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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Methyl 4-iodobenzoate Manufacturer/High quality/Best price/In stock

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 4-iodobenzoate supplier in China

Cas:619-44-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hubei Vanz Pharm Co.,Ltd

1 high purity 2 able to provide COA/HNMR/HPLC 3 High quality 4 low price 5 Best service Appearance:white powder Storage:Refrigerator Package:bag/bottle/drum Application:pharmaceutical intermediate Transportation:common transportation Port:Sha

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name Methyl 4-iodobenzoate CAS No. 619

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Unique advantages for Methyl 4-iodobenzoate Cas 619-44-3 Guaranteed purity High quality & competitive price Quality control Fast feedback Prompt shipment Appearance:White crystalline powder Storage:N/A Package:25kg/drum Application:F

Factory supply Methyl 4-iodobenzoate Cas 619-44-3 with high quality and best price

Cas:619-44-3

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:white powder Storage:Sealed, dry, microtherm , avoid light and smell Package:According to the demand of customer Application:Pharmaceutical intermediates Transportation:by air or by sea Port:shanghai

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Iodobenzoic acid methyl ester

Cas:619-44-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details

China Largest factory Manufacturer Supply Methyl 4-iodobenzoate CAS 619-44-3

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

619-44-3 Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New product CAS 619-44-3 with high-quality service

Cas:619-44-3

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:10 Gram

FOB Price: $0.5 / 1.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: Methyl 4-iodobenzoate Synonyms: 4-Iodobenzoic acid methyl ester CAS: 619-44-3 MF: C8H7IO2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Syntheses Material Intermediates Tra

Methyl 4-iodobenzoate CAS: 619-44-3

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzoicacid, 4-iodo-, methyl ester 619-44-3

Cas:619-44-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

organic intermediates, Methyl 4-iodobenzoate CAS:619-44-3

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $43.0 / 48.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:619-44-3

Cas:619-44-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL 4-IODOBENZOATE 619-44-3

Cas:619-44-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:beige to pale pink crystalline powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:suzuki reaction Transportation:a

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Siwei Development Group Ltd.

Product name: Methyl 4-Iodobenzoate CAS No.: 619-44-3 Molecule Formula:C8H7IO2 Molecule Weight:262.04 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS

Lower Price Methyl 4-Iodobenzoate on stock

Cas:619-44-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: Methyl 4-iodobenzoate CAS: 619-44-3 MF: C8H7IO2 MW: 262.04 EINECS: 210-597-1 Mol File: 619-44-3.mol Methyl 4-iodobenzoate Structure Methyl 4-iodobenzoate Chemical Properties Melting point 112-116 °C Boiling

Methyl 4-iodobenzoateoxylic acid

Cas:619-44-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Benzoicacid, 4-iodo-, methyl ester

Cas:619-44-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Methyl 4-iodobenzoate

Cas:619-44-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With acetyl chloride at 60℃; for 12h;100%
With sulfuric acid for 30h; Reflux;99%
With sulfuric acid Reflux;99%
sodium (¹²⁵I)iodide

sodium (¹²⁵I)iodide

methyl 4-tri-n-butylstannylbenzoate
91734-76-8

methyl 4-tri-n-butylstannylbenzoate

sodium iodide
7681-82-5

sodium iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With N-chloro-succinimide In methanol; acetic acid to a soln. of Sn-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (10% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 min; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;98%
With N-chloro-succinimide In methanol; acetic acid to a soln. of Sn-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;98%
4-(Pyrrolidin-1-ylazo)-benzoic acid methyl ester

4-(Pyrrolidin-1-ylazo)-benzoic acid methyl ester

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With iodine In various solvent(s) at 100℃; for 9h;97%
methyl 4-(3,3-diethyltriaz-1-en-1-yl)benzoate
77726-96-6

methyl 4-(3,3-diethyltriaz-1-en-1-yl)benzoate

methyl iodide
74-88-4

methyl iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
at 110 - 120℃; for 6h;97%
methanol
67-56-1

methanol

p-(iodophenyl)carboxaldehyde
15164-44-0

p-(iodophenyl)carboxaldehyde

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With dihydrogen peroxide at 20℃; for 20h;97%
With oxygen; potassium carbonate at 65℃; for 3h; Catalytic behavior;82 %Chromat.
sodium (¹²⁵I)iodide

sodium (¹²⁵I)iodide

sodium iodide
7681-82-5

sodium iodide

4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of two equivalents of NCS in MeOH, the mixture was stirred at 25°C for 24 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;96%
With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;70%
With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 3 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;60%
With N-chloro-succinimide In methanol; acetic acid to a soln. of B-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (10% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 min; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;>99
methanol
67-56-1

methanol

4-iodo-N,N-bis(pyridin-2-ylmethyl)benzamide
1314659-41-0

4-iodo-N,N-bis(pyridin-2-ylmethyl)benzamide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With copper(II) bis(trifluoromethanesulfonate) at 20℃; for 16h;96%
methanol
67-56-1

methanol

C10H7IN2O3

C10H7IN2O3

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With triethylamine at 100℃; for 24h; Inert atmosphere;96%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
In methanol at 20℃;95%
methanol
67-56-1

methanol

4-iodobenzoic acid chloride
1711-02-0

4-iodobenzoic acid chloride

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h;93%
Stage #1: 4-iodobenzoic acid chloride With pyridine In dichloromethane at 20℃; for 16h;
Stage #2: With pyridinium p-toluenesulfonate In toluene at 50℃; for 16h;
Stage #3: methanol With sodium amide In tetrahydrofuran for 0.5h; Further stages.;
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

tris(o-methoxyphenyl)phosphine
4731-65-1

tris(o-methoxyphenyl)phosphine

A

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

B

2-((2-hydroxyphenyl)(2-methoxyphenyl)(methyl)phosphonio)phenolate

2-((2-hydroxyphenyl)(2-methoxyphenyl)(methyl)phosphonio)phenolate

Conditions
ConditionsYield
With dirhodium tetraacetate In cyclohexane at 120℃; for 12h; Reagent/catalyst; Schlenk technique; Inert atmosphere;A 93%
B 89%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-(4-iodophenyl)-5,5-dimethyl-1,3,2-dioxaborinane
5572-94-1

2-(4-iodophenyl)-5,5-dimethyl-1,3,2-dioxaborinane

methyl iodide
74-88-4

methyl iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
Stage #1: di-tert-butyl dicarbonate; 5,5-dimethyl-2-(4-iodophenyl)-1,3,2-dioxaborinane With 4,4'-dimethyl-2,2'-bipyridines; lithium methanolate; copper(l) chloride In N,N-dimethyl acetamide at 30℃; for 6h; Inert atmosphere; Schlenk technique;
Stage #2: methyl iodide In N,N-dimethyl acetamide at 30℃; for 2h; Schlenk technique;
92%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine]
88016-29-9

μ-oxobis[(trifluoromethanesulfonato)(phenyl)iodine]

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
palladium diacetate In N,N-dimethyl-formamide under 760 Torr; for 0.5h; Ambient temperature;91%
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

tris(o-methoxyphenyl)phosphine
4731-65-1

tris(o-methoxyphenyl)phosphine

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With dirhodium tetraacetate In cyclohexane at 120℃; for 12h; Schlenk technique; Inert atmosphere;91%
methyl 4-tri-n-butylstannylbenzoate
91734-76-8

methyl 4-tri-n-butylstannylbenzoate

sodium iodide
7681-82-5

sodium iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With N-chloro-succinimide In methanol; acetic acid to a soln. of Sn-compd. in MeOH was added one equivalent NaI in MeOH/AcOH and one equivalent NCS, the mixture was stirred for 15 min at 25°C; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn.;90%
4-methoxycarbonylphenylboronic acid
99768-12-4

4-methoxycarbonylphenylboronic acid

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With iodine; potassium carbonate In acetonitrile at 80℃; for 8h; Inert atmosphere; Schlenk technique; Sealed tube;90%
With 1,10-Phenanthroline; oxygen; potassium iodide; copper(ll) bromide In N,N-dimethyl-formamide at 80℃; for 20h;88%
With copper(I) oxide; ammonium hydroxide; oxygen; potassium iodide In water at 25℃; for 24h;80%
With copper(l) iodide; N-iodomorpholine-hydrogen iodide In methanol at 20℃; for 24h;
sodium (¹²⁵I)iodide

sodium (¹²⁵I)iodide

p-(methoxycarbonyl)phenylmercuric chloride
20883-45-8

p-(methoxycarbonyl)phenylmercuric chloride

sodium iodide
7681-82-5

sodium iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With N-chloro-succinimide In methanol; acetic acid to a soln. of Hg-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (10% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 min; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;89%
With N-chloro-succinimide In methanol; acetic acid to a soln. of Hg-compd. in MeOH was added NaI in MeOH, then Na(125)I was added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 72 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;60%
With N-chloro-succinimide In methanol; acetic acid to a soln. of Hg-compd. in MeOH was added NaI in MeOH, then was Na(125)I added (100% stoichiometric amount of NaI/Na(125)I), addn. of AcOH followed by addn. of NCS in MeOH, the mixture was stirred at 25°C for 20 h; the reaction was monitored by use of HPLC equipped with a UV detector, the yield was calculated by HPLC analysis of a solution of known concn., the established yield is the radiochemical yield;40%
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

methyl iodide
74-88-4

methyl iodide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide88%
With N'',N'''''-1,8-naphthalenediyl bis[N,N,N',N'-tetramethyl]guanidine In N,N-dimethyl-formamide at 20℃; Kinetics;
With potassium carbonate In N,N-dimethyl-formamide
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

bis-(2-methoxy-phenyl)-phenyl-phosphane
36802-41-2

bis-(2-methoxy-phenyl)-phenyl-phosphane

A

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

B

2-((2-hydroxyphenyl)(methyl)(phenyl)phosphonio)phenolate

2-((2-hydroxyphenyl)(methyl)(phenyl)phosphonio)phenolate

Conditions
ConditionsYield
With dirhodium tetraacetate In cyclohexane at 160℃; for 12h; Schlenk technique; Inert atmosphere;A 87%
B 86%
chlorido(η-cycloocta-1,5-diene)[tris(2-methoxyphenyl)phosphine]rhodium
102844-63-3

chlorido(η-cycloocta-1,5-diene)[tris(2-methoxyphenyl)phosphine]rhodium

4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

A

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

B

2-((2-hydroxyphenyl)(2-methoxyphenyl)(methyl)phosphonio)phenolate

2-((2-hydroxyphenyl)(2-methoxyphenyl)(methyl)phosphonio)phenolate

C

2-(bis(2-methoxyphenyl)(methyl)phosphonio)phenolate

2-(bis(2-methoxyphenyl)(methyl)phosphonio)phenolate

Conditions
ConditionsYield
In cyclohexane at 120℃; for 12h; Schlenk technique; Inert atmosphere;A 85%
B 82%
C 5%
methanol
67-56-1

methanol

4-iodo-benzyl alcohol
18282-51-4

4-iodo-benzyl alcohol

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With Oxone; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutylammomium bromide at 60℃; for 48h; Sealed tube;77%
With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 24h; Schlenk technique; Green chemistry;94 %Chromat.
With carbon-nitrogen embedded cobalt nanoparticles (800); air In hexane at 25℃; under 760.051 Torr; for 96h;> 99 %Chromat.
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; (2-((2-(diphenylphosphanyl)ethyl)(quinolin-2-ylmethyl)amino)ethyl)diphenylphosphine oxide; potassium carbonate In n-heptane at 120℃; for 16h;35 %Chromat.
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

(4-nitro-phenyl)-phenyl-iodonium ; bromide
4072-48-4

(4-nitro-phenyl)-phenyl-iodonium ; bromide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
palladium diacetate In N,N-dimethyl-formamide under 760 Torr; for 1h; Ambient temperature;76%
Monomethyl terephthalate
1679-64-7

Monomethyl terephthalate

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With N-iodo-succinimide; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; iodine; caesium carbonate In 1,2-dichloro-ethane at 50℃; for 24h; Inert atmosphere; Irradiation; Sealed tube;76%
With tris-(dibenzylideneacetone)dipalladium(0); 1-iodo-butane; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; chloro-N,N,N',N'-bis(tetramethylene)formamidinium hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 120℃; for 16h; Sealed tube; Inert atmosphere;63%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

phenyl(4-methoxyphenyl)iodonium triflate
115298-63-0

phenyl(4-methoxyphenyl)iodonium triflate

A

1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

B

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
palladium diacetate In N,N-dimethyl-formamide under 760 Torr; for 0.5h; Ambient temperature;A 13%
B 72%
palladium diacetate under 760 Torr; Ambient temperature;A 13%
B 72%
4-Methoxycarbonylbenzoyl chloride
7377-26-6

4-Methoxycarbonylbenzoyl chloride

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 100℃; for 12h;68%
4-methoxycarbonyl aniline
619-45-4

4-methoxycarbonyl aniline

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
Stage #1: 4-methoxycarbonyl aniline With sulfuric acid; sodium nitrite at 0℃; for 5h; Sandmeyer Reaction;
Stage #2: With potassium iodide In water at 20℃; Sandmeyer Reaction;
66%
Stage #1: 4-methoxycarbonyl aniline With tert.-butylnitrite; methanesulfonic acid In dimethyl sulfoxide at 20℃; for 0.045h; Flow reactor;
Stage #2: With tetra-(n-butyl)ammonium iodide In dimethyl sulfoxide at 20℃; for 0.333333h; Solvent; Flow reactor;
With iodine; sodium nitrite
C13H16BO5(1-)*K(1+)

C13H16BO5(1-)*K(1+)

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
With chloroamine-T; sodium iodide In tetrahydrofuran; water at 50℃; for 0.5h;64%
tributylphenylstannane
960-16-7

tributylphenylstannane

MeO-PEG5000 bound para-iodobenzoate

MeO-PEG5000 bound para-iodobenzoate

A

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

B

MeO-PEG5000-(4-phenylbenzoate)

MeO-PEG5000-(4-phenylbenzoate)

Conditions
ConditionsYield
With lithium chloride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 24h; Stille coupling; Heating;A 63%
B 7%
tris(2,4,6-trimethoxyphenyl)phosphine
91608-15-0

tris(2,4,6-trimethoxyphenyl)phosphine

4-iodobenzoyl fluoride

4-iodobenzoyl fluoride

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Conditions
ConditionsYield
In toluene at 130℃; for 24h; Schlenk technique; Inert atmosphere;63%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

phenylacetylene
536-74-3

phenylacetylene

methyl 4-(phenylethynyl)benzoate
42497-80-3

methyl 4-(phenylethynyl)benzoate

Conditions
ConditionsYield
With copper(l) iodide; triethylamine; triphenylphosphine In water at 60℃; for 24h; Sonogashira Cross-Coupling; Schlenk technique; Inert atmosphere;100%
With potassium hydroxide In N,N-dimethyl-formamide at 135℃; for 2h; Sonogashira Cross-Coupling; Inert atmosphere;100%
With copper(l) iodide; iron; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 110℃; for 1h; Sonogashira coupling; Inert atmosphere;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

4-trimethylsilanylethynyl-benzoic acid methyl ester
75867-41-3

4-trimethylsilanylethynyl-benzoic acid methyl ester

Conditions
ConditionsYield
With triethylamine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In tetrahydrofuran at 20℃; for 8h;100%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine In N,N-dimethyl-formamide at 20℃; for 3h; Inert atmosphere;100%
With copper(l) iodide; N-ethyl-N,N-diisopropylamine; bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 60℃; for 18h; Castro-Stephens/Sonogashira coupling;98%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

2-methyl-but-3-yn-2-ol
115-19-5

2-methyl-but-3-yn-2-ol

methyl 4-(3-hydroxy-3-methylbut-1-ynyl)benzoate
33577-98-9

methyl 4-(3-hydroxy-3-methylbut-1-ynyl)benzoate

Conditions
ConditionsYield
With copper(l) iodide; (Ph3)2PdCl2; triphenylphosphine; triethylamine for 68h; Sonogashira reaction; Heating;100%
With copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triethylamine at 20℃; Inert atmosphere;96.07%
With copper(l) iodide; triethylamine; polymer-bound Pt(0)-phoshine In water; acetonitrile at 55℃; for 8h;95%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

phenylboronic acid
98-80-6

phenylboronic acid

methyl 4-phenylbenzoate
720-75-2

methyl 4-phenylbenzoate

Conditions
ConditionsYield
With potassium phosphate; second generation phosphine dendrimer-stabilized palladium In 1,4-dioxane for 20h; Suzuki coupling; Heating;100%
With potassium phosphate; silica gel; palladium In toluene at 110℃; for 5h; Suzuki-Miyaura reaction;100%
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0); tri-tert-butyl phosphine In 1,1,1,2,3,3,3-Heptafluoropropane; ethanol; 1,1,1,3,3-pentafluorobutane at 20℃; for 24h; Suzuki-Miyaura cross-coupling reaction; Inert atmosphere;99%
1-ethynyl-2-methoxybenzene
767-91-9

1-ethynyl-2-methoxybenzene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

methyl 4-((2-methoxyphenyl)ethynyl)benzoate
229174-44-1

methyl 4-((2-methoxyphenyl)ethynyl)benzoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 60℃;100%
With copper(l) iodide; bis(triphenylphosphine)palladium(II) chloride; triethylamine In tetrahydrofuran at 0 - 20℃; for 1h; Sonogashira Cross-Coupling; Inert atmosphere;90%
With pyridine; bis-triphenylphosphine-palladium(II) chloride at 80℃; for 1h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;73%
With copper(l) iodide; tris(2,4,6-trimethylphenyl)phosphine; tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In N,N-dimethyl-formamide at -20℃; for 0.333333h; Yield given;
bis(4-tert-butylphenyl) diselenide
71518-97-3

bis(4-tert-butylphenyl) diselenide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4-(4-tert-butyl-phenylselanyl)-benzoic acid methyl ester

4-(4-tert-butyl-phenylselanyl)-benzoic acid methyl ester

Conditions
ConditionsYield
With polymer supported borohydride; bis(bipyridine)nickel(II) bromide In ethanol at 70℃; for 16h; Substitution;100%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

N-benzyl 4-cyclohexylidene-2-propylacrylamide
463930-76-9

N-benzyl 4-cyclohexylidene-2-propylacrylamide

N-benzyl (4-(4-methoxycarbonylphenyl)-3-propyl-1-oxa-spiro[4,5]dec-3-enylidene) amine

N-benzyl (4-(4-methoxycarbonylphenyl)-3-propyl-1-oxa-spiro[4,5]dec-3-enylidene) amine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); tetrabutylammomium bromide; potassium carbonate In toluene at 70℃; for 44h;100%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

propargyl alcohol methyl ether
627-41-8

propargyl alcohol methyl ether

methyl 4-(3-methoxy-1-propynyl)benzoate
827028-02-4

methyl 4-(3-methoxy-1-propynyl)benzoate

Conditions
ConditionsYield
With triethylamine; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide at 80℃; for 6h;100%
tert-Butyl acrylate
1663-39-4

tert-Butyl acrylate

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

(E)-methyl 4-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)benzoate
683246-09-5

(E)-methyl 4-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)benzoate

Conditions
ConditionsYield
With C36H36Cl2N6Pd; triethylamine In methanol at 70℃; for 24h; Heck Reaction;100%
With C43H54NO5P; palladium diacetate; triethylamine In water at 40℃; for 12h; Heck Reaction;92 %Spectr.
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

N-tosyl-N-allylpropargylamine
133886-40-5

N-tosyl-N-allylpropargylamine

methyl 4-(3-((N-allyl-4-methylphenyl)sulfonamido)prop-1-yn-1-yl)benzoate

methyl 4-(3-((N-allyl-4-methylphenyl)sulfonamido)prop-1-yn-1-yl)benzoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 50℃;100%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline
214360-73-3

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)aniline

methyl 4’-amino-[1,1’-biphenyl]-4-carboxylate
5730-76-7

methyl 4’-amino-[1,1’-biphenyl]-4-carboxylate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water at 100℃; for 10h;100%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4,4'-biphenyldicarboxylic acid dimethyl ester
792-74-5

4,4'-biphenyldicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With caesium carbonate; hydroquinone; palladium diacetate In N,N-dimethyl acetamide at 75℃; for 2h; Ullmann coupling;99%
With dipotassium hydrogenphosphate; digold(I)bis(diphenylphosphinomethane)dichloride; triethylamine In methanol; acetonitrile at 20℃; for 16h; Inert atmosphere; UV-irradiation;91%
With Palladacycle; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 100℃; for 12h;76%
styrene
292638-84-7

styrene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

(E)-methyl 4-styrylbenzoate
1149-18-4

(E)-methyl 4-styrylbenzoate

Conditions
ConditionsYield
With palladium diacetate; triethylamine In N,N-dimethyl-formamide at 20℃; for 24h; Heck Reaction; Inert atmosphere; Schlenk technique; Irradiation;99%
With triethylamine In water; N,N-dimethyl-formamide at 90℃; for 21h; Heck Reaction;96%
With tributyl-amine; Si-SH-Pd(0) In xylene at 100℃; for 6h;91%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

1,4-benzenedicarboxylic acid dimethyl ester
120-61-6

1,4-benzenedicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With potassium hydroxide at 100℃; under 5171.62 Torr; for 6h; Autoclave;99%
With palladium/palladium oxide-supported N-doped carbon at 120℃; under 15001.5 Torr; for 24h; Autoclave; Sealed tube;55%
palladium diacetate In N,N-dimethyl-formamide under 760 Torr; for 0.5h; Ambient temperature;
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4-n-methylphenylacetylene
766-97-2

4-n-methylphenylacetylene

4-[2-(4-methylphenyl)ethynyl]benzoic acid methyl ester

4-[2-(4-methylphenyl)ethynyl]benzoic acid methyl ester

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In water; acetonitrile at 90℃; for 7h; Heck Reaction; Sealed tube;99%
With copper(l) iodide; tris(2,4,6-trimethylphenyl)phosphine; tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex In N,N-dimethyl-formamide at -20℃; for 1.33333h;86%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine In dimethyl sulfoxide at 70℃; for 0.441667h; Sonogashira Cross-Coupling; Flow reactor;154 mg
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

3-bromo-4-iodobenzoic acid methyl ester
249647-24-3

3-bromo-4-iodobenzoic acid methyl ester

Conditions
ConditionsYield
With N-Bromosuccinimide; sulfuric acid at 20℃; for 15h; Bromination;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

hex-1-yne
693-02-7

hex-1-yne

1-(4-methoxycarbonylphenyl)-1-hexyne
462637-32-7

1-(4-methoxycarbonylphenyl)-1-hexyne

Conditions
ConditionsYield
With piperidine; copper(l) iodide; polystyrene-N(CH2PPh2)2PdCl2 In 1,4-dioxane at 60℃; for 8h; Sonogashira coupling reaction;99%
Sonogashira coupling; Inert atmosphere;
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; Sonogashira Cross-Coupling; Inert atmosphere;
di-tert-butyl 1-phenylhydrazine-1,2-dicarboxylate
65578-58-7

di-tert-butyl 1-phenylhydrazine-1,2-dicarboxylate

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

C6H5NN(C(CH3)3CO2)2C6H4COOCH3

C6H5NN(C(CH3)3CO2)2C6H4COOCH3

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In N,N-dimethyl-formamide at 80℃; for 3h;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

N,N-dimethylethylenediamine
108-00-9

N,N-dimethylethylenediamine

methyl 4-{[2-(dimethylamino)ethyl]amino}benzoate
956427-71-7

methyl 4-{[2-(dimethylamino)ethyl]amino}benzoate

Conditions
ConditionsYield
With caesium carbonate; copper(l) iodide; 2-acetylcyclohexanone In N,N-dimethyl-formamide at 90℃; for 18h;99%
With caesium carbonate; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100 - 110℃; Sealed tube;
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

hexamethyldistannane
661-69-8

hexamethyldistannane

(4-carbomethoxyphenyl)trimethylstannane
65488-27-9

(4-carbomethoxyphenyl)trimethylstannane

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In 1,4-dioxane at 60℃; for 15h; Inert atmosphere;99%
dichloro bis(acetonitrile) palladium(II) In N,N-dimethyl-formamide byproducts: (CH3)3SnI; Me6Sn2, p-MeO2CC6H4I dissolved in DMF in a flask, catalyst added with stirring, reacted for 15 min at 20°C; water added, extracted with ether, extracts filtered, washed with water, dried with Na2SO4, chromy.(silica gel, hexane/ether 2:1);97%
With tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 100℃; for 18h; Inert atmosphere;83%
4-tert-Butylphenylacetylene
772-38-3

4-tert-Butylphenylacetylene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

C20H20O2
1038987-07-3

C20H20O2

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine at 20℃; Inert atmosphere;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

lithio dimethyl [2-(4-iodophenyl)-2-oxoethyl]phosphonate

lithio dimethyl [2-(4-iodophenyl)-2-oxoethyl]phosphonate

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran Barbier reaction; Cooling with ice; Inert atmosphere;99%
Cyclopropylacetylene
6746-94-7

Cyclopropylacetylene

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

4-(methoxycarbonyl)phenylethynylcyclopropane
1057284-07-7

4-(methoxycarbonyl)phenylethynylcyclopropane

Conditions
ConditionsYield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); diisopropylamine In tetrahydrofuran at 20℃; Sonogashira coupling; Inert atmosphere;99%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 20℃; for 5.66667h; Sonogashira Cross-Coupling;98%
With copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triethylamine at 0 - 20℃; Inert atmosphere;90.21%
2-(diisopropylsilyl)pyridine
1232692-92-0

2-(diisopropylsilyl)pyridine

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

C19H25NO2Si
1312936-25-6

C19H25NO2Si

Conditions
ConditionsYield
With potassium phosphate; di-μ-chlorobis(norbornadiene)dirhodium(I) In 1,4-dioxane at 20℃; Inert atmosphere;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

phenylpropyolic acid
637-44-5

phenylpropyolic acid

methyl 4-(phenylethynyl)benzoate
42497-80-3

methyl 4-(phenylethynyl)benzoate

Conditions
ConditionsYield
With copper(l) iodide; potassium carbonate; triphenylphosphine In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;99%
With copper(l) iodide; potassium carbonate; triphenylphosphine In dimethyl sulfoxide at 100℃; for 24h; Inert atmosphere;99%
With bis-triphenylphosphine-palladium(II) chloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; 1,8-diazabicyclo[5.4.0]undec-7-ene In diethylene glycol dimethyl ether at 80℃; for 4h; Mechanism; Temperature; Time;98%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

[1-methoxyprop-1-enyloxy]trimethylsilane
34880-70-1

[1-methoxyprop-1-enyloxy]trimethylsilane

C12H14O4

C12H14O4

Conditions
ConditionsYield
With (R)-1-(bis(4-methoxy-3,5-dimethylphenyl)phosphano)-2-((S)-1-(dicyclohexylphosphano)ethyl)ferrocene; palladium diacetate; thallium(I) acetate In toluene at 70℃; for 6h; optical yield given as %ee; enantioselective reaction;99%
methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

Trimethyl-((E)-1-propoxy-propenyloxy)-silane
88584-69-4

Trimethyl-((E)-1-propoxy-propenyloxy)-silane

C14H18O4

C14H18O4

Conditions
ConditionsYield
With (R)-1-(bis(4-methoxy-3,5-dimethylphenyl)phosphano)-2-((S)-1-(dicyclohexylphosphano)ethyl)ferrocene; palladium diacetate; thallium(I) acetate In toluene at 70℃; for 6h; optical yield given as %ee; enantioselective reaction;99%
3-phenyl-1,1-di(pyridin-2-yl)prop-2-yn-1-ol
87446-01-3

3-phenyl-1,1-di(pyridin-2-yl)prop-2-yn-1-ol

methyl 4-iodobenzoate
619-44-3

methyl 4-iodobenzoate

methyl 4-(1-oxo-3-phenyl-8a-(pyridin-2-yl)-1,8a-dihydroindolizin-2-yl)benzoate
1383711-46-3

methyl 4-(1-oxo-3-phenyl-8a-(pyridin-2-yl)-1,8a-dihydroindolizin-2-yl)benzoate

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In acetonitrile at 90℃; for 13h;99%

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