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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-Thiophenemethanol Manufacturer/High quality/Best price/In stock

Cas:636-72-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Thiophenemethanol supplier in China

Cas:636-72-6

Min.Order:1 Metric Ton

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Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

Good quality Good price Appearance:powder Storage:dry condition Package:A Application:intermediate Port:Shanghai Port

636-72-6, 2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Thiophenemethanol

Cas:636-72-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 2-Thiophenemethanol CAS No. 636-72-6

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Metric Ton

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

636-72-6 2-Thiophenemethanol Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate (

636-72-6 2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Chinese Standard CAS 636-72-6 with high-quality service

Cas:636-72-6

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:636-72-6

Cas:636-72-6

Min.Order:0

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Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

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Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

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Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Thiophenemethanol

Cas:636-72-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

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Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

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Type:Other

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Manufacturers

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Colorless or light yellow liquid Storage:sealed and stored Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediates Transportation:as per your

2-Thiophenemethanol

Cas:636-72-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:Colorless to light yellow liquid Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Thiophenemethanol cas no. 636-72-6 98%

Cas:636-72-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Thiophene-2-methanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Other

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Manufacturers

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Shandong Xinhua Pharmaceutical Co.,Ltd

Used as a pharmaceutical intermediate Application:Used as a pharmaceutical intermediate

Thiophene-2-ethanol

Cas:636-72-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Name 2-Thiophenemethanol Synonyms 2-Thienylmethanol; Thiophene-2-methanol; 2-Hydroxymethylthiophene Molecular Structure

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou Fandachem Co.,Ltd

2-Thiophenemethanol cas 636-72-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Thiophenemethanol cas 636-72-6

Cas:636-72-6

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:clear colourless to light yellow liquid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-Thiophenemethanol

Cas:636-72-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

2-Thiophenemethanol

Cas:636-72-6

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Synthetic route

thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With hydrogen; phosphotungstic acid 44-hydrate; [Fe(C5H4P(i-Pr)2)2Rh(C8H12)]BF4 In water; isopropyl alcohol at 20℃; under 5171.62 Torr; for 16h;100%
With isopropyl alcohol; hydrotalcite at 81.84℃; for 3h; Kinetics; Further Variations:; Temperatures; Reagents; ratio educt:reagent;100%
With trichlorosilane; N,N-dimethyl-formamide In dichloromethane at 0℃; for 6h;99%
C20H20BO4S4(1-)*Na(1+)

C20H20BO4S4(1-)*Na(1+)

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With water100%
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

A

2-thiophenylcarboxylic acid
527-72-0

2-thiophenylcarboxylic acid

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
Stage #1: thiophene-2-carbaldehyde With potassium hydroxide for 0.0833333h; Cannizzaro Reaction; Milling; Inert atmosphere; Sealed tube; Green chemistry;
Stage #2: With hydrogenchloride In water for 0.0833333h; Green chemistry;
A 98%
B 98%
With aluminum oxide; water; sodium hydroxide at 100℃; for 0.0333333h; Cannizzaro Reaction; Microwave irradiation;A 47%
B 47%
With aluminum oxide; sodium hydroxide; water for 0.00416667h; Irradiation; Yield given; Yields of byproduct given;
(thiophen-2-yl)methyl acetate
13679-77-1

(thiophen-2-yl)methyl acetate

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With zirconocene dichloride; diisobutylaluminium hydride In tetrahydrofuran at -20℃; Inert atmosphere; regioselective reaction;97%
With lipase B from Candida antarctica immobilized on Immobead 150 In aq. phosphate buffer at 40℃; for 0.333333h; pH=7.4;87%
4,4,5,5-tetramethyl-2-(thiophen-2-ylmethoxy)-1,3,2-dioxaborolane

4,4,5,5-tetramethyl-2-(thiophen-2-ylmethoxy)-1,3,2-dioxaborolane

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With silica gel In hexane; ethyl acetate96%
With silica gel at 25℃; Inert atmosphere; Glovebox;94%
With water; silica gel In methanol at 60℃; Inert atmosphere;88%
trimethyl-(thiophen-2-ylmethoxy)-silane

trimethyl-(thiophen-2-ylmethoxy)-silane

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With Nafion-H(R); silica gel In hexane at 20℃; for 0.666667h;95%
With silica chromate; silica gel In dichloromethane at 20℃; for 0.75h;70%
(CH3CNO)2(CH3CNOH)2Co(C5H5N)(OOCH2C4H3S)

(CH3CNO)2(CH3CNOH)2Co(C5H5N)(OOCH2C4H3S)

A

thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
In methanol decomposition of the complex by refluxing in methanol under N2 for 6-8 h; evapn. of the solvent, extn. of the organic compounds with ether, gas chromatography;A 5%
B 95%
(4-bromothiophen-2-yl)methanol
79757-77-0

(4-bromothiophen-2-yl)methanol

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; for 2h; Inert atmosphere;95%
tetrahydropyranyl ether of 2-thiophenemethanol
121851-24-9

tetrahydropyranyl ether of 2-thiophenemethanol

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
ammonium cerium(IV) nitrate In alkaline aq. solution; acetonitrile at 70℃; for 2h; pH=8; Decomposition;91%
tert-butyl dimethyl(thiophen-2-ylmethoxy)silane

tert-butyl dimethyl(thiophen-2-ylmethoxy)silane

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In methanol at 30℃; for 1h;90%
2-thiophenecarboxaldehyde diacetate
63011-97-2

2-thiophenecarboxaldehyde diacetate

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In methanol at 20℃; for 4h; chemoselective reaction;88%
(5-bromothien-2-yl)methanol
79387-71-6

(5-bromothien-2-yl)methanol

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; for 10h; Inert atmosphere;85%
thiophene-2-carboxylic acid methyl ester
5380-42-7

thiophene-2-carboxylic acid methyl ester

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
Stage #1: thiophene-2-carboxylic acid methyl ester With sodium triethylborohydride In diethyl ether; toluene at 20℃; for 8h; Inert atmosphere;
Stage #2: With sodium hydroxide In methanol; diethyl ether; toluene at 20℃; for 2h; Reagent/catalyst; Solvent; Time;
78%
With lithium aluminium tetrahydride In diethyl ether at -10℃; for 1h;1.07 g
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

propargyl bromide
106-96-7

propargyl bromide

A

(+/-)-1-(2-thienyl)-3-butyn-1-ol
38597-97-6

(+/-)-1-(2-thienyl)-3-butyn-1-ol

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With ammonium chloride; calcium chloride; zinc In tetrahydrofuran; water for 1h;A 74%
B 15 % Spectr.
With ammonium chloride; calcium chloride; zinc In tetrahydrofuran; water for 1h;A 74 % Spectr.
B 15 % Spectr.
2-thiophenylcarboxylic acid
527-72-0

2-thiophenylcarboxylic acid

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 20℃; for 0.5h; Inert atmosphere;64%
Stage #1: 2-thiophenylcarboxylic acid With trimethylphenylsilane; C69H55ClP3Ru In tetrahydrofuran at 60℃; for 16h; Glovebox;
Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 1h; Glovebox; chemoselective reaction;
60%
Multi-step reaction with 2 steps
2: 1.07 g / LiAlH4 / diethyl ether / 1 h / -10 °C
View Scheme
2-thenyl bromide
45438-73-1

2-thenyl bromide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With oxygen; eosin y In dimethyl sulfoxide at 25℃; for 12h; Irradiation;61%
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

A

2-thiophenemethanol
636-72-6

2-thiophenemethanol

B

(1S,2S)-1-(2-thienyl)-1,2-propanediol
189032-31-3

(1S,2S)-1-(2-thienyl)-1,2-propanediol

C

(1S,2R)-1-(thiophen-2-yl)propane-1,2-diol

(1S,2R)-1-(thiophen-2-yl)propane-1,2-diol

Conditions
ConditionsYield
brewers' yeast; Yields of byproduct given;A 52%
B n/a
C n/a
brewers' yeast; Yield given;A 52%
B n/a
C n/a
Ethyl thiophene-2-carboxylate
2810-04-0

Ethyl thiophene-2-carboxylate

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With [RuCl2(N-heterocyclic carbene)(bis[2-(diphenylphosphino)ethyl]amine)]; potassium tert-butylate; hydrogen In tetrahydrofuran; 2-methyltetrahydrofuran at 45℃; under 3750.38 Torr; for 2.5h; Autoclave;52%
Multi-step reaction with 2 steps
1: sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; C24H23ClCrIrNO3 / dichloromethane / 15 h / 25 °C / Schlenk technique; Glovebox; Inert atmosphere
2: tetrabutyl ammonium fluoride / tetrahydrofuran / 12 h / Inert atmosphere
View Scheme
5-methyl-2-thienyl-2,3-dihydro-1,3-benzazaphosphole

5-methyl-2-thienyl-2,3-dihydro-1,3-benzazaphosphole

5-methyl-2-thienyl-2,3-dihydro-1,3-benzazaphosphole

5-methyl-2-thienyl-2,3-dihydro-1,3-benzazaphosphole

A

5-methyl-2-(thien-2-yl)-1H-1,3-benzazaphosphole
1443767-97-2

5-methyl-2-(thien-2-yl)-1H-1,3-benzazaphosphole

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In 5,5-dimethyl-1,3-cyclohexadiene for 12h; Inert atmosphere; Reflux;A 50%
B n/a
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

3,4,5-triamino-1,2,6-thiadiazine 1,1-dioxide
61403-61-0

3,4,5-triamino-1,2,6-thiadiazine 1,1-dioxide

A

2-thiophenemethanol
636-72-6

2-thiophenemethanol

B

4-amino-6-(2-thienyl)-1H,5H-imidazo<4,5-c>1,2,6-thiadiazine 2,2-dioxide
116256-01-0

4-amino-6-(2-thienyl)-1H,5H-imidazo<4,5-c>1,2,6-thiadiazine 2,2-dioxide

C

4-amino-6,7-di(2'-thienyl)-8H-pyrazino<2,3-c>-1,2,6-thiadiazine 2,2-dioxide
116544-19-5

4-amino-6,7-di(2'-thienyl)-8H-pyrazino<2,3-c>-1,2,6-thiadiazine 2,2-dioxide

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 3h; Product distribution; Heating; other solvent;A n/a
B 36%
C 32%
In N,N-dimethyl-formamide for 8h; Heating;A n/a
B 36%
C 32%
In acetic acid for 8h; Heating;A n/a
B 33%
C 32%
2-(diazomethyl)thiophene
5919-31-3

2-(diazomethyl)thiophene

A

2-thiophenemethanol
636-72-6

2-thiophenemethanol

(Z)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan
76836-84-5, 76836-85-6

(Z)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan

(E)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan
76836-84-5, 76836-85-6

(E)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan

D

thiophene-2-carboxaldehyde azine
24523-46-4

thiophene-2-carboxaldehyde azine

Conditions
ConditionsYield
With 2,3-dimethyl-buta-1,3-diene In diethyl ether for 10h; Irradiation; Yields of byproduct given;A 4%
B n/a
C n/a
D 27%
In diethyl ether for 10h; Irradiation; Yields of byproduct given;A 4%
B n/a
C n/a
D 27%
2-(diazomethyl)thiophene
5919-31-3

2-(diazomethyl)thiophene

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

2-thiophenemethanol
636-72-6

2-thiophenemethanol

(Z)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan
76836-84-5, 76836-85-6

(Z)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan

(E)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan
76836-84-5, 76836-85-6

(E)-1-Isopropenyl-1-methyl-2-(2-thienyl)cyclopropan

D

thiophene-2-carboxaldehyde azine
24523-46-4

thiophene-2-carboxaldehyde azine

Conditions
ConditionsYield
In diethyl ether for 10h; Irradiation; Yield given. Yields of byproduct given. Title compound not separated from byproducts;A 4%
B n/a
C n/a
D 27%
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

ethanol
64-17-5

ethanol

A

Ethyl thiophene-2-carboxylate
2810-04-0

Ethyl thiophene-2-carboxylate

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
carbonylhydridetris(triphenylphosphine)rhodium(I) for 504h; Heating;A 25%
B 7%
thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

formaldehyd
50-00-0

formaldehyd

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With methanol; sodium hydroxide
2-Chloromethylthiophene
765-50-4

2-Chloromethylthiophene

A

bis(thienylmethyl) ether
35250-78-3

bis(thienylmethyl) ether

B

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With sodium hydroxide; sodium acetate
2-Chloromethylthiophene
765-50-4

2-Chloromethylthiophene

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With sodium hydroxide; sodium acetate
formaldehyd
50-00-0

formaldehyd

2-thienylmagnesium iodide
89180-57-4

2-thienylmagnesium iodide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With diethyl ether
thiophen-2-ylmethanamine monohydrochloride
7404-63-9

thiophen-2-ylmethanamine monohydrochloride

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With water; silver nitrate
formaldehyd
50-00-0

formaldehyd

thiophen-2-yl magnesium bromide
5713-61-1

thiophen-2-yl magnesium bromide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

Conditions
ConditionsYield
With diethyl ether
2-thiophenemethanol
636-72-6

2-thiophenemethanol

2-thenyl bromide
45438-73-1

2-thenyl bromide

Conditions
ConditionsYield
With boron tribromide; triphenylphosphine In dichloromethane at 0 - 20℃; for 3h; Inert atmosphere;100%
With phosphorus tribromide In diethyl ether at 0 - 20℃; for 1h;89%
With hydrogen bromide; acetic acid In diethyl ether at 0 - 20℃; for 16h; Inert atmosphere;85%
triphenylphosphine hydrobromide
6399-81-1

triphenylphosphine hydrobromide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

2-thienylmethyltriphenylphosphonium bromide
23259-98-5

2-thienylmethyltriphenylphosphonium bromide

Conditions
ConditionsYield
In chloroform for 1h; Heating;100%
In chloroform Reflux;95%
In chloroform for 6h; Heating;
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

2-thiophenemethanol
636-72-6

2-thiophenemethanol

C16H24O4S2Ti
1346523-10-1

C16H24O4S2Ti

Conditions
ConditionsYield
In cyclohexane Inert atmosphere; Reflux;100%
In cyclohexane for 0.5h; Schlenk technique; Inert atmosphere; Reflux;100%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

Conditions
ConditionsYield
With 2,2,6,6-tetramethyl-piperidine-N-oxyl; oxygen; copper(I) bromide dimethylsulfide complex In chlorobenzene at 80℃; for 8h;99%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; N-methyl-N-[3-(4'-diacetoxyiodo)phenoxy-1-propyl]pyrrolidinium 4-methylbenzenesulfonate In dichloromethane at 20℃; for 3h;99%
With Pd(0) nanoparticle supported on aminopropyl grafted silica-based mesocellular foam; air In para-xylene at 110℃; under 760.051 Torr; for 10h;99%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

1,1'-carbonyldiimidazole
530-62-1

1,1'-carbonyldiimidazole

imidazole-1-carboxylic acid thiophen-2-ylmethyl ester

imidazole-1-carboxylic acid thiophen-2-ylmethyl ester

Conditions
ConditionsYield
In ethyl acetate at 20℃; for 7h;99%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

thiophene-2-carbonitrile
1003-31-2

thiophene-2-carbonitrile

Conditions
ConditionsYield
Stage #1: 2-thiophenemethanol With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; 1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #2: With ammonia; iodine In dichloromethane; water at 20℃; for 3h; Inert atmosphere;
99%
With copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; ammonium hydroxide at 100℃; for 24h;96%
With ammonia; oxygen In ethanol; water for 3h; Reflux;91%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

prenyl halide

prenyl halide

prenyl 2-thiophenemethyl ether

prenyl 2-thiophenemethyl ether

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h;99%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

ethylenediamine
107-15-3

ethylenediamine

2-(thiophen-2-yl)-4,5-dihydro-1H-imidazole
45753-18-2

2-(thiophen-2-yl)-4,5-dihydro-1H-imidazole

Conditions
ConditionsYield
Stage #1: 2-thiophenemethanol With iodine; potassium carbonate In tert-butyl alcohol at 70℃; for 8h;
Stage #2: ethylenediamine In tert-butyl alcohol at 70℃; for 2h;
99%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

benzyl bromide
100-39-0

benzyl bromide

2-((benzyloxy)methyl)thiophene
184040-47-9

2-((benzyloxy)methyl)thiophene

Conditions
ConditionsYield
Stage #1: 2-thiophenemethanol With sodium hydride In tetrahydrofuran at 0 - 20℃; Schlenk technique; Inert atmosphere;
Stage #2: benzyl bromide In tetrahydrofuran at 0 - 20℃; for 3h; Schlenk technique; Inert atmosphere;
99%
With tetra-(n-butyl)ammonium iodide; sodium hydroxide at 40 - 50℃; for 7h;83%
In tetrahydrofuran78%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

aniline
62-53-3

aniline

N-(thiophen-2-ylmethyl)aniline
40625-28-3

N-(thiophen-2-ylmethyl)aniline

Conditions
ConditionsYield
With copper; potassium hydroxide In toluene at 180℃; for 48h; Inert atmosphere;99%
With potassium hydroxide In neat (no solvent) at 80℃; for 12h; Green chemistry;91%
With zinc(II) nitrate hexahydrate; potassium tert-butylate In toluene at 140℃; for 36h; Sealed tube; Inert atmosphere; Schlenk technique;91%
carbon disulfide
75-15-0

carbon disulfide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

C6H5OS3(1-)*K(1+)

C6H5OS3(1-)*K(1+)

Conditions
ConditionsYield
With potassium hydroxide In diethyl ether at 20℃; for 12h;99%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

2-Hydroxymethyl-5-iodothiophene
13781-27-6

2-Hydroxymethyl-5-iodothiophene

Conditions
ConditionsYield
With N-iodo-succinimide; toluene-4-sulfonic acid In ethanol at 25℃; for 0.166667h; Green chemistry; regioselective reaction;98%
With iodine; mercury(II) oxide In toluene for 3h;95%
With iodine; mercury(II) oxide In benzene for 1h;
With iodine; mercury(II) oxide In toluene Inert atmosphere; Schlenk technique;
2-thiophenemethanol
636-72-6

2-thiophenemethanol

(2,4-dinitro-phenyl)-hydrazine
119-26-6

(2,4-dinitro-phenyl)-hydrazine

1-(thiophen-2-ylmethylene)-2-(2,4-dinitrophenyl)hydrazine

1-(thiophen-2-ylmethylene)-2-(2,4-dinitrophenyl)hydrazine

Conditions
ConditionsYield
Stage #1: 2-thiophenemethanol With 1-methyl-1H-imidazole; tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; 4,4'-Dimethoxy-2,2'-bipyridin; 9-azabicyclo[3.3.1]nonane N-oxyl; oxygen In acetonitrile at 20℃; for 1h;
Stage #2: (2,4-dinitro-phenyl)-hydrazine With hydrogenchloride In water; acetonitrile for 1h;
98%
Stage #1: 2-thiophenemethanol With peracetic acid; C9H17NO5S(1-)*C11H12IN2(1+); acetic acid In 1,1,1,3',3',3'-hexafluoro-propanol at 20℃; for 8h;
Stage #2: (2,4-dinitro-phenyl)-hydrazine With sulfuric acid In diethyl ether; ethanol; water
86%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

benzamide
55-21-0

benzamide

N-(thiophen-2-yl-methyl)benzamide
4595-96-4

N-(thiophen-2-yl-methyl)benzamide

Conditions
ConditionsYield
With C44H39IrN2P(1+)*C32H12BF24(1-); caesium carbonate In toluene at 120℃; for 12h; Inert atmosphere;98%
With C23H24ClIrN3OS(1+)*F6P(1-); caesium carbonate In toluene at 120℃;96%
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; caesium carbonate In toluene at 130℃; for 12h;86%
With caesium carbonate In toluene at 130℃; for 12h; Inert atmosphere; Schlenk technique;185 mg
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; caesium carbonate In toluene at 130℃; for 12h;
4-methylbenzensulphonamide potassium salt
29281-83-2

4-methylbenzensulphonamide potassium salt

2-thiophenemethanol
636-72-6

2-thiophenemethanol

4-methyl-N-(thiophen-2-ylmethyl)benzenesulfonamide
545358-50-7

4-methyl-N-(thiophen-2-ylmethyl)benzenesulfonamide

Conditions
ConditionsYield
With potassium hydroxide at 130℃; for 25h; Schlenk technique; Inert atmosphere;98%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

pivaloyl chloride
3282-30-2

pivaloyl chloride

thiophen-2-ylmethyl pivalate

thiophen-2-ylmethyl pivalate

Conditions
ConditionsYield
With dmap In dichloromethane at 24℃; Inert atmosphere;98%
With dmap; triethylamine In dichloromethane at 0℃; Inert atmosphere;0.85 g
diphenylphosphinamide
5994-87-6

diphenylphosphinamide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

P,P-diphenyl-N-(thiophen-2-ylmethyl)phosphinic amide
1283087-86-4

P,P-diphenyl-N-(thiophen-2-ylmethyl)phosphinic amide

Conditions
ConditionsYield
With carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)-amino]ruthenium(II); potassium hydroxide In toluene at 110℃; for 16h; Inert atmosphere; Sealed tube; Glovebox;98%
With potassium hydroxide In toluene at 110℃; for 4h;92%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl dimethyl(thiophen-2-ylmethoxy)silane

tert-butyl dimethyl(thiophen-2-ylmethoxy)silane

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide for 24h;97%
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃;97%
With 1H-imidazole; dmap In N,N-dimethyl-formamide at 20℃; for 12h;95%
With 1H-imidazole; dmap In N,N-dimethyl-formamide at 20℃; for 12h;90%
With 1H-imidazole In N,N-dimethyl-formamide at 23℃; for 2h;78%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

acetic anhydride
108-24-7

acetic anhydride

(thiophen-2-yl)methyl acetate
13679-77-1

(thiophen-2-yl)methyl acetate

Conditions
ConditionsYield
With H3[P(Mo3O10)4]*nH2O at 20℃; for 0.166667h;97%
With pyridine In dichloromethane at 20℃; for 24h; Inert atmosphere;91%
With thalium(III) chloride tetrahydrate at 20℃; for 0.333333h;87%
With dmap; triethylamine In dichloromethane at 20℃; for 19h;86%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

A

thiophene-2-carbaldehyde
98-03-3

thiophene-2-carbaldehyde

B

2-Chloromethylthiophene
765-50-4

2-Chloromethylthiophene

Conditions
ConditionsYield
With hydrogenchloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium nitrite In dichloromethane; water at 20℃; under 760.051 Torr; for 12h; in air;A 97%
B 3%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

acetophenone
98-86-2

acetophenone

2,6‑diphenyl‑4‑(thiophen‑2‑yl)pyridine
133726-93-9

2,6‑diphenyl‑4‑(thiophen‑2‑yl)pyridine

Conditions
ConditionsYield
Stage #1: 2-thiophenemethanol With 1-methylimidazolium nitrate; 1-butyl-3-methylimidazolium Tetrafluoroborate at 96℃; for 0.0555556h; Ionic liquid; Microwave irradiation;
Stage #2: acetophenone With ammonium acetate at 96℃; for 0.133333h; Ionic liquid; Microwave irradiation;
97%
N,N-phenyl-p-toluenesulfonylbenzamide
74542-54-4

N,N-phenyl-p-toluenesulfonylbenzamide

2-thiophenemethanol
636-72-6

2-thiophenemethanol

thiophen-2-yl-methyl benzoate
85455-66-9

thiophen-2-yl-methyl benzoate

Conditions
ConditionsYield
With cesium fluoride In acetonitrile at 100℃; for 15h; Sealed tube;97%
9H-fluorene
86-73-7

9H-fluorene

2-thiophenemethanol
636-72-6

2-thiophenemethanol

2-((9H-fluoren-9-yl)methyl)thiophene

2-((9H-fluoren-9-yl)methyl)thiophene

Conditions
ConditionsYield
With potassium tert-butylate In toluene at 120℃; for 24h; Inert atmosphere;97%
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate In toluene at 120℃; for 18h; Inert atmosphere; Sealed tube;62%
2-thiophenemethanol
636-72-6

2-thiophenemethanol

2-Chloromethylthiophene
765-50-4

2-Chloromethylthiophene

Conditions
ConditionsYield
With thionyl chloride In toluene at 20 - 55℃; microwave irradiation;96%
With thionyl chloride In toluene at 55℃; for 0.333333h; microwave irradiation;96%
With thionyl chloride at 0 - 75℃; for 4h;94%
methanol
67-56-1

methanol

2-thiophenemethanol
636-72-6

2-thiophenemethanol

thiophene-2-carboxylic acid methyl ester
5380-42-7

thiophene-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With dihydrogen peroxide for 3h; Irradiation;96%
With oxygen at 20℃; for 12h; Irradiation;93%
With iodine; potassium carbonate for 39h; Heating;91%

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