1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ
Cas:690-94-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
Cas:690-94-8
Min.Order:1 Kilogram
FOB Price: $2.0
Type:Lab/Research institutions
inquiry2-methylhex-5-en-3-yn-2-ol, CAS 690-94-8,liquid, commercial Qty Shanghai Massive Chemical Technology Co., Ltd. is engaged in development, production and marketing Specialty Chemicals to satisfy the changing needs of the chemical industry. We spec
Cas:690-94-8
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:690-94-8
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Trading Company
inquiry1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryOur own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryWe are committed to providing our customers with the best products and services at the most competitive prices.Appearance:Powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary and sec
best seller Application:API
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryGood Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen
best seller Application:API
Cas:690-94-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-Methyl-hex-5-en-3-yn-2-ol, CAS:690-94-8 with the most competitive price and the bes
Conditions | Yield |
---|---|
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; diethylamine at 0 - 20℃; for 12h; | 91% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); potassium hydroxide In tetrahydrofuran; diethylamine at 0 - 20℃; for 12h; | 91% |
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diethylamine In tetrahydrofuran at 23℃; for 2.5h; | 84% |
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; diethylamine at 23℃; for 2.5h; | 84% |
With copper(l) iodide; diisopropylamine; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 20℃; Sonogashira coupling; | 80% |
(vinyl)trimethoxylsilane
2-methyl-but-3-yn-2-ol
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride; copper diacetate In 1,4-dioxane at 30℃; | 47% |
Vinyl bromide
2-methyl-but-3-yn-2-ol
A
2,7-dimethyl-octa-3,5-diyne-2,7-diol
B
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine In tetrahydrofuran at 20℃; Inert atmosphere; | A 20% B 42% |
Conditions | Yield |
---|---|
With diethyl ether unter starkem Kuehlen mit KOH; | |
With potassium hydroxide; sodium hydroxide | |
With diethyl ether unter starkem Kuehlen mit NaNH2; | |
With potassium hydroxide In ammonia at 30 - 40℃; |
Conditions | Yield |
---|---|
With ammonia; sodium amide |
3,4-dichlorobut-1-ene
acetone
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With ammonia; sodium amide |
Conditions | Yield |
---|---|
With diethyl ether | |
With diethyl ether | |
With diethyl ether |
3-buten-1-yne
2-hydroxy-2-methylpropiophenone
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With ammonia; sodium; ferric nitrate |
5-chloro-5-methyl-1-hexen-3-yne
diethyl ether
A
1,1,3,3-Tetramethyl-4-vinyl-phthalan
B
dimethyl(vinylethynyl)carbinol
C
2-methyl-hexa-1,5-dien-3-yne
Conditions | Yield |
---|---|
at 0℃; |
Conditions | Yield |
---|---|
In benzene byproducts: BuOH; react. of Ti(OBu)4 with the alcohol under azeotropic distn. of BuOH (20-60°C, 1-3 h, inert atmosphere); evapn. (< 0.2 mm), vac. distn.; elem. anal.; | 95% |
dimethyl(vinylethynyl)carbinol
1-chloro-5-methylhex-3-yne-2,5-diol
Conditions | Yield |
---|---|
With hydrogenchloride; dihydrogen peroxide at 54.84℃; for 7.5h; Product distribution; Kinetics; Further Variations:; Temperatures; reagent concentrations, reaction time; | 94.3% |
dimethyl(vinylethynyl)carbinol
1-bromo-5-methylhex-3-yne-2,5-diol
Conditions | Yield |
---|---|
With hydrogen bromide; dihydrogen peroxide at 54.84℃; for 7.5h; Product distribution; Further Variations:; Temperatures; reagent concentrations, reaction time; | 92.8% |
dimethyl(vinylethynyl)carbinol
methyl iodide
5-methoxy-5-methylhex-1-en-3-yne
Conditions | Yield |
---|---|
Stage #1: dimethyl(vinylethynyl)carbinol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 0.25h; Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 0 - 20℃; | 90% |
dimethyl(vinylethynyl)carbinol
4-methoxy-benzoyl chloride
4-methoxybenzoic acid 1,1-dimethylpent-4-en-2-ynyl ester
Conditions | Yield |
---|---|
With pyridine at 90℃; for 14h; | 89% |
In pyridine at 90℃; for 14h; | 89% |
Conditions | Yield |
---|---|
With triethylamine In benzene at 80℃; for 5h; | 88% |
Conditions | Yield |
---|---|
With triethylamine In benzene at 80℃; for 5h; | 88% |
Conditions | Yield |
---|---|
With ion-exchange resin KU-23 at 30℃; under 100 Torr; for 2h; Dehydration; | 87% |
With sulfuric acid at 10 - 65℃; for 4.5h; | 73% |
With sulfuric acid at 70℃; | |
With sulfuric acid | |
With benzenesulfonyl chloride In pyridine |
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With triethylamine In benzene at 80℃; for 5h; | 87% |
dimethyl(vinylethynyl)carbinol
tert-butyldimethylsilyl chloride
tert-butyldimethyl((2-methylhex-5-en-3-yn-2-yl)oxy)silane
Conditions | Yield |
---|---|
With 1H-imidazole; dmap In N,N-dimethyl-formamide at 65℃; for 16h; Inert atmosphere; | 86% |
o-tetrachloroquinone
dimethyl(vinylethynyl)carbinol
1,4,5,6-Tetrachloro-7-(3-hydroxy-3-methyl-but-1-ynyl)-bicyclo[2.2.2]oct-5-ene-2,3-dione
Conditions | Yield |
---|---|
With hydroquinone In toluene at 108℃; for 18h; | 85.3% |
Conditions | Yield |
---|---|
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); isopropyl alcohol; 1,4-di(diphenylphosphino)-butane In tetrahydrofuran at 90℃; for 48h; Inert atmosphere; Sealed tube; diastereoselective reaction; | 85% |
dimethyl(vinylethynyl)carbinol
(E)-2-methyl-3,5-hexadien-2-ol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride | 82% |
With lithium aluminium tetrahydride; diethyl ether | |
With lithium aluminium tetrahydride; water 1.) ether, 20 deg C; Multistep reaction; |
dimethyl(vinylethynyl)carbinol
5,6-dibromo-2-methylhex-3-yn-2-ol
Conditions | Yield |
---|---|
With hydrogen bromide; dihydrogen peroxide at 39.84℃; for 4h; | 82% |
With chloroform; bromine |
dimethyl(vinylethynyl)carbinol
p-toluenesulfonyl iodide
B
5-Iodo-2-methyl-6-(toluene-4-sulfonyl)-hex-3-yn-2-ol
Conditions | Yield |
---|---|
In acetonitrile at 110℃; for 96h; Yields of byproduct given. Title compound not separated from byproducts; | A n/a B 80% |
dimethyl(vinylethynyl)carbinol
5,6-dichloro-2-methylhex-3-yn-2-ol
Conditions | Yield |
---|---|
With hydrogenchloride; dihydrogen peroxide at 39.84℃; for 4h; | 78% |
Conditions | Yield |
---|---|
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); isopropyl alcohol; 1,4-di(diphenylphosphino)-butane In tetrahydrofuran at 100℃; for 48h; Reagent/catalyst; Time; Inert atmosphere; Sealed tube; diastereoselective reaction; | 73% |
Conditions | Yield |
---|---|
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); d8-isopropanol; 1,4-di(diphenylphosphino)-butane In tetrahydrofuran at 90℃; for 48h; Inert atmosphere; Sealed tube; | 72% |
Conditions | Yield |
---|---|
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane; water at 28 - 30℃; for 4h; | 69% |
dimethyl(vinylethynyl)carbinol
Conditions | Yield |
---|---|
With hydrogenchloride; air; hypophosphorous acid | 68% |
dimethyl(vinylethynyl)carbinol
chloro-diphenylphosphine
diphenyl 3-methylhexa-1,3,4-trien-3-yl phosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at -70 - 20℃; for 5h; | 65% |
dimethyl(vinylethynyl)carbinol
(5-methyl-1,3,4-hexatrien-3-yl)phosphonous acid
Conditions | Yield |
---|---|
With hypophosphorous acid | 62% |
dimethyl(vinylethynyl)carbinol
triisopropylsilyl chloride
triisopropyl((2-methylhex-5-en-3-yn-2-yl)oxy)silane
Conditions | Yield |
---|---|
Stage #1: dimethyl(vinylethynyl)carbinol With sodium hydride In tetrahydrofuran at 20℃; for 0.5h; Stage #2: triisopropylsilyl chloride In tetrahydrofuran at 0 - 20℃; | 60% |
Conditions | Yield |
---|---|
With sulfuric acid; hydroquinone at 20℃; for 20h; | 58% |
dimethyl(vinylethynyl)carbinol
methylsulphinyl chloride
5-methyl-3-(methylsulfonyl)hexa-1,3,4-triene
Conditions | Yield |
---|---|
Stage #1: dimethyl(vinylethynyl)carbinol; methylsulphinyl chloride With triethylamine In diethyl ether at -40 - 20℃; Stage #2: In toluene for 5h; Heating; | 55% |
Conditions | Yield |
---|---|
With (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); isopropyl alcohol; 1,4-di(diphenylphosphino)-butane In tetrahydrofuran at 90℃; for 48h; Inert atmosphere; Sealed tube; diastereoselective reaction; | 54% |
Conditions | Yield |
---|---|
With sulfuric acid; water; mercury(II) sulfate at 85℃; for 5h; | 53% |
With sulfuric acid; mercury(II) sulfate |
Conditions | Yield |
---|---|
With sulfuric acid; hydroquinone at 20℃; for 20h; | 53% |
dimethyl(vinylethynyl)carbinol
2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazaphospholidine
Conditions | Yield |
---|---|
With triethylamine In benzene for 5h; | 50.6% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View