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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-methyl-1,3-pentadiene

Cas:926-56-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

4-METHYL-1,3-PENTADIENE Basic information Product Name: 4-METHYL-1,3-PENTADIENE Synonyms: 4-METHYL-1,3-PENTADIENE;(CH3)2C=CHCH=CH2;1,3-Pentadiene, 4-methyl-;1,3-pen

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Methyl-1,3-pentadiene

Cas:926-56-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:1 Kilogram

FOB Price: $2.0 / 10.0

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

4-METHYL-1,3-PENTADIENE CAS926-56-7

Cas:926-56-7

Min.Order:1 Kilogram

FOB Price: $2.0 / 10.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,3-Pentadiene,4-methyl-

Cas:926-56-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:A clear colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to

1,3-Pentadiene,4-methyl-

Cas:926-56-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

1,3-Pentadiene,4-methyl-

Cas:926-56-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and

4-methyl-1,3-pentadiene

Cas:926-56-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Harmonious Natural Bio-Technology Co., Ltd.

Before-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

4-METHYL-1,3-PENTADIENE

Cas:926-56-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

4-methylpenta-1,3-diene

Cas:926-56-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

N-(1-isopropylallyloxycarbonyl)aniline
76109-67-6

N-(1-isopropylallyloxycarbonyl)aniline

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methyl-3-(phenylamino)pent-1-ene
97206-71-8

4-methyl-3-(phenylamino)pent-1-ene

C

aniline
62-53-3

aniline

Conditions
ConditionsYield
PdLn In 1,4-dioxane at 100℃; for 0.25h;A n/a
B 2 % Chromat.
C 98%
((E)-4-Benzenesulfonyl-4-methyl-pent-2-enyl)-trimethyl-silane

((E)-4-Benzenesulfonyl-4-methyl-pent-2-enyl)-trimethyl-silane

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 25℃;72%
(E)-but-2-en-1-yl phenylcarbamate
146514-07-0

(E)-but-2-en-1-yl phenylcarbamate

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

(E)-N-(2-butenyl)aniline
35755-80-7

(E)-N-(2-butenyl)aniline

C

aniline
62-53-3

aniline

Conditions
ConditionsYield
PdLn In 1,4-dioxane at 100℃; for 6h;A n/a
B 70%
C 30%
3,3-dimethyl acrylaldehyde
107-86-8

3,3-dimethyl acrylaldehyde

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane for 12h; Ambient temperature;57%
With n-butyllithium In diethyl ether; toluene at 20℃; Inert atmosphere;14%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

Conditions
ConditionsYield
In pentane at 23℃; Irradiation; Further byproducts given;A 37%
B 14%
C 31%
D 11%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

Conditions
ConditionsYield
In pentane at 23℃; Irradiation; Further byproducts given;A 37%
B 14%
C 31%
D 7%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

E

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

Conditions
ConditionsYield
In pentane at 23℃; Product distribution; Irradiation;A 37%
B 14%
C 31%
D 11%
E 7%
(Z)-1,4-Diiodo-2-methyl-pent-1-ene

(Z)-1,4-Diiodo-2-methyl-pent-1-ene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

C

1,3-dimethylcyclobutene
1489-61-8

1,3-dimethylcyclobutene

Conditions
ConditionsYield
With tert.-butyl lithiumA 19%
B 32%
C 37%
2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

Conditions
ConditionsYield
With hydrogen bromide In water Dehydration;A 7%
B n/a
2,4,4,6-tetramethyl-1,3-dioxane
5182-37-6

2,4,4,6-tetramethyl-1,3-dioxane

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With phosphate-catalyst; water at 325℃;
2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methyl-4-penten-2-ol
2004-67-3

4-methyl-4-penten-2-ol

C

(E)-2-methyl-1,3-heptadiene
116374-76-6

(E)-2-methyl-1,3-heptadiene

2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With iodine
With hydrogen bromide
With aniline hydrobromide
With aluminium trichloride at 160℃;
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
Abspaltung von Wasser;
With dimethyl sulfoxide
Multi-step reaction with 2 steps
1: aluminium phosphate / 300 - 310 °C
2: zirconium (IV)-oxide /pumice stone / 300 - 310 °C
View Scheme
Multi-step reaction with 2 steps
1: chromium (III)-oxide-aluminium oxide / 200 °C
2: chromium (III)-oxide-aluminium oxide / 250 °C
View Scheme
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With chromium corundum at 250℃;
4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

2-methyl-1,4-pentadiene
763-30-4

2-methyl-1,4-pentadiene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With chromium corundum at 250℃;
With pumice stone; zirconium(IV) oxide at 300℃;
With pumice stone; zirconium(IV) oxide at 300 - 310℃;
2,5-dibromo-2-methylpentane
52278-94-1

2,5-dibromo-2-methylpentane

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With potassium hydroxide
2,5-dibromo-2-methylpentane
52278-94-1

2,5-dibromo-2-methylpentane

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

5-ethoxy-2-methyl-pent-2-ene
857825-89-9

5-ethoxy-2-methyl-pent-2-ene

Conditions
ConditionsYield
With potassium hydroxide
4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
Destillation ueber mit H2SO4 gatraenkten Bimsstein;
With hydrogen bromide
With acetic anhydride at 100℃;
With hydrogen bromide Destillation;
With aniline hydrobromide
2-methyl-pent-3-en-2-ol
63468-05-3, 71195-14-7, 71195-16-9

2-methyl-pent-3-en-2-ol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
Wasserabspaltung;
2-methyl-pent-3-en-2-ol
63468-05-3, 71195-14-7, 71195-16-9

2-methyl-pent-3-en-2-ol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With hydrogen bromide
5-chloro-2-methyl-pent-2-ene
7712-60-9

5-chloro-2-methyl-pent-2-ene

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With 2-ethoxy-ethanol; potassium hydroxide
1-bromo-4-methylpent-3-ene
2270-59-9

1-bromo-4-methylpent-3-ene

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With potassium hydroxide
With 2-ethoxy-ethanol; potassium hydroxide
With potassium hydroxide
4-chloro-4-methyl-1-pentetne
53875-83-5

4-chloro-4-methyl-1-pentetne

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With alcoholic alkali
(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; iodide

(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; iodide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With silver(l) oxide nachfolgende Destillation der erhaltenen Ammoniumbase;
(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; hydroxide

(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; hydroxide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
bei der trocknen Destillation;
(1,3-dimethyl-but-2-enyl)-trimethyl-ammonium; hydroxide

(1,3-dimethyl-but-2-enyl)-trimethyl-ammonium; hydroxide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
bei der Destillation;
ethyl-(1,1-dimethyl-but-3-enyl)-dimethyl-ammonium; hydroxide

ethyl-(1,1-dimethyl-but-3-enyl)-dimethyl-ammonium; hydroxide

A

N,N-dimethyl-ethanamine
598-56-1

N,N-dimethyl-ethanamine

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
bei der Destillation;
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

oxalic acid
144-62-7

oxalic acid

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
at 130 - 140℃;
(π-CD3CDCDCD2NiI)2

(π-CD3CDCDCD2NiI)2

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

(π-C4D7CH2CHCHC(CH3)2NiI)2

(π-C4D7CH2CHCHC(CH3)2NiI)2

Conditions
ConditionsYield
In benzene educts in stoich. amt.;100%
(π-CD3CDCDCD2NiI)2

(π-CD3CDCDCD2NiI)2

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

anti-(C4(2)H7CH2CHCHC(CH3)2NiI)2

anti-(C4(2)H7CH2CHCHC(CH3)2NiI)2

Conditions
ConditionsYield
in stoihometric amt.;100%
in stoihometric amt.;100%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C18H23F3O5S
1227628-62-7

C18H23F3O5S

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
1227628-64-9

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C18H23F3O5S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere;
99%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C17H21F3O4S
1227628-27-4

C17H21F3O4S

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
1227628-29-6

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C17H21F3O4S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere;
98%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

di-μ-chlorobis[(1,2,3-η)-4-hydroxy-4-methyl-2-penten-1-yl]dipalladium
116363-69-0

di-μ-chlorobis[(1,2,3-η)-4-hydroxy-4-methyl-2-penten-1-yl]dipalladium

Conditions
ConditionsYield
With water; potassium hydrogencarbonate In acetone to slurry of PdCl2(MeCN)2 (1.25 mmol) and KHCO3 (1.25 mmol) in acetone at 20°C added soln. of CH2CHCHCMe2 (1.00 mmol) and H2O (20.0 mmol) in acetone, stirred for 26 h at 20°C; filtered through Celite, ppt. washed with EtOAc, combined soln. concd. at water-aspirator pressure, flash chromd. (column, silica gel 60 (0.040-0.063 mm, Merck), EtOAc);95%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C17H21F3O4S
1227628-27-4

C17H21F3O4S

(1S,9aR)-8-methoxy-1,9a-dimethyl-2,3,9,9a-tetrahydro-1H-fluorene
1227628-31-0

(1S,9aR)-8-methoxy-1,9a-dimethyl-2,3,9,9a-tetrahydro-1H-fluorene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C17H21F3O4S With tetrakis(triphenylphosphine) palladium(0); cesium fluoride In tetrahydrofuran; 1,4-dioxane at 85℃; Suzuki coupling; Inert atmosphere;
91%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N’-di-tert-butylthiadiaziridine-1,1-dioxide
40121-14-0, 42028-73-9

N,N’-di-tert-butylthiadiaziridine-1,1-dioxide

C14H28N2O2S
1262436-55-4

C14H28N2O2S

Conditions
ConditionsYield
With tributylphosphine; copper(l) chloride In chloroform at 20℃; for 24h; sealed vial; Inert atmosphere; regioselective reaction;89%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

L-menthyl diazoacetate
63254-50-2

L-menthyl diazoacetate

2-(2-Methyl-propenyl)-cyclopropanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

2-(2-Methyl-propenyl)-cyclopropanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Conditions
ConditionsYield
With trans-RuIICl2-(2,6-di-<<(S)-4-isopropyl>oxazol-2-yl>pyridine)-(CH2=CH2) In dichloromethane86%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C13H12O

C13H12O

(1R*,3R*,4S*,6S*)-1-methyl-2-methylene-6-(2-methylprop-1-enyl)-3-phenylbicyclo[2.2.1]heptan-7-one

(1R*,3R*,4S*,6S*)-1-methyl-2-methylene-6-(2-methylprop-1-enyl)-3-phenylbicyclo[2.2.1]heptan-7-one

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -78℃; for 0.0833333h; Nazarov cyclization; stereoselective reaction;85%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

HSiPh3
789-25-3

HSiPh3

(Z)-(2-ethylidene-6-methylhept-5-en-1-yl)triphenylsilane

(Z)-(2-ethylidene-6-methylhept-5-en-1-yl)triphenylsilane

Conditions
ConditionsYield
With Hexamethyldisiloxane; mono(trimethylphosphine)(diallyl ether)palladium(0) In benzene-d6 at 30℃; for 2h;85%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

dimedone
126-81-8

dimedone

3,4,5,6,7,8-hexahydro-2,2,7,7-tetramethyl-2H-1-benzopyran-5-one

3,4,5,6,7,8-hexahydro-2,2,7,7-tetramethyl-2H-1-benzopyran-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;84%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

1-Methyl-2-acetyl-1,3-dithiolanium fluorosulfonate
73496-48-7

1-Methyl-2-acetyl-1,3-dithiolanium fluorosulfonate

2-Acetyl-3,6-dihydro-3,5-dimethyl-2-methylthio-2H-thiopyran
73496-54-5

2-Acetyl-3,6-dihydro-3,5-dimethyl-2-methylthio-2H-thiopyran

Conditions
ConditionsYield
With 2,6-dimethylpyridine In dichloromethane for 60h; Ambient temperature;82%
7-acetoxy-8-iodoflavone
693800-72-5

7-acetoxy-8-iodoflavone

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

8-(2-methyl-1-propenyl)-2-phenyl-8,9-dihydro-4H-furo[2,3-h]-1-benzopyran-4-one

8-(2-methyl-1-propenyl)-2-phenyl-8,9-dihydro-4H-furo[2,3-h]-1-benzopyran-4-one

Conditions
ConditionsYield
Stage #1: 7-acetoxy-8-iodoflavone With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane for 0.0833333h;
Stage #2: 4-methyl-1,3-pentadiene In 1,4-dioxane; water at 100℃; for 24h;
82%
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;82%
silver hexafluoroantimonate

silver hexafluoroantimonate

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride
854045-93-5

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

([P(t-Bu)2-o-biphenyl]Au[η2-4-methyl-1,3-pentadiene])SbF6
1301268-04-1

([P(t-Bu)2-o-biphenyl]Au[η2-4-methyl-1,3-pentadiene])SbF6

Conditions
ConditionsYield
In dichloromethane (N2); dissolving a mixt. of Au complex, Ag salt and diene in CH2Cl2, stirring in the dark at room temp. for 6 h; filtration through Celite, eluting with CH2Cl2, concn., addn. of hexanes, cooling to 4°C overnight; elem. anal.;82%
5-phenyl-cyclohexane-1,3-dione
493-72-1

5-phenyl-cyclohexane-1,3-dione

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2,2-dimethyl-7-phenyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

2,2-dimethyl-7-phenyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Reagent/catalyst; Solvent; Temperature; Sealed tube;82%
5-methylcyclohexan-1,3-dione
4341-24-6

5-methylcyclohexan-1,3-dione

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2,2,7-trimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

2,2,7-trimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;81%
Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide electroreductive coupling;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate
126554-34-5

ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate

ethyl 4,4-dimethyl-3-((E)-2-phenylethenyl)cyclohepta-1,5-diene-1-carboxylate
134418-91-0

ethyl 4,4-dimethyl-3-((E)-2-phenylethenyl)cyclohepta-1,5-diene-1-carboxylate

Conditions
ConditionsYield
rhodium(II) hexanoate In dichloromethane a) 10 deg C, 30 min, b) reflux, 10 min;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

benzaldehyde
100-52-7

benzaldehyde

2-ethyl-3-methyl-1-phenyl-3-buten-1-one
1073808-77-1

2-ethyl-3-methyl-1-phenyl-3-buten-1-one

Conditions
ConditionsYield
With carbonylchlorohydridotris(triphenylphosphine)ruthenium (II) In toluene at 90℃; for 24h; Inert atmosphere;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

7-acetoxy-4,8-dimethyl-6-iodocoumarin
512786-78-6

7-acetoxy-4,8-dimethyl-6-iodocoumarin

2,3-dihydro-5,9-dimethyl-2-(2-methyl-1-propenyl)-7H-furo[3,2-g][1]-benzopyran-7-one

2,3-dihydro-5,9-dimethyl-2-(2-methyl-1-propenyl)-7H-furo[3,2-g][1]-benzopyran-7-one

Conditions
ConditionsYield
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;79%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

7-acetoxy-8-iodo-4-methylcoumarin
343217-96-9

7-acetoxy-8-iodo-4-methylcoumarin

8,9-dihydro-4-methyl-8-(2-methyl-1-propenyl)-2H-furo[2,3-h]-1-benzopyran-2-one

8,9-dihydro-4-methyl-8-(2-methyl-1-propenyl)-2H-furo[2,3-h]-1-benzopyran-2-one

Conditions
ConditionsYield
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;78%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

2,2-dimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one
57545-47-8

2,2-dimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;74%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

2,2-Dichloro-3-(2-methylpropenyl)-cyclobutanone
90056-45-4

2,2-Dichloro-3-(2-methylpropenyl)-cyclobutanone

Conditions
ConditionsYield
With zinc; trichlorophosphate In diethyl ether for 12h; Ambient temperature;71%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2-oxopent-3-enenitrile
6047-88-7

2-oxopent-3-enenitrile

4-Methyl-6-(2-methyl-propenyl)-5,6-dihydro-4H-pyran-2-carbonitrile
344906-20-3

4-Methyl-6-(2-methyl-propenyl)-5,6-dihydro-4H-pyran-2-carbonitrile

Conditions
ConditionsYield
With aluminium trichloride In benzene Ambient temperature;70%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

phenylselenyl benzenesulfonate
60805-71-2

phenylselenyl benzenesulfonate

4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene
102860-20-8

4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid In dichloromethane Ambient temperature; 1) 17 h, 2) 15 min;68%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N-dibenzylformamide
5464-77-7

N,N-dibenzylformamide

1-(N,N-dibenzylamino)-2-ethenyl-3,3-dimethylcyclopropane
220247-77-8

1-(N,N-dibenzylamino)-2-ethenyl-3,3-dimethylcyclopropane

Conditions
ConditionsYield
With titanium(IV) isopropylate; methylmagnesium chloride; cyclohexylmagnesium bromide In tetrahydrofuran; diethyl ether at 20℃; for 10h;64%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N'-di-tert-butyldiaziridinone
19656-74-7

N,N'-di-tert-butyldiaziridinone

C15H28N2O

C15H28N2O

Conditions
ConditionsYield
With triphenyl phosphite; copper(l) chloride In benzene-d6 at 20℃; for 6h;62%

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