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Wuhan Shengmao Corp

HIgh quality and competitive price Appearance:colorless transparent liquid Package:170kg or 200L/drum Application:629-14-1

Ethyleneglycol diethyl ether

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Ethyleneglycol diethyl ether

Cas:629-14-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

top Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product name 1,2-Diethoxyethane CAS No. 629-14-1

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Metric Ton

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Uses Can be used in acrylic resin, methacrylic resin, epoxy resin and nitro, ethyl cellulose & solvents, it can also be used in the pharmaceutical industry for extraction agent, lubricating oil additive, paint remover,

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:5 Metric Ton

FOB Price: $1.0

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:629-14-1

Cas:629-14-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ethyleneglycol diethyl ether

Cas:629-14-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Ethyleneglycol diethyl ether

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Ethylene Glycol Diethyl Ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting 1,2-Diethoxyethane, CAS NO.: 629-14-1 Please contact us by email freely. We are leading exporter in China. If you really need this cargo, please

1,2-Diethoxyethane, CAS NO.: 629-14-1

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless transparent liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application: Used in organic sy

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 629-14-1 with competitive price

Cas:629-14-1

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Preview CBNumber: CB8854036 Chemical Name: Ethylene glycol diethyl ether Molecular Formula:

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

HeBei Oriental Industry Co., Ltd

As a professional chemical export company for many years,We can provide the high quality service in this field. Good quality is our life. Clients' satisfaction is our principle. Good reputation is our origin. Be honest and p

Ethyl glyme series

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SuZhou LaiTeou

1, Quality: Our company is a professional production of intermediates and chemicals for many years, our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other country, and we have got very good feedback fro

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Kilogram

FOB Price: $18.0

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Profile HeBei Ruishun Trade Co.LTD, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,Seek development by credit

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:500 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

Best price Ethylene Glycol Dimethyl Ether

Cas:629-14-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Nanjing Raymon Biotech Co., Ltd.

Quality: 1. Testing before each delivery, including Nuclear Magnetic Resonance(NMR), Gas Chromatography(GC)/High Performance Liquid Chromatography(HPLC), Mass detection(MS), Optical rotation for chiral products. There are many other methods avail

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Other

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi

Ethylene Glycol Diethyl Ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1,2-Diethoxyethane

Cas:629-14-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

ORCHID CHEMICAL SUPPLIES LTD

Ethylene glycol diethyl ether CAS#629-14-1 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

Ethylene glycol diethyl ether

Cas:629-14-1

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

ethene
74-85-1

ethene

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With sulfuric acid at 40 - 70℃; under 3000.3 Torr; for 3h; Autoclave; Inert atmosphere;74.6%
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With sulfuric acid
With H-type ZSM-5(SiO2/Al2O3=280) at 180℃; for 3h;
With sulfuric acid
1-ethoxy-2-vinyloxy-ethane
18861-14-8

1-ethoxy-2-vinyloxy-ethane

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With nickel Hydrogenation.von gasfoermigem oder in Alkoholen geloestem;
With nickel Hydrogenation.von gasfoermigem oder in Alkoholen geloestem;
2-chloroethyl ethyl ether
628-34-2

2-chloroethyl ethyl ether

sodium ethanolate
141-52-6

sodium ethanolate

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With ethanol
1-ethoxy-2-trityloxy-ethane
4673-60-3

1-ethoxy-2-trityloxy-ethane

A

2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

C

triphenylmethane
519-73-3

triphenylmethane

D

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
at 325 - 330℃;
ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With copper
With tetrahydrofuran; magnesium
With tetrahydrofuran; sodium
With diethyl ether; sodium
Diazoethan
1117-96-0

Diazoethan

ethylene glycol
107-21-1

ethylene glycol

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

ethoxymethylmagnesium chloride
4279-03-2

ethoxymethylmagnesium chloride

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With benzyl bromide In tetrahydrofuran at -30℃;
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

A

ethanol
64-17-5

ethanol

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

C

acetaldehyde
75-07-0

acetaldehyde

D

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
With hydrogen; Ni-Cab-O-Sil at 300℃; Yield given. Yields of byproduct given;
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

A

2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

B

ethanol
64-17-5

ethanol

C

ethane
74-84-0

ethane

D

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

E

acetic acid
64-19-7

acetic acid

F

ethyl acetate
141-78-6

ethyl acetate

Conditions
ConditionsYield
With hydrogen; Pt-Cab-O-Sil at 300℃; Product distribution; Mechanism; var. of catalyst, temp.;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

1-butyl-1-nitrosourea
869-01-2

1-butyl-1-nitrosourea

A

2-Butoxyethanol
111-76-2

2-Butoxyethanol

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

C

1-(2-Ethoxyethoxy)butan
4413-13-2

1-(2-Ethoxyethoxy)butan

D

ethylene glycol sec-butyl ethyl ether
77078-19-4

ethylene glycol sec-butyl ethyl ether

Conditions
ConditionsYield
With sodium hydrogencarbonate for 24h; Ambient temperature; Further byproducts given;A 2.9 % Chromat.
B 0.9 % Chromat.
C 81.9 % Chromat.
D 12.6 % Chromat.
(E/Z)-1,2-dibromo-1,2-difluoroethylene
359-21-7

(E/Z)-1,2-dibromo-1,2-difluoroethylene

sodium 2-ethoxyethoxide
16993-83-2

sodium 2-ethoxyethoxide

A

3,6,9-trioxaundecane
112-36-7

3,6,9-trioxaundecane

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

C

(E)-1,2-Dibromo-1-(2-ethoxy-ethoxy)-2-fluoro-ethene

(E)-1,2-Dibromo-1-(2-ethoxy-ethoxy)-2-fluoro-ethene

D

2-ethoxyethyl bromofluoroacetate

2-ethoxyethyl bromofluoroacetate

E

(E)-1-Bromo-2-(2-ethoxy-ethoxy)-1,2-difluoro-ethene

(E)-1-Bromo-2-(2-ethoxy-ethoxy)-1,2-difluoro-ethene

F

(Z)-1-Bromo-2-(2-ethoxy-ethoxy)-1,2-difluoro-ethene

(Z)-1-Bromo-2-(2-ethoxy-ethoxy)-1,2-difluoro-ethene

Conditions
ConditionsYield
In 2-ethoxy-ethanol at 30 - 40℃; Product distribution;
O,O'-diethyl dithiooxalate
54129-84-9

O,O'-diethyl dithiooxalate

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With nickel In diethyl ether 1.) -15 deg C, 2.) -10 deg C, 2 min;23 % Chromat.
tetrahydrofuran
109-99-9

tetrahydrofuran

ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

magnesium

magnesium

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

tetrahydrofuran
109-99-9

tetrahydrofuran

ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

sodium

sodium

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

chloroethane
75-00-3

chloroethane

sodium compound of ethylene glycol-monoethyl ether

sodium compound of ethylene glycol-monoethyl ether

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

1,1-bis-(2-ethoxy-ethoxy)-ethane
39114-77-7

1,1-bis-(2-ethoxy-ethoxy)-ethane

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: platinized asbestos / 260 °C
2: nickel / Hydrogenation.von gasfoermigem oder in Alkoholen geloestem
View Scheme
3,6,9-trioxaundecane
112-36-7

3,6,9-trioxaundecane

A

1,4-dioxane
123-91-1

1,4-dioxane

B

diethyl ether
60-29-7

diethyl ether

C

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With Cp*Si(1+)* B(C6F5)4(1-) In dichloromethane-d2 at -30℃; for 144h; Inert atmosphere;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

ethanol
64-17-5

ethanol

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With MCM-22 zeolite at 50℃; under 750.075 Torr; Reagent/catalyst; Pressure; Temperature;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

diethyl ether
60-29-7

diethyl ether

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With MCM-22 In 1,4-dioxane at 90℃; under 6750.68 Torr; Reagent/catalyst; Temperature; Pressure; Inert atmosphere;
With hydrogen-type Beta molecular sieve at 220℃; under 22502.3 Torr; Temperature; Pressure; Reagent/catalyst; Autoclave;
ethanol
64-17-5

ethanol

ethylene glycol
107-21-1

ethylene glycol

A

1,4-dioxane
123-91-1

1,4-dioxane

B

2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

C

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With HY zeolite In water at 209.84℃; under 2250.23 Torr; for 4h; Catalytic behavior; Time; Flow reactor; Inert atmosphere; Green chemistry;
2-ethoxy-ethanol
110-80-5

2-ethoxy-ethanol

diethyl ether
60-29-7

diethyl ether

A

1,4-dioxane
123-91-1

1,4-dioxane

B

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

Conditions
ConditionsYield
With sulfonated styrene-divinylbenzene copolymer acidic cation exchange resin (D005) at 140℃; under 45004.5 Torr; Reagent/catalyst; Autoclave;
tantalum pentafluoride

tantalum pentafluoride

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

[TaF4(κ2-1,2-diethoxyethane)2][Ta2F11]
1203465-01-3

[TaF4(κ2-1,2-diethoxyethane)2][Ta2F11]

Conditions
ConditionsYield
In dichloromethane a suspn. of TaF5 treated with ligand, stirred at room temp.; filtered, evapd. (vac.), crystd. from CH2Cl2/heptane at room temp.; elem. anal.;78%
benzoxazole
273-53-0

benzoxazole

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]oxazole

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]oxazole

Conditions
ConditionsYield
With tert.-butylhydroperoxide; cobalt(II) carbonate In decane at 120℃; for 14h; Sealed tube; regioselective reaction;78%
With tert.-butylhydroperoxide In decane at 100℃; for 24h; Inert atmosphere;61%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

niobium pentachloride
10026-12-7

niobium pentachloride

NbCl4O(CH2CH3)CH2CH2O
1107601-61-5

NbCl4O(CH2CH3)CH2CH2O

Conditions
ConditionsYield
In dichloromethane (under Ar, Schlenk); suspn. of NbCl5 in CH2Cl2 treated with 1,2-diethoxyethane, stirred at room temp. for 30 min; filtered, layered with pentane, 12 h at -20°C; elem. anal.;77%
niobium pentafluoride

niobium pentafluoride

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

[NbF4(κ2-1,2-diethoxyethane)2][NbF6]
1203464-93-0

[NbF4(κ2-1,2-diethoxyethane)2][NbF6]

Conditions
ConditionsYield
In dichloromethane a suspn. of NbF5 treated with ligand, stirred at room temp.; evapd. (vac.), crystd. from CH2Cl2/pentane at room temp.; elem. anal.;77%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

niobium pentabromide
13478-45-0

niobium pentabromide

NbBr4[OCH2CH2OEt]
1310341-75-3

NbBr4[OCH2CH2OEt]

Conditions
ConditionsYield
In dichloromethane byproducts: CH3CH2Br; (Ar); addn. of dme to a suspn. of Nb compd. in CH2Cl2, stirring for 1 h at room temp.; pptn. by addn. of pentane; elem. anal.;77%
In chloroform-d1 byproducts: CH3CH2Br; (Ar); react. dme and Nb compd. in CDCl3; detected by NMR;
i-Amyl alcohol
123-51-3

i-Amyl alcohol

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

6-n-decyloxynaphthalene-2-carboxylic acid
122527-97-3

6-n-decyloxynaphthalene-2-carboxylic acid

1,2,3,4-tetrahydro-6-n-decyloxynaphthalene-2-carboxylic acid
137270-01-0

1,2,3,4-tetrahydro-6-n-decyloxynaphthalene-2-carboxylic acid

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water75%
In ethanol; water
In ethanol; water
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(Z)-1,2-bis(phenylsulfonyl)ethene
963-15-5

(Z)-1,2-bis(phenylsulfonyl)ethene

A

C14H20O4S

C14H20O4S

B

C14H20O4S

C14H20O4S

Conditions
ConditionsYield
With Benzoylformic acid at 20℃; Sealed tube; Irradiation; diastereoselective reaction;A 75%
B 21%
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)
121393-39-3

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl

Conditions
ConditionsYield
With PPh3; KOH; Ph4PBr In further solvent(s) under N2; in the dark; Rh compd. reacted with (MeCH2OCH2)2 in presence of PPh3 (1 equiv.), KOH (10 equiv.), H2O (50 equiv.) and Ph4PBr (0.1 equiv.) at 25°C for 10 min;74%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

tri-n-butyl(vinyl)tin
7486-35-3

tri-n-butyl(vinyl)tin

7-bromo-2-(3-fluoro-4-hydroxyphenyl)-1,3-benzoxazol-5-ol
544704-73-6

7-bromo-2-(3-fluoro-4-hydroxyphenyl)-1,3-benzoxazol-5-ol

prinaberel
524684-52-4

prinaberel

Conditions
ConditionsYield
trans-dichlorobis(tri-o-tolyl-phosphine)palladium(II)72%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

MoCl4[κ2-ROCH2CH2OEt]

MoCl4[κ2-ROCH2CH2OEt]

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere;72%
niobium(V) iodide
13779-92-5

niobium(V) iodide

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

[NbI4(κ1-OCH2CH2OEt))2
1310341-78-6

[NbI4(κ1-OCH2CH2OEt))2

Conditions
ConditionsYield
In dichloromethane byproducts: CH3CH2I; (Ar); addn. of dme to a suspn. of Nb compd. in CH2Cl2, stirring for 120 h at room temp.; pptn. by addn. of pentane; elem. anal.;61%
In chloroform-d1 byproducts: CH3CH2I; (Ar); react. dme and Nb compd. in CDCl3; detected by NMR;
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(5-fluoro-2-isocyanophenyl)(methyl)sulfane

(5-fluoro-2-isocyanophenyl)(methyl)sulfane

2-(1-(2-ethoxyethoxy)ethyl)-6-fluorobenzo[d]thiazole

2-(1-(2-ethoxyethoxy)ethyl)-6-fluorobenzo[d]thiazole

Conditions
ConditionsYield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile at 20℃; for 24h; Inert atmosphere; Irradiation; Green chemistry;60%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

tetramethyl titanium
2371-70-2

tetramethyl titanium

(CH3)4Ti(C2H5OC2H4OC2H5)

(CH3)4Ti(C2H5OC2H4OC2H5)

Conditions
ConditionsYield
In diethyl ether addn. of precooled 1,2-diethoxyethane to a soln. of Me4Ti in Et2O at -30°C; evapn. of solvent in vac. at -30°C;; dissolving residue in cold pentane, filtering; cooling to -78°C; crystn. after several days; decanting, drying at -30°C in vac.;;59.4%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(η6-indenyl-1,3-(SiMe3)2)(η5-indenyl-1,3-(SiMe3)2)Zr
573982-92-0, 831174-19-7

(η6-indenyl-1,3-(SiMe3)2)(η5-indenyl-1,3-(SiMe3)2)Zr

(η6-indenyl-1,3-(SiMe3)2)(η5-indenyl-1,3-(SiMe3)2)Zr(1,2-diethoxyethane)
863313-34-2

(η6-indenyl-1,3-(SiMe3)2)(η5-indenyl-1,3-(SiMe3)2)Zr(1,2-diethoxyethane)

Conditions
ConditionsYield
In pentane ligand added to Zr complex in pentane at 23°C; NMR;58%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(2-isocyanophenyl)(methyl)sulfane
175694-99-2

(2-isocyanophenyl)(methyl)sulfane

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

Conditions
ConditionsYield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile at 20℃; for 24h; Inert atmosphere; Irradiation; Green chemistry;54%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

A

ethoxymethyl 4-methoxybenzoate
1380825-76-2

ethoxymethyl 4-methoxybenzoate

B

1,2-diethoxyethyl 4-methoxybenzoate
1380825-77-3

1,2-diethoxyethyl 4-methoxybenzoate

Conditions
ConditionsYield
With copper(I) oxide; oxygen; potassium carbonate at 110℃; under 760.051 Torr; for 18h;A 43%
B 50%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(2-isocyano-5-methylphenyl)(methyl)sulfane

(2-isocyano-5-methylphenyl)(methyl)sulfane

2-(1-(2-ethoxyethoxy)ethyl)-6-methylbenzo[d]thiazole

2-(1-(2-ethoxyethoxy)ethyl)-6-methylbenzo[d]thiazole

Conditions
ConditionsYield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile at 20℃; for 24h; Inert atmosphere; Irradiation; Green chemistry;50%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(5-chloro-2-isocyanophenyl)(methyl)sulfane

(5-chloro-2-isocyanophenyl)(methyl)sulfane

6-chloro-2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

6-chloro-2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

Conditions
ConditionsYield
With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile at 20℃; for 24h; Inert atmosphere; Irradiation; Green chemistry;48%
benzoimidazole
51-17-2

benzoimidazole

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

A

1-(1-(2-ethoxyethoxy)ethyl)-1H-benzo[d]imidazole
1224507-26-9

1-(1-(2-ethoxyethoxy)ethyl)-1H-benzo[d]imidazole

B

1-(1,2-diethoxyethyl)-1H-benzo[d]imidazole
1224507-27-0

1-(1,2-diethoxyethyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
With tert.-butylhydroperoxide; iron(III) chloride hexahydrate In decane; ethyl acetate at 80℃; for 3h; Inert atmosphere; Molecular sieve;A 46%
B 40%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

tungsten(VI) chloride
13283-01-7

tungsten(VI) chloride

A

[WCl5(κ1-OCH2CH2OEt)]

[WCl5(κ1-OCH2CH2OEt)]

B

[WCl4(κ2-EtOCH2CH2OEt)]

[WCl4(κ2-EtOCH2CH2OEt)]

Conditions
ConditionsYield
In dichloromethane at 24.84℃; for 24h;A 45%
B 9%
1,3-Benzothiazole
95-16-9

1,3-Benzothiazole

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

A

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

2-(1-(2-ethoxyethoxy)ethyl)benzo[d]thiazole

B

C13H17NO2S

C13H17NO2S

Conditions
ConditionsYield
With tert.-butylhydroperoxide In decane at 100℃; for 24h; Inert atmosphere;A 45%
B 21%
monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

2-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide
1620193-47-6

2-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

A

2-(1-(2-ethoxyethoxy)ethyl)-6-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

2-(1-(2-ethoxyethoxy)ethyl)-6-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

B

2-(1,2-diethoxyethyl)-6-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

2-(1,2-diethoxyethyl)-6-methyl-N-(2-(pyridin-2-yl)propan-2-yl)benzamide

Conditions
ConditionsYield
With di-tert-butyl peroxide; bis(acetylacetonato)cobalt(II) at 140℃; for 12h; Schlenk technique; Inert atmosphere;A 36%
B 42%
perfluoropropylene
116-15-4

perfluoropropylene

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

1,1,1,2,3,3,10,10,11,12,12,12-dodecafluoro-4,9-dimethyl-6-(1,1,2,3,3,3-hexafluoropropyl)-5,8-dioxadodecane
166166-63-8

1,1,1,2,3,3,10,10,11,12,12,12-dodecafluoro-4,9-dimethyl-6-(1,1,2,3,3,3-hexafluoropropyl)-5,8-dioxadodecane

Conditions
ConditionsYield
In acetone for 72h; Addition; UV-irradiation;41%
α-picoline
109-06-8

α-picoline

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

A

2-(1-(2-ethoxyethoxy)ethyl)-6-methylpyridine

2-(1-(2-ethoxyethoxy)ethyl)-6-methylpyridine

B

2-(1,2-diethoxyethyl)-6-methylpyridine

2-(1,2-diethoxyethyl)-6-methylpyridine

Conditions
ConditionsYield
With di-tert-butyl peroxide; yttrium(III) trifluoromethanesulfonate at 120℃; for 24h; Sealed tube;A 33%
B 14%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

triethylamine
121-44-8

triethylamine

phenylmercury(II) chloride
100-56-1

phenylmercury(II) chloride

[(μ-SHg(phenyl))[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]

[(μ-SHg(phenyl))[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]

Conditions
ConditionsYield
In tetrahydrofuran N2; stirring Fe3(CO)12, CH3(CH2OCH2)2CH3, triethylamine in THF at room temp. for 45 min, adding (S2)Fe2(CO)6 to the resulting soln., stirring for 2 h at room temp., addn. of ClHgC6H5, stirring for 24 h; solvent removal under reduced pressure, chromy. (TLC, CH2Cl2/petroleum ether 2:1 vol.); elem. anal.;30%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

1,2-bis-(2-bromo-ethoxy)-ethane
31255-10-4

1,2-bis-(2-bromo-ethoxy)-ethane

triethylamine
121-44-8

triethylamine

[[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]2
681801-92-3

[[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]2

Conditions
ConditionsYield
In tetrahydrofuran N2; stirring Fe3(CO)12, CH3(CH2OCH2)2CH3, triethylamine in THF at room temp. for 45 min, adding (S2)Fe2(CO)6 to the resulting soln., stirring for 2 h at room temp., addn. of BrCH2(CH2OCH2)2CH2Br, stirring for 24 h; solvent removal under reduced pressure, chromy. (TLC, CH2Cl2/petroleum ether 2:1 vol.); elem. anal.;23%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

chloroacetic acid ethyl ester
105-39-5

chloroacetic acid ethyl ester

triethylamine
121-44-8

triethylamine

[(μ-SCH2COO(ethyl)[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]
681801-81-0

[(μ-SCH2COO(ethyl)[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ]

Conditions
ConditionsYield
In tetrahydrofuran N2; stirring Fe3(CO)12, CH3(CH2OCH2)2CH3, triethylamine in THF at room temp. for 45 min, adding (S2)Fe2(CO)6 to the resulting soln., stirring for 2 h at room temp., addn. of ClCH2C(O)OC2H5, stirring for 24 h; solvent removal under reduced pressure, chromy. (TLC, CH2Cl2/petroleum ether 2:1 vol.); elem. anal.;20%
triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

1-bromo-2-{2-[2-(2-bromoethoxy)ethoxy]-ethoxy}ethane
31255-26-2

1-bromo-2-{2-[2-(2-bromoethoxy)ethoxy]-ethoxy}ethane

triethylamine
121-44-8

triethylamine

[[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ][μ-SCH2(CH2OCH2)3CH2S-μ]
681801-97-8

[[Fe2(CO)6]2(μ4-S)]2[μ-SCH2(CH2OCH2)2CH2S-μ][μ-SCH2(CH2OCH2)3CH2S-μ]

Conditions
ConditionsYield
In tetrahydrofuran N2; stirring Fe3(CO)12, CH3(CH2OCH2)2CH3, triethylamine in THF at room temp. for 45 min, adding (S2)Fe2(CO)6 to the resulting soln., stirring for 2 h at room temp., addn. of BrCH2(CH2OCH2)3CH2Br, stirring for 24 h; solvent removal under reduced pressure, chromy. (TLC, CH2Cl2/petroleum ether 2:1 vol.); elem. anal.;19%
(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide
85990-32-5

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

monoethylene glycol diethyl ether
629-14-1

monoethylene glycol diethyl ether

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate)rhodium(III) methyl

Conditions
ConditionsYield
With KOH In further solvent(s) reaction of rhodium compd. with diisopentyl ether in presence of 10 equiv. of KOH at 100°C for 1 d under N2;19%

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