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inquiry4-METHYL-1,3-PENTADIENE Basic information Product Name: 4-METHYL-1,3-PENTADIENE Synonyms: 4-METHYL-1,3-PENTADIENE;(CH3)2C=CHCH=CH2;1,3-Pentadiene, 4-methyl-;1,3-pen
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inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
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inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
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inquiry1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
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inquirysuperior quality moderate price & quick delivery Appearance:A clear colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to
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inquiryOur own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin
Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP
Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and
Cas:926-56-7
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inquiryBefore-Sale Service:---Any inquiries will be replied within 12 hours.---Golden Manufactory under?ISO/GMP?with?large stock.---Dedication to quality,We?have?strict?quality?control?system.?---OEM/ODM Available.---Sample is available for your evaluation
Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat
CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio
N-(1-isopropylallyloxycarbonyl)aniline
A
4-methyl-1,3-pentadiene
B
4-methyl-3-(phenylamino)pent-1-ene
C
aniline
Conditions | Yield |
---|---|
PdLn In 1,4-dioxane at 100℃; for 0.25h; | A n/a B 2 % Chromat. C 98% |
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 25℃; | 72% |
(E)-but-2-en-1-yl phenylcarbamate
A
4-methyl-1,3-pentadiene
B
(E)-N-(2-butenyl)aniline
C
aniline
Conditions | Yield |
---|---|
PdLn In 1,4-dioxane at 100℃; for 6h; | A n/a B 70% C 30% |
3,3-dimethyl acrylaldehyde
Methyltriphenylphosphonium bromide
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With n-butyllithium In diethyl ether; pentane for 12h; Ambient temperature; | 57% |
With n-butyllithium In diethyl ether; toluene at 20℃; Inert atmosphere; | 14% |
1,3,3-trimethylcyclopropene
A
4-methyl-1,3-pentadiene
B
4-methylpent-2-yne
C
2-methyl-2,3-pentadiene
D
trans-2-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
In pentane at 23℃; Irradiation; Further byproducts given; | A 37% B 14% C 31% D 11% |
1,3,3-trimethylcyclopropene
A
4-methyl-1,3-pentadiene
B
4-methylpent-2-yne
C
2-methyl-2,3-pentadiene
D
2,3-dimethyl-buta-1,3-diene
Conditions | Yield |
---|---|
In pentane at 23℃; Irradiation; Further byproducts given; | A 37% B 14% C 31% D 7% |
1,3,3-trimethylcyclopropene
A
4-methyl-1,3-pentadiene
B
4-methylpent-2-yne
C
2-methyl-2,3-pentadiene
D
trans-2-methyl-1,3-pentadiene
E
2,3-dimethyl-buta-1,3-diene
Conditions | Yield |
---|---|
In pentane at 23℃; Product distribution; Irradiation; | A 37% B 14% C 31% D 11% E 7% |
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
C
1,3-dimethylcyclobutene
Conditions | Yield |
---|---|
With tert.-butyl lithium | A 19% B 32% C 37% |
2-methyl-2,4-pentanediol
A
4-methyl-1,3-pentadiene
B
trans-2-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With hydrogen bromide In water Dehydration; | A 7% B n/a |
2,4,4,6-tetramethyl-1,3-dioxane
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
Conditions | Yield |
---|---|
With phosphate-catalyst; water at 325℃; |
2-methyl-2,4-pentanediol
aniline hydrobromide
A
4-methyl pent-3-en-2-ol
B
4-methyl-1,3-pentadiene
2-methyl-2,4-pentanediol
aniline hydrobromide
A
4-methyl-1,3-pentadiene
B
4-methyl-4-penten-2-ol
C
(E)-2-methyl-1,3-heptadiene
Conditions | Yield |
---|---|
With iodine | |
With hydrogen bromide | |
With aniline hydrobromide | |
With aluminium trichloride at 160℃; |
Conditions | Yield |
---|---|
Abspaltung von Wasser; | |
With dimethyl sulfoxide | |
Multi-step reaction with 2 steps 1: aluminium phosphate / 300 - 310 °C 2: zirconium (IV)-oxide /pumice stone / 300 - 310 °C View Scheme | |
Multi-step reaction with 2 steps 1: chromium (III)-oxide-aluminium oxide / 200 °C 2: chromium (III)-oxide-aluminium oxide / 250 °C View Scheme |
2-methylpent-4-en-2-ol
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
Conditions | Yield |
---|---|
With chromium corundum at 250℃; |
4-methyl-pent-3-en-2-one
aluminum tri-sec-butoxide
A
4-methyl pent-3-en-2-ol
B
4-methyl-1,3-pentadiene
C
1,3-Dimethyl-1,3-butadien
2-methyl-1,4-pentadiene
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
Conditions | Yield |
---|---|
With chromium corundum at 250℃; | |
With pumice stone; zirconium(IV) oxide at 300℃; | |
With pumice stone; zirconium(IV) oxide at 300 - 310℃; |
2,5-dibromo-2-methylpentane
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With potassium hydroxide |
2,5-dibromo-2-methylpentane
A
4-methyl-1,3-pentadiene
B
5-ethoxy-2-methyl-pent-2-ene
Conditions | Yield |
---|---|
With potassium hydroxide |
Conditions | Yield |
---|---|
Destillation ueber mit H2SO4 gatraenkten Bimsstein; | |
With hydrogen bromide | |
With acetic anhydride at 100℃; | |
With hydrogen bromide Destillation; | |
With aniline hydrobromide |
2-methyl-pent-3-en-2-ol
aniline hydrobromide
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
Conditions | Yield |
---|---|
Wasserabspaltung; |
2-methyl-pent-3-en-2-ol
A
4-methyl-1,3-pentadiene
B
1,3-Dimethyl-1,3-butadien
Conditions | Yield |
---|---|
With hydrogen bromide |
Conditions | Yield |
---|---|
With 2-ethoxy-ethanol; potassium hydroxide |
Conditions | Yield |
---|---|
With potassium hydroxide | |
With 2-ethoxy-ethanol; potassium hydroxide | |
With potassium hydroxide |
4-chloro-4-methyl-1-pentetne
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With alcoholic alkali |
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With silver(l) oxide nachfolgende Destillation der erhaltenen Ammoniumbase; |
Conditions | Yield |
---|---|
bei der trocknen Destillation; |
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
bei der Destillation; |
Conditions | Yield |
---|---|
bei der Destillation; |
Conditions | Yield |
---|---|
at 130 - 140℃; |
Conditions | Yield |
---|---|
In benzene educts in stoich. amt.; | 100% |
Conditions | Yield |
---|---|
in stoihometric amt.; | 100% |
in stoihometric amt.; | 100% |
4-methyl-1,3-pentadiene
C18H23F3O5S
1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
Conditions | Yield |
---|---|
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere; Stage #2: C18H23F3O5S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere; | 99% |
4-methyl-1,3-pentadiene
C17H21F3O4S
1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
Conditions | Yield |
---|---|
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere; Stage #2: C17H21F3O4S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere; | 98% |
dichloro bis(acetonitrile) palladium(II)
4-methyl-1,3-pentadiene
di-μ-chlorobis[(1,2,3-η)-4-hydroxy-4-methyl-2-penten-1-yl]dipalladium
Conditions | Yield |
---|---|
With water; potassium hydrogencarbonate In acetone to slurry of PdCl2(MeCN)2 (1.25 mmol) and KHCO3 (1.25 mmol) in acetone at 20°C added soln. of CH2CHCHCMe2 (1.00 mmol) and H2O (20.0 mmol) in acetone, stirred for 26 h at 20°C; filtered through Celite, ppt. washed with EtOAc, combined soln. concd. at water-aspirator pressure, flash chromd. (column, silica gel 60 (0.040-0.063 mm, Merck), EtOAc); | 95% |
4-methyl-1,3-pentadiene
C17H21F3O4S
(1S,9aR)-8-methoxy-1,9a-dimethyl-2,3,9,9a-tetrahydro-1H-fluorene
Conditions | Yield |
---|---|
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere; Stage #2: C17H21F3O4S With tetrakis(triphenylphosphine) palladium(0); cesium fluoride In tetrahydrofuran; 1,4-dioxane at 85℃; Suzuki coupling; Inert atmosphere; | 91% |
4-methyl-1,3-pentadiene
N,N’-di-tert-butylthiadiaziridine-1,1-dioxide
C14H28N2O2S
Conditions | Yield |
---|---|
With tributylphosphine; copper(l) chloride In chloroform at 20℃; for 24h; sealed vial; Inert atmosphere; regioselective reaction; | 89% |
4-methyl-1,3-pentadiene
L-menthyl diazoacetate
Conditions | Yield |
---|---|
With trans-RuIICl2-(2,6-di-<<(S)-4-isopropyl>oxazol-2-yl>pyridine)-(CH2=CH2) In dichloromethane | 86% |
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane at -78℃; for 0.0833333h; Nazarov cyclization; stereoselective reaction; | 85% |
Conditions | Yield |
---|---|
With Hexamethyldisiloxane; mono(trimethylphosphine)(diallyl ether)palladium(0) In benzene-d6 at 30℃; for 2h; | 85% |
Conditions | Yield |
---|---|
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube; | 84% |
4-methyl-1,3-pentadiene
1,3-Dimethyl-1,3-butadien
1-Methyl-2-acetyl-1,3-dithiolanium fluorosulfonate
2-Acetyl-3,6-dihydro-3,5-dimethyl-2-methylthio-2H-thiopyran
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine In dichloromethane for 60h; Ambient temperature; | 82% |
7-acetoxy-8-iodoflavone
4-methyl-1,3-pentadiene
Conditions | Yield |
---|---|
Stage #1: 7-acetoxy-8-iodoflavone With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane for 0.0833333h; Stage #2: 4-methyl-1,3-pentadiene In 1,4-dioxane; water at 100℃; for 24h; | 82% |
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h; | 82% |
2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride
4-methyl-1,3-pentadiene
([P(t-Bu)2-o-biphenyl]Au[η2-4-methyl-1,3-pentadiene])SbF6
Conditions | Yield |
---|---|
In dichloromethane (N2); dissolving a mixt. of Au complex, Ag salt and diene in CH2Cl2, stirring in the dark at room temp. for 6 h; filtration through Celite, eluting with CH2Cl2, concn., addn. of hexanes, cooling to 4°C overnight; elem. anal.; | 82% |
Conditions | Yield |
---|---|
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Reagent/catalyst; Solvent; Temperature; Sealed tube; | 82% |
Conditions | Yield |
---|---|
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube; | 81% |
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide electroreductive coupling; | 80% |
4-methyl-1,3-pentadiene
ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate
ethyl 4,4-dimethyl-3-((E)-2-phenylethenyl)cyclohepta-1,5-diene-1-carboxylate
Conditions | Yield |
---|---|
rhodium(II) hexanoate In dichloromethane a) 10 deg C, 30 min, b) reflux, 10 min; | 80% |
4-methyl-1,3-pentadiene
benzaldehyde
2-ethyl-3-methyl-1-phenyl-3-buten-1-one
Conditions | Yield |
---|---|
With carbonylchlorohydridotris(triphenylphosphine)ruthenium (II) In toluene at 90℃; for 24h; Inert atmosphere; | 80% |
4-methyl-1,3-pentadiene
7-acetoxy-4,8-dimethyl-6-iodocoumarin
Conditions | Yield |
---|---|
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h; | 79% |
4-methyl-1,3-pentadiene
7-acetoxy-8-iodo-4-methylcoumarin
Conditions | Yield |
---|---|
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h; | 78% |
4-methyl-1,3-pentadiene
1,3-cylohexanedione
2,2-dimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one
Conditions | Yield |
---|---|
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube; | 74% |
4-methyl-1,3-pentadiene
Trichloroacetyl chloride
2,2-Dichloro-3-(2-methylpropenyl)-cyclobutanone
Conditions | Yield |
---|---|
With zinc; trichlorophosphate In diethyl ether for 12h; Ambient temperature; | 71% |
4-methyl-1,3-pentadiene
2-oxopent-3-enenitrile
4-Methyl-6-(2-methyl-propenyl)-5,6-dihydro-4H-pyran-2-carbonitrile
Conditions | Yield |
---|---|
With aluminium trichloride In benzene Ambient temperature; | 70% |
4-methyl-1,3-pentadiene
phenylselenyl benzenesulfonate
4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid In dichloromethane Ambient temperature; 1) 17 h, 2) 15 min; | 68% |
4-methyl-1,3-pentadiene
N,N-dibenzylformamide
1-(N,N-dibenzylamino)-2-ethenyl-3,3-dimethylcyclopropane
Conditions | Yield |
---|---|
With titanium(IV) isopropylate; methylmagnesium chloride; cyclohexylmagnesium bromide In tetrahydrofuran; diethyl ether at 20℃; for 10h; | 64% |
Conditions | Yield |
---|---|
With triphenyl phosphite; copper(l) chloride In benzene-d6 at 20℃; for 6h; | 62% |
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