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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3,5,5-Trimethyl-1,2-Cyclohexanedione supplier in China

Cas:57696-89-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality 3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details 3,5,5-Trimethylcyclohexane-1,2-dione Chemical Properties Melting point 89-92℃ Boiling point 214.6

China Largest factory Manufacturer Supply 3,5,5-Trimethylcyclohexane-1,2-dione CAS 57696-89-6

Cas:57696-89-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

3,5,5-Trimethylcyclohexane-1,2-dione-

Cas:57696-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be sent

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 57696-89-6 with best quality

Cas:57696-89-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:white powder Storage:Store in sealed containers at cool & dr

3,5,5-Trimethylcyclohexane-1,2-dione 2-Hydroxyisophorone CAS 57696-89-6

Cas:57696-89-6

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

3,5,5-Trimethylcyclohexane-1,2-dione 57696-89-6

Cas:57696-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

3,5,5-Trimethylcyclohexane-1,2-dione CAS57696-89-6

Cas:57696-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/2-Hydroxyisophorone CAS NO.57696-89-6

Cas:57696-89-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 3,5,5-Trimethylcyclohexane-1,2-dione CAS:4883-60-7; 57696-89-6, Please contact us by email freely. We are leading exporter in China.

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

57696-89-6 CAS NO.57696-89-6

Cas:57696-89-6

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

3,5,5-Trimethyl-1,2-cyclohexanedione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/3,5,5-Trimethylcyclohexane-1,2-dione/SAGECHEM/Manufacturer in China

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

3,5,5-trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-hydroxy-3,5,5-trimethylcyclohex-2-en-1-one

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Other

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

High Purity 3,5,5-Trimethyl-1,2-Cyclohexanedione 57696-89-6

Cas:57696-89-6

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

3,5,5-Trimethyl-1,2-cyclohexanedione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Enterprise standard Application:Pharma Intermediate

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

3,5,5-Trimethyl-1,2-cyclohexanedione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

2-hydroxy-3,5,5-trimethylcyclohex-2-en-1-one

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

3,5,5-Trimethylcyclohexane-1,2-dioneAppearance:Solid Storage:Refrigerator Package:in foil bag or customized Application:Orally active estrogenic steroid. It was the estrogen used in many of the first oral contraceptives Transportation:shipping by cou

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 876kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

3,5,5-Trimethylcyclohexane-1,2-dione

Cas:57696-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

isophorone oxide
10276-21-8

isophorone oxide

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

benzene
71-43-2

benzene

A

2,4,4-trimethylcyclopentan-1-one
4694-12-6

2,4,4-trimethylcyclopentan-1-one

B

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

C

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde
10275-88-4

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde

isophorone oxide
10276-21-8

isophorone oxide

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With hydrogenchloride
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With permanganate(VII) ion at 0℃; Destillation des angesaeuerten Reaktionsprodukts;
Multi-step reaction with 2 steps
1: methanol; aqueous hydrogen peroxide; aq. NaOH solution
2: aqueous HCl
View Scheme
3-(1,1-dimethyl-3-oxo-butyl)-furan-2,4-dione

3-(1,1-dimethyl-3-oxo-butyl)-furan-2,4-dione

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With hydrogenchloride at 120℃;
6-bromo-2,4,4-trimethyl-cyclohex-2-enone
684214-94-6

6-bromo-2,4,4-trimethyl-cyclohex-2-enone

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With sulfuric acid
2,2-dibromo-3,5,5-trimethyl-cyclohexanone

2,2-dibromo-3,5,5-trimethyl-cyclohexanone

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With potassium hydroxide
2,2-dibromo-3,5,5-trimethyl-cyclohexanone

2,2-dibromo-3,5,5-trimethyl-cyclohexanone

A

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

B

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid
861573-63-9

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid

Conditions
ConditionsYield
With potassium hydroxide
(+/-)-2r,6t-dibromo-2,4,4-trimethyl-cyclohexanone
108127-54-4

(+/-)-2r,6t-dibromo-2,4,4-trimethyl-cyclohexanone

sodium acetate
127-09-3

sodium acetate

acetic acid
64-19-7

acetic acid

A

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

B

6-bromo-2,4,4-trimethyl-cyclohex-2-enone
684214-94-6

6-bromo-2,4,4-trimethyl-cyclohex-2-enone

2,6-Diacetoxy-3,3,5-trimethyl-cyclohexanon-(1)
100533-42-4

2,6-Diacetoxy-3,3,5-trimethyl-cyclohexanon-(1)

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With hydrogenchloride In ethanol
dihydroisophorone
873-94-9

dihydroisophorone

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
(i) Br2, (ii) aq. KOH; Multistep reaction;
Multi-step reaction with 2 steps
1: glacial acetic acid; bromine
2: diluted KOH-solution
View Scheme
Multi-step reaction with 2 steps
1: glacial acetic acid; bromine
2: KOH-solution
View Scheme
hydrogenchloride
7647-01-0

hydrogenchloride

isophorone oxide
10276-21-8

isophorone oxide

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

hydrogenchloride
7647-01-0

hydrogenchloride

3-(1,1-dimethyl-3-oxo-butyl)-furan-2,4-dione

3-(1,1-dimethyl-3-oxo-butyl)-furan-2,4-dione

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

isophorone oxide
10276-21-8

isophorone oxide

methanol. KOH-solution

methanol. KOH-solution

A

2-methoxy-3,5,5-trimethylcyclohex-2-enone
5682-76-8

2-methoxy-3,5,5-trimethylcyclohex-2-enone

B

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

permanganate

permanganate

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
at 0℃; Destillation des angesaeuerten Reaktionsprodukts;
methanol
67-56-1

methanol

3,4-epoxy-1,1,3-trimethyl-cyclohexanone-(5)

3,4-epoxy-1,1,3-trimethyl-cyclohexanone-(5)

A

2-methoxy-3,5,5-trimethylcyclohex-2-enone
5682-76-8

2-methoxy-3,5,5-trimethylcyclohex-2-enone

B

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With potassium hydroxide
4-methoxy-1.1.3-trimethyl-cyclohexen-(3)-one-(5)

4-methoxy-1.1.3-trimethyl-cyclohexen-(3)-one-(5)

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With hydrogenchloride; acetic acid
2,2-dibromo-3,5,5-trimethyl-cyclohexanone

2,2-dibromo-3,5,5-trimethyl-cyclohexanone

diluted KOH-solution

diluted KOH-solution

A

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

B

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid
861573-63-9

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid

isophorone oxide

isophorone oxide

A

2,4,4-trimethylcyclopentan-1-one
4694-12-6

2,4,4-trimethylcyclopentan-1-one

B

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In benzene at 20℃; for 0.166667h; Rearrangement;A 76 % Spectr.
B 2 % Spectr.
isophorone oxide

isophorone oxide

A

2,4,4-trimethylcyclopentan-1-one
4694-12-6

2,4,4-trimethylcyclopentan-1-one

B

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

C

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde
10275-88-4

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde

Conditions
ConditionsYield
With 1,3,5-Tri-tert-butylbenzene; zeolite beta according Wadlinger In benzene at 80℃; for 2h; Product distribution; Further Variations:; Reagents; Solvents; Temperatures; Rearrangement;A 25 % Spectr.
B 15 % Spectr.
C 56 % Spectr.
With zeolite NaHY In chlorobenzene at 132℃; for 2h; Rearrangement;A 7 % Spectr.
B 29 % Spectr.
C 58 % Spectr.
isophorone oxide

isophorone oxide

A

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

B

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde
10275-88-4

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In benzene at 20℃; for 0.166667h; Rearrangement;A 2 % Spectr.
B 76 % Spectr.
3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

PhX

PhX

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 30percent H2O2; NaOH (6M) / methanol / 15 - 20 °C
1.2: 65 percent / Na2SO3; NaHCO3 / H2O; methanol
2.1: 2 percent Spectr. / BF3*Et2O / benzene / 0.17 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: 30percent H2O2; NaOH (6M) / methanol / 15 - 20 °C
1.2: 65 percent / Na2SO3; NaHCO3 / H2O; methanol
2.1: 2 percent Spectr. / BF3*Et2O / benzene / 0.17 h / 20 °C
View Scheme
isophorone oxide
10276-21-8

isophorone oxide

A

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

B

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde
10275-88-4

(+/-)-1,4,4-trimethyl-2-oxo-cyclopentanecarbaldehyde

Conditions
ConditionsYield
With ZSM-5 zeolite In toluene at 80℃; Autoclave;
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

2-(phenylsulfinyl)thiophene
578017-25-1, 790714-98-6

2-(phenylsulfinyl)thiophene

2-hydroxy-4,4,6-trimethyl-6-(2-(phenylthio)thiophen-3-yl)cyclohex-2-en-1-one

2-hydroxy-4,4,6-trimethyl-6-(2-(phenylthio)thiophen-3-yl)cyclohex-2-en-1-one

Conditions
ConditionsYield
With trifluoroacetic anhydride In 1,2-dichloro-ethane at -10℃; for 4h; regioselective reaction;60%
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

3,3-dimethyl-5-oxohexanoic acid
20624-63-9

3,3-dimethyl-5-oxohexanoic acid

Conditions
ConditionsYield
With methanol; potassium hydroxide; dihydrogen peroxide
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

2,4,4-trimethyl-adipic acid
3937-59-5

2,4,4-trimethyl-adipic acid

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide; magnesium sulfate
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid
861573-63-9

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid

Conditions
ConditionsYield
With potassium hydroxide at 140℃;
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

N,N-Dimethylthiocarbamoyl chloride
16420-13-6

N,N-Dimethylthiocarbamoyl chloride

3,5,5-trimethyl-2-<(dimethylthiocarbamoyl)oxy>-2-cyclohexen-1-one
112621-58-6

3,5,5-trimethyl-2-<(dimethylthiocarbamoyl)oxy>-2-cyclohexen-1-one

Conditions
ConditionsYield
With lithium hydroxide In chloroform for 2h; Ambient temperature;
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

magnesium sulfate
7487-88-9

magnesium sulfate

aqueous NaOH

aqueous NaOH

2,4,4-trimethyl-adipic acid
3937-59-5

2,4,4-trimethyl-adipic acid

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

aqueous methanol. KOH

aqueous methanol. KOH

A

3,3-dimethyl-5-oxohexanoic acid
20624-63-9

3,3-dimethyl-5-oxohexanoic acid

B

2,4,4-trimethyl-adipic acid
3937-59-5

2,4,4-trimethyl-adipic acid

3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

KOH-solution

KOH-solution

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid
861573-63-9

1-hydroxy-2,4,4-trimethyl-cyclopentanecarboxylic acid

Conditions
ConditionsYield
at 140℃;
3,5,5-Trimethyl-1,2-cyclohexanedione
57696-89-6

3,5,5-Trimethyl-1,2-cyclohexanedione

3,5,5-Trimethylcyclohex-2-en-1-one
78-59-1

3,5,5-Trimethylcyclohex-2-en-1-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1 M aq. LiOH / CHCl3 / 2 h / Ambient temperature
2: 83 percent / Li, LiOAc, AcOH / 0.25 h / Heating
View Scheme

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