dioxane and water was treated by ultrasonic vibration, sealed in Teflon-lined stainless steel container and heated at 358 K for 3 days; react. mixt. was cooled to room temp.; elem. anal.;90%
barium(II) nitrate

barium(II) nitrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

Ba(2+)*C27H15O6(3-)*C2H7N*H(1+)*H2O

Ba(2+)*C27H15O6(3-)*C2H7N*H(1+)*H2O

Conditions
ConditionsYield
at 100℃; for 120h; Sonication;90%
zinc(II) chloride hexahydrate

zinc(II) chloride hexahydrate

1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

C27H16O6(2-)*C27H18N6*Zn(2+)*2C3H7NO*H2O

C27H16O6(2-)*C27H18N6*Zn(2+)*2C3H7NO*H2O

Conditions
ConditionsYield
at 80℃; for 48h; Autoclave; High pressure;90%
samarium(III) nitrate hexahydrate

samarium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

[{Sm(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

[{Sm(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 100℃; for 72h; High pressure; Autoclave;88%
[Cu24(isophthalate)24(DMF)14(H2O)10]

[Cu24(isophthalate)24(DMF)14(H2O)10]

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

1,3,5-tris(4-carboxyphenyl) benzene

1,3,5-tris(4-carboxyphenyl) benzene

Conditions
ConditionsYield
In ethanol; water; N,N-dimethyl-formamide at 130℃; for 24h; Autoclave;87%
gadolinium(III) nitrate hexahydrate

gadolinium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

[{Gd(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

[{Gd(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 100℃; for 72h; High pressure; Autoclave;87%
lithium hydroxide monohydrate
1310-66-3

lithium hydroxide monohydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

nickel(II) acetate tetrahydrate
6018-89-9

nickel(II) acetate tetrahydrate

cobalt(II) diacetate tetrahydrate
6147-53-1

cobalt(II) diacetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

2.8Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)*3.2Co(2+)

2.8Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)*3.2Co(2+)

Conditions
ConditionsYield
In water at 20℃; for 48h; Sealed tube;86%
terbium(III) nitrate hexahydrate

terbium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

poly-[Tb(benzene-1,3,5-tribenzoate)(N,Ndimethylformamide)]*1.5(N,Ndimethylformamide)*2.5H2O

poly-[Tb(benzene-1,3,5-tribenzoate)(N,Ndimethylformamide)]*1.5(N,Ndimethylformamide)*2.5H2O

Conditions
ConditionsYield
With lithium hydroxide monohydrate In water at 130℃; for 72h; Autoclave; High pressure;85%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

europium(III) nitrate hexahydrate

europium(III) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[Eu(1,3,5-benzenetribenzoate)(1,10-phenanthroline)]*4.5DMF*2H2O

[Eu(1,3,5-benzenetribenzoate)(1,10-phenanthroline)]*4.5DMF*2H2O

Conditions
ConditionsYield
In water at 100℃; for 72h; Autoclave;85%
1,3,5-tris(1-imidazolyl)benzene

1,3,5-tris(1-imidazolyl)benzene

N-formyldiethylamine
617-84-5

N-formyldiethylamine

cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

[Cd3(tib)2(BTB)2 ]*3DEF*4.5H2O

[Cd3(tib)2(BTB)2 ]*3DEF*4.5H2O

Conditions
ConditionsYield
at 90℃; for 72h; Sealed tube;85%
1,3,5-tris(1-imidazolyl)benzene

1,3,5-tris(1-imidazolyl)benzene

cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[Co3(1,3,5-tris(1-imidazolyl)benzene)2(4,4',4''-benzene-1,3,5-triyltribenzoate)2]*2DMF*6H2O

[Co3(1,3,5-tris(1-imidazolyl)benzene)2(4,4',4''-benzene-1,3,5-triyltribenzoate)2]*2DMF*6H2O

Conditions
ConditionsYield
at 90℃; for 72h;85%
cadmium(II) nitrate tetrhydrate

cadmium(II) nitrate tetrhydrate

1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[(cadmium)3(1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene)2(1,3,5-tris(4′-carboxyphenyl)benzene)2(H2O)2]*8(dimethylformamide)*4H2O

[(cadmium)3(1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene)2(1,3,5-tris(4′-carboxyphenyl)benzene)2(H2O)2]*8(dimethylformamide)*4H2O

Conditions
ConditionsYield
at 80℃; for 48h; Autoclave; High pressure;85%
europium(III) acetate tetrahydrate

europium(III) acetate tetrahydrate

lithium hydroxide monohydrate
1310-66-3

lithium hydroxide monohydrate

N,N-dimethyl acetamide
127-19-5

N,N-dimethyl acetamide

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

water
7732-18-5

water

[H3O]2[Eu2.5(1,3,5-benzenetribenzoate)3(OAc)0.5(H2O)3]*2DMA*2.5H2O

[H3O]2[Eu2.5(1,3,5-benzenetribenzoate)3(OAc)0.5(H2O)3]*2DMA*2.5H2O

Conditions
ConditionsYield
at 130℃; for 72h; Autoclave;83%
lithium hydroxide monohydrate
1310-66-3

lithium hydroxide monohydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

nickel(II) acetate tetrahydrate
6018-89-9

nickel(II) acetate tetrahydrate

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

6Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)

6Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)

Conditions
ConditionsYield
In water at 20℃; for 48h; Sealed tube;82%
1-methyl-pyrrolidin-2-one
872-50-4

1-methyl-pyrrolidin-2-one

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

2C27H15O6(3-)*3Ca(2+)*6H2O*3C5H9NO

2C27H15O6(3-)*3Ca(2+)*6H2O*3C5H9NO

Conditions
ConditionsYield
With water; calcium chloride at 120℃; for 120h; Autoclave;82%
1-hydroxy-pyrrolidine-2,5-dione
6066-82-6

1-hydroxy-pyrrolidine-2,5-dione

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

C39H27N3O12

C39H27N3O12

Conditions
ConditionsYield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere;82%
cobalt(II) nitrate hexahydrate

cobalt(II) nitrate hexahydrate

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane

1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

[Co3(BTB)2(1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane)2]·4DMF

[Co3(BTB)2(1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane)2]·4DMF

Conditions
ConditionsYield
Stage #1: cobalt(II) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene; 1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane; N,N-dimethyl-formamide With air In ethanol; water Sonication;
Stage #2: With air In ethanol; water at 100℃; for 48h;
81.7%
N-formyldiethylamine
617-84-5

N-formyldiethylamine

1,3,5,-tris(4-carboxyphenyl)benzene
50446-44-1

1,3,5,-tris(4-carboxyphenyl)benzene

Zn4O(BTB)2

Zn4O(BTB)2

Conditions
ConditionsYield
With zinc(II) nitrate at 100℃; for 16h;81%

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