Name: 4-Acetyl-1-methyl-1-cyclohexene Synonyms: 1-(4-methylcyclohex-3-en-1-yl)ethanone CAS: 6090-09-1 MF: C9H14O Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:Organic synt
Cas:6090-09-1
Min.Order:1 Kilogram
FOB Price: $1.0
Type:Other
inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:6090-09-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryAs a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry4-acetyl-1-methyl-1-cyclohexene CAS:6090-09-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality o
Cas:6090-09-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:6090-09-1
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:6090-09-1
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiry1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry4-Acetyl-1-methyl-1-cyclohexeneAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry6090-09-1 Application:intermediate
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquirygood quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:50mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any por
Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen
bulk?production Application:Pharmaceutical intermediates
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical
1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:6090-09-1
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryBetterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in
Cas:6090-09-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryU-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi
United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryJoyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryShanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete
Cas:6090-09-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiry4-acetyl-1-methyl-1-cyclohexene Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/S
Supply top quality products with a reasonable price Application:api
Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en
methyl vinyl ketone
isoprene
A
5-acetyl-1-methylcyclohexene
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With zeolite ZSM-5 In dichloromethane Heating; | A 2% B 98% |
scandium tris(trifluoromethanesulfonate) In dichloromethane at 0℃; for 13h; | A 6.7% B 91% |
With tin (IV) chloride pentahydrate In benzene at 21℃; for 1h; Inert atmosphere; | A n/a B 10% |
Conditions | Yield |
---|---|
With C36H47AlClN2O(1+)*C24H12BCl8(1-) In dichloromethane at 20℃; for 12h; Reagent/catalyst; Schlenk technique; | 97% |
With tris(pentafluoroethyl)difluorophosphorane In dichloromethane at 0 - 25℃; for 21h; Catalytic behavior; Kinetics; Mechanism; Temperature; Time; Diels-Alder Cycloaddition; | 93% |
With methyltrioxorhenium(VII) In chloroform for 18h; Ambient temperature; | 90% |
1-(4-methyl-3-cyclohexen-1-yl)ethanol
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With pyridinium chlorochromate In dichloromethane at 0 - 20℃; for 2h; | 93% |
A
(Z)-α-bisabolene
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide at 70℃; for 1h; | A 90.7% B n/a |
A
(E)‐α‐bisabolene
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 50℃; for 1h; | A 83.3% B n/a |
1-(c-4'-hydroxy-4'-methyl-r-1'-cyclohexyl)ethanone
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With iodine In toluene for 0.25h; Heating; | 81% |
C9H15O(1+)*F6Sb(1-)
A
methyl-4 cyclohexenyl-1 methyle cetone
B
1-(4-methyl-cyclohex-2-enyl)-ethanone
C
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
at 40℃; for 1h; Yields of byproduct given. Title compound not separated from byproducts; | A n/a B n/a C 70% |
methyl vinyl ketone
isoprene
A
3-acetyl-1-methylcyclohexene
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
at 20℃; for 0.666667h; deposition of a mixture of the substrates on the silica gel; reaction with acroleine; acceleration of a Diels-Alder reaction under adsorption conditions; | A n/a B 70% |
With tin(IV) chloride In benzene at 5 - 10℃; for 2h; |
4-acetyl-1-trimethylsilylmethyl-1-cyclohexene
A
1-(4-Methylenecyclohexyl)ethanone
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With potassium fluoride In dimethyl sulfoxide at 120℃; for 12h; | A 10% B 62% |
With potassium fluoride In dimethyl sulfoxide at 120℃; for 12h; Yield given; | |
With potassium fluoride In dimethyl sulfoxide at 120℃; for 12h; Mechanism; Product distribution; Method for preparation of exo-methylenecyclohexanes and cyclohexenes.; |
1-acetyl-2-methyl-2-vinylcyclobutane
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
ethylaluminum dichloride In dichloromethane at 0℃; for 0.5h; | 51% |
α-4-dimethyl-3-cyclohexene-1-acetaldehyde
A
(+-)-4-acetyl-1-methylcyclohexene
B
1-(4-methyl-3-cyclohexen-1-yl)ethanol
Conditions | Yield |
---|---|
With dihydrogen peroxide; potassium hydroxide In water; dimethyl sulfoxide; isopropyl alcohol at 20 - 80℃; for 3.5h; | A 12% B 46% |
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With chromium(VI) oxide; sulfuric acid 1-methyl-4-acetyl-cyclohexen-(1) of unknown optical behaviour; |
p-menthane-1,8,9-triol
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With chromium(VI) oxide; sulfuric acid optically inactive 1-methyl-4-acetyl-cyclohexene-(1); |
p-menthane-1,8,9-triol
A
1-(4-hydroxy-4-methylcyclohexyl)ethan-1-one
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With sulfate of CrO3 |
1-(4-hydroxy-4-methyl-cyclohexyl)-ethanone semicarbazone
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With oxalic acid isomer(ic) mixture; |
Conditions | Yield |
---|---|
With sulfuric acid; mercury(II) oxide at 45℃; isomer(ic) mixture; |
(R)-2-methyl-2-(4-methylcyclohex-3-en-1-yl)-1,3-dioxolane
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With hydrogenchloride In acetone |
Conditions | Yield |
---|---|
With oxygen; uranyl acetate In pyridine Irradiation; | |
Stage #1: limonene. With cis-[Ru(2,9-Me2phen)2(OH2)2](PF6)2 In acetonitrile at 55℃; for 0.5h; Stage #2: With dihydrogen peroxide In acetonitrile for 8h; | |
Multi-step reaction with 3 steps 1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere 1.2: 2 h / 0 °C / Inert atmosphere 2.1: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C 3.1: dihydrogen peroxide; potassium hydroxide / dimethyl sulfoxide; isopropyl alcohol; water / 3.5 h / 20 - 80 °C View Scheme | |
Multi-step reaction with 4 steps 1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 3 h / 0 - 20 °C / Inert atmosphere 1.2: 2 h / 0 °C / Inert atmosphere 2.1: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C 3.1: dihydrogen peroxide; potassium hydroxide / dimethyl sulfoxide; isopropyl alcohol; water / 3.5 h / 20 - 80 °C 4.1: pyridinium chlorochromate / dichloromethane / 2 h / 0 - 20 °C View Scheme |
4-oxocyclohexanecarboxylic acid
methyl iodide
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
(i) Li, Et2O, (ii) /BRN= 1635956/; Multistep reaction; |
2-phenylsulfinylmethyl-1,3-butadiene
methyl vinyl ketone
A
5-acetyl-1-methylcyclohexene
B
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
methyl vinyl ketone
isoprene
A
(+-)-4-acetyl-1-methylcyclohexene
B
1-(5-methylcyclohex-3-enyl)ethanone
Conditions | Yield |
---|---|
In toluene at 120℃; for 15h; Yield given; |
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With naphthalene-2-sulfonate at 160 - 180℃; isomer(ic) mixture; |
Conditions | Yield |
---|---|
With diethyl ether isomer(ic) mixture; |
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With chromium(VI) oxide; sulfuric acid 1-methyl-4-acetyl-cyclohexen-(1) of unknown optical behaviour; |
sulfuric acid
p-menthane-1,8,9-triol
A
(+-)-4-acetyl-1-methylcyclohexene
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With acetic acid; zinc |
(4-Methyl-3-pentenyl) diphenylphosphine oxide
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1.) butyllithium / 1.) hexane, THF, 0 deg C, 30 min; 2.) hexane, THF, -78 deg C; 3.) allowed to warm to r.t. during 2 h 2: sodium hydride / dimethylformamide / 1 h / 70 °C View Scheme | |
Multi-step reaction with 2 steps 1: 1.) butyllithium / 1.) hexane, THF, 0 deg C, 30 min; 2.) hexane, THF, -78 deg C; 3.) allowed to warm to r.t. during 2 h 2: 85 percent potassium hydroxide / dimethylsulfoxide / 1 h / 50 °C View Scheme |
trimethyl(2-methylenebut-3-enyl)silane
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 64 percent / aluminium chloride / benzene / 3.5 h / 15 - 20 °C / without cat. at 80 deg C, 36 h 2: KF / dimethylsulfoxide / 12 h / 120 °C View Scheme |
1-acetyl-2-methylcyclobutene
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1) CuBr*Me2S / 1) THF, 40 min, -40 deg C or 30 min, -20 deg C 2) 280 min, -40 deg C 2: 51 percent / EtAlCl2 / CH2Cl2 / 0.5 h / 0 °C View Scheme |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 4h; Claisen-Schmidt Condensation; | 98% |
Conditions | Yield |
---|---|
In diethyl ether for 0.5h; Ambient temperature; | 97% |
With hydrogenchloride 1.) Et2O, 35 deg C, 2 h, 2.) methanol, r.t., 20 min; Yield given. Multistep reaction; |
(+-)-4-acetyl-1-methylcyclohexene
1-(4-methyl-3-cyclohexen-1-yl)ethanol
Conditions | Yield |
---|---|
With aluminium trichloride; diphenylstibane In tetrahydrofuran for 2h; Ambient temperature; | 96% |
With ethanol; sodium | |
With C46H45ClN3O2PRu; sodium hydroxide In isopropyl alcohol at 90℃; for 24h; Reagent/catalyst; Glovebox; |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 2h; Reagent/catalyst; Claisen-Schmidt Condensation; | 96% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 3h; Claisen-Schmidt Condensation; | 95% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 2h; Claisen-Schmidt Condensation; | 93% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 3h; Claisen-Schmidt Condensation; | 92% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 4h; Claisen-Schmidt Condensation; | 92% |
(+-)-4-acetyl-1-methylcyclohexene
4-acetyl-1,2-epoxy-1-methylcyclohexane
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane Ambient temperature; | 86% |
(+-)-4-acetyl-1-methylcyclohexene
1-(4-methyl-3-cyclohexen-1-yl)-1-ethanone oxime
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In water; acetonitrile at 20℃; for 3h; | 86% |
Conditions | Yield |
---|---|
In diethyl ether for 0.25h; Ambient temperature; | 85% |
With diethyl ether dl-α-terpineol; |
Conditions | Yield |
---|---|
With sodium acetate In water; acetonitrile at 20℃; for 8h; | 82% |
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
With ruthenium trichloride; sodium periodate In ethyl acetate; acetonitrile for 0.05h; | 81% |
Conditions | Yield |
---|---|
With 5 weight% palladium(0) nanoparticles supported on mesoporous natural phosphate In neat (no solvent) for 24h; Reflux; | 80% |
With sulfuric acid |
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide electroreductive coupling; | 80% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 4h; Claisen-Schmidt Condensation; | 80% |
(+-)-4-acetyl-1-methylcyclohexene
Conditions | Yield |
---|---|
Stage #1: (+-)-4-acetyl-1-methylcyclohexene With iron(III) chloride In dichloromethane; water at 20℃; Stage #2: With sodium hypochlorite In dichloromethane; water at 20℃; for 0.583333h; | 80% |
Conditions | Yield |
---|---|
With tetraethylammonium tosylate In N,N-dimethyl-formamide electrolytic coupling; | 79% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 2h; Claisen-Schmidt Condensation; | 72% |
(+-)-4-acetyl-1-methylcyclohexene
propargyl magnesium bromide
Conditions | Yield |
---|---|
In diethyl ether for 2h; Ambient temperature; | 70% |
4-methyleneoxetan-2-one
(+-)-4-acetyl-1-methylcyclohexene
6-methyl-2-(4-methylcyclohex-3-en-1-yl)-1,3-dioxin-4-one
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In benzene for 20h; Heating; | 70% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol; water at 20℃; for 5h; Claisen-Schmidt Condensation; | 68% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View