1,3,5-Tri(4-carboxyphenyl)benzene supplier

Name
1,3,5-Tri(4-carboxyphenyl)benzene
EINECS
CAS No. 50446-44-1
Article Data24
CAS DataBase
Density 1.358g/cm³
Solubility
Melting Point 322-327 °C
Formula C₂₇H₁₈O₆
Boiling Point 710.973°C at 760 mmHg
Molecular Weight 438.436
Flash Point 397.736°C
Transport Information
Appearance
Safety 36/37-60-61-62-26
Risk Codes 10-48/20-50/53-63-65-67-36/38
Molecular Structure
Hazard Symbols F,Xn,N,Xi
Synonyms 1,3,5-Tri(4-carboxyphenyl)benzene;1,4-Di-(4-carboxyphenyl)-naphthalene;1,3,5-Tris(4-carboxyphenyl)benzene;4,4μ,4μμ,-Benzene-1,3,5-triyl-tris(benzoic acid);5-(4-carboxyphenyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid;Benzene-1,3,5-tribenzoic acid;Benzene-1,3,5-tris(4-benzoic acid);Benzene-1,3,5-triyltris(4-benzoic acid)
PSA 111.90000
LogP 5.78220

Synthetic route

: 50446-43-0
1,3,5-tris(4-methyl-phenyl)-benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
With pyridine; ammonium cerium (IV) nitrate; dihydrogen peroxide; sodium carbonate; cobalt(II) nitrate at 110℃; under 15001.5 Torr; for 6h; Reagent/catalyst; Temperature; Pressure; Green chemistry;	97%
With 2-aminoisonicotinic acid; oxygen; antimony(III) acetate; acetic anhydride; acetic acid; potassium nitrate; 1-aza-adamantane-1-oxide; Dimethyl succinate In 1,2-dichloro-benzene at 180℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Solvent; Temperature; Pressure;	92%
With dihydrogen peroxide; sodium carbonate at 100℃; under 7500.75 Torr; for 12h; Reagent/catalyst; Solvent;	90%
With nitric acid at 160 - 180℃; im geschlossenen Rohr;
With nitric acid at 170℃;

: 117100-41-1
dimethyl 5'-(4-(methoxycarbonyl)phenyl)-[1,1:3,1''-terphenyl]-4,4''-dicarboxylate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
With methanol; sodium hydroxide In tetrahydrofuran	92%
With water; sodium hydroxide In tetrahydrofuran; methanol	92%
With water; sodium hydroxide In tetrahydrofuran; methanol	92%

: 124-38-9
carbon dioxide

: 15797-52-1
1,3,5-tris(4-hydroxyphenyl)benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 90℃; electrochemical reaction;	75%

: 1-[4-[3,5-bis(4-acetylphenyl)phenyl]phenyl]ethanone

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
With bromine; sodium hydroxide In 1,4-dioxane; water at 60℃; for 2h;	75%
With sodium hypobromide In 1,4-dioxane at 60℃; for 2h;

: 124-38-9
carbon dioxide

: 7511-49-1
1,3,5-tris(4-bromophenyl)benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at -60℃;	60%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -60℃; Stage #2: carbon dioxide In tetrahydrofuran; hexane at -60 - 20℃;	57%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -60℃; Inert atmosphere; Stage #2: carbon dioxide at -60℃;	33%
Stage #1: 1,3,5-tris(4-bromophenyl)benzene With n-butyllithium In tetrahydrofuran; hexane at -65 - -60℃; for 1h; Inert atmosphere; Stage #2: carbon dioxide With hydrogenchloride In tetrahydrofuran; hexane; water at -65 - -60℃; for 1h; Inert atmosphere;	0.29 g

: 124-38-9
carbon dioxide

: 15797-52-1
1,3,5-tris(4-hydroxyphenyl)benzene

A: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

B: 1,3-bis(4-carboxyphenyl)-5-(4-hydroxyphenyl)benzene

Conditions

Conditions	Yield
bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 90℃; electrochemical reaction;	A 43% B 34%

...Expand

: 10602-00-3
4-Ethynyl-benzoic acid

A poly((4-carboxyphenyl)acetylene), Mn (GPC): ca. 2000 g/mol: poly((4-carboxyphenyl)acetylene), Mn (GPC): ca. 2000 g/mol

B: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
at 125℃; for 72h; Title compound not separated from byproducts.;

: 109613-00-5
4-acetophenyl triflate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo 2: 67 percent / dimethylformamide / Ambient temperature; electrolysis 3: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme
Multi-step reaction with 3 steps 1: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo 2: 67 percent / dimethylformamide / Ambient temperature; electrolysis 3: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme

: 99-93-4
4-Hydroxyacetophenone

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: triethylamine / CH2Cl2 / -50 deg C (1 h) to r.t (8 h) 2: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo 3: 67 percent / dimethylformamide / Ambient temperature; electrolysis 4: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme
Multi-step reaction with 4 steps 1: triethylamine / CH2Cl2 / -50 deg C (1 h) to r.t (8 h) 2: 97 percent / triflic acid / 1.5 h / 140 - 150 °C / in vacuo 3: 67 percent / dimethylformamide / Ambient temperature; electrolysis 4: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme

: 214049-70-4
1,3,5-tris[4-[(trifluoromethanesulfonyl)oxy]phenyl]benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 67 percent / dimethylformamide / Ambient temperature; electrolysis 2: 75 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme
Multi-step reaction with 2 steps 1: 67 percent / dimethylformamide / Ambient temperature; electrolysis 2: 43 percent / PdCl2(PPh3)2 / dimethylformamide / 90 °C / electrochemical reaction View Scheme

: 99-90-1
para-bromoacetophenone

HNO3+H2SO4: HNO3+H2SO4

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 41 percent / triethyl orthoformate 2: 60 percent / 1.6 M n-BuLi / tetrahydrofuran; hexane / -60 °C View Scheme

: 3609-53-8
methyl 4-acetylbenzoate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: toluene-4-sulfonic acid; toluene View Scheme
Multi-step reaction with 2 steps 1: toluene View Scheme

: 104-15-4
toluene-4-sulfonic acid

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: toluene View Scheme

: 122-00-9
para-methylacetophenone

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: hydrogen chloride 2: nitric acid / 160 - 180 °C / im geschlossenen Rohr View Scheme

: 122-00-9
para-methylacetophenone

W2(OCH2-t-Bu)6(O)(CMe2)(py): W2(OCH2-t-Bu)6(O)(CMe2)(py)

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: AlCl3 / 210 °C 2: aq. HNO3 / 170 °C View Scheme

: 50446-45-2
C33H30O6

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
With water; sodium hydroxide	1.18 g

: 124-38-9
carbon dioxide

: 99-90-1
para-bromoacetophenone

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Stage #1: para-bromoacetophenone Stage #2: With n-butyllithium Stage #3: carbon dioxide

: 99-90-1
para-bromoacetophenone

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: sulfuric acid; potassium hydrogensulfate / 18 h / 180 °C 1.2: 7 h / Reflux 2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -65 - -60 °C / Inert atmosphere 2.2: 1 h / -65 - -60 °C / Inert atmosphere View Scheme

: 626-39-1
1,3,5-trisbromobenzene

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: cesium fluoride; tetrakis(triphenylphosphine) palladium(0) / 1,2-dimethoxyethane / 48 h / Schlenk technique; Inert atmosphere; Reflux 2: methanol; sodium hydroxide / tetrahydrofuran View Scheme
Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); cesium fluoride / 1,2-dimethoxyethane / 48 h / Schlenk technique; Inert atmosphere; Reflux 2: water; sodium hydroxide / tetrahydrofuran; methanol View Scheme

: 99768-12-4
4-methoxycarbonylphenylboronic acid

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 4 h / 110 °C / 6000.6 Torr / Inert atmosphere; Microwave irradiation 2: sodium hydroxide / tetrahydrofuran; methanol / 16 h / 20 °C View Scheme

: 14047-29-1
4-carboxyphenylboronic acid

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: thionyl chloride / 2.5 h / 50 °C / Inert atmosphere 2: sodium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol / 4 h / 110 °C / 6000.6 Torr / Inert atmosphere; Microwave irradiation 3: sodium hydroxide / tetrahydrofuran; methanol / 16 h / 20 °C View Scheme

: 553-26-4
4,4'-bipyridine

: 2NO3(1-)*Co(1+)*6H2O

: 2NO3(1-)*Ni(1+)*6H2O

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 3C10H8N2*4C27H15O6(3-)*0.7Ni(2+)*5.3Co(2+)*43C3H7NO*67H2O

Conditions

Conditions	Yield
at 100℃; for 72h;	95.2%

...Expand

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: C24H12O24S8(4-)*4Na(1+)

: 7646-79-9
cobalt(II) chloride

: 6C24H8O24S8(8-)*8C27H15O6(3-)*24Co(2+)*6HO(1-)

Conditions

Conditions	Yield
In methanol at 85℃; for 12h;	95%

...Expand

: europium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: [Eu(1,3,5-benzenetrisbenzoate)(H2O)]

Conditions

Conditions	Yield
Stage #1: europium(III) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene With 3-ethyl-1-methyl-1H-imidazol-3-ium bromide at 100℃; Heating; Stage #2: water In N,N-dimethyl-formamide at 160℃; for 72h; Reagent/catalyst; Solvent; Autoclave;	94%
In N,N-dimethyl-formamide at 150℃; for 72h; High pressure; Autoclave;	44%

...Expand

: terbium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: [Eu(1,3,5-benzenetrisbenzoate)(H2O)]

Conditions

Conditions	Yield
Stage #1: terbium(III) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene With 3-ethyl-1-methyl-1H-imidazol-3-ium bromide at 100℃; Heating; Stage #2: water In N,N-dimethyl-formamide at 160℃; for 72h; Reagent/catalyst; Solvent; Autoclave;	94%

...Expand

: 123-91-1
1,4-dioxane

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: copper(II) nitrate

: catena-[triaquatris(1,4-dioxane)tetrakis{4,4',4"-benzene-1,3,5-triyltris(benzoate)}hexacopper(II)] 1,4-dioxane tetrasolvate decahydrate

Conditions

Conditions	Yield
With (S)-Malic acid at 100℃;	94%

...Expand

: 553-26-4
4,4'-bipyridine

: 2NO3(1-)*Ni(1+)*6H2O

: 2NO3(1-)*Zn(1+)*6H2O

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 3C10H8N2*4C27H15O6(3-)*1.2Ni(2+)*4.8Zn(2+)*47C3H7NO*47H2O

Conditions

Conditions	Yield
at 100℃; for 72h;	93.5%

...Expand

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: 113682-56-7
1,4-bis(4-pyridyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 7646-79-9
cobalt(II) chloride

: C27H15O6(3-)*1.5Co(2+)*H2O*C3H7NO*C16H12N2

Conditions

Conditions	Yield
at 120℃; for 72h; pH=5; Autoclave; High pressure;	92%

...Expand

: 280-57-9
1,4-diaza-bicyclo[2.2.2]octane

: copper(II) nitrate trihydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Cu3([1,1':3',1''-terphenyl]-4,4'',5'-tricarboxylate)2(1,4-diazabicylo[2.2.2]octane)(H2O)]*15H2O*9DMF

Conditions

Conditions	Yield
With HCl In 1,4-dioxane; water; N,N-dimethyl-formamide High Pressure; mixt. Cu(NO3)2*3H2O, (1,1':3',1''-terphenyl)-4,4'',5'-tricarboxylic acid, DABCO, concd. HCl, DMF, dioxane and water was treated by ultrasonic vibration, sealed in Teflon-lined stainless steel container and heated at 358 K for 3 days; react. mixt. was cooled to room temp.; elem. anal.;	90%

...Expand

: barium(II) nitrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: Ba(2+)*C27H15O6(3-)*C2H7N*H(1+)*H2O

Conditions

Conditions	Yield
at 100℃; for 120h; Sonication;	90%

...Expand

: zinc(II) chloride hexahydrate

: 1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: C27H16O6(2-)*C27H18N6*Zn(2+)*2C3H7NO*H2O

Conditions

Conditions	Yield
at 80℃; for 48h; Autoclave; High pressure;	90%

...Expand

: samarium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: [{Sm(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

Conditions

Conditions	Yield
In water; N,N-dimethyl-formamide at 100℃; for 72h; High pressure; Autoclave;	88%

: [Cu24(isophthalate)24(DMF)14(H2O)10]

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 1,3,5-tris(4-carboxyphenyl) benzene

Conditions

Conditions	Yield
In ethanol; water; N,N-dimethyl-formamide at 130℃; for 24h; Autoclave;	87%

: gadolinium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: [{Gd(1,3,5-tris(4-carboxyphenyl)benzene)(H2O)}·H2O]n

Conditions

Conditions	Yield
In water; N,N-dimethyl-formamide at 100℃; for 72h; High pressure; Autoclave;	87%

: 1310-66-3
lithium hydroxide monohydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 6018-89-9
nickel(II) acetate tetrahydrate

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 2.8Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)*3.2Co(2+)

Conditions

Conditions	Yield
In water at 20℃; for 48h; Sealed tube;	86%

...Expand

: terbium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: poly-[Tb(benzene-1,3,5-tribenzoate)(N,Ndimethylformamide)]*1.5(N,Ndimethylformamide)*2.5H2O

Conditions

Conditions	Yield
With lithium hydroxide monohydrate In water at 130℃; for 72h; Autoclave; High pressure;	85%

...Expand

: 66-71-7
1,10-Phenanthroline

: europium(III) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Eu(1,3,5-benzenetribenzoate)(1,10-phenanthroline)]*4.5DMF*2H2O

Conditions

Conditions	Yield
In water at 100℃; for 72h; Autoclave;	85%

...Expand

: 1,3,5-tris(1-imidazolyl)benzene

: 617-84-5
N-formyldiethylamine

: cadmium(II) nitrate tetrhydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: [Cd3(tib)2(BTB)2 ]*3DEF*4.5H2O

Conditions

Conditions	Yield
at 90℃; for 72h; Sealed tube;	85%

...Expand

: 1,3,5-tris(1-imidazolyl)benzene

: cobalt(II) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Co3(1,3,5-tris(1-imidazolyl)benzene)2(4,4',4''-benzene-1,3,5-triyltribenzoate)2]*2DMF*6H2O

Conditions

Conditions	Yield
at 90℃; for 72h;	85%

...Expand

: cadmium(II) nitrate tetrhydrate

: 1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [(cadmium)3(1,3,5-tri(1H-benzo[d]imidazol-1-yl)benzene)2(1,3,5-tris(4′-carboxyphenyl)benzene)2(H2O)2]*8(dimethylformamide)*4H2O

Conditions

Conditions	Yield
at 80℃; for 48h; Autoclave; High pressure;	85%

...Expand

: europium(III) acetate tetrahydrate

: 1310-66-3
lithium hydroxide monohydrate

: 127-19-5
N,N-dimethyl acetamide

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 7732-18-5
water

: [H3O]2[Eu2.5(1,3,5-benzenetribenzoate)3(OAc)0.5(H2O)3]*2DMA*2.5H2O

Conditions

Conditions	Yield
at 130℃; for 72h; Autoclave;	83%

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 6018-89-9
nickel(II) acetate tetrahydrate

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 6Ni(2+)*4HO(1-)*10H2O*9C3H7NO*2.7C27H15O6(3-)

Conditions

Conditions	Yield
In water at 20℃; for 48h; Sealed tube;	82%

...Expand

: 872-50-4
1-methyl-pyrrolidin-2-one

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 2C27H15O6(3-)*3Ca(2+)*6H2O*3C5H9NO

Conditions

Conditions	Yield
With water; calcium chloride at 120℃; for 120h; Autoclave;	82%

: 6066-82-6
1-hydroxy-pyrrolidine-2,5-dione

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: C39H27N3O12

Conditions

Conditions	Yield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere;	82%

: cobalt(II) nitrate hexahydrate

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: 1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Co3(BTB)2(1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane)2]·4DMF

Conditions

Conditions	Yield
Stage #1: cobalt(II) nitrate hexahydrate; 1,3,5,-tris(4-carboxyphenyl)benzene; 1,7-bis{(pyridin-4′-yl)methanol}-1,7-dicarba-closo-dodecaborane; N,N-dimethyl-formamide With air In ethanol; water Sonication; Stage #2: With air In ethanol; water at 100℃; for 48h;	81.7%

...Expand

: 617-84-5
N-formyldiethylamine

: 50446-44-1
1,3,5,-tris(4-carboxyphenyl)benzene

: Zn4O(BTB)2

Conditions

Conditions	Yield
With zinc(II) nitrate at 100℃; for 16h;	81%

1,3,5-Tri(4-carboxyphenyl)benzene Chemical Properties

Molecular Formula: C₂₇H₁₈O₆
Molecular Weight: 438.43 g/mol
Structure of 1,3,5-Tri(4-carboxyphenyl)benzene (CAS NO.50446-44-1):

1,3,5-Tri(4-carboxyphenyl)benzene Specification

1,3,5-Tri(4-carboxyphenyl)benzene , its cas register number is 50446-44-1.

Product Name

1,3,5-Tri(4-carboxyphenyl)benzene

Synthetic route

1,3,5-Tri(4-carboxyphenyl)benzene Chemical Properties

1,3,5-Tri(4-carboxyphenyl)benzene Specification

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