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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

5,6-Dimethylbenzimidazole Manufacturer/High quality/Best price/In stock

Cas:582-60-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 5,6-Dimethylbenzimidazole(Mbi) supplier in China

Cas:582-60-5

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5,6-dimethylbenzimidazole

Cas:582-60-5

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 582-60-5 with best quality

Cas:582-60-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam

5,6-Dimethylbenzimidazole CAS582-60-5

Cas:582-60-5

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name 5,6-Dimethylbenzimidazole CAS NO 582-60-5 Appearance White crystalline powder Molecular for

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

5,6-Dimethylbenzimidazole 582-60-5

Cas:582-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

582-60-5 5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Metric Ton

FOB Price: $5000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 5,6-Dimethylbenzimidazole CAS No.:582-60-5 Molecule Formula:C9H10N2 Molecule Weight:146.19 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard

Best Quality 5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Trading Company

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

582-60-5 CAS NO.582-60-5

Cas:582-60-5

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Wuhu Nuowei Chemistry Technologies Co., Ltd.

Wuhu Nuovo Chemical Technology Co., Ltd. was established in August 2014, mainly engaged in the development, production and sales of ionic liquids, ribose, nucleosides, nucleotides and related chemicals; Products are mainly used in new energy, new ma

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

5,6-Dimethylbenzimidazole cas no. 582-60-5 98%

Cas:582-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

5,6-DiMethyl-1H-benzo[d]iMidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers334.Safe and fa

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

5,6-DiMethylbenziMidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

5,6-Dimethylbenzimidazole(Mbi)

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

5,6-Dimethylbenzimidazole

Cas:582-60-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With gallium(III) triflate at 20℃; for 0.1h;99%
With aminosulfonic acid In methanol at 20℃; for 1h;94%
iodine In acetonitrile at 20℃; for 0.666667h;93%
methanol
67-56-1

methanol

4,5-dimethyl-2-nitrobenzenamine
6972-71-0

4,5-dimethyl-2-nitrobenzenamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With iron; ammonium chloride at 68 - 70℃; for 48h; Inert atmosphere;99%
N-formylbenzamide
4252-31-7

N-formylbenzamide

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In tetrahydrofuran at 50℃; for 9h; Inert atmosphere; Green chemistry;96%
formic acid
64-18-6

formic acid

4,5-dimethyl-1,2-dinitrobenzene
610-23-1

4,5-dimethyl-1,2-dinitrobenzene

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With gold nano particles supported on rutile TiO2 In toluene at 70℃; under 750.075 Torr; for 6h; Inert atmosphere; chemoselective reaction;95%
4,5-dimethyl-2-nitrobenzenamine
6972-71-0

4,5-dimethyl-2-nitrobenzenamine

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With 10% Pd/C; hydrogen; acetic acid In methanol at 20℃; under 760.051 Torr;94%
With iron; ytterbium(III) triflate at 75℃; for 3h;82%
formic acid
64-18-6

formic acid

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride In water; toluene at 160℃; for 0.166667h; Microwave irradiation;93%
With chloro-trimethyl-silane In water; N,N-dimethyl-formamide at 120℃; for 0.166667h; Microwave irradiation;93%
In methanol at 20℃; under 1551.49 Torr; Flow reactor; Inert atmosphere;38%
carbon dioxide
124-38-9

carbon dioxide

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride; hydrogen at 120℃; under 112511 Torr; for 40h; Green chemistry;93%
With dimethylamine borane In ethanol; water at 100℃; under 750.075 Torr; for 24h;93%
With tris(pentafluorophenyl)borate; phenylsilane In tetrahydrofuran at 120℃; under 7500.75 Torr; for 24h; Autoclave;62%
4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With Imidazole hydrochloride at 120℃; for 6h;93%
With phenylsilane at 120℃; for 12h;50%
With Triethoxysilane; carbon dioxide; tris(pentafluorophenyl)borate at 120℃; for 24h;99 %Spectr.
1-benzyl-5,6-dimethyl-1H-benzo[d]imidazole
15776-99-5

1-benzyl-5,6-dimethyl-1H-benzo[d]imidazole

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With triethylsilane; palladium 10% on activated carbon In tetrahydrofuran at 20℃; for 18h; Inert atmosphere;92%
oxalic acid
144-62-7

oxalic acid

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
In 1,4-dioxane at 120℃; for 6h; Green chemistry;92%
formic acid
64-18-6

formic acid

4,5-dimethyl-2-nitrobenzenamine
6972-71-0

4,5-dimethyl-2-nitrobenzenamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With palladium 10% on activated carbon; triethylamine at 150℃; for 0.0833333h; Microwave irradiation;91%
methanol
67-56-1

methanol

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With potassium tert-butylate In 1,4-dioxane at 130℃; for 48h; Autoclave;90%
formic acid
64-18-6

formic acid

N-(2-amino-4,5-dimethylphenyl)formamide
132382-43-5

N-(2-amino-4,5-dimethylphenyl)formamide

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
at 110℃; for 6h; Temperature;87.9%
5,6-dimethyl-2-mercaptobenzimidazole
3287-79-4

5,6-dimethyl-2-mercaptobenzimidazole

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With rose bengal; water; oxygen; sodium chloride In N,N-dimethyl-formamide at 25℃; for 48h; Irradiation; Green chemistry;87%
carbon dioxide
124-38-9

carbon dioxide

4,5-dimethyl-2-nitrobenzenamine
6972-71-0

4,5-dimethyl-2-nitrobenzenamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With palladium 10% on activated carbon; phenylsilane; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In acetonitrile at 70℃; under 7500.75 Torr; for 15h;84%
With gold on titanium oxide; hydrogen In 1-methyl-pyrrolidin-2-one at 100℃; under 60006 Torr; for 12h; Sealed tube; Green chemistry;81%
carbon dioxide
124-38-9

carbon dioxide

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

A

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

B

C10H10N2O

C10H10N2O

Conditions
ConditionsYield
With phenylsilane at 50℃; under 22502.3 Torr; for 3h; Pressure; Autoclave;A 78%
B 11%
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With oxygen; toluene-4-sulfonic acid In water at 110℃; Sealed tube;77%
D-Glucose
2280-44-6

D-Glucose

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With tert.-butylhydroperoxide; trifluorormethanesulfonic acid; water at 100℃; for 1h; Sealed tube;75%
methanol
67-56-1

methanol

4,5-dimethyl-2-nitrobenzenamine
6972-71-0

4,5-dimethyl-2-nitrobenzenamine

A

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

B

1,5,6-trimethylbenzimidazole
1128-27-4

1,5,6-trimethylbenzimidazole

Conditions
ConditionsYield
With Cu-Zn-PMO at 250℃; for 3h; Sealed tube; Supercritical conditions; Green chemistry;A 73%
B n/a
tert-butylisonitrile
119072-55-8, 7188-38-7

tert-butylisonitrile

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With chloro-trimethyl-silane In acetonitrile at 70℃; for 24h;60%
1-Amino-5,6-dimethylbenzimidazole
78288-57-0

1-Amino-5,6-dimethylbenzimidazole

A

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

B

Bis-(5,6-dimethyl-benzoimidazol-1-yl)-diazene
127845-08-3

Bis-(5,6-dimethyl-benzoimidazol-1-yl)-diazene

Conditions
ConditionsYield
With bromine; sodium carbonate In water at 0 - 5℃; for 1h;A 55%
B 10%
dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With ammonium acetate; water at 140℃; for 10h; Inert atmosphere; Schlenk technique;42%
With ammonium acetate In water at 140℃; for 11h; Schlenk technique; Inert atmosphere;42%
N-D-ribityl-4,5-dimethyl-1,2-phenylenediamine
64598-64-7

N-D-ribityl-4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
With oxygen In water at 20℃; for 96h;8%
With potassium hexacyanoferrate(III)
4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

A

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

B

1-(5,6-dimethyl-2,3-dihydro-2H-benzimidazol-2-yl)-butane-1,2,3,4-tetrol 4-O-phosphate

1-(5,6-dimethyl-2,3-dihydro-2H-benzimidazol-2-yl)-butane-1,2,3,4-tetrol 4-O-phosphate

Conditions
ConditionsYield
With 4-morpholineethanesulfonic acid In water at 37℃; pH=6;
N-(ribityl),N'-(Boc)-diamino-4,5-dimethylbenzene
569343-11-9

N-(ribityl),N'-(Boc)-diamino-4,5-dimethylbenzene

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
Stage #1: N-(ribityl),N'-(Boc)-diamino-4,5-dimethylbenzene With hydrogenchloride In water
Stage #2: With sodium hydroxide In water at 20℃; for 5h; pH=7 - 8;
Multi-step reaction with 2 steps
1: hydrogenchloride / water / 3 h / 20 °C
2: oxygen / water / 96 h / 20 °C
View Scheme
4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 82 percent / NaHCO3 / H2O; tetrahydrofuran / 12 h
2.1: 85 mg / H2 / Pd(OH)2 / methanol / 2 h
3.1: HCl / H2O
3.2: NaOH / H2O / 5 h / 20 °C / pH 7 - 8
View Scheme
Multi-step reaction with 4 steps
1: sodium hydrogencarbonate / 1,4-dioxane; water / 3 h / 20 °C
2: sodium cyanoborohydride / methanol / 48 h / Inert atmosphere; Reflux
3: hydrogenchloride / water / 3 h / 20 °C
4: oxygen / water / 96 h / 20 °C
View Scheme
(2-amino-4,5-dimethyl-phenyl)-carbamic acid tert-butyl ester
371158-46-2

(2-amino-4,5-dimethyl-phenyl)-carbamic acid tert-butyl ester

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 85 mg / H2 / Pd(OH)2 / methanol / 2 h
2.1: HCl / H2O
2.2: NaOH / H2O / 5 h / 20 °C / pH 7 - 8
View Scheme
Multi-step reaction with 3 steps
1: sodium cyanoborohydride / methanol / 48 h / Inert atmosphere; Reflux
2: hydrogenchloride / water / 3 h / 20 °C
3: oxygen / water / 96 h / 20 °C
View Scheme
C17H16N2O2

C17H16N2O2

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
In methanol at 20℃;
4-amino-o-xylene
95-64-7

4-amino-o-xylene

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 0.17 h / 55 °C
2: nitric acid / dichloromethane / 2 h / 15 - 25 °C
3: hydrogen; palladium 10% on activated carbon / methanol / 10 h / 20 °C
4: 6 h / 110 °C
View Scheme
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

(E)-11-(2-chloroethylidene)-6,11-dihydrodibenzoxepin-2-carboxylic acid methyl ester
127167-47-9

(E)-11-(2-chloroethylidene)-6,11-dihydrodibenzoxepin-2-carboxylic acid methyl ester

(E)-11-<2-(5,6-dimethyl-1-benzimidazoyl)ethylidene>-6,11-dihydrodibenzoxepin-2-carboxylic acid methyl ester
127165-95-1

(E)-11-<2-(5,6-dimethyl-1-benzimidazoyl)ethylidene>-6,11-dihydrodibenzoxepin-2-carboxylic acid methyl ester

Conditions
ConditionsYield
In N,N-dimethyl-formamide; toluene for 3h; Heating;100%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

bromocyane
506-68-3

bromocyane

1-Cyano-5,6-dimethylbenzimidazole

1-Cyano-5,6-dimethylbenzimidazole

Conditions
ConditionsYield
With trimethylamine Ambient temperature;100%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

1-(halomethyl)-3,5-dimethylbenzene

1-(halomethyl)-3,5-dimethylbenzene

1-(3,5-dimethylbenzyl)-5,6-dimethyl-1H-benzo[d]imidazole

1-(3,5-dimethylbenzyl)-5,6-dimethyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium hydroxide In ethanol at 20℃; for 0.25h; Schlenk technique; Inert atmosphere;
Stage #2: 1-(halomethyl)-3,5-dimethylbenzene In ethanol for 25h; Reflux; Schlenk technique; Inert atmosphere;
100%
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole In ethanol at 20℃; for 1h; Inert atmosphere; Schlenk technique; Alkaline conditions;
Stage #2: 1-(halomethyl)-3,5-dimethylbenzene In ethanol at 80℃; Schlenk technique; Inert atmosphere;
93%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

C13H15N2O(1+)*BF4(1-)

C13H15N2O(1+)*BF4(1-)

4'-(5,6-Dimethyl-benzoimidazol-1-yl)-2,6,3'-trimethyl-4'H-[1,1']bipyridinyl-4-one
77487-30-0

4'-(5,6-Dimethyl-benzoimidazol-1-yl)-2,6,3'-trimethyl-4'H-[1,1']bipyridinyl-4-one

Conditions
ConditionsYield
With sodium methylate In methanol; acetonitrile at 20℃; for 0.5h;99%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

bis(trimethylsilyl)acetylenetitanocene

bis(trimethylsilyl)acetylenetitanocene

C76H76N8Ti4

C76H76N8Ti4

Conditions
ConditionsYield
In toluene at 60℃; for 24h; Inert atmosphere; Schlenk technique; Glovebox;99%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

1-(2-bromophenyl)-5,6-dimethylbenzimidazole

1-(2-bromophenyl)-5,6-dimethylbenzimidazole

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 150℃;99%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

(β-D-ribofuranosyl)-5,6-dimethylbenzimidazole
13082-84-3

(β-D-ribofuranosyl)-5,6-dimethylbenzimidazole

Conditions
ConditionsYield
for 1.5h; purine nucleoside phosphorylase of whole cells of E. coli BMT 1D/1A;98%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2'-Deoxyguanosine
961-07-9

2'-Deoxyguanosine

1-(5,6-dimethyl-benzoimidazol-1-yl)-β-D-erythro-1,2-dideoxy-pentofuranose
4600-72-0

1-(5,6-dimethyl-benzoimidazol-1-yl)-β-D-erythro-1,2-dideoxy-pentofuranose

Conditions
ConditionsYield
for 1.5h; purine nucleoside phosphorylase of whole cells of E. coli BMT 1D/1A;98%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

isoflavone
574-12-9

isoflavone

2-(5,6-dimethyl-1H-benzo[d]imidazol-1-yl)-3-phenyl-4H-chromen-4-one

2-(5,6-dimethyl-1H-benzo[d]imidazol-1-yl)-3-phenyl-4H-chromen-4-one

Conditions
ConditionsYield
With iodine; potassium carbonate In N,N-dimethyl-formamide at 80℃; regioselective reaction;98%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

5,6-Dimethyl-n-nitrobenzimidazol
21472-08-2

5,6-Dimethyl-n-nitrobenzimidazol

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With tert-butyl methyl ether; nitric acid In tetrahydrofuran at 0℃;
Stage #2: With sulfuric acid In dichloromethane at 0 - 5℃; for 1h; Further stages.;
97%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

isopropyl bromide
75-26-3

isopropyl bromide

1,3-diisopropyl-(5,6-dimethyl)benzimidazolium bromide
1435268-00-0

1,3-diisopropyl-(5,6-dimethyl)benzimidazolium bromide

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium carbonate In acetonitrile at 20℃; for 1h;
Stage #2: isopropyl bromide In acetonitrile for 96h; Reflux;
97%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

cyclohexane-1,2-epoxide
286-20-4

cyclohexane-1,2-epoxide

1-(2-hydroxycyclohexyl)-5,6-dimethylbenzimidazole
1184249-74-8

1-(2-hydroxycyclohexyl)-5,6-dimethylbenzimidazole

Conditions
ConditionsYield
In neat (no solvent) at 70℃; for 12h;97%
In neat (no solvent) at 70℃; for 12h;78%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2-bromo-N-(4-methoxyphenyl)benzenesulfonamide
1178125-92-2

2-bromo-N-(4-methoxyphenyl)benzenesulfonamide

C22H19N3O3S

C22H19N3O3S

Conditions
ConditionsYield
With copper(l) iodide; oxygen; sodium methylate; L-proline In N,N-dimethyl-formamide at 130℃; for 24h; Schlenk technique; Sealed tube;97%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

(2,3,4,5,6-pentamethylbenzyl) halide

(2,3,4,5,6-pentamethylbenzyl) halide

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium hydroxide In ethanol at 20℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: (2,3,4,5,6-pentamethylbenzyl) halide In ethanol at 80℃; Inert atmosphere; Schlenk technique;
97%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

1-(halomethyl)-2,3,4,5,6-pentamethylbenzene

1-(halomethyl)-2,3,4,5,6-pentamethylbenzene

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole In ethanol at 20℃; for 1h; Inert atmosphere; Schlenk technique; Alkaline conditions;
Stage #2: 1-(halomethyl)-2,3,4,5,6-pentamethylbenzene In ethanol at 80℃; Schlenk technique; Inert atmosphere;
97%
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium hydroxide In ethanol at 20℃; for 1h;
Stage #2: 1-(halomethyl)-2,3,4,5,6-pentamethylbenzene In ethanol at 80℃; for 24h;
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

N-phenacyl-p-toluidine
4831-18-9

N-phenacyl-p-toluidine

2-(5,6-Dimethyl-1H-benzo[d]imidazol-1-yl)-1-phenyl-2-(p-tolylimino)ethan-1-one

2-(5,6-Dimethyl-1H-benzo[d]imidazol-1-yl)-1-phenyl-2-(p-tolylimino)ethan-1-one

Conditions
ConditionsYield
With di-tert-butyl peroxide; copper(l) chloride In chlorobenzene at 110℃;97%
With di-tert-butyl peroxide; copper(l) chloride In chlorobenzene at 110℃; for 2h;77%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2,3,4,5,6-pentamethylbenzyl chloride
484-65-1

2,3,4,5,6-pentamethylbenzyl chloride

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

5,6-dimethyl-1-(2,3,4,5,6-pentamethylbenzyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium hydroxide In ethanol at 20℃; for 0.25h;
Stage #2: 2,3,4,5,6-pentamethylbenzyl chloride In ethanol at 20℃; for 17h; Reflux;
97%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

carbonochloridic acid 1-chloro-ethyl ester
50893-53-3

carbonochloridic acid 1-chloro-ethyl ester

allyltributylstanane
24850-33-7

allyltributylstanane

2-allyl-1,3-bis<(1-chloroethoxy)carbonyl>-5,6-dimethylbenzimidazoline

2-allyl-1,3-bis<(1-chloroethoxy)carbonyl>-5,6-dimethylbenzimidazoline

Conditions
ConditionsYield
With triethylamine In dichloromethane 0 deg C to room temp., 3 h;96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

C14H14BrNO2S

C14H14BrNO2S

C23H21N3O2S

C23H21N3O2S

Conditions
ConditionsYield
With copper(l) iodide; oxygen; sodium methylate; L-proline In N,N-dimethyl-formamide at 130℃; for 24h; Schlenk technique; Sealed tube;96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2-bromo-N-p-tolylbenzenesulfonamide
1183123-34-3

2-bromo-N-p-tolylbenzenesulfonamide

C22H19N3O2S

C22H19N3O2S

Conditions
ConditionsYield
With copper(l) iodide; oxygen; sodium methylate; L-proline In N,N-dimethyl-formamide at 130℃; for 24h; Schlenk technique; Sealed tube;96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2-chloro-5-fluoropyrimidine
62802-42-0

2-chloro-5-fluoropyrimidine

1-(5-fluoropyrimidin-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

1-(5-fluoropyrimidin-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 70℃; for 24h; Inert atmosphere;96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

6-(chloromethyl)-2-(methylthio)benzo[d]thiazole

6-(chloromethyl)-2-(methylthio)benzo[d]thiazole

6-((5,6-dimethyl-1H-benzo[d]imidazol-1-yl)methyl)-2-(methylthio)benzo[d]thiazole

6-((5,6-dimethyl-1H-benzo[d]imidazol-1-yl)methyl)-2-(methylthio)benzo[d]thiazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.0833333h; Inert atmosphere;
Stage #2: 6-(chloromethyl)-2-(methylthio)benzo[d]thiazole In N,N-dimethyl-formamide; mineral oil at 20℃; for 1h;
96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2,5-difluoropyrimidine
17573-84-1

2,5-difluoropyrimidine

1-(5-fluoropyrimidin-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

1-(5-fluoropyrimidin-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 70℃; for 24h; Schlenk technique;96%
isochromane
493-05-0

isochromane

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

C18H18N2O

C18H18N2O

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene In 1,2-dichloro-ethane at 20 - 80℃; for 6h; Schlenk technique;96%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

methyl iodide
74-88-4

methyl iodide

1,5,6-trimethylbenzimidazole
1128-27-4

1,5,6-trimethylbenzimidazole

Conditions
ConditionsYield
With potassium hydroxide; 18-crown-6 ether In tetrachloromethane for 30h; Ambient temperature;95%
With sodium hydroxide In water; acetonitrile at 0 - 20℃; for 72h; Inert atmosphere;65%
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With sodium hydroxide In tetrahydrofuran for 0.166667h;
Stage #2: methyl iodide In tetrahydrofuran at 20℃;
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With sodium hydride In mineral oil at 0 - 20℃; for 0.5h; Schlenk technique;
Stage #2: methyl iodide In mineral oil at 20℃; Schlenk technique;
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

1H-benzimidazole-5,6-dicarboxylic acid
10351-75-4

1H-benzimidazole-5,6-dicarboxylic acid

Conditions
ConditionsYield
With potassium permanganate In water; tert-butyl alcohol at 70℃; for 0.5h;95%
With potassium permanganate In tert-butyl alcohol at 75℃; for 1.5h;60%
With potassium permanganate at 75℃;55%
With potassium permanganate In water; tert-butyl alcohol at 70℃;48%

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