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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

2-Bromofluorobenzene Manufacturer/High quality/Best price/In stock

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------- Hangzhou Dingyan Chem is a leading manufacturer and supplier

high purity 1072-85-1 2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $1.9 / 2.5

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality O-Bromofluorobenzene supplier in China

Cas:1072-85-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 2-Bromofluorobenzene CAS number 1072-85-1 Assay ≥99% Appearance Colorless to yellowish transparent liquid Capacity 200mt/year Application Ph

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Intermediates Transportation:by air or by sea Port:Shanghai, Qingdao

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply O-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1

Negotiable

Type:Other

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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Name 2-Bromofluorobenzene Synonyms 1-Bromo-2-fluorobenzene Molecular Structure Molecular Formula

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

2-bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2-Bromofluorobenzene-

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 1072-85-1 with fast shipping

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material 2-Bromofluorobenzene CAS 1072-85-1

Cas:1072-85-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name Benzene, 1-bromo-2-fluoro- Synonyms 2-Bromofluorobenzene CAS No. 1072-85-1 Molecular weight 175.00 Molecular formula C6H4Br

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

1072-85-1 2-BromofluorobenzeneCAS NO.: 1072-85-1

Cas:1072-85-1

Min.Order:1 Gram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear colorless to light yellow liquid Storage:room temperature Package:200kg/Drum Application:1-Bromo-2-fluorobenzene is used as a reactant with cyclopenta-1,3-diene to produce 1,4-dihydro-1,4-methano-naphthalene. This reaction will ne

2-Bromofluorobenzene with high quality

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best serv

2-Bromofluorobenzene 1072-85-1

Cas:1072-85-1

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-2-fluoro- 1072-85-1

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

2-Bromofluorobenzene 99%

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $75.0 / 89.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

2-Bromofluorobenzene CAS:1072-85-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

2-Bromofluorobenzene CAS:1072-85-1

Cas:1072-85-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-2-fluoro-

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Benzene,1-bromo-2-fluoro-/ LIDE PHARMA- Factory supply / Best price

Cas:1072-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

2-Bromofluorobenzene CAS 1072-85-1

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Fluorobromobenzene

Cas:1072-85-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 1-Bromo-2-fluorobenzene(1072-85-1)

Cas:1072-85-1

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality O-Bromofluorobenzene

Cas:1072-85-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 2-Bromofluorobenzene CAS No.:1072-85-1 Molecule Formula:C6H4BrF Molecule Weight:175.00 Purity: 98.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

High Quality 2-Bromofluorobenzene on stock

Cas:1072-85-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

2-Bromofluorobenzene Chemical Properties Melting point -8°C Boiling point 78-82 °C50 mm Hg density 1.601 g/mL at 25 °C(lit.) refractive index n20/D 1.534(lit.) Fp 110 °F storage temp. Flammables area solubility

2-Bromofluorobenzene

Cas:1072-85-1

Min.Order:200 Kilogram

FOB Price: $65.0

Type:Lab/Research institutions

inquiry

Synthetic route

2-bromoaniline
615-36-1

2-bromoaniline

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
90%
(2-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate
1202186-81-9

(2-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 80℃; for 2h;71%
fluorobenzene
462-06-6

fluorobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With lead(IV) acetate; trifluoroacetic acid; potassium bromide at 25℃; for 0.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With manganese triacetate; trifluoroacetic acid; potassium bromide for 72h; Product distribution; Ambient temperature; Co(CH3COO)3, 67percent aq. CF3COOH, 15 - 10 h;
With potassium nitrate; potassium bromide In water; trifluoroacetic acid at 20℃; for 10h; Product distribution; under argon;
fluorobenzene
462-06-6

fluorobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2,4-dibromo-1-fluorobenzene
1435-53-6

2,4-dibromo-1-fluorobenzene

C

2,4,6-Tribromofluorobenzene
3925-78-8

2,4,6-Tribromofluorobenzene

D

1-Fluoro-1,2,3,4,5,6-hexabromocyclohexane
359-90-0

1-Fluoro-1,2,3,4,5,6-hexabromocyclohexane

E

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With bromine In trichlorofluoromethane for 42h; Irradiation; other compounds: o-, m-, p-difluorobenzene;
fluorobenzene
462-06-6

fluorobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2,4-dibromo-1-fluorobenzene
1435-53-6

2,4-dibromo-1-fluorobenzene

C

1-Fluoro-1,2,3,4,5,6-hexabromocyclohexane
359-90-0

1-Fluoro-1,2,3,4,5,6-hexabromocyclohexane

D

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With bromine In trichlorofluoromethane for 42h; Irradiation; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With fluorine In trichlorofluoromethane at -78℃; for 1h;A 23 % Chromat.
B 17 % Chromat.
C 60 % Chromat.
With fluorine In trichlorofluoromethane at -78℃; for 1h; Rate constant; Product distribution; competitive reaction with benzene;A 23 % Chromat.
B 17 % Chromat.
C 60 % Chromat.
With xenon difluoride; boron trifluoride diethyl etherate In acetonitrile at -35 - 20℃; for 2.5h; Inert atmosphere; Overall yield = 56 %;
(4-Bromo-3-fluoro-phenyl)-trimethyl-silane

(4-Bromo-3-fluoro-phenyl)-trimethyl-silane

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With potassium fluoride In N,N-dimethyl-formamide at 80℃; for 3h; Yield given;
1-chloro-2-fluorobenzene
348-51-6

1-chloro-2-fluorobenzene

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism;11.2 % Chromat.
2-bromo-benzenediazonium-(1)-hexafluoro phosphate

2-bromo-benzenediazonium-(1)-hexafluoro phosphate

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2-bromo-benzenediazonium-(1)-tetrafluoroborate

2-bromo-benzenediazonium-(1)-tetrafluoroborate

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

fluorobenzene
462-06-6

fluorobenzene

bromine
7726-95-6

bromine

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
Leiten durch ein Quarz-Rohr bei Temperaturen von 260grad bis 680grad;
Leiten durch ein Pyrex-Rohr bei Temperaturen von 425grad bis 475grad;
fluorobenzene
462-06-6

fluorobenzene

bromine
7726-95-6

bromine

iron

iron

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
at 100℃;
carbon disulfide
75-15-0

carbon disulfide

fluorobenzene
462-06-6

fluorobenzene

bromine
7726-95-6

bromine

aluminium

aluminium

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
at 55℃; Product distribution;
tetrachloromethane
56-23-5

tetrachloromethane

fluorobenzene
462-06-6

fluorobenzene

iodo monobromide

iodo monobromide

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

D

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
Product distribution;
fluorobenzene
462-06-6

fluorobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

D

HBr

HBr

Conditions
ConditionsYield
With bromine at 25℃; for 16h; Irradiation; Yield given;
o-fluorophenylboronic acid
1993-03-9

o-fluorophenylboronic acid

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione; sodium methylate In methanol; water; acetonitrile at 40℃; for 4h;98 % Chromat.
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2-bromo-1-oxypentafluorosulfanylbenzene
1000995-64-1

2-bromo-1-oxypentafluorosulfanylbenzene

C

4-bromo-1-oxypentafluorosulfanylbenzene
344455-90-9

4-bromo-1-oxypentafluorosulfanylbenzene

D

3-bromo-1-oxypentafluorosulfanylbenzene

3-bromo-1-oxypentafluorosulfanylbenzene

E

C6H3FBrOSF5

C6H3FBrOSF5

F

C6H3FBrOSF5

C6H3FBrOSF5

G

C6H3FBrOSF5

C6H3FBrOSF5

H

C6H3FBrOSF5

C6H3FBrOSF5

I

C6H3FBrOSF5

C6H3FBrOSF5

J

C6H3FBrOSF5

C6H3FBrOSF5

K

C6H3FBrOSF5

C6H3FBrOSF5

L

C6H3FBrOSF5

C6H3FBrOSF5

M

C6H3FBrOSF5

C6H3FBrOSF5

N

C6H3FBrOSF5

C6H3FBrOSF5

O

C6H4(OSF5)2

C6H4(OSF5)2

P

C6H4(OSF5)2

C6H4(OSF5)2

Q

C6H4(OSF5)2

C6H4(OSF5)2

R

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

S

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

T

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

U

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

V

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With bis(pentafluorosulfur) peroxide at 100℃; for 17h;
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2-bromo-1-oxypentafluorosulfanylbenzene
1000995-64-1

2-bromo-1-oxypentafluorosulfanylbenzene

C

4-bromo-1-oxypentafluorosulfanylbenzene
344455-90-9

4-bromo-1-oxypentafluorosulfanylbenzene

D

3-bromo-1-oxypentafluorosulfanylbenzene

3-bromo-1-oxypentafluorosulfanylbenzene

E

C6H3BrClOSF5

C6H3BrClOSF5

F

C6H3BrClOSF5

C6H3BrClOSF5

G

C6H3BrClOSF5

C6H3BrClOSF5

H

C6H3BrClOSF5

C6H3BrClOSF5

I

C6H3BrClOSF5

C6H3BrClOSF5

J

C6H3BrClOSF5

C6H3BrClOSF5

K

C6H3BrClOSF5

C6H3BrClOSF5

L

C6H3BrClOSF5

C6H3BrClOSF5

M

C6H3BrClOSF5

C6H3BrClOSF5

N

C6H3BrClOSF5

C6H3BrClOSF5

O

C6H4(OSF5)2

C6H4(OSF5)2

P

C6H4(OSF5)2

C6H4(OSF5)2

Q

C6H4(OSF5)2

C6H4(OSF5)2

R

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

S

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

T

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

U

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

V

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With bis(pentafluorosulfur) peroxide In dichloromethane at 150℃; for 22h;
2-Fluoro-1,4-bis-trimethylsilanyl-benzene
128254-27-3

2-Fluoro-1,4-bis-trimethylsilanyl-benzene

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Br2
2: KF / dimethylformamide / 3 h / 80 °C
View Scheme
2-bromoaniline
615-36-1

2-bromoaniline

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

o-bromobenzene diazonium fluoride

o-bromobenzene diazonium fluoride

Conditions
ConditionsYield
With hydrogen fluoride; sodium nitrite
C14H13BrN3Pol

C14H13BrN3Pol

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With tetrafluoroboric acid diethyl ether In tetradecafluorohexane at 100℃; for 1h; Balz-Schiemann reaction; Autoclave; solid phase reaction;52 %Chromat.
3-bromo-4-fluorobenzoic acid
1007-16-5

3-bromo-4-fluorobenzoic acid

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With dipotassium peroxodisulfate; silver(I) acetate In acetonitrile at 100℃; for 24h;
1-Fluoro-2-iodobenzene
348-52-7

1-Fluoro-2-iodobenzene

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid
2: copper(I) bromide / acetonitrile / 2 h / 80 °C
View Scheme
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2-bromo-1,4-difluorobenzene
399-94-0

2-bromo-1,4-difluorobenzene

C

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

D

1-bromo-3,4-difluorobenzene
348-61-8

1-bromo-3,4-difluorobenzene

E

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With xenon difluoride; boron trifluoride diethyl etherate at 0 - 25℃; Cooling with ice;A 0.06 mmol
B 0.01 mmol
C 0.03 mmol
D 0.004 mmol
E 0.16 mmol
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With 2-chloro-[1,10]phenanthroline; {Pd(2,2':6',2''-terpyridine)(acetonitrile)}(BF4)2; Selectfluor In acetonitrile at 50℃; for 12h; Reagent/catalyst; Temperature;
With [(terpy)Pd(2-Cl-phen)][BF4]; Selectfluor In acetonitrile at 50℃; Overall yield = 49 %Spectr.;
(2-bromophenyl)boronic acid
244205-40-1

(2-bromophenyl)boronic acid

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium fluoride / acetonitrile / 16 h / 90 °C
2: 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate / chloroform / 6 h / 60 °C
View Scheme
C19H12BiBrF3NOS

C19H12BiBrF3NOS

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
With 2,6-dichloro-1-fluoropyridin-1-ium tetrafluoroborate In chloroform at 60℃; for 6h;74 %Spectr.
2-bromobenzoic-acid
88-65-3

2-bromobenzoic-acid

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Conditions
ConditionsYield
Stage #1: 2-bromobenzoic-acid With tetrakis(acetonitrile)copper(I)tetrafluoroborate; tetrabutylammonium tetra(tert-butyl alcohol) coordinate fluoride; copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 23℃; for 0.5h; Sealed tube; Inert atmosphere;
Stage #2: In acetonitrile at 35℃; for 6h; Irradiation; Sealed tube; Inert atmosphere;
85 %Spectr.
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2-bromo-1-fluoro-4-nitrobenzene
701-45-1

2-bromo-1-fluoro-4-nitrobenzene

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 20℃; for 16h;100%
With sulfuric acid; nitric acid In water at 10 - 20℃;89%
With sulfuric acid; nitric acid at 10 - 20℃;89%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

6-amino-2,3,5-trimethylbenzo[b]thiophene
22988-70-1

6-amino-2,3,5-trimethylbenzo[b]thiophene

6-(2-fluorophenyl)amino-2,3,5-trimethylbenzo[b]thiophene

6-(2-fluorophenyl)amino-2,3,5-trimethylbenzo[b]thiophene

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 21h; Buchwald-Hartwig coupling;100%
With palladium diacetate; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 100℃; for 21h;100%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2-Fluoroaniline
348-54-9

2-Fluoroaniline

N,N-bis(2-fluorophenyl)amine
328-15-4

N,N-bis(2-fluorophenyl)amine

Conditions
ConditionsYield
With potassium tert-butylate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene for 24h; Heating / reflux;100%
Stage #1: o-fluorobromobenzene; 2-Fluoroaniline With sodium t-butanolate; palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether In toluene for 24h; Heating / reflux;
Stage #2: With water In toluene
91.4%
With sodium t-butanolate; palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether In toluene for 24h; Heating / reflux;91.4%
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; sodium t-butanolate In toluene at 110℃; for 16h; Buchwald-Hartwig Coupling;89%
With tri-tert-butyl phosphine; sodium t-butanolate; palladium diacetate In toluene at 90℃; for 16h;78%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

4-methoxy-phenol
150-76-5

4-methoxy-phenol

1-bromo-2-(4-methoxyphenoxy)benzene

1-bromo-2-(4-methoxyphenoxy)benzene

Conditions
ConditionsYield
With TMS-NEt2; phosphazene base t-Bu-P4 In hexane; N,N-dimethyl-formamide at 100℃; for 48h;100%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

bis(diethylamino)chlorophosphine
685-83-6

bis(diethylamino)chlorophosphine

(ortho-F-C6H4)P(NEt2)2
1219134-57-2

(ortho-F-C6H4)P(NEt2)2

Conditions
ConditionsYield
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexenes at -89 - -85℃; for 3h; Inert atmosphere;
Stage #2: bis(diethylamino)chlorophosphine In diethyl ether; hexenes at -100 - 20℃; Inert atmosphere;
100%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2,2'-difluorobiphenyl
388-82-9

2,2'-difluorobiphenyl

Conditions
ConditionsYield
With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; (C5H5)2Zr(OC4H8)N(Si(CH3)3)CH(C6H5); bis(dibenzylideneacetone)-palladium(0) In toluene at 80℃; for 16h; Sealed tube; Inert atmosphere;99%
With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; cesium fluoride In dimethyl sulfoxide at 100℃; for 1.5h;90%
Ni-2,2'-dipyridylamine In ethanol at 20℃; Reduction; Electrolysis;68%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Pentafluorobenzene
363-72-4

Pentafluorobenzene

2'-fluoro-2,3,4,5,6-pentafluoro-1,1'-biphenyl
41877-27-4

2'-fluoro-2,3,4,5,6-pentafluoro-1,1'-biphenyl

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium carbonate In Isopropyl acetate at 80℃; for 12h;99%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

benzoimidazole
51-17-2

benzoimidazole

1-(2-bromophenyl)-1H-benzo[d]imidazole
1198007-13-4

1-(2-bromophenyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 150℃;99%
With potassium phosphate In N,N-dimethyl-formamide at 190℃; for 1h; Microwave irradiation;86%
With caesium carbonate In N,N-dimethyl acetamide
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

1-(2-bromophenyl)-5,6-dimethylbenzimidazole

1-(2-bromophenyl)-5,6-dimethylbenzimidazole

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 150℃;99%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

9-phenyl-3,3'-bicarbazole
1060735-14-9

9-phenyl-3,3'-bicarbazole

C36H23BrN2

C36H23BrN2

Conditions
ConditionsYield
With caesium carbonate In 1-methyl-pyrrolidin-2-one at 170℃; for 24h; Inert atmosphere;99%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

2-fluorobiphenyl
321-60-8

2-fluorobiphenyl

Conditions
ConditionsYield
With caesium carbonate; palladium diacetate In toluene at 80℃; for 10h; Suzuki-Miyaura cross-coupling;98%
With potassium carbonate In ethanol; water at 20℃; for 6h; Suzuki-Miyaura coupling;91%
With potassium carbonate; bis(η3-allyl)palladium; Tedicyp In xylene at 140℃; for 20h; Suzuki cross-coupling;87%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

bromoacetic acid tert-butyl ester
5292-43-3

bromoacetic acid tert-butyl ester

tert-butyl α-(2-fluorophenyl)acetate
476429-08-0

tert-butyl α-(2-fluorophenyl)acetate

Conditions
ConditionsYield
Stage #1: bromoacetic acid tert-butyl ester With zinc In tetrahydrofuran at 20℃; for 0.166667h; Inert atmosphere; Sealed tube;
Stage #2: o-fluorobromobenzene With monophosphine 1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 20℃; for 4h; Inert atmosphere; Sealed tube;
98%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

carbon monoxide
201230-82-2

carbon monoxide

3-methylbenzenecarboximidamide hydrochloride
20680-59-5

3-methylbenzenecarboximidamide hydrochloride

2-(3-methylphenyl)-4(3H)-quinazolinone
18818-40-1

2-(3-methylphenyl)-4(3H)-quinazolinone

Conditions
ConditionsYield
With palladium diacetate; N-ethyl-N,N-diisopropylamine; catacxium A In N,N-dimethyl acetamide at 140℃; under 7500.75 Torr; for 22h; Inert atmosphere; Autoclave;98%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

4,7,10-trioxa-1,13-diaminotridecane
4246-51-9

4,7,10-trioxa-1,13-diaminotridecane

N,N'-(((oxybis(ethan-2,1-diyl))bis(oxy))bis(propane-3,1-diyl))bis(2-fluoroaniline)

N,N'-(((oxybis(ethan-2,1-diyl))bis(oxy))bis(propane-3,1-diyl))bis(2-fluoroaniline)

Conditions
ConditionsYield
Stage #1: o-fluorobromobenzene With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane Inert atmosphere;
Stage #2: 4,7,10-trioxa-1,13-diaminotridecane With sodium t-butanolate In 1,4-dioxane for 8h; Reagent/catalyst; Reflux;
98%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

Trimethyl borate
121-43-7

Trimethyl borate

o-fluorophenylboronic acid
1993-03-9

o-fluorophenylboronic acid

Conditions
ConditionsYield
Stage #1: o-fluorobromobenzene With n-butyllithium In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -30℃; Inert atmosphere; Flow reactor;
97%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2,6-diphenylmethyl-4-methylaniline
56138-96-6

2,6-diphenylmethyl-4-methylaniline

C39H32FN

C39H32FN

Conditions
ConditionsYield
With C36H37NP2; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 110℃; for 120h; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox;97%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

6-(6-(2,2,2-trifluoroethyl)thieno[2,3-d]pyrimidin-4-yl)-6-azaspiro[3.4]octan-2-amine trifluoroacetate

6-(6-(2,2,2-trifluoroethyl)thieno[2,3-d]pyrimidin-4-yl)-6-azaspiro[3.4]octan-2-amine trifluoroacetate

C21H20F4N4S

C21H20F4N4S

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; sodium t-butanolate In 1,4-dioxane at 130℃; for 12h; Inert atmosphere;97%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

N′-(1-(4-fluorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide
75230-49-8

N′-(1-(4-fluorophenyl)ethylidene)-4-methylbenzenesulfonohydrazide

1-(2-Fluorophenyl)-1-(4-fluorophenyl)-ethene

1-(2-Fluorophenyl)-1-(4-fluorophenyl)-ethene

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); di(1-adamantyl)-4-(N,N-dimethyl)amino-phenyl-phosphane trifluoroacetic acid; lithium tert-butoxide In 1,4-dioxane; water at 110℃; Sealed tube; Inert atmosphere;97%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene)
102632-49-5

1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene)

7,7'-bis(7-methyl-1,4,5,6-tetraphenyl-7-sila-2,3-benzonorbornadiene)

7,7'-bis(7-methyl-1,4,5,6-tetraphenyl-7-sila-2,3-benzonorbornadiene)

Conditions
ConditionsYield
With magnesium In tetrahydrofuran96%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

2-(2-fluorophenyl)-2-methyl-1,3-dioxolane
261966-94-3

2-(2-fluorophenyl)-2-methyl-1,3-dioxolane

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane; triethylamine; 1-butyl-3-methylimidazolium Tetrafluoroborate; palladium diacetate at 115℃; for 24h; Heck reaction;96%
With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; triethylamine In ethylene glycol at 145℃; Heck reaction; Inert atmosphere; regioselective reaction;77%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

benzo[c]carbazole
205-25-4

benzo[c]carbazole

7-(2-bromophenyl)-7H-benzo[c]carbazole

7-(2-bromophenyl)-7H-benzo[c]carbazole

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 150℃; for 6h;96%
With caesium carbonate In N,N-dimethyl-formamide at 150℃; for 12h; Inert atmosphere;92%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

N,N-dimethylaminodichlorophosphane
683-85-2

N,N-dimethylaminodichlorophosphane

bis(2-fluorophenyl)dimethylaminophosphine

bis(2-fluorophenyl)dimethylaminophosphine

Conditions
ConditionsYield
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether at -85 - -75℃; for 1h;
Stage #2: N,N-dimethylaminodichlorophosphane In diethyl ether at -85 - 20℃;
95.95%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

A

fluorobenzene
462-06-6

fluorobenzene

B

2,2'-difluorobiphenyl
388-82-9

2,2'-difluorobiphenyl

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride In 2-pentanol at 100℃; for 18h; Inert atmosphere;A 95.5%
B 4.5%
With palladium; hydroquinone; potassium hydroxide In glycerol at 90℃; for 18h; chemoselective reaction;A n/a
B 71 %Chromat.
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

benzyl alcohol
100-51-6

benzyl alcohol

2-bromophenyl benzyl ether
31575-75-4

2-bromophenyl benzyl ether

Conditions
ConditionsYield
With 1-methyl-pyrrolidin-2-one; sodium hydride at 100℃; for 1h;95%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

1-cyano-2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)naphthalene
918630-49-6

1-cyano-2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)naphthalene

1-cyano-2-(2-fluorophenyl)naphthalene
918630-57-6

1-cyano-2-(2-fluorophenyl)naphthalene

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 100℃; for 6h;95%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

diethylphosphoramidous dichloride
1069-08-5

diethylphosphoramidous dichloride

(ortho-F-C6H4)2P-NEt2
1065188-97-7

(ortho-F-C6H4)2P-NEt2

Conditions
ConditionsYield
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexane at -85 - -78℃; for 3h;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at -85 - -10℃;
95%
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexane at -85 - -78℃; for 3h;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at -85 - -10℃;
95%
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexane at -85 - -78℃; for 3h;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at -85 - -10℃;
95%
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexane at -85℃; for 3h; Inert atmosphere;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at -85 - -10℃;
95%
Stage #1: o-fluorobromobenzene With n-butyllithium In diethyl ether; hexane at -85 - -78℃; for 3h;
Stage #2: diethylphosphoramidous dichloride In diethyl ether; hexane at -85 - -10℃;
95%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

thieno<2,3-b>indole

thieno<2,3-b>indole

C16H10BrNS

C16H10BrNS

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 150℃; for 12h; Inert atmosphere;94.7%
With caesium carbonate In N,N-dimethyl-formamide at 150℃; for 12h; Inert atmosphere;94.7%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene
1257220-47-5

12,12-dimethyl-10,12-dihydro-10-azaindeno[2,1-b]fluorene

5-(2-bromophenyl)-7,7-dimethyl-5,7-dihydroindeno[2,1-b]carbazole

5-(2-bromophenyl)-7,7-dimethyl-5,7-dihydroindeno[2,1-b]carbazole

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide for 6h; Reflux;94.7%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene)
102632-49-5

1,1-bis(1-methyl-2,3,4,5-tetraphenyl-1-silacyclopentadiene)

11,11'-Dimethyl-1,8,9,10,1',8',9',10'-octaphenyl-[11,11']bi[11-sila-tricyclo[6.2.1.02,7]undecyl]-2(7),3,5,9,2'(7'),3',5',9'-octaene
102649-09-2

11,11'-Dimethyl-1,8,9,10,1',8',9',10'-octaphenyl-[11,11']bi[11-sila-tricyclo[6.2.1.02,7]undecyl]-2(7),3,5,9,2'(7'),3',5',9'-octaene

Conditions
ConditionsYield
With magnesium In tetrahydrofuran94%
o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

4-(2-fluoro-phenyl)-2-methyl-but-3-yn-2-ol
178173-84-7

4-(2-fluoro-phenyl)-2-methyl-but-3-yn-2-ol

Conditions
ConditionsYield
With piperidine; tetrakis(triphenylphosphine) palladium(0); triphenylphosphine; copper(I) bromide; lithium bromide In tetrahydrofuran for 0.5h; Heating;94%
With copper(l) iodide; diisopropylamine; triphenylphosphine; palladium dichloride In N,N-dimethyl-formamide at 60℃; for 24h;78%

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