Product Name

  • Name

    4-METHYL-1,3-PENTADIENE

  • EINECS
  • CAS No. 926-56-7
  • Article Data73
  • CAS DataBase
  • Density 0.707g/cm3
  • Solubility
  • Melting Point -94.9°C (estimate)
  • Formula C6H10
  • Boiling Point 76.5°Cat760mmHg
  • Molecular Weight 82.1454
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety A very dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also 2-METHYL-1,3-PENTADIENE.
  • Risk Codes 11-65
  • Molecular Structure Molecular Structure of 926-56-7 (4-METHYL-1,3-PENTADIENE)
  • Hazard Symbols
  • Synonyms 1,1-Dimethyl-1,3-butadiene;1,1-Dimethylbutadiene; 2-Methyl-2,4-pentadiene; 4-Methyl-1,3-pentadiene
  • PSA 0.00000
  • LogP 2.13860

Synthetic route

N-(1-isopropylallyloxycarbonyl)aniline
76109-67-6

N-(1-isopropylallyloxycarbonyl)aniline

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methyl-3-(phenylamino)pent-1-ene
97206-71-8

4-methyl-3-(phenylamino)pent-1-ene

C

aniline
62-53-3

aniline

Conditions
ConditionsYield
PdLn In 1,4-dioxane at 100℃; for 0.25h;A n/a
B 2 % Chromat.
C 98%
((E)-4-Benzenesulfonyl-4-methyl-pent-2-enyl)-trimethyl-silane

((E)-4-Benzenesulfonyl-4-methyl-pent-2-enyl)-trimethyl-silane

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In dimethyl sulfoxide at 25℃;72%
(E)-but-2-en-1-yl phenylcarbamate
146514-07-0

(E)-but-2-en-1-yl phenylcarbamate

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

(E)-N-(2-butenyl)aniline
35755-80-7

(E)-N-(2-butenyl)aniline

C

aniline
62-53-3

aniline

Conditions
ConditionsYield
PdLn In 1,4-dioxane at 100℃; for 6h;A n/a
B 70%
C 30%
3,3-dimethyl acrylaldehyde
107-86-8

3,3-dimethyl acrylaldehyde

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane for 12h; Ambient temperature;57%
With n-butyllithium In diethyl ether; toluene at 20℃; Inert atmosphere;14%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

Conditions
ConditionsYield
In pentane at 23℃; Irradiation; Further byproducts given;A 37%
B 14%
C 31%
D 11%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

Conditions
ConditionsYield
In pentane at 23℃; Irradiation; Further byproducts given;A 37%
B 14%
C 31%
D 7%
1,3,3-trimethylcyclopropene
3664-56-0

1,3,3-trimethylcyclopropene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methylpent-2-yne
21020-27-9

4-methylpent-2-yne

C

2-methyl-2,3-pentadiene
3043-33-2

2-methyl-2,3-pentadiene

D

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

E

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

Conditions
ConditionsYield
In pentane at 23℃; Product distribution; Irradiation;A 37%
B 14%
C 31%
D 11%
E 7%
(Z)-1,4-Diiodo-2-methyl-pent-1-ene

(Z)-1,4-Diiodo-2-methyl-pent-1-ene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

C

1,3-dimethylcyclobutene
1489-61-8

1,3-dimethylcyclobutene

Conditions
ConditionsYield
With tert.-butyl lithiumA 19%
B 32%
C 37%
2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

trans-2-methyl-1,3-pentadiene
926-54-5

trans-2-methyl-1,3-pentadiene

Conditions
ConditionsYield
With hydrogen bromide In water Dehydration;A 7%
B n/a
2,4,4,6-tetramethyl-1,3-dioxane
5182-37-6

2,4,4,6-tetramethyl-1,3-dioxane

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With phosphate-catalyst; water at 325℃;
2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

4-methyl-4-penten-2-ol
2004-67-3

4-methyl-4-penten-2-ol

C

(E)-2-methyl-1,3-heptadiene
116374-76-6

(E)-2-methyl-1,3-heptadiene

2-methyl-2,4-pentanediol
107-41-5

2-methyl-2,4-pentanediol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With iodine
With hydrogen bromide
With aniline hydrobromide
With aluminium trichloride at 160℃;
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
Abspaltung von Wasser;
With dimethyl sulfoxide
Multi-step reaction with 2 steps
1: aluminium phosphate / 300 - 310 °C
2: zirconium (IV)-oxide /pumice stone / 300 - 310 °C
View Scheme
Multi-step reaction with 2 steps
1: chromium (III)-oxide-aluminium oxide / 200 °C
2: chromium (III)-oxide-aluminium oxide / 250 °C
View Scheme
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With chromium corundum at 250℃;
4-methyl-pent-3-en-2-one
141-79-7

4-methyl-pent-3-en-2-one

aluminum tri-sec-butoxide
2269-22-9

aluminum tri-sec-butoxide

A

4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

2-methyl-1,4-pentadiene
763-30-4

2-methyl-1,4-pentadiene

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With chromium corundum at 250℃;
With pumice stone; zirconium(IV) oxide at 300℃;
With pumice stone; zirconium(IV) oxide at 300 - 310℃;
2,5-dibromo-2-methylpentane
52278-94-1

2,5-dibromo-2-methylpentane

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With potassium hydroxide
2,5-dibromo-2-methylpentane
52278-94-1

2,5-dibromo-2-methylpentane

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

5-ethoxy-2-methyl-pent-2-ene
857825-89-9

5-ethoxy-2-methyl-pent-2-ene

Conditions
ConditionsYield
With potassium hydroxide
4-methyl pent-3-en-2-ol
4325-82-0

4-methyl pent-3-en-2-ol

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
Destillation ueber mit H2SO4 gatraenkten Bimsstein;
With hydrogen bromide
With acetic anhydride at 100℃;
With hydrogen bromide Destillation;
With aniline hydrobromide
2-methyl-pent-3-en-2-ol
63468-05-3, 71195-14-7, 71195-16-9

2-methyl-pent-3-en-2-ol

aniline hydrobromide
542-11-0

aniline hydrobromide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
Wasserabspaltung;
2-methyl-pent-3-en-2-ol
63468-05-3, 71195-14-7, 71195-16-9

2-methyl-pent-3-en-2-ol

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

Conditions
ConditionsYield
With hydrogen bromide
5-chloro-2-methyl-pent-2-ene
7712-60-9

5-chloro-2-methyl-pent-2-ene

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With 2-ethoxy-ethanol; potassium hydroxide
1-bromo-4-methylpent-3-ene
2270-59-9

1-bromo-4-methylpent-3-ene

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With potassium hydroxide
With 2-ethoxy-ethanol; potassium hydroxide
With potassium hydroxide
4-chloro-4-methyl-1-pentetne
53875-83-5

4-chloro-4-methyl-1-pentetne

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With alcoholic alkali
(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; iodide

(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; iodide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
With silver(l) oxide nachfolgende Destillation der erhaltenen Ammoniumbase;
(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; hydroxide

(1,1-dimethyl-but-3-enyl)-trimethyl-ammonium; hydroxide

A

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

B

trimethylamine
75-50-3

trimethylamine

Conditions
ConditionsYield
bei der trocknen Destillation;
(1,3-dimethyl-but-2-enyl)-trimethyl-ammonium; hydroxide

(1,3-dimethyl-but-2-enyl)-trimethyl-ammonium; hydroxide

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
bei der Destillation;
ethyl-(1,1-dimethyl-but-3-enyl)-dimethyl-ammonium; hydroxide

ethyl-(1,1-dimethyl-but-3-enyl)-dimethyl-ammonium; hydroxide

A

N,N-dimethyl-ethanamine
598-56-1

N,N-dimethyl-ethanamine

B

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
bei der Destillation;
2-methylpent-4-en-2-ol
624-97-5

2-methylpent-4-en-2-ol

oxalic acid
144-62-7

oxalic acid

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Conditions
ConditionsYield
at 130 - 140℃;
(π-CD3CDCDCD2NiI)2

(π-CD3CDCDCD2NiI)2

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

(π-C4D7CH2CHCHC(CH3)2NiI)2

(π-C4D7CH2CHCHC(CH3)2NiI)2

Conditions
ConditionsYield
In benzene educts in stoich. amt.;100%
(π-CD3CDCDCD2NiI)2

(π-CD3CDCDCD2NiI)2

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

anti-(C4(2)H7CH2CHCHC(CH3)2NiI)2

anti-(C4(2)H7CH2CHCHC(CH3)2NiI)2

Conditions
ConditionsYield
in stoihometric amt.;100%
in stoihometric amt.;100%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C18H23F3O5S
1227628-62-7

C18H23F3O5S

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
1227628-64-9

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C18H23F3O5S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere;
99%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C17H21F3O4S
1227628-27-4

C17H21F3O4S

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene
1227628-29-6

1-(((1R,6S)-1,6-dimethyl-2-(4-methylpent-3-enyl)cyclohex-2-enyl)methyl)-2-methoxybenzene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C17H21F3O4S With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; potassium phosphate; triphenyl-arsane In tetrahydrofuran; water; N,N-dimethyl-formamide at 55℃; Suzuki coupling; Inert atmosphere;
98%
dichloro bis(acetonitrile) palladium(II)
21264-30-2, 90243-59-7, 14592-56-4

dichloro bis(acetonitrile) palladium(II)

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

di-μ-chlorobis[(1,2,3-η)-4-hydroxy-4-methyl-2-penten-1-yl]dipalladium
116363-69-0

di-μ-chlorobis[(1,2,3-η)-4-hydroxy-4-methyl-2-penten-1-yl]dipalladium

Conditions
ConditionsYield
With water; potassium hydrogencarbonate In acetone to slurry of PdCl2(MeCN)2 (1.25 mmol) and KHCO3 (1.25 mmol) in acetone at 20°C added soln. of CH2CHCHCMe2 (1.00 mmol) and H2O (20.0 mmol) in acetone, stirred for 26 h at 20°C; filtered through Celite, ppt. washed with EtOAc, combined soln. concd. at water-aspirator pressure, flash chromd. (column, silica gel 60 (0.040-0.063 mm, Merck), EtOAc);95%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C17H21F3O4S
1227628-27-4

C17H21F3O4S

(1S,9aR)-8-methoxy-1,9a-dimethyl-2,3,9,9a-tetrahydro-1H-fluorene
1227628-31-0

(1S,9aR)-8-methoxy-1,9a-dimethyl-2,3,9,9a-tetrahydro-1H-fluorene

Conditions
ConditionsYield
Stage #1: 4-methyl-1,3-pentadiene With 9-borabicyclo[3.3.1]nonane dimer In tetrahydrofuran at 0 - 23℃; for 2.5h; Suzuki coupling; Inert atmosphere;
Stage #2: C17H21F3O4S With tetrakis(triphenylphosphine) palladium(0); cesium fluoride In tetrahydrofuran; 1,4-dioxane at 85℃; Suzuki coupling; Inert atmosphere;
91%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N’-di-tert-butylthiadiaziridine-1,1-dioxide
40121-14-0, 42028-73-9

N,N’-di-tert-butylthiadiaziridine-1,1-dioxide

C14H28N2O2S
1262436-55-4

C14H28N2O2S

Conditions
ConditionsYield
With tributylphosphine; copper(l) chloride In chloroform at 20℃; for 24h; sealed vial; Inert atmosphere; regioselective reaction;89%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

L-menthyl diazoacetate
63254-50-2

L-menthyl diazoacetate

2-(2-Methyl-propenyl)-cyclopropanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

2-(2-Methyl-propenyl)-cyclopropanecarboxylic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Conditions
ConditionsYield
With trans-RuIICl2-(2,6-di-<<(S)-4-isopropyl>oxazol-2-yl>pyridine)-(CH2=CH2) In dichloromethane86%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

C13H12O

C13H12O

(1R*,3R*,4S*,6S*)-1-methyl-2-methylene-6-(2-methylprop-1-enyl)-3-phenylbicyclo[2.2.1]heptan-7-one

(1R*,3R*,4S*,6S*)-1-methyl-2-methylene-6-(2-methylprop-1-enyl)-3-phenylbicyclo[2.2.1]heptan-7-one

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -78℃; for 0.0833333h; Nazarov cyclization; stereoselective reaction;85%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

HSiPh3
789-25-3

HSiPh3

(Z)-(2-ethylidene-6-methylhept-5-en-1-yl)triphenylsilane

(Z)-(2-ethylidene-6-methylhept-5-en-1-yl)triphenylsilane

Conditions
ConditionsYield
With Hexamethyldisiloxane; mono(trimethylphosphine)(diallyl ether)palladium(0) In benzene-d6 at 30℃; for 2h;85%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

dimedone
126-81-8

dimedone

3,4,5,6,7,8-hexahydro-2,2,7,7-tetramethyl-2H-1-benzopyran-5-one

3,4,5,6,7,8-hexahydro-2,2,7,7-tetramethyl-2H-1-benzopyran-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;84%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

1,3-Dimethyl-1,3-butadien
1118-58-7

1,3-Dimethyl-1,3-butadien

1-Methyl-2-acetyl-1,3-dithiolanium fluorosulfonate
73496-48-7

1-Methyl-2-acetyl-1,3-dithiolanium fluorosulfonate

2-Acetyl-3,6-dihydro-3,5-dimethyl-2-methylthio-2H-thiopyran
73496-54-5

2-Acetyl-3,6-dihydro-3,5-dimethyl-2-methylthio-2H-thiopyran

Conditions
ConditionsYield
With 2,6-dimethylpyridine In dichloromethane for 60h; Ambient temperature;82%
7-acetoxy-8-iodoflavone
693800-72-5

7-acetoxy-8-iodoflavone

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

8-(2-methyl-1-propenyl)-2-phenyl-8,9-dihydro-4H-furo[2,3-h]-1-benzopyran-4-one

8-(2-methyl-1-propenyl)-2-phenyl-8,9-dihydro-4H-furo[2,3-h]-1-benzopyran-4-one

Conditions
ConditionsYield
Stage #1: 7-acetoxy-8-iodoflavone With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane for 0.0833333h;
Stage #2: 4-methyl-1,3-pentadiene In 1,4-dioxane; water at 100℃; for 24h;
82%
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;82%
silver hexafluoroantimonate

silver hexafluoroantimonate

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride
854045-93-5

2-(di-tert-butylphosphino)-1,1'-biphenylgold(I) chloride

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

([P(t-Bu)2-o-biphenyl]Au[η2-4-methyl-1,3-pentadiene])SbF6
1301268-04-1

([P(t-Bu)2-o-biphenyl]Au[η2-4-methyl-1,3-pentadiene])SbF6

Conditions
ConditionsYield
In dichloromethane (N2); dissolving a mixt. of Au complex, Ag salt and diene in CH2Cl2, stirring in the dark at room temp. for 6 h; filtration through Celite, eluting with CH2Cl2, concn., addn. of hexanes, cooling to 4°C overnight; elem. anal.;82%
5-phenyl-cyclohexane-1,3-dione
493-72-1

5-phenyl-cyclohexane-1,3-dione

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2,2-dimethyl-7-phenyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

2,2-dimethyl-7-phenyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Reagent/catalyst; Solvent; Temperature; Sealed tube;82%
5-methylcyclohexan-1,3-dione
4341-24-6

5-methylcyclohexan-1,3-dione

4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2,2,7-trimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

2,2,7-trimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;81%
Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In N,N-dimethyl-formamide electroreductive coupling;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate
126554-34-5

ethyl (E)-2-diazo-6-phenyl-1-hexa-3,5-dienoate

ethyl 4,4-dimethyl-3-((E)-2-phenylethenyl)cyclohepta-1,5-diene-1-carboxylate
134418-91-0

ethyl 4,4-dimethyl-3-((E)-2-phenylethenyl)cyclohepta-1,5-diene-1-carboxylate

Conditions
ConditionsYield
rhodium(II) hexanoate In dichloromethane a) 10 deg C, 30 min, b) reflux, 10 min;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

benzaldehyde
100-52-7

benzaldehyde

2-ethyl-3-methyl-1-phenyl-3-buten-1-one
1073808-77-1

2-ethyl-3-methyl-1-phenyl-3-buten-1-one

Conditions
ConditionsYield
With carbonylchlorohydridotris(triphenylphosphine)ruthenium (II) In toluene at 90℃; for 24h; Inert atmosphere;80%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

7-acetoxy-4,8-dimethyl-6-iodocoumarin
512786-78-6

7-acetoxy-4,8-dimethyl-6-iodocoumarin

2,3-dihydro-5,9-dimethyl-2-(2-methyl-1-propenyl)-7H-furo[3,2-g][1]-benzopyran-7-one

2,3-dihydro-5,9-dimethyl-2-(2-methyl-1-propenyl)-7H-furo[3,2-g][1]-benzopyran-7-one

Conditions
ConditionsYield
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;79%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

7-acetoxy-8-iodo-4-methylcoumarin
343217-96-9

7-acetoxy-8-iodo-4-methylcoumarin

8,9-dihydro-4-methyl-8-(2-methyl-1-propenyl)-2H-furo[2,3-h]-1-benzopyran-2-one

8,9-dihydro-4-methyl-8-(2-methyl-1-propenyl)-2H-furo[2,3-h]-1-benzopyran-2-one

Conditions
ConditionsYield
With silver carbonate; 1,2-bis-(diphenylphosphino)ethane; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane; water at 100℃; for 24h;78%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

2,2-dimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one
57545-47-8

2,2-dimethyl-2,3,4,6,7,8-hexahydro-5H-chromen-5-one

Conditions
ConditionsYield
With nafion In 1,2-dichloro-ethane at 110℃; for 24h; Sealed tube;74%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

Trichloroacetyl chloride
76-02-8

Trichloroacetyl chloride

2,2-Dichloro-3-(2-methylpropenyl)-cyclobutanone
90056-45-4

2,2-Dichloro-3-(2-methylpropenyl)-cyclobutanone

Conditions
ConditionsYield
With zinc; trichlorophosphate In diethyl ether for 12h; Ambient temperature;71%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

2-oxopent-3-enenitrile
6047-88-7

2-oxopent-3-enenitrile

4-Methyl-6-(2-methyl-propenyl)-5,6-dihydro-4H-pyran-2-carbonitrile
344906-20-3

4-Methyl-6-(2-methyl-propenyl)-5,6-dihydro-4H-pyran-2-carbonitrile

Conditions
ConditionsYield
With aluminium trichloride In benzene Ambient temperature;70%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

phenylselenyl benzenesulfonate
60805-71-2

phenylselenyl benzenesulfonate

4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene
102860-20-8

4-Methyl-2-(phenylsulfonyl)-1,3-pentadiene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid In dichloromethane Ambient temperature; 1) 17 h, 2) 15 min;68%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N-dibenzylformamide
5464-77-7

N,N-dibenzylformamide

1-(N,N-dibenzylamino)-2-ethenyl-3,3-dimethylcyclopropane
220247-77-8

1-(N,N-dibenzylamino)-2-ethenyl-3,3-dimethylcyclopropane

Conditions
ConditionsYield
With titanium(IV) isopropylate; methylmagnesium chloride; cyclohexylmagnesium bromide In tetrahydrofuran; diethyl ether at 20℃; for 10h;64%
4-methyl-1,3-pentadiene
926-56-7

4-methyl-1,3-pentadiene

N,N'-di-tert-butyldiaziridinone
19656-74-7

N,N'-di-tert-butyldiaziridinone

C15H28N2O

C15H28N2O

Conditions
ConditionsYield
With triphenyl phosphite; copper(l) chloride In benzene-d6 at 20℃; for 6h;62%

4-Methylpenta-1,3-diene Chemical Properties

IUPAC Name:  4-Methylpenta-1,3-diene
Synonyms:  4-Methylpenta-1,3-diene ; 1,3-Pentadiene, 4-methyl- ; 3-Methyl-1,4-pentadiene ; 4-Methyl-1,3-pentadiene ; Penta-1,3-diene, 4-methyl-
The Molecular Formula of  4-Methylpenta-1,3-diene (CAS NO.926-56-7):C6H10
The Molecular Weight of  4-Methylpenta-1,3-diene (CAS NO.926-56-7):82.1436g/mol
The Molecular Structure of  4-Methylpenta-1,3-diene (CAS NO.926-56-7):
Index of Refraction: 1.421
Molar Refractivity: 29.47 cm3
Molar Volume: 116  cm3
Surface Tension: 19.2 dyne/cm
Density: 0.707 g/ cm3
Flash Point: -18°C
Enthalpy of Vaporization: 30.44 kJ/mol
Boiling Point: 76.5 °C at 760 mmHg
Vapour Pressure: 111 mmHg at 25°C

4-Methylpenta-1,3-diene Uses

  4-Methylpenta-1,3-diene ,whose cas register No. is 926-56-7, can be used as reducing agent.

4-Methylpenta-1,3-diene Safety Profile

A very dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also 2-METHYL-1,3-PENTADIENE.
 Hazard Codes: FlammableF,HarmfulXn
Risk Statements: 11-65 
R11:Highly flammable. 
R65:Harmful: may cause lung damage if swallowed.
Safety Statements: 16-36-62 
S16:Keep away from sources of ignition. 
S36:Wear suitable protective clothing. 
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 2461 3/PG 2
WGK Germany: 3
HazardClass: 3.1
PackingGroup: II

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