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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Phenylthiophene Manufacturer/High quality/Best price/In stock

Cas:825-55-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 2-Phenylthiophene CAS 825-55-8 with good quality Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed addit

Factory supply 2-Phenylthiophene CAS 825-55-8 with good quality

Cas:825-55-8

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Blue or White solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

2-PHENYLTHIOPHENE

Cas:825-55-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

2-PHENYLTHIOPHENE made in China

Cas:825-55-8

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 825-55-8 2-PHENYLTHIOPHENE Manufacturer

Cas:825-55-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2-Phenylthiophene

Cas:825-55-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Phenylthiophene

Cas:825-55-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2-PHENYLTHIOPHENE

Cas:825-55-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2-PHENYLTHIOPHENE-

Cas:825-55-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 825-55-8 with best quality

Cas:825-55-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product name 2-PHENYLTHIOPHENE Synonyms 2-PHENYLTHIOPHENE;5-PHENYLTHIOPHENE;2-Phenylthiophene,96%;Thiophene, 2-phenyl-;2-Phenylthiophene 95% Cas 825-55-8

2-Phenylthiophene

Cas:825-55-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Phenylthiophene 825-55-8

Cas:825-55-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-PHENYLTHIOPHENE CAS:825-55-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedi

2-PHENYLTHIOPHENE CAS:825-55-8

Cas:825-55-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Phenylthiophene Powder USP Standard

Cas:825-55-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

2-Phenylthiophene 825-55-8 For Human Health

Cas:825-55-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-Phenylthiophene

Cas:825-55-8

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Phenylthiophene

Cas:825-55-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

PhenylthiopheneAppearance:White or Almost White crystalline powder Storage:Store in refrigerator Package:according to customers' requirements Application:Steroids injection For Body building Transportation:By air(EMS or EUB or FedEx or TNT ect...) or

Phenylthiophene

Cas:825-55-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Minstar Chemical Co., Ltd

2-PHENYLTHIOPHENE Basic information Product Name: 2-PHENYLTHIOPHENE Synonyms: 5-PHENYLTHIOPHENE;2-PHENYLTHIOPHENE;2-Phenylthiophene,96%;Thiophene, 2-phenyl-;2-Phenylthiophene 95%;2-Phenylthiophene>;2-PHENYLTHIOPHENE ISO 9001:2015 REACH CAS:

2-PHENYLTHIOPHENE

Cas:825-55-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Phenylthiophene 825-55-8 For Human Health

Cas:825-55-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Phenylthiophene 825-55-8 For Human Health

Cas:825-55-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-Phenylthiophene 825-55-8 For Human Health

Cas:825-55-8

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Phenylthiophene 825-55-8 For Human Health

Cas:825-55-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratoryAppearance:White to blue soild Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Phenylthiophene cas no. 825-55-8 96%

Cas:825-55-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Vanz Pharm Co.,Ltd

ISO/factory/goodqualityAppearance:off white Storage:Dry,cool place Package:drum Application:active pharmaceutical ingredients Transportation:by air/sea/express Port:shenzhen/shanghai

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-Phenylthiophene

Cas:825-55-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

2-Phenyl-2-thiophen-2-yl-4,5-dihydro-3λ5,2λ5-[1,3,2]oxazaborole

2-Phenyl-2-thiophen-2-yl-4,5-dihydro-3λ5,2λ5-[1,3,2]oxazaborole

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With N-Bromosuccinimide In methanol; dichloromethane; water Borax buffer;100%
2-bromothiophene
1003-09-4

2-bromothiophene

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; potassium hydroxide In tetrahydrofuran; water at 24℃; for 0.0833333h; Suzuki-Miyaura Coupling; Flow reactor;100%
With [Pd{κ2(C,C)-C6H4PPh2C(H)CO(C6H4-NO2-4)}Br(Ph-NCS)]; sodium carbonate In methanol at 85℃; for 2h; Reagent/catalyst; Suzuki-Miyaura Coupling;100%
With palladium diacetate; potassium fluoride; johnphos In tetrahydrofuran at 20℃; for 3h; Suzuki coupling;99%
2-Iodothiophene
3437-95-4

2-Iodothiophene

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With Tedicyp; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)) In xylene at 130℃; for 20h; Suzuki cross-coupling reaction;100%
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
With caesium carbonate In water; N,N-dimethyl-formamide at 50℃; for 2h; Suzuki Coupling;99%
2-Iodothiophene
3437-95-4

2-Iodothiophene

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole
24388-23-6

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium carbonate In methanol at 60℃; for 1h; Suzuki-Miyaura Coupling;99.8%
2-thienylphenyliodonium tosylate
91228-44-3

2-thienylphenyliodonium tosylate

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water for 0.0833333h; Ambient temperature;99%
With copper(l) iodide; sodium carbonate In 1,2-dimethoxyethane; water at 35℃; for 0.333333h;97%
thiophene boronic acid
6165-68-0

thiophene boronic acid

iodobenzene
591-50-4

iodobenzene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium carbonate; [PS-PEG-adppp-Pd(η3-C3H5)]Cl In water at 50℃; for 12h; Suzuki-Miyaura coupling;99%
Stage #1: thiophene boronic acid; iodobenzene With potassium phosphate In 1,2-dimethoxyethane at 80℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere;
Stage #2: In 1,2-dimethoxyethane; water at 100℃; for 10h;
94%
With potassium phosphate; C24H44BClN2P2Pd In toluene at 80℃; for 1h; Catalytic behavior; Suzuki-Miyaura Coupling; Inert atmosphere;94%
2-bromothiophene
1003-09-4

2-bromothiophene

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With sodium hydroxide; 4,4'-dichlorobenzophenone oxime-derived palladacycle at 120℃; under 7500.6 Torr; for 0.166667h; Hiyama coupling; microwave irradiation;99%
With potassium fluoride; propylene glycol; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In dichloromethane at 100℃; for 12h; Hiyama Coupling; Inert atmosphere;91%
With sodium hydroxide In ethanol; water at 110℃; for 0.133333h; Hiyama coupling; Microwave irradiation;90%
thiophene boronic acid
6165-68-0

thiophene boronic acid

chlorobenzene
108-90-7

chlorobenzene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With dichlorido(pyridine)[4-(4-nitrophenyl)-1,3-bis-(2,4,6-trimethylphenyl)-4,5-dihydro-3H-imidazol-2-ylidene]palladium(II); potassium carbonate In water; isopropyl alcohol at 20℃; for 6h; Suzuki-Miyaura Coupling;98%
With [PdCl{[(η5-C5H5)]Fe[(η5-C5H3)-N2C4H2-Cl]}(DCPAB)]; potassium tert-butylate at 120℃; for 12h; Suzuki coupling;92%
With 1,4-diaza-bicyclo[2.2.2]octane; caesium carbonate; palladium diacetate In N,N-dimethyl-formamide at 110℃; for 24h; Suzuki-Miyaura cross-coupling;88%
2-thienyl chloride
96-43-5

2-thienyl chloride

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium tert-butylate; C38H29ClNPPd In isopropyl alcohol at 80℃; for 2h; Reagent/catalyst;98%
With [{Pd(μ-OH)Cl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)}2]; oxygen; potassium hydroxide In ethanol at 22℃; for 24h; Suzuki-Miyaura Coupling;97%
With di-tert-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; PdCl(π-allyl)(cyclohexyl-(1-methyl-2,2-diphenylcyclopropylphophine)); potassium carbonate In tetrahydrofuran; toluene at 80℃; for 2h; Suzuki-Miyaura Coupling; Inert atmosphere;95%
thiophene boronic acid
6165-68-0

thiophene boronic acid

bromobenzene
108-86-1

bromobenzene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; potassium hydroxide In tetrahydrofuran; water at 24℃; for 0.0833333h; Suzuki-Miyaura Coupling; Flow reactor;97%
With caesium carbonate; copper(l) iodide; tetrabutylammomium bromide In dimethyl sulfoxide at 135 - 140℃; for 21h; Suzuki-Miyaura cross-coupling reaction;96%
With 1,4-diaza-bicyclo[2.2.2]octane; caesium carbonate; palladium diacetate In N,N-dimethyl-formamide at 110℃; for 12h; Suzuki-Miyaura cross-coupling;95%
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

2-thienylphenyliodonium tosylate
91228-44-3

2-thienylphenyliodonium tosylate

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
palladium dichloride In water for 0.00555556h; Suzuki coupling; microwave irradiation;97%
for 0.05h; Suzuki coupling; microwave irradiation;83%
With toluene-4-sulfonic acid In water at 50℃; for 2h; Suzuki coupling;81%
In water at 100℃; for 0.05h; Suzuki coupling reaction; microwave irradiation;80%
Thien-3-ylboronic acid
6165-69-1

Thien-3-ylboronic acid

(trifluoromethylsulfonyl)benzene
426-58-4

(trifluoromethylsulfonyl)benzene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium phosphate; palladium(II) acetylacetonate; ruphos In 1,4-dioxane; dimethyl sulfoxide at 80℃; for 16h; Suzuki-Miyaura Coupling; Sealed tube; Inert atmosphere;97%
bromobenzene
108-86-1

bromobenzene

bis(thien-2-yl)zinc
15106-95-3

bis(thien-2-yl)zinc

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With dichloro{bis[1-(dicyclohexylphosphanyl)piperidine]}palladium(II) In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 100℃; for 3h; Negishi cross-coupling reaction; In air;96%
With catalyst 1 (aliphatic, phosphine based pincer complex of palladium) In 1,4-dioxane; 1-methyl-pyrrolidin-2-one at 100℃; for 1h; Negishi cross-coupling reaction;89%
2-chloro-5-phenylthiophene
35717-20-5

2-chloro-5-phenylthiophene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine; PdCl2(1,1′-bis(di-tertbutylphosphino)ferrocene) In tetrahydrofuran at 65℃; for 8h; Reagent/catalyst; Temperature; Time; Inert atmosphere;96%
With sodium tetrahydroborate; dichloro[1,1′-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P′]palladium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 65℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere;96%
C10H13S(1+)*F6Sb(1-)

C10H13S(1+)*F6Sb(1-)

sodium tetra(thiophen-2-yl)borate

sodium tetra(thiophen-2-yl)borate

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran at 80℃; for 1h; Schlenk technique;96%
tributyl(thien-2-yl)stannane
54663-78-4

tributyl(thien-2-yl)stannane

phenyl bromide/chloride

phenyl bromide/chloride

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 90℃; for 6h; Catalytic behavior; Stille Cross Coupling;96%
2-thienyl chloride
96-43-5

2-thienyl chloride

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With tBu2P-N=P(iBuPCH2CH2)3N; tetrabutyl ammonium fluoride; palladium diacetate at 80℃; for 1h; Hiyama coupling; Inert atmosphere; Neat (no solvent);95%
With sodium hydroxide; [[(t-Bu)2P(OH)(t-Bu)2PO]PdCl2] at 135℃; for 24h;44%
2-Iodothiophene
3437-95-4

2-Iodothiophene

benzene
71-43-2

benzene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With 9,9′-(ethane-1,2-diylbis(azanediyl))bis(1Hphenalen-1-one); potassium tert-butylate In neat (no solvent) at 130℃; for 12h; Reagent/catalyst; Temperature; Time; Sealed tube;95%
With potassium tert-butylate at 110℃; for 3h;89%
With potassium tert-butylate at 130℃; for 12h; Sealed tube;82%
bromobenzene
108-86-1

bromobenzene

C10H19AlOS

C10H19AlOS

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With palladium diacetate; tris-(o-tolyl)phosphine In toluene at 20℃; for 5h; Inert atmosphere;95%
2-hydroxymethyl-5-phenylthiophene
439108-60-8

2-hydroxymethyl-5-phenylthiophene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With potassium tert-butylate; oxygen In toluene at 80℃; for 14h;95%
2-Iodothiophene
3437-95-4

2-Iodothiophene

trimethyl(phenyl)stannane
934-56-5

trimethyl(phenyl)stannane

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With iodophenylbis(triphenylphosphine)palladium In N,N,N,N,N,N-hexamethylphosphoric triamide at 70℃; for 0.5h;94%
5-phenylthiophene-2-carboxaldehyde
19163-21-4

5-phenylthiophene-2-carboxaldehyde

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; air; triphenylphosphine In 1,4-dioxane for 48h; Heating;94%
With Pd-γ-Fe2O3 In cyclohexane at 130℃; for 24h; Inert atmosphere; Molecular sieve; Sealed tube;82%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate; methanol / 1 h / 20 °C
2: potassium tert-butylate; oxygen / toluene / 14 h / 80 °C
View Scheme
3-chloro-1-methyl-1H-indole
124589-41-9

3-chloro-1-methyl-1H-indole

phenylboronic acid
98-80-6

phenylboronic acid

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
Stage #1: 3-chloro-1-methyl-1H-indole; phenylboronic acid With palladium diacetate; (R)-6-dicyclohexylphoshino-6'-diphenylphosphino-3,3'-dimethoxy-2,2',4,4'-tetramethyl-1,1'-biphenyl In dodecane; butan-1-ol at 25℃; for 1h; Suzuki-Miyaura Coupling; Glovebox; Inert atmosphere;
Stage #2: With cesiumhydroxide monohydrate In dodecane; water; butan-1-ol at 25℃; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox;
94%
2-Bromo-5-phenyl-thiophene
29488-24-2

2-Bromo-5-phenyl-thiophene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine; palladium diacetate; triphenylphosphine In tetrahydrofuran at 20℃; for 2h; Reagent/catalyst; Time; Inert atmosphere;94%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; for 1h; Reagent/catalyst; Inert atmosphere;92%
With tetraethylammonium perchlorate; triethylamine In ethanol; dimethyl sulfoxide at 20℃; for 18h; Electrolysis; Green chemistry;90%
With Pd-γ-Fe2O3; potassium tert-butylate In isopropyl alcohol at 70℃; for 12h; Inert atmosphere; Sealed tube;84%
4-bromo-2-phenyl thiophene
38071-58-8

4-bromo-2-phenyl thiophene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine; palladium diacetate In tetrahydrofuran at 20℃; for 3h; Reagent/catalyst; Time; Inert atmosphere;94%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; Reagent/catalyst; Inert atmosphere;94%
2-Iodothiophene
3437-95-4

2-Iodothiophene

phenylacetylene
536-74-3

phenylacetylene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In N,N-dimethyl-formamide at 60℃; for 15h; Sonogashira Cross-Coupling; Inert atmosphere;94%
thiophene boronic acid
6165-68-0

thiophene boronic acid

4-iodophenylhydrazine
13116-27-3

4-iodophenylhydrazine

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
Stage #1: 4-iodophenylhydrazine With polystyrene-NHCO(CH2)4COOH; benzotriazol-1-ol; diisopropyl-carbodiimide In dichloromethane Solid phase reaction;
Stage #2: thiophene boronic acid With tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate In N,N-dimethyl-formamide at 90℃; for 24h; Suzuki coupling reaction;
Stage #3: With pyridine; copper diacetate In methanol at 20℃; for 2h; Oxidation;
93%
Stage #1: 4-iodophenylhydrazine With adipic acid-functionalized polystyrene; benzotriazol-1-ol; diisopropyl-carbodiimide; triethylamine In dichloromethane
Stage #2: thiophene boronic acid With potassium carbonate; tris-(dibenzylideneacetone)dipalladium(0) In N,N-dimethyl-formamide at 90℃; for 24h; Suzuki reaction;
Stage #3: With pyridine; copper diacetate In methanol at 20℃; for 2h; Further stages.;
2-thienyl chloride
96-43-5

2-thienyl chloride

tri(allyl)phenylsilane
2633-57-0

tri(allyl)phenylsilane

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
Stage #1: triallyl(phenyl)silane With tetrabutyl ammonium fluoride In tetrahydrofuran; water at 20℃; for 1h;
Stage #2: 2-thienyl chloride With XPhos; bis(η3-allyl-μ-chloropalladium(II)) In tetrahydrofuran; water at 80℃; for 12h;
93%
[2-(hydroxymethyl)phenyl](dimethyl)phenylsilane
853955-69-8

[2-(hydroxymethyl)phenyl](dimethyl)phenylsilane

2-Iodothiophene
3437-95-4

2-Iodothiophene

2-phenylthiophene
825-55-8

2-phenylthiophene

Conditions
ConditionsYield
With N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; potassium carbonate; palladium dichloride In water; dimethyl sulfoxide at 50℃; for 13h;93%
With potassium carbonate; N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; palladium dichloride In water; dimethyl sulfoxide at 50℃; for 13h;93%
2-phenylthiophene
825-55-8

2-phenylthiophene

2-Bromo-5-phenyl-thiophene
29488-24-2

2-Bromo-5-phenyl-thiophene

Conditions
ConditionsYield
With N-Bromosuccinimide In chloroform at 20℃; for 0.5h;100%
With N-Bromosuccinimide95%
With bromine; sodium acetate In acetic acid at 20℃;83%
2-phenylthiophene
825-55-8

2-phenylthiophene

C10H6(2)H2S

C10H6(2)H2S

Conditions
ConditionsYield
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; deuterium In tetrahydrofuran at 55℃; under 750.075 Torr; for 22h; Inert atmosphere;100%
2-phenylthiophene
825-55-8

2-phenylthiophene

2-deuterio-5-phenylthiophene
35309-06-9

2-deuterio-5-phenylthiophene

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water-d2 In tetrahydrofuran; toluene at 90℃; for 2h; Microwave irradiation;98%
Stage #1: 2-phenylthiophene With tert.-butyl lithium In diethyl ether; pentane at -78 - 0℃;
Stage #2: With d(4)-methanol In diethyl ether; pentane at -78 - 20℃;
90%
With deuteromethanol; silver carbonate; johnphos at 50 - 80℃;85%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

2-phenylthiophene
825-55-8

2-phenylthiophene

2-phenyl-5-(4-vinylphenyl)thiophene

2-phenyl-5-(4-vinylphenyl)thiophene

Conditions
ConditionsYield
With NHC-Pd(II)-Im; potassium tert-butylate; copper(II) oxide In tetrahydrofuran at 130℃; for 3h; Inert atmosphere; Sealed tube;98%
2-phenylthiophene
825-55-8

2-phenylthiophene

methyl iodide
74-88-4

methyl iodide

2-methyl-5-phenylthiophene
5069-26-1

2-methyl-5-phenylthiophene

Conditions
ConditionsYield
Stage #1: 2-phenylthiophene With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 3h;
Stage #2: methyl iodide In tetrahydrofuran; hexane at 0 - 20℃; Further stages.;
97%
Stage #1: 2-phenylthiophene With n-butyllithium In tetrahydrofuran at -15℃; for 2h;
Stage #2: methyl iodide In tetrahydrofuran Further stages.;
86%
2-phenylthiophene
825-55-8

2-phenylthiophene

glyoxylic acid ethyl ester
924-44-7

glyoxylic acid ethyl ester

ethyl (R)-(5-phenylthiophen-2-yl)hydroxyacetate
1273326-28-5

ethyl (R)-(5-phenylthiophen-2-yl)hydroxyacetate

Conditions
ConditionsYield
Stage #1: glyoxylic acid ethyl ester With titanium(IV) isopropylate; (S)-6,6'-dibromo-1,1'-bi-2-naphthol In toluene at -40℃; for 0.166667h; Friedel Crafts alkylation;
Stage #2: 2-phenylthiophene In toluene at 0℃; for 7h; Friedel Crafts alkylation; optical yield given as %ee; enantioselective reaction;
96%
2-phenylthiophene
825-55-8

2-phenylthiophene

tributyltin chloride
1461-22-9

tributyltin chloride

tri-n-butyl(5-phenylthiophen-2-yl)stannane
137937-89-4

tri-n-butyl(5-phenylthiophen-2-yl)stannane

Conditions
ConditionsYield
Stage #1: 2-phenylthiophene With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: tributyltin chloride In tetrahydrofuran at -78 - 20℃;
96%
Stage #1: 2-phenylthiophene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at 30℃; for 1h; Inert atmosphere;
Stage #2: tributyltin chloride In tetrahydrofuran; hexane at 20℃; for 20h; Cooling with ice;
Stage #1: 2-phenylthiophene With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 1.5h; Inert atmosphere;
Stage #2: tributyltin chloride In tetrahydrofuran at -78 - 20℃; for 13h; Inert atmosphere;

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