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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Biphenyl Dimethyl Dicarboxylate supplier in China

Cas:792-74-5

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Biphenyl Dimethyl Dicarboxylate

Cas:792-74-5

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 792-74-5 Dimethyl biphenyl-4,4'-dicarboxylate Manufacturer

Cas:792-74-5

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Biphenyl dimethyl dicarboxylate Manufacturer/High quality/Best price/In stock

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Biphenyl dimethyl dicarboxylate CAS 792-74-5 In stock

Cas:792-74-5

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Shandong Xingshun New Material Co., Ltd.

Linchuan's expertise and flexibility have made the company become one of the leading manufacturer of Naphthalene series, Biphenyl series , Anthracene series and 1-(CHLOROMETHYL)-4-ETHENYLBENZENE series, which are wildly used in the field of

High quality Biphenyl dimethyl dicarboxylate low price suppliers

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

CAS 792-74-5 Biphenyl Dimethyl Dicarboxylate

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 792-74-5 with best quality

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: Biphenyl dimethyl dicarboxylate Synonyms: TIMTEC-BB SBB005981;RARECHEM AL BF 1412;4,4'-Biscarbomethoxybiphenyl; 4,4-Dicarboxymethylbiphenyl;Dimethyldiphenyldicarboxylate;v0

Biphenyl dimethyl dicarboxylate CAS: 792-74-5

Cas:792-74-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

(1,1'-Biphenyl)-4,4'-dicarboxylic acid, 4,4'-dimethyl ester 792-74-5

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Biphenyl dimethyl dicarboxylate CAS:792-74-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality org

Biphenyl dimethyl dicarboxylate CAS:792-74-5

Cas:792-74-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

(1,1'-Biphenyl)-4,4'-dicarboxylic acid, 4,4'-dimethyl ester

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

(1,1'-Biphenyl)-4,4'-dicarboxylic acid, 4,4'-dimethyl ester

Cas:792-74-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Dimethyl [1,1"-biphenyl]-4,4"-dicarboxylate

Cas:792-74-5

Min.Order:1 Gram

FOB Price: $41.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Biphenyl 4,4-dimethyl dicarboxylate

Cas:792-74-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $30.0 / 50.0

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BIPHENYL DIMETHYL DICARBOXYLATE

Cas:792-74-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Biphenyl 4,4-dimethyl dicarboxylate

Cas:792-74-5

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Dimethyl Biphenyl-4,4’-Dicarboxylate CAS No.: 792-74-5 Molecule Formula:C16H14O4 Molecule Weight:270.28 Purity: 99.0% Package: 25kg/drum Description:White or off-white crystalline powder Manufacture Standards:Enterprise St

Lower Price Dimethyl Biphenyl-4,4’-Dicarboxylate in stock

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate. In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so o

TIANFU CHEM Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam

Biphenyl dimethyl dicarboxylate CAS792-74-5

Cas:792-74-5

Min.Order:1 Metric Ton

FOB Price: $7.0 / 10.0

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Biphenyl dimethyl dicarboxylate Manufacturer/High quality/Best price/In stock

Cas:792-74-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Buy Top Purity Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Biphenyldimethyldicarboxylate

Cas:792-74-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Biphenyl dimethyl dicarboxylate Basic information Product Name: Biphenyl dimethyl dicarboxylate Synonyms: TIMTEC-BB SBB005981;RARECHEM AL BF 1412;4,4''-BIPHENYLDICARBOXYLIC ACID DIMETHYL ESTER 98+%;B.D.D.;4,4'-Biscarbomethoxybiphen

Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Biphenyl 4,4-dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Biphenyl dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Biphenyl 4,4-dimethyl dicarboxylate

Cas:792-74-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With caesium carbonate; hydroquinone; palladium diacetate In N,N-dimethyl acetamide at 75℃; for 2h; Ullmann coupling;99%
With dipotassium hydrogenphosphate; digold(I)bis(diphenylphosphinomethane)dichloride; triethylamine In methanol; acetonitrile at 20℃; for 16h; Inert atmosphere; UV-irradiation;91%
With Palladacycle; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 100℃; for 12h;76%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With (1E,2E)-N1,N2-bis(2,6-dimethylphenyl)ethane-1,2-diimine; nickel dibromide; zinc In tetrahydrofuran at 70℃; for 10h; Inert atmosphere;99%
With Ni(acetylacetate)2; 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclo-hexadiene In toluene at 80℃; for 18h;96%
With sodium hydroxide; triethylammonium formate; zinc In methanol for 3h; Heating;95%
methyl 4-(methanesulfonyloxy)benzoate
161497-18-3

methyl 4-(methanesulfonyloxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With tetraethylammonium iodide; zinc; bis(triphenylphosphine)nickel(II) chloride In tetrahydrofuran at 67℃; for 10h;99%
bis(triphenylphosphine)nickel(II) chloride; tetraethylammonium iodide; zinc In tetrahydrofuran 1.) r.t., 5 min, 2.) 67 deg C, 10 h; Yield given;
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With palladium diacetate; cesium fluoride; CyJohnPhos In 1,4-dioxane at 25℃; Inert atmosphere;99%
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine In tetrahydrofuran at 23℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;97%
With cesium fluoride; palladium diacetate; CyJohnPhos In 1,4-dioxane at 25℃; for 18h; Product distribution / selectivity;96%
With potassium phosphate; (1,2-bis(diphenylphosphino)ethane)nickel(II) chloride; 1,2-bis-(diphenylphosphino)ethane In 1,4-dioxane at 110℃; for 18h; Suzuki-Miyaura cross-coupling; Inert atmosphere;67%
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine In tetrahydrofuran at 23℃; for 20h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;99%
With potassium phosphate; (1,2-bis(diphenylphosphino)ethane)nickel(II) chloride; 1,2-bis-(diphenylphosphino)ethane In 1,4-dioxane at 110℃; for 18h; Suzuki-Miyaura cross-coupling; Inert atmosphere;79%
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

methyl 4-(methanesulfonyloxy)benzoate
161497-18-3

methyl 4-(methanesulfonyloxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); potassium phosphate; tricyclohexylphosphine In tetrahydrofuran at 25℃; for 4h; Inert atmosphere;99%
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine In tetrahydrofuran at 23℃; for 1.5h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;97%
With potassium phosphate; trans-chloro(1-naphthyl)bis-(triphenylphosphine)nickel(II); tricyclohexylphosphine In tetrahydrofuran at 25℃; for 12h; Suzuki coupling; Inert atmosphere;95%
With bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; tricyclohexylphosphine In toluene at 120℃; for 24h;20%
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium phosphate tribasic hydrate; NiIICl(1-naphthyl)(tricyclohexylphosphine)2; tricyclohexylphosphine In tetrahydrofuran at 23℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;98%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 80℃; for 10h; Catalytic behavior; Suzuki Coupling;97.3%
4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With C54H74Cl2N4O2Pd2 In ethanol at 22℃; for 6h;97%
With Cu2(ophen)2 In N,N-dimethyl-formamide at 20℃; for 20h;95%
With palladium diacetate at 20℃; for 0.5h;93%
methanol
67-56-1

methanol

4,4'-diphenic acid
787-70-2

4,4'-diphenic acid

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
Stage #1: 4,4'-diphenic acid With thionyl chloride Reflux;
Stage #2: methanol at 0℃;
95%
With phosphorus pentachloride
Stage #1: 4,4'-diphenic acid With thionyl chloride Reflux;
Stage #2: methanol at 0℃;
With sulfuric acid Reflux;
4,4'-diphenic acid
787-70-2

4,4'-diphenic acid

methyl iodide
74-88-4

methyl iodide

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium carbonate In acetone at 70℃; for 24h; Sealed tube;95%
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

methyl 4-(tosyloxy)benzoate
51207-43-3

methyl 4-(tosyloxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium phosphate; bis (1,5-cyclopentadiene)nickel (0); tricyclohexylphosphine In tetrahydrofuran at 25℃; for 8h; Inert atmosphere;93%
With potassium phosphate; bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In tetrahydrofuran at 20 - 25℃; for 8 - 12h; Product distribution / selectivity;93%
methanol
67-56-1

methanol

(4,4'-dimethyl-1,1'-biphenyl)
613-33-2

(4,4'-dimethyl-1,1'-biphenyl)

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With carbon tetrabromide; oxygen for 48h; Irradiation;93%
With 2,3-dicarboxyanthraquinone; oxygen for 48h; Irradiation;87%
With hydrogenchloride; oxygen; 9-(2-mesityl)-10-methylacridinium perchlorate at 20℃; under 760.051 Torr; for 30h; Schlenk technique; Irradiation; Green chemistry;76%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

potassium benzyltrifluoroborate

potassium benzyltrifluoroborate

A

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

B

methyl 4-benzylbenzoate
23450-30-8

methyl 4-benzylbenzoate

Conditions
ConditionsYield
With (1,2-dimethoxyethane)dichloronickel(II); lithium perchlorate; potassium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine In N,N-dimethyl-formamide at 20℃; Catalytic behavior; Solvent; Reagent/catalyst; Electrochemical reaction; Inert atmosphere; Glovebox;A 5%
B 93%
methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate
905966-40-7

methyl 4-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)benzoate

methyl 4-((N, N-dimethylsulfamoyl)oxy)benzoate
338396-06-8

methyl 4-((N, N-dimethylsulfamoyl)oxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium phosphate; trans-chloro(1-naphthyl)bis-(triphenylphosphine)nickel(II); tricyclohexylphosphine In tetrahydrofuran at 25℃; for 18h; Suzuki coupling; Inert atmosphere;91%
With bis(1,5-cyclooctadiene)nickel (0); cesium fluoride; tricyclohexylphosphine In toluene at 120℃; for 24h;38%
4-iodoanisol
529-28-2

4-iodoanisol

2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

2,2'-Dimethoxybiphenyl
4877-93-4

2,2'-Dimethoxybiphenyl

C

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

D

2'-methoxy-biphenyl-2-carboxylic acid methyl ester
63506-58-1

2'-methoxy-biphenyl-2-carboxylic acid methyl ester

Conditions
ConditionsYield
With pyridine; tetrabutylammonium tetrafluoroborate In acetonitrile at 20℃; Electrolysis; iron rod as anode; stainless steel grid as cathode;A n/a
B n/a
C n/a
D 90%
[(E)-2-bromoethenyl]benzene
588-72-7

[(E)-2-bromoethenyl]benzene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

A

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

B

(E)-methyl 4-styrylbenzoate
1149-18-4

(E)-methyl 4-styrylbenzoate

Conditions
ConditionsYield
With C26H31IN2NiO2; zinc for 1.2h;A 10%
B 90%
Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

2-bromoanisole
578-57-4

2-bromoanisole

A

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

B

methyl 2’-methoxy-[1,1'-biphenyl]-4-carboxylate
89901-00-8

methyl 2’-methoxy-[1,1'-biphenyl]-4-carboxylate

Conditions
ConditionsYield
With manganese; cobalt (II) bromide; triphenylphosphine; trifluoroacetic acid In pyridine; N,N-dimethyl-formamide at 50℃;A 3 %Chromat.
B 89%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

C8H8BO4Pol

C8H8BO4Pol

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
Stage #1: methyl 4-iodobenzoate; C8H8BO4Pol With palladium diacetate; potassium carbonate In water; acetonitrile at 100℃; for 5h; Wang resin; Suzuki-Miyaura Coupling; Sealed tube;
Stage #2: With trifluoroacetic acid In dichloromethane at 20℃; for 0.833333h; Wang resin;
Stage #3: diazomethane
89%
methyl 4-(sodiosulfonyl)benzoate

methyl 4-(sodiosulfonyl)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With di-tert-butyl peroxide; palladium diacetate In acetonitrile at 60℃; for 12h;88%
methyl 4-(tosyloxy)benzoate
51207-43-3

methyl 4-(tosyloxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(acetylacetonato)palladium(II); zinc In tetrahydrofuran at 25℃; for 6h;87%
bis(triphenylphosphine)nickel(II) chloride; tetraethylammonium iodide; zinc In tetrahydrofuran 1.) r.t., 5 min, 2.) 67 deg C, 10 h; Yield given;
methyl coumalate
6018-41-3

methyl coumalate

methyl 4-vinylbenzoate
1076-96-6

methyl 4-vinylbenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
palladium on activated charcoal In m-xylene at 140℃; for 12h;86%
Methyl 4-(((4-fluorophenyl)sulfonyl)oxy)benzoate
161497-16-1

Methyl 4-(((4-fluorophenyl)sulfonyl)oxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
bis(triphenylphosphine)nickel(II) chloride; tetraethylammonium iodide; zinc In tetrahydrofuran 1.) r.t., 5 min, 2.) 67 deg C, 5 h;85%
methanol
67-56-1

methanol

[1,1'-biphenyl]-4,4'-diyl bis(trifluoromethanesulfonate)

[1,1'-biphenyl]-4,4'-diyl bis(trifluoromethanesulfonate)

CO

CO

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With 1,3-bis-(diphenylphosphino)propane; triethylamine; palladium diacetate In dimethyl sulfoxide at 70℃; for 1h;85%
methanol
67-56-1

methanol

4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

4-carboxyphenylboronic acid
14047-29-1

4-carboxyphenylboronic acid

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium cyanide at 20℃; for 24h;85%
Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With manganese; 3-chloroprop-1-ene; trifluoroacetic acid; cobalt(II) bromide In pyridine; acetonitrile at 50℃; for 1.5h;84%
With bis(triphenylphosphine)nickel(II) chloride; tetra-(n-butyl)ammonium iodide; zinc
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

A

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

B

methyl 4-(4'-methoxyphenyl)benzoate
729-17-9

methyl 4-(4'-methoxyphenyl)benzoate

Conditions
ConditionsYield
With manganese; cobalt (II) bromide; triphenylphosphine; trifluoroacetic acid In pyridine; N,N-dimethyl-formamide at 50℃;A 6 %Chromat.
B 84%
Methyl 4-((phenylsulfonyl)oxy)benzoate
161497-17-2

Methyl 4-((phenylsulfonyl)oxy)benzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
bis(triphenylphosphine)nickel(II) chloride; tetraethylammonium iodide; zinc In tetrahydrofuran 1.) r.t, 5 min, 2.) 67 deg C, 5 h;83%
2-bromobenzoic acid methyl ester
610-94-6

2-bromobenzoic acid methyl ester

Ethyl 4-bromobenzoate
5798-75-4

Ethyl 4-bromobenzoate

A

benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

B

diethyl biphenyl-4,4'-dicarboxylate
47230-38-6

diethyl biphenyl-4,4'-dicarboxylate

C

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

D

biphenyl-2,4'-dicarboxylic acid 4'-ethyl ester 2-methyl ester

biphenyl-2,4'-dicarboxylic acid 4'-ethyl ester 2-methyl ester

Conditions
ConditionsYield
With pyridine; tetrabutylammonium tetrafluoroborate In acetonitrile at 20℃; Electrolysis; iron rod as anode; stainless steel grid as cathode;A n/a
B n/a
C n/a
D 82%
bromostyrene
103-64-0

bromostyrene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

A

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

B

(E)-methyl 4-styrylbenzoate
1149-18-4

(E)-methyl 4-styrylbenzoate

C

1,4-diphenyl-1,3-butadiene
886-65-7, 82598-07-0

1,4-diphenyl-1,3-butadiene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); 4,4'-di-tert-butyl-2,2'-bipyridine; magnesium chloride; zinc In tetrahydrofuran at 0 - 20℃; for 12h; Reagent/catalyst; Schlenk technique; Sealed tube; Inert atmosphere;A 8%
B 82%
C 20%
With bis(1,5-cyclooctadiene)nickel (0); 4,4'-di-tert-butyl-2,2'-bipyridine; lithium chloride; magnesium chloride; zinc In tetrahydrofuran at 0 - 20℃; for 12h; Time; Temperature; Reagent/catalyst; Schlenk technique; Sealed tube; Inert atmosphere;A 14%
B 81%
C 16%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

trans,trans dimethyl bicyclohexyl-4,4'-dicarboxylate

trans,trans dimethyl bicyclohexyl-4,4'-dicarboxylate

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In acetic acid under 2844.3 Torr; for 0.5h;100%
With rhodium(III) oxide; palladium 10% on activated carbon; hydrogen; acetic acid In water at 250℃; under 15201 - 45603.1 Torr; for 16h;96%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid
23613-32-3

dibenzothiophene-5,5′-dioxide-3,7-dicarboxylic acid

Conditions
ConditionsYield
With chlorosulfonic acid at 130 - 155℃; for 3h;99%
With chlorosulfonic acid at 150℃; for 3h;95%
With chlorosulfonic acid at 140℃; for 3h;0.862 g
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

dimethyl 2,2’-dinitro-[1,1’-biphenyl]-4,4’-dicarboxylate
65235-35-0

dimethyl 2,2’-dinitro-[1,1’-biphenyl]-4,4’-dicarboxylate

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 20℃; for 11h;98.3%
Stage #1: 4,4'-biphenyldicarboxylic acid dimethyl ester With sulfuric acid at 20℃; for 0.166667h;
Stage #2: With nitric acid at 20℃; for 4.33333h; Cooling with ice;
90%
Stage #1: 4,4'-biphenyldicarboxylic acid dimethyl ester With sulfuric acid at 20℃; for 0.166667h;
Stage #2: With nitric acid at 20℃; for 4.33333h;
90%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

dimethyl 2-nitro-[1,1’-biphenyl]-4,4’-dicarboxylate
1007568-39-9

dimethyl 2-nitro-[1,1’-biphenyl]-4,4’-dicarboxylate

Conditions
ConditionsYield
With sulfuric acid; nitric acid at 5℃; Cooling with ice;97%
With sulfuric acid; nitric acid at 0 - 20℃; for 24h;93%
With sulfuric acid; nitric acid at -20 - 0℃; for 0.5h;89%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

water
7732-18-5

water

4,4'-bis(hydroxymethyl)biphenyl
1667-12-5

4,4'-bis(hydroxymethyl)biphenyl

Conditions
ConditionsYield
With LiAlH4 In tetrahydrofuran; ethanol; acetone96.6%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

4,4'-bis(hydroxymethyl)biphenyl
1667-12-5

4,4'-bis(hydroxymethyl)biphenyl

Conditions
ConditionsYield
With LiAlH4 In tetrahydrofuran; tetrahydrofuran-water; acetone96.6%
With lithium aluminium tetrahydride In tetrahydrofuran for 2h; Reflux;90%
With lithium aluminium tetrahydride at 75℃; for 12h;90%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

4,4'-diphenic acid
787-70-2

4,4'-diphenic acid

Conditions
ConditionsYield
With sulfuric acid In water; acetic acid at 120℃; for 24h; Reflux;96.6%
With sodium hydroxide In tetrahydrofuran; water at 80℃; for 48h; Reflux;88%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

2-amino-[1,1′-biphenyl]-4,4′-dicarboxylic acid
1240557-01-0

2-amino-[1,1′-biphenyl]-4,4′-dicarboxylic acid

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; water for 16h; Reflux;95%
Multi-step reaction with 3 steps
1: sulfuric acid; nitric acid / 0.25 h / 0 - 5 °C
2: tin; hydrogenchloride / water / 2 h / Reflux
3: potassium hydroxide; water / tetrahydrofuran / Reflux
View Scheme
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

1,1′-Biphenyl-4,4′-dicarbohydrazide
4073-75-0

1,1′-Biphenyl-4,4′-dicarbohydrazide

Conditions
ConditionsYield
With hydrazine hydrate at 70℃; for 24h;94%
With hydrazine hydrate at 100℃; for 24h;92.6%
With hydrazine hydrate In methanol; water for 12h;80%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

3-amino-4-hydroxytoluene
95-84-1

3-amino-4-hydroxytoluene

C28H20N2O2

C28H20N2O2

Conditions
ConditionsYield
With boric acid In pyridine; diphenylether at 160 - 250℃; for 13h;92.4%
4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

2-amino-4-phenylphenol
1134-36-7

2-amino-4-phenylphenol

C38H24N2O2
24343-10-0

C38H24N2O2

Conditions
ConditionsYield
With boric acid In pyridine; diphenylether at 160 - 260℃; for 15h;89.7%

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