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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality P-Isopropylbenzaldehyde supplier in China

Cas:122-03-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 4-isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Cuminaldehyde HACCP manufacturer

Cas:122-03-2

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Cuminaldehyde

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Cuminaldehyde

Cas:122-03-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

122-03-2 4-Isopropylbenzaldehyde Basic information Product Name: 4-Isopropylbenzaldehyde Synonyms: 4-(1-methylethyl)-benzaldehyd;4-(1-Methylethyl)benzaldehyde;4-(1-methylethyl)-Benzald

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Isopropylbenzaldehyde CAS 122-03-2

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 122-03-2 with best quality

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

P-Isopropylbenzaldehyde/Cuminaldehyde

Cas:122-03-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 4-Isopropylbenzaldehyde Synonyms Cuminaldehyde CAS 122-03-2 Molecular Formula C10H12O Molecular Weight

4-Isopropylbenzaldehyde CAS:122-03-2

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-Isopropylbenzaldehyde 122-03-2

Cas:122-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:colorless to yellow liquid Storage:Inert atmosphere,2-8°C Package:200kg/Drum Application:Cuminaldehyde is a flavoring agent that is a liquid, colorless to yellow in appearance, with a strong pungent odor resembling cumin oil. It is inso

Cuminaldehyde with high quality

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

JINING XINHE CHEMICAL CO., LTD

Advantage 1: The product passed the professional production process and quality inspection, the purity is 99% +. 2: Highly qualified engineers to provide technical documents and service. 3: We could provide sample for your test. 4: High qualit

P-Isopropylbenzaldehyde122-03-2

Cas:122-03-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

P-ISOPROPYLBENZALDEHYDE

Cas:122-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

p-IsopropylbenzaldehydeAppearance:Colorless transparent liquid Storage:Keep away of light, cool place Package:according to customers' requirements Application:pharmaceutical intermediates Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by

p-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Cuminaldehyde CAS: 122-03-2 MF: C10H12O MW: 148.2 EINECS: 204-516-9 Mol File: 122-03-2.mol Cuminaldehyde Structure Cuminaldehyde Chemical Properties Boiling point 235-236 °C(lit.) density 0.977 g/mL at 25

Cuminaldehyde

Cas:122-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

P-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

p-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

4-Isopropylbenzaldehyde

Cas:122-03-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

cuminol
536-60-7

cuminol

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In dichloromethane; water under 760.051 Torr; for 2h; Green chemistry;100%
With dmap; C25H30F17N5O4S(1-)*K(1+); oxygen; copper(II) sulfate In water at 25℃; for 2h; chemoselective reaction;99%
With titanium(IV) oxide; oxygen at 29.84℃; under 760.051 Torr; for 6h; Sealed tube; Irradiation;99%
isopropyllithium
1888-75-1

isopropyllithium

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: 4-bromo-benzaldehyde With bis(tri-tert-butylphosphine)palladium(0); sodium chloride In water at 20℃; for 0.166667h; Negishi Coupling; Schlenk technique;
Stage #2: isopropyllithium With zinc(II) chloride In 2-methyltetrahydrofuran; water at 10℃; for 0.00555556h; Schlenk technique; chemoselective reaction;
98%
4-isopropylbenzaldehyde oxime
3717-17-7, 3717-18-8, 13372-80-0

4-isopropylbenzaldehyde oxime

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With iron(III) chloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In water; toluene at 60℃; under 760.051 Torr; for 4h;95%
With tungsten(VI) chloride; zinc In acetonitrile at 20℃; for 0.333333h;92%
2-(4-isopropylphenyl)-1,3-dithiane

2-(4-isopropylphenyl)-1,3-dithiane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 1h;94%
2-(4-isopropylphenyl)-1,3-dithiolane
23229-31-4

2-(4-isopropylphenyl)-1,3-dithiolane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 2.45h;93%
With Oxone; potassium bromide In water; acetonitrile at 20℃; for 0.333333h;92%
With iodosylbenzene In dichloromethane at 20℃; for 0.25h;91%
4-isopropylstyrene
2055-40-5

4-isopropylstyrene

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With dihydrogen peroxide In acetonitrile at 65℃; for 6h;93%
With sodium periodate In water; ethyl acetate; acetonitrile at 0℃; for 3.5h;63%
Stage #1: 4-isopropylstyrene With BO40W12(5-)*2C12H12N6*Co(2+)*3H(1+)*10H2O In acetonitrile for 0.0833333h;
Stage #2: With dihydrogen peroxide In acetonitrile at 70℃; for 7h;
4-isopropylbenzyl chloride
2051-18-5

4-isopropylbenzyl chloride

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With potassium hydroxide; cetyltrimethylammonim bromide; potassium nitrate In water for 4h; pH=10 - 11; Reflux;92%
With 4Na(1+)*6H(1+)*NiMo6O24(10-)=Na4H6NiMo6O24; oxygen In water; acetonitrile at 20℃; under 760.051 Torr; for 12h; Irradiation;92%
With potassium nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; potassium bromide In water for 5h; Reflux;89%
4-i-propylbenzyl bromide
73789-86-3

4-i-propylbenzyl bromide

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With potassium nitrite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In water for 4h; Reflux;92%
Multi-step reaction with 2 steps
1: eosin y; oxygen / dimethyl sulfoxide / 12 h / 25 °C / Irradiation
2: eosin y / dimethyl sulfoxide / 24 h / 80 °C / Irradiation
View Scheme
4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

isopropyl zinc bromide
77047-87-1

isopropyl zinc bromide

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: 4-bromo-benzaldehyde With C40H55Cl5N3Pd In toluene at 0℃; for 0.0833333h; Negishi Coupling; Inert atmosphere; Cooling with ice;
Stage #2: isopropyl zinc bromide In tetrahydrofuran; toluene at 23℃; for 0.5h; Inert atmosphere;
92%
With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II) In tetrahydrofuran; toluene at 0 - 20℃; for 3h; Negishi coupling reaction; Inert atmosphere;78%
tert-butyl-(4-isopropyl-benzyloxy)-dimethyl-silane

tert-butyl-(4-isopropyl-benzyloxy)-dimethyl-silane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With N-hydroxyphthalimide; oxygen; cobalt(II) benzoate In acetonitrile at 20℃; for 0.666667h;90%
1,1-diacetoxy-1-(4-i-propylphenyl)methane
7154-10-1

1,1-diacetoxy-1-(4-i-propylphenyl)methane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With saccharin sulfonic acid at 90℃; for 0.0333333h; Neat (no solvent);90%
With water at 20℃; for 0.166667h; Green chemistry;96 %Chromat.
2-(4-isopropyl-phenyl)-[1,3]oxathiolane
23229-35-8

2-(4-isopropyl-phenyl)-[1,3]oxathiolane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With Iron(III) nitrate nonahydrate at 90℃; for 0.05h;90%
4-iso-propylbenzyl trimethylsilyl ether
71700-48-6

4-iso-propylbenzyl trimethylsilyl ether

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With N-hydroxyphthalimide; oxygen; cobalt(II) benzoate In acetonitrile at 20℃; for 0.333333h;89%
With silica chromate; silica gel In dichloromethane at 20℃; for 0.666667h;82%
2-(4-Isopropylbenzyloxy)-tetrahydropyran
394738-99-9

2-(4-Isopropylbenzyloxy)-tetrahydropyran

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride In water at 50℃; for 0.25h; pH=7;88%
1-(4-isopropylphenyl)ethanol
1475-10-1

1-(4-isopropylphenyl)ethanol

A

4-Isopropylbenzoic acid
536-66-3

4-Isopropylbenzoic acid

B

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With sodium nitrate; water; oxygen In dimethyl sulfoxide at 130℃; for 24h;A 88%
B 8%
4-isopropylbenzylamine
4395-73-7

4-isopropylbenzylamine

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With immobilised amine transaminase from the moderate halophilic bacterium Halomonas elongata; sodium pyruvate In aq. phosphate buffer; dimethyl sulfoxide at 37℃; under 760.051 Torr; for 5h; pH=8;84%
4-i-propylbenzyl bromide
73789-86-3

4-i-propylbenzyl bromide

A

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

B

cuminol
536-60-7

cuminol

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In water for 4h; Reflux;A 19%
B 76%
4-isopropylbenzyl chloride
2051-18-5

4-isopropylbenzyl chloride

A

4-Isopropylbenzoic acid
536-66-3

4-Isopropylbenzoic acid

B

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With potassium hydroxide; cetyltrimethylammonim bromide; potassium nitrate In water for 4h; pH=10 - 11; Reflux;A 2 g
B 71%
Isopropylbenzene
98-82-8

Isopropylbenzene

carbon dioxide
124-38-9

carbon dioxide

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: carbon dioxide With zinc(II) cyanide; ruthenium trichloride; rhodium (III) acetate; cobalt(II) acetate; zirconium(IV) acetate for 1h; Autoclave;
Stage #2: Isopropylbenzene at 50℃; under 15001.5 Torr; for 5h;
70.2%
4-isopropylbenzaldehyde oxime
3717-17-7, 3717-18-8, 13372-80-0

4-isopropylbenzaldehyde oxime

A

p-Cyanocumen
13816-33-6

p-Cyanocumen

B

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With pyridine; N-chloro-succinimide In acetonitrile at 20℃;A 70%
B n/a
(4-isopropylphenyl)acetic acid
4476-28-2

(4-isopropylphenyl)acetic acid

A

1-(fluoromethyl)-4-isopropylbenzene
477219-29-7

1-(fluoromethyl)-4-isopropylbenzene

B

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With xenon fluoride In dichloromethane at 20℃; for 14 - 18h; Inert atmosphere;A 67%
B 10%
isopropylboronic acid
80041-89-0

isopropylboronic acid

4-(trifluormethanesulfonyloxy)benzaldehyde
17763-69-8

4-(trifluormethanesulfonyloxy)benzaldehyde

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With potassium phosphate; C20H34O3P2; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere;67%
4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

A

(4-Isopropyl-phenyl)-nitromethan
33241-77-9

(4-Isopropyl-phenyl)-nitromethan

B

4-isopropylbenzyl nitrate
95543-77-4

4-isopropylbenzyl nitrate

C

para-methylacetophenone
122-00-9

para-methylacetophenone

D

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In acetonitrile at 17℃; for 0.666667h; Irradiation;A 3%
B 62%
C 6%
D 6%
With ammonium cerium(IV) nitrate In acetonitrile at 17℃; for 0.666667h; Irradiation; Further byproducts given;A 3%
B 62%
C 6%
D 6%
2-hydroxy-2-(4-isopropylphenyl)acetonitrile
91132-18-2

2-hydroxy-2-(4-isopropylphenyl)acetonitrile

A

4-Isopropylbenzoic acid
536-66-3

4-Isopropylbenzoic acid

B

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: 2-hydroxy-2-(4-isopropylphenyl)acetonitrile With (η(6)-benzene)chloro[1,2-bis(diphenylphosphino)ethane]ruthenium(II) chloride In benzene at 120℃; for 24h; Inert atmosphere; Schlenk technique;
Stage #2: With water In dichloromethane; ethyl acetate; benzene for 24h;
A 58%
B 36%
4-isopropyl-1-cyclopropylbenzene
27546-49-2

4-isopropyl-1-cyclopropylbenzene

A

(E)-3-(4-isopropylphenyl)acrylaldehyde
86604-05-9

(E)-3-(4-isopropylphenyl)acrylaldehyde

B

5-(4-isopropylphenyl)isoxazoline
119200-34-9

5-(4-isopropylphenyl)isoxazoline

C

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With dinitrogen tetraoxide; triethylamine In dichloromethane at -30℃; for 1h;A 28%
B 50%
C 7%
With dinitrogen tetraoxide In pentane at -30℃; for 6h;A 41%
B 40%
C 10%
With dinitrogen tetraoxide In pentane at -30℃; for 6h;A 40%
B 40%
C 10%
With dinitrogen tetraoxide In dichloromethane at -30℃; for 1h;A 39%
B 40%
C 8%
4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

A

1-methyl-4-isopropenylbenzene
1195-32-0

1-methyl-4-isopropenylbenzene

B

2-(4-isopropylbenzyl)-1,4-benzoquinone
69897-58-1

2-(4-isopropylbenzyl)-1,4-benzoquinone

C

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde
81036-81-9

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde

D

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With sodium persulfate; sulfuric acid; silver nitrate; p-benzoquinone In water at 60℃; for 0.5h;A 5%
B 45%
C 10%
D 20%
4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

A

2-(4-isopropylbenzyl)-1,4-benzoquinone
69897-58-1

2-(4-isopropylbenzyl)-1,4-benzoquinone

B

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde
81036-81-9

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde

C

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

D

cuminol
536-60-7

cuminol

Conditions
ConditionsYield
With sodium persulfate; sulfuric acid; silver nitrate; p-benzoquinone In water at 60℃; for 0.5h; Further byproducts given;A 45%
B 10%
C 20%
D 5%
4-methylisopropylbenzene
99-87-6

4-methylisopropylbenzene

p-benzoquinone
106-51-4

p-benzoquinone

A

2-(4-isopropylbenzyl)-1,4-benzoquinone
69897-58-1

2-(4-isopropylbenzyl)-1,4-benzoquinone

B

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde
81036-81-9

4-(2-hydroxy-2-propyl)benzene-1-carbaldehyde

C

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

D

cuminol
536-60-7

cuminol

Conditions
ConditionsYield
With sodium persulfate; sulfuric acid; silver nitrate In water at 60℃; for 0.5h; Further byproducts given;A 45%
B 10%
C 20%
D 5%
Isopropylbenzene
98-82-8

Isopropylbenzene

tris(diformylamino)methane
332047-72-0

tris(diformylamino)methane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: Isopropylbenzene; tris(diformylamino)methane With aluminium trichloride In 1,2-dichloro-ethane at -13 - -1℃; for 14h;
Stage #2: With water
38%
With aluminium trichloride In 1,2-dichloro-ethane at -13 - -1℃; for 14h;38%
(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

4-isopropylbenzaldehyde oxime
3717-17-7, 3717-18-8, 13372-80-0

4-isopropylbenzaldehyde oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In ethanol; water Reflux;100%
With hydroxylamine hydrochloride; sodium carbonate In methanol; water at 20℃; for 19.5h;99%
With bismuth(lll) trifluoromethanesulfonate; acetylhydroxamic acid In methanol for 24h; Reflux;97%
cis, trans-1,3-dimethylaminocyclohexane
2579-20-6

cis, trans-1,3-dimethylaminocyclohexane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C28H38N2
1217526-87-8

C28H38N2

Conditions
ConditionsYield
In methanol at 20℃; Molecular sieve;100%
In methanol at 20℃; Molecular sieve;
propylamine
107-10-8

propylamine

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C13H19N
100617-19-4

C13H19N

Conditions
ConditionsYield
at 20℃; for 12h;100%
1.3-propanedithiol
109-80-8

1.3-propanedithiol

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

2-(4-isopropylphenyl)-1,3-dithiane

2-(4-isopropylphenyl)-1,3-dithiane

Conditions
ConditionsYield
With 1-methyl-3-octylimidazolium hydrogen sulfate ionic liquid [OMIm]HSO4 inside the mesochannels of SBA-15-Pr-SO3H In neat (no solvent) at 20℃; for 2h; chemoselective reaction;100%
With oxygen In acetonitrile at 20℃; for 24h; Irradiation; Green chemistry; chemoselective reaction;95%
With cobalt(II) chloride In acetonitrile at 20℃;93%
With boron trifluoride diethyl etherate In dichloromethane Inert atmosphere;
C17H25NO3

C17H25NO3

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C27H36N2O2

C27H36N2O2

Conditions
ConditionsYield
With ammonium acetate In ethanol at 20℃; for 17h; Inert atmosphere;100%
C21H27NO3

C21H27NO3

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C31H38N2O2

C31H38N2O2

Conditions
ConditionsYield
With ammonium acetate In ethanol at 60℃; Inert atmosphere; Sealed tube;100%
C21H28FNO3

C21H28FNO3

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C31H37FN2O2

C31H37FN2O2

Conditions
ConditionsYield
With ammonium acetate In ethanol at 20℃; for 16h; Inert atmosphere; Sealed tube;100%
ethylenediamine
107-15-3

ethylenediamine

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

N,N‐bis(4‐isopropylbenzylidene)ethane‐1,2‐diamine

N,N‐bis(4‐isopropylbenzylidene)ethane‐1,2‐diamine

Conditions
ConditionsYield
In ethanol at 20℃; for 6h;99%
In methanol for 6h;92%
In ethanol at 40℃; for 10h;80%
at 120℃;
In methanol Inert atmosphere;
(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

4-Isopropylbenzoic acid
536-66-3

4-Isopropylbenzoic acid

Conditions
ConditionsYield
With C4H11FeMo6NO24(3-)*3C16H36N(1+); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 8h; Green chemistry;99%
With 4H3N*4H(1+)*CuMo6O18(OH)6(4-); water; oxygen; sodium carbonate at 50℃; under 760.051 Torr; for 12h;99%
With tris[2-(4,6-difluorophenyl)pyridinato-C2,N]-iridium(III); oxygen In acetonitrile at 20℃; Irradiation; Sealed tube; Green chemistry; chemoselective reaction;95%
acetone
67-64-1

acetone

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

(E)-4-(4-isopropylphenyl)but-3-en-2-one
74389-78-9, 81467-89-2

(E)-4-(4-isopropylphenyl)but-3-en-2-one

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; for 6h; Claisen-Schmidt Condensation;99%
With sodium hydroxide In water at 25℃; for 18h;41%
With sodium hydroxide In water Ambient temperature;16%
With sodium hydroxide In water at 25℃; for 12h;
With sodium hydroxide at 20℃; for 24h; Claisen-Schmidt Condensation;
cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

3-(p-isopropylphenyl)propionic acid
58420-21-6

3-(p-isopropylphenyl)propionic acid

Conditions
ConditionsYield
Stage #1: cycl-isopropylidene malonate; (4-isopropylbenzaldehyde) With formic acid; triethylamine In N,N-dimethyl-formamide at 0 - 80℃; for 14h;
Stage #2: With hydrogenchloride; water In N,N-dimethyl-formamide pH=1 - 2;
99%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

malononitrile
109-77-3

malononitrile

6-amino-2,4-dihydro-4-(4-isopropylphenyl)-3-methylpyrano[2,3-c]pyrazole-5-carbonitrile
326915-75-7, 340812-03-5

6-amino-2,4-dihydro-4-(4-isopropylphenyl)-3-methylpyrano[2,3-c]pyrazole-5-carbonitrile

Conditions
ConditionsYield
With hydrazine hydrate; heptakis(6-amino-6-deoxy)-β-cyclodextrin at 20℃; for 0.0166667h; Neat (no solvent);99%
With hydrazine hydrate; 2-amino-2-hydroxymethyl-1,3-propanediol In ethanol; water at 20℃; for 2.5h; Green chemistry;84%
(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

malononitrile
109-77-3

malononitrile

β,β-dicyano-4-isopropylstyrene
26088-83-5

β,β-dicyano-4-isopropylstyrene

Conditions
ConditionsYield
With Zn(N4,N4'-di(pyridin-4-yl)biphenyl-4,4'-dicarboxamide)(5-aminoisophthalate) In neat (no solvent) for 4h; Knoevenagel Condensation;99%
With 1-butyl-1,2,4-triazolium tetrafluoroborate In ethanol; water at 70℃; for 0.25h; Reagent/catalyst; Knoevenagel Condensation;92%
With tin dioxide In neat (no solvent) at 20℃; Knoevenagel Condensation; Green chemistry;90%
2-Hydroxy-1,4-naphthoquinone
83-72-7

2-Hydroxy-1,4-naphthoquinone

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C26H22O4

C26H22O4

Conditions
ConditionsYield
With silica-supported tungstic acid In neat (no solvent) at 60℃; for 0.0666667h; Sonication; Green chemistry;99%
(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-((4-isopropylbenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-((4-isopropylbenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With C34H28N6Zn In neat (no solvent) at 20℃; for 1h; Glovebox; Schlenk technique;99%
With C24H34N5PSeTi In neat (no solvent) at 30℃; for 2h; Glovebox; Schlenk technique; chemoselective reaction;96%
With [{2-(AdN=CH)–C4H3NK(THF)}n] at 30℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;92 %Spectr.
triethylsilane
617-86-7

triethylsilane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

triethyl((4-isopropylbenzyl)oxy)silane
53172-95-5

triethyl((4-isopropylbenzyl)oxy)silane

Conditions
ConditionsYield
With C42H43BN3P2(1+)*C18HBF15(1-) In chloroform at 40℃; for 1h; Reagent/catalyst; Temperature; Schlenk technique; Glovebox;99%
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

2-(4-isopropylphenyl)-1,3-dithiolane
23229-31-4

2-(4-isopropylphenyl)-1,3-dithiolane

Conditions
ConditionsYield
at 20℃;99%
1-methylindole
603-76-9

1-methylindole

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

bis(1-methyl-indol-3-yl)-4-isopropylphenylmethane

bis(1-methyl-indol-3-yl)-4-isopropylphenylmethane

Conditions
ConditionsYield
With ruthenium trichloride In methanol at 20℃; for 0.05h;98%
2-hydroxy-2-phenylacetophenone
119-53-9

2-hydroxy-2-phenylacetophenone

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

2‐(4‐isopropylphenyl)‐4,5‐diphenyl‐1H‐imidazole
5496-37-7

2‐(4‐isopropylphenyl)‐4,5‐diphenyl‐1H‐imidazole

Conditions
ConditionsYield
With 4,4'-diiodobiphenyl; ammonium acetate In ethanol for 0.5h; Heating;98%
With oxaline; ammonium acetate at 110℃; for 1h;80%
3-amino-2-methyl-6,7-methylenedioxyquinazolin-4(3H)-one
66117-84-8

3-amino-2-methyl-6,7-methylenedioxyquinazolin-4(3H)-one

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

3-[(4-isopropylbenzylidene)amino]-2-methyl-6,7-methylenedioxy-quinazolin-4(3H)-one
1192243-22-3

3-[(4-isopropylbenzylidene)amino]-2-methyl-6,7-methylenedioxy-quinazolin-4(3H)-one

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water at 20℃; for 1h; diastereoselective reaction;98%
anthranilic acid amide
28144-70-9

anthranilic acid amide

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

2,3-dihydro-2-(4-isopropylphenyl)quinazolin-4(1H)-one
83800-96-8

2,3-dihydro-2-(4-isopropylphenyl)quinazolin-4(1H)-one

Conditions
ConditionsYield
With phosphatidylcholine In water at 80℃; for 1h; Green chemistry;98%
With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at 20℃; for 0.166667h; chemoselective reaction;90%
With silica supported ceric ammonium nitrate (CAN*SiO2) In acetonitrile at 20℃; for 0.166667h;90%
2-oxo-propionic acid
127-17-3

2-oxo-propionic acid

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

C12H16O2

C12H16O2

Conditions
ConditionsYield
With cyclohexane-1,2-dione hydrolase In aq. buffer at 30℃; for 48h; pH=6.5; Enzymatic reaction;98%
1H-benzimidazol-2-amine
934-32-7

1H-benzimidazol-2-amine

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

malononitrile
109-77-3

malononitrile

2-amino-4-(4-isopropylphenyl)-1,4-dihydrobenzo[4,5]imidazolo[1,2-a]pyrimidine-3-carbonitrile
932995-93-2

2-amino-4-(4-isopropylphenyl)-1,4-dihydrobenzo[4,5]imidazolo[1,2-a]pyrimidine-3-carbonitrile

Conditions
ConditionsYield
With poly(vinylpyrrolidonium) perchlorate ([PVPH]ClO4) at 100℃; for 0.0666667h;98%
With toluene-4-sulfonic acid In neat (no solvent) at 80℃; for 0.55h; Green chemistry;92%
With 1-methyl-3-(trimethoxysilylpropyl)imidazolium hydrogen sulfate supported on rice husk ash In neat (no solvent) at 100℃; for 0.0833333h; Green chemistry;88%
cyclohexanecarbohydrazide
38941-47-8

cyclohexanecarbohydrazide

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

(E)-N'-(4-isopropylbenzylidene)cyclohexanecarbohydrazide

(E)-N'-(4-isopropylbenzylidene)cyclohexanecarbohydrazide

Conditions
ConditionsYield
In ethanol at 20℃; for 2h;98%
diisopropyl hydrogenphosphonate
1809-20-7

diisopropyl hydrogenphosphonate

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

malononitrile
109-77-3

malononitrile

diisopropyl [2,2-dicyano-1-(4-isopropylphenyl)ethyl]phosphonate

diisopropyl [2,2-dicyano-1-(4-isopropylphenyl)ethyl]phosphonate

Conditions
ConditionsYield
With dibutylamine In neat (no solvent) at 20℃; Green chemistry;98%
1-(7-hydroxy-2,2-dimethylchroman-6-yl)ethanone
31273-58-2

1-(7-hydroxy-2,2-dimethylchroman-6-yl)ethanone

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

(E)-1-(7-hydroxy-2,2-dimethylchroman-6-yl)-3-(4-isopropylphenyl)prop-2-en-1-one

(E)-1-(7-hydroxy-2,2-dimethylchroman-6-yl)-3-(4-isopropylphenyl)prop-2-en-1-one

Conditions
ConditionsYield
With potassium hydroxide In ethanol at 90℃; Claisen-Schmidt Condensation; Microwave irradiation;98%
cuminol
536-60-7

cuminol

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In dichloromethane; water under 760.051 Torr; for 2h; Green chemistry;100%
With dmap; C25H30F17N5O4S(1-)*K(1+); oxygen; copper(II) sulfate In water at 25℃; for 2h; chemoselective reaction;99%
With titanium(IV) oxide; oxygen at 29.84℃; under 760.051 Torr; for 6h; Sealed tube; Irradiation;99%
isopropyllithium
1888-75-1

isopropyllithium

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
Stage #1: 4-bromo-benzaldehyde With bis(tri-tert-butylphosphine)palladium(0); sodium chloride In water at 20℃; for 0.166667h; Negishi Coupling; Schlenk technique;
Stage #2: isopropyllithium With zinc(II) chloride In 2-methyltetrahydrofuran; water at 10℃; for 0.00555556h; Schlenk technique; chemoselective reaction;
98%
4-isopropylbenzaldehyde oxime
3717-17-7, 3717-18-8, 13372-80-0

4-isopropylbenzaldehyde oxime

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With iron(III) chloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen In water; toluene at 60℃; under 760.051 Torr; for 4h;95%
With tungsten(VI) chloride; zinc In acetonitrile at 20℃; for 0.333333h;92%
2-(4-isopropylphenyl)-1,3-dithiane

2-(4-isopropylphenyl)-1,3-dithiane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 1h;94%
2-(4-isopropylphenyl)-1,3-dithiolane
23229-31-4

2-(4-isopropylphenyl)-1,3-dithiolane

(4-isopropylbenzaldehyde)
122-03-2

(4-isopropylbenzaldehyde)

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 2.45h;93%
With Oxone; potassium bromide In water; acetonitrile at 20℃; for 0.333333h;92%
With iodosylbenzene In dichloromethane at 20℃; for 0.25h;91%

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