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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyl trans-2-octenoate

Cas:7367-81-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Methyl (E)-2-octenoate

Cas:7367-81-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

METHYL TRANS-2-OCTENOATE CAS 7367-81-9

Cas:7367-81-9

Min.Order:1 Kilogram

FOB Price: $40.0 / 80.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 7367-81-9 with competitive price

Cas:7367-81-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Octenoic acid, methylester, (2E)- 7367-81-9

Cas:7367-81-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

METHYL TRANS-2-OCTENOATE CAS:7367-81-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

METHYL TRANS-2-OCTENOATE CAS:7367-81-9

Cas:7367-81-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: METHYL TRANS-2-OCTENOATE Synonyms: METHYL T2 OCTENOATE;METHYL OCT-2-ENOATE;METHYL 2-OCTENOATE;FEMA 3712;Methyltransoctenoate;methyl (E)-oct-2-enoate;METHYL TRANS-2-OCTENOATE 96+%;2-Octenoic acid, methyl ester, (2E)- CAS: 7367-81-

METHYL TRANS-2-OCTENOATE big supplier with lower price

Cas:7367-81-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:By Sea/Air/Courier Port:Qingdao

Methyl trans-2-octenoate 7367-81-9

Cas:7367-81-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl trans-2-octenoate

Cas:7367-81-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Octenoic acid, methylester, (2E)- factory

Cas:7367-81-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl trans-2-octenoate

Cas:7367-81-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

High Purity METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Methyl Trans-2-Octenoate

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl trans-2-Octenoate

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

2-Octenoic acid, methylester, (2E)-

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

METHYL TRANS-2-OCTENOATE

Cas:7367-81-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methyl 2-octynoate
111-12-6

methyl 2-octynoate

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
Stage #1: methyl 2-octynoate With tris-(dibenzylideneacetone)dipalladium(0); 1,4-di(diphenylphosphino)-butane In 1,4-dioxane; water at 20℃; for 0.25h; Inert atmosphere;
Stage #2: With formic acid In 1,4-dioxane at 80℃; for 10h; Inert atmosphere; optical yield given as %ee; stereoselective reaction;
93%
Stage #1: methyl 2-octynoate With Triethoxysilane; tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate In dichloromethane at 20℃; for 0.5h;
Stage #2: With copper(l) iodide; tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 20h; Further stages.;
83%
methyl (2Z)-3-iodooct-2-enoate
160729-74-8

methyl (2Z)-3-iodooct-2-enoate

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
Stage #1: methyl (2Z)-3-iodooct-2-enoate In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; diethyl ether at -78℃; for 0.5h;
Stage #2: With water In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; diethyl ether at 20℃; for 0.5h; Further stages.;
92%
((1R,2S)-1-Methoxy-2-pentyl-cyclopropoxy)-trimethyl-silane

((1R,2S)-1-Methoxy-2-pentyl-cyclopropoxy)-trimethyl-silane

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

(E)-methyl oct-3-enoate
35234-16-3

(E)-methyl oct-3-enoate

C

2,3-dichloro-5,6-dicyanohydroquinone
4640-41-9

2,3-dichloro-5,6-dicyanohydroquinone

D

methyl (Z)-oct-3-enoate
69668-85-5

methyl (Z)-oct-3-enoate

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 60℃; for 20h; Yields of byproduct given;A 76%
B n/a
C 86%
D n/a
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 60℃; for 20h; Yield given;A 76%
B n/a
C 86%
D n/a
(E)-allyl methyl hept-1-en-1-ylphosphonate

(E)-allyl methyl hept-1-en-1-ylphosphonate

(E)-diallyl hept-1-en-1-ylphosphonate

(E)-diallyl hept-1-en-1-ylphosphonate

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-methoxy-2,5-dihydro-1,2-oxaphosphole 2-oxide

2-methoxy-2,5-dihydro-1,2-oxaphosphole 2-oxide

C

(E)-methyl 4-((2-oxido-1,2-oxaphosphol-2(5H)-yl)oxy)but-2-enoate

(E)-methyl 4-((2-oxido-1,2-oxaphosphol-2(5H)-yl)oxy)but-2-enoate

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(l) iodide In dichloromethane for 16h; Inert atmosphere; Reflux;A 86%
B n/a
C n/a
hexanal
66-25-1

hexanal

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 17h; Wittig Olefination; Inert atmosphere;85%
In benzene for 48h; Heating;83%
In tetrahydrofuran for 4h; Reflux;80%
In dichloromethane at 23℃; for 17h; Inert atmosphere;70%
methanol
67-56-1

methanol

1-Heptyne
628-71-7

1-Heptyne

carbon monoxide
201230-82-2

carbon monoxide

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl α-pentyl acrylate
69565-06-6

methyl α-pentyl acrylate

Conditions
ConditionsYield
With palladium diacetate; toluene-4-sulfonic acid; 1,4-di(diphenylphosphino)-butane In acetonitrile at 110℃; under 5171.62 Torr; for 1h; Autoclave; regioselective reaction;A 85%
B 15%
methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

hexan-1-ol
111-27-3

hexan-1-ol

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

Conditions
ConditionsYield
Stage #1: hexan-1-ol With Celite; pyridinium chlorochromate In dichloromethane at 20℃;
Stage #2: methyl (triphenylphosphoranylidene)acetate In dichloromethane at 20℃; for 24h; Wittig olefination;
A 82%
B n/a
hexanal
66-25-1

hexanal

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

Conditions
ConditionsYield
for 3h; Heating;A 80%
B n/a
In water at 20℃; for 1h; Wittig reaction; Title compound not separated from byproducts.;
(E)-allyl methyl hept-1-en-1-ylphosphonate

(E)-allyl methyl hept-1-en-1-ylphosphonate

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-methoxy-2,5-dihydro-1,2-oxaphosphole 2-oxide

2-methoxy-2,5-dihydro-1,2-oxaphosphole 2-oxide

Conditions
ConditionsYield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; copper(l) iodide In dichloromethane for 16h; Inert atmosphere; Reflux;A 78%
B n/a
(+/-)-trimethyl(1-methoxy-2-pentylcyclopropoxy)silane
344332-97-4

(+/-)-trimethyl(1-methoxy-2-pentylcyclopropoxy)silane

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl (Z)-non-3-enoate
41654-16-4

methyl (Z)-non-3-enoate

C

methyl (trans-3-nonenoate)
36781-67-6

methyl (trans-3-nonenoate)

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 60℃; for 20h; Yields of byproduct given;A 76%
B n/a
C n/a
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 60℃; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
methyl (2S,3S)-2-iodo-3-hydroxyoctanoate
171016-45-8

methyl (2S,3S)-2-iodo-3-hydroxyoctanoate

C5H3F3O4S

C5H3F3O4S

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl (2S,3S)-2-iodo-3-(butynoyloxy)octanoate
171231-65-5

methyl (2S,3S)-2-iodo-3-(butynoyloxy)octanoate

Conditions
ConditionsYield
In dichloromethane 1.) from -20 deg C to r.t.; 2.) r.t., 10 h;A 25%
B 75%
methyl (2R,3S)-3-pentyloxiranecarboxylate
107797-02-4

methyl (2R,3S)-3-pentyloxiranecarboxylate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl (2S,3S)-2-iodo-3-hydroxyoctanoate
171016-45-8

methyl (2S,3S)-2-iodo-3-hydroxyoctanoate

C

methyl (2S,3R)-2-hydroxy-3-iodooctanoate

methyl (2S,3R)-2-hydroxy-3-iodooctanoate

Conditions
ConditionsYield
With chloro-trimethyl-silane; sodium iodide In acetonitrile at -20℃; for 1h;A 7 % Spectr.
B 72%
C 6 % Spectr.
methyl (2S,3S)-2-iodo-3-hydroxyoctanoate
171016-45-8

methyl (2S,3S)-2-iodo-3-hydroxyoctanoate

TMS-propynoyl triflate
1026856-11-0

TMS-propynoyl triflate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl (2S,3S)-2-iodo-3-(trimethylsilylpropynoyloxy)octanoate
171231-64-4

methyl (2S,3S)-2-iodo-3-(trimethylsilylpropynoyloxy)octanoate

Conditions
ConditionsYield
In dichloromethane 1.) from -20 deg C to r.t.; 2.) r.t., 10 h;A 25%
B 71%
(E)-8-bromooct-2-enoic acid methyl ester
68750-34-5

(E)-8-bromooct-2-enoic acid methyl ester

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

methyl cyclohexylacetate
14352-61-5

methyl cyclohexylacetate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 10h; Heating;A n/a
B 66%
Malonic acid monomethyl ester
16695-14-0

Malonic acid monomethyl ester

hexanal
66-25-1

hexanal

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With pyrrolidine; pyridine at 20℃; for 24h;66%
hexanal
66-25-1

hexanal

bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With triphenyl phosphite; tri-n-butylarsine; potassium carbonate In tetrahydrofuran; acetonitrile for 31h; Ambient temperature;64%
methyl 2-diazooctanoate

methyl 2-diazooctanoate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

C

C9H16O2

C9H16O2

Conditions
ConditionsYield
With Li[Al(perfluoro-tertbutoxide)4]; [Fe(N,N’-bis(pentafluorophenyl)-o-phenylenediamide)(tetrahydrofuran)]2 In dichloromethane at 25℃; for 24h; Schlenk technique; Inert atmosphere;A n/a
B n/a
C 64%
Methyl diethylphosphonoacetate
1067-74-9

Methyl diethylphosphonoacetate

hexanal
66-25-1

hexanal

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With triethylamine In acetonitrile at 20℃; under 6000480 Torr; for 24h; Horner-Wadsworth-Emmons reaction;54%
With sodium hydride In diethylene glycol dimethyl ether
Stage #1: Methyl diethylphosphonoacetate With sodium hydride In 1,2-dimethoxyethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: hexanal In 1,2-dimethoxyethane at 0 - 20℃; for 3h; Inert atmosphere;
2-methylpropen-1-ylmagnesium bromide
38614-36-7

2-methylpropen-1-ylmagnesium bromide

methyl (E)-2-iodo-2-octenoate
144079-78-7

methyl (E)-2-iodo-2-octenoate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

7,8-di(carbomethoxy)-6,8-tetradecadiene
144079-84-5

7,8-di(carbomethoxy)-6,8-tetradecadiene

C

methyl (Z)-2-(2-methyl-1-propenyl)-2-octenoate
145099-83-8

methyl (Z)-2-(2-methyl-1-propenyl)-2-octenoate

D

methyl (E)-2-(2-methyl-1-propenyl)-2-octenoate
145099-84-9

methyl (E)-2-(2-methyl-1-propenyl)-2-octenoate

Conditions
ConditionsYield
With zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran 1) -25 deg C, 3.5 h, 2) room temperature, 16 h, 3) reflux, 4 h; Further byproducts given. Yields of byproduct given;A n/a
B 16%
C n/a
D n/a
With zinc(II) chloride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran 1) -25 deg C, 3.5 h, 2) room temperature, 16 h, 3) reflux, 4 h; Yield given. Further byproducts given. Title compound not separated from byproducts;A n/a
B 16%
C n/a
D n/a
3-hydroxyoctanoic acid methyl ester
7367-87-5

3-hydroxyoctanoic acid methyl ester

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

methyl 3-fluorooctanoate

methyl 3-fluorooctanoate

methyl 3-fluorooctanoate

methyl 3-fluorooctanoate

Conditions
ConditionsYield
With diethylamino-sulfur trifluoride In dichloromethane at -70℃; for 0.333333h; Inert atmosphere; Overall yield = 40 %; Overall yield = 17 mg;A 15%
B n/a
C n/a
methyl 2-octynoate
111-12-6

methyl 2-octynoate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide; methyllithium; diisobutylaluminium hydride In tetrahydrofuran; hexane at -50℃; for 1h;A 12%
B 7%
With quinoline; hydrogen; Lindlar's catalyst In ethyl acetate under 760 Torr; Yield given. Yields of byproduct given;
(E)-oct-2-enoic acid
1871-67-6

(E)-oct-2-enoic acid

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With diethyl ether durch Veresterung;
In diethyl ether
1,1-dimethoxyethylene
922-69-0

1,1-dimethoxyethylene

hexanal
66-25-1

hexanal

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
at 200℃;
methanol
67-56-1

methanol

1-Heptyne
628-71-7

1-Heptyne

carbon monoxide
201230-82-2

carbon monoxide

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; tin(ll) chloride
trans-Methyl-N-phenyl-2-octenoimidat
56830-01-4

trans-Methyl-N-phenyl-2-octenoimidat

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

Conditions
ConditionsYield
With hydrogenchloride
dichloromethane
75-09-2

dichloromethane

Z-dimethyltertiobutylsilyloxy-1 methoxy-1 heptene-1
100340-44-1

Z-dimethyltertiobutylsilyloxy-1 methoxy-1 heptene-1

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

tert-Butyl-((1S,2R,3R)-2-chloro-1-methoxy-3-pentyl-cyclopropoxy)-dimethyl-silane

tert-Butyl-((1S,2R,3R)-2-chloro-1-methoxy-3-pentyl-cyclopropoxy)-dimethyl-silane

tert-Butyl-((1S,2S,3R)-2-chloro-1-methoxy-3-pentyl-cyclopropoxy)-dimethyl-silane

tert-Butyl-((1S,2S,3R)-2-chloro-1-methoxy-3-pentyl-cyclopropoxy)-dimethyl-silane

Conditions
ConditionsYield
With sodium hexamethyldisilazane Product distribution; Mechanism; multistep reaction: 1.) pentane -15 deg C; 2.) methanol-triethylamine, reflux; studied: the stereochemistry (E or Z) in the addition reaction of ketene alkylsilyl acetals with chloro-, chloromethyl- and chlorophenyl carbenes;
methyl hexanoate
106-70-7

methyl hexanoate

trimethyl phosphonoacetate
5927-18-4

trimethyl phosphonoacetate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

2-cis octenoic acid methyl ester
68854-59-1

2-cis octenoic acid methyl ester

Conditions
ConditionsYield
With n-butyllithium; diisobutylaluminium hydride In tetrahydrofuran at -78℃; Yield given. Yields of byproduct given;
methyl α-iodocaprylate
73635-61-7

methyl α-iodocaprylate

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

(E)-methyl oct-3-enoate
35234-16-3

(E)-methyl oct-3-enoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 80℃; for 3h; Yield given;
methyl 2-phenylsulfinylacetate
14090-83-6

methyl 2-phenylsulfinylacetate

1-Iodohexane
638-45-9

1-Iodohexane

A

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

B

(E)-2-Hexyl-oct-2-enoic acid methyl ester
111036-55-6, 135987-03-0

(E)-2-Hexyl-oct-2-enoic acid methyl ester

Conditions
ConditionsYield
With sodium hydride 1) DMF, 20 deg C, 0.2 h, 2) toluene, 110 deg C, 15 min; Yield given. Multistep reaction. Yields of byproduct given;
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

methyl (2R,3S)-2,3-dihydroxyoctanoate
1593758-37-2

methyl (2R,3S)-2,3-dihydroxyoctanoate

Conditions
ConditionsYield
With methanesulfonamide; AD-mix-α In water; tert-butyl alcohol at 0 - 20℃; for 96h;98%
With methanesulfonamide; AD-mix-α; water In tert-butyl alcohol at 0℃; for 96h; Sharpless Dihydroxylation; Inert atmosphere; stereoselective reaction;75%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

2-hydroxyoctanoic acid methyl ester
73634-76-1

2-hydroxyoctanoic acid methyl ester

Conditions
ConditionsYield
With phenylsilane; oxygen; bis(dipivaloylmethanato)manganese(II) In isopropyl alcohol at 0℃; under 760 Torr; for 5h;94%
nitromethane
75-52-5

nitromethane

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

3-nitrooctanoic acid methyl ester
664304-85-2

3-nitrooctanoic acid methyl ester

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene at 20℃;94%
tert-butyl acetoacetate
1694-31-1

tert-butyl acetoacetate

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

C16H26O4

C16H26O4

Conditions
ConditionsYield
With sodium methylate In methanol for 2.5h; Inert atmosphere; Reflux;91%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

lithium benzyl-(R)-1-phenylethylamide

lithium benzyl-(R)-1-phenylethylamide

(R)-3-[Benzyl-((R)-1-phenyl-ethyl)-amino]-octanoic acid methyl ester
486449-97-2

(R)-3-[Benzyl-((R)-1-phenyl-ethyl)-amino]-octanoic acid methyl ester

Conditions
ConditionsYield
90%
2,2-dimethyl-3-butyne
917-92-0

2,2-dimethyl-3-butyne

methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

methyl 3-[(E)-3,3-dimethyl-1-butene-1-yl]octanoate

methyl 3-[(E)-3,3-dimethyl-1-butene-1-yl]octanoate

Conditions
ConditionsYield
Stage #1: 3,3-Dimethylbut-1-yne With CpZrHCl In dichloromethane at 20℃; for 0.25h;
Stage #2: methyl (E)-oct-2-enoate; chloro(1,5-cyclooctadiene)rhodium(I) dimer In 1,4-dioxane at 20℃; for 1h; Further stages.;
90%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

(E)-oct-2-enoic acid
1871-67-6

(E)-oct-2-enoic acid

Conditions
ConditionsYield
With potassium fluoride; tetrabutyl ammonium fluoride In tetrahydrofuran; water at 70℃; for 7h;90%
With lithium hydroxide In tetrahydrofuran; water for 2.5h; Reflux;
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

2,2,2-trifluoroethyl 2-(4-bromophenyl)-2-diazoacetate

2,2,2-trifluoroethyl 2-(4-bromophenyl)-2-diazoacetate

1-methyl 9-(2,2,2-trifluoroethyl) (7R,8S,E)-8-(4-bromophenyl)-7-methylnon-2-enedioate

1-methyl 9-(2,2,2-trifluoroethyl) (7R,8S,E)-8-(4-bromophenyl)-7-methylnon-2-enedioate

Conditions
ConditionsYield
Stage #1: methyl (E)-oct-2-enoate With dirhodium tetrakis((S)-1-(5-trifluoromethyl-2-chlorophenyl)-2,2-diphenylcyclopropanecarboxylate) In dichloromethane at 23℃; for 0.166667h; Inert atmosphere;
Stage #2: 2,2,2-trifluoroethyl 2-(4-bromophenyl)-2-diazoacetate In dichloromethane at 23℃; for 2h; Reagent/catalyst; Inert atmosphere; stereoselective reaction;
90%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

(2S,3R)-(+)-methyl 2,3-dihydroxyoctanoate
132486-46-5

(2S,3R)-(+)-methyl 2,3-dihydroxyoctanoate

Conditions
ConditionsYield
With methanesulfonamide; AD-mix-β In water; tert-butyl alcohol at 0 - 20℃; for 96h;88%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

(2S*,3R*)-methyl 2,3-epoxyoctanoate
100939-32-0

(2S*,3R*)-methyl 2,3-epoxyoctanoate

Conditions
ConditionsYield
With [2,2]bipyridinyl; silver(I) acetate; lithium perchlorate In water; acetonitrile electrochemical oxidation;80%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

(S)-Methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)octanoate
1198171-98-0

(S)-Methyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)octanoate

Conditions
ConditionsYield
With [CN2(C6H3-2-Mes-5-iPr)(Mes)C2H2Ph2]BF4; 1,8-diazabicyclo[5.4.0]undec-7-ene; MeOH In tetrahydrofuran (N2), 22°C, 14 h;80%
With methanol; BF4(1-)*C42H45N2(1+); 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 22℃; for 14h; Inert atmosphere; enantioselective reaction;80%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

methyl 3-oxooctanoate
22348-95-4

methyl 3-oxooctanoate

Conditions
ConditionsYield
With methanol; water; oxygen; toluene-4-sulfonic acid; palladium dichloride In N,N-dimethyl acetamide at 80℃; under 4560.31 Torr; for 3h; Reagent/catalyst; Solvent; Time; Pressure; Concentration; Autoclave; regioselective reaction;79%
methyl (E)-oct-2-enoate
7367-81-9

methyl (E)-oct-2-enoate

(1Z,4Z)-1,5-diiodopenta-1,4-diene
63382-68-3

(1Z,4Z)-1,5-diiodopenta-1,4-diene

(E)-1-heptenylbenzene
10201-58-8

(E)-1-heptenylbenzene

Conditions
ConditionsYield
Stage #1: (1Z,4Z)-1,5-diiodopenta-1,4-diene With n-butyllithium; isopropylmagnesium chloride In tetrahydrofuran; hexane at -20℃; for 2h; Inert atmosphere;
Stage #2: methyl (E)-oct-2-enoate In tetrahydrofuran; hexane at -20℃; for 2h; Inert atmosphere;
60%

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