With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin
As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph
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Cas:917-57-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryVINYL LITHIUM CAS:917-57-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates
Cas:917-57-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
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Cas:917-57-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:917-57-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryJ&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals
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Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
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factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl
Cas:917-57-7
Min.Order:1 Gram
FOB Price: $1.0
Type:Trading Company
inquiryLithium, ethenyl- (9CI)Appearance:Off white to slight yellow solid Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediates Transportation:By Sea,by Air,By courie
Supply top quality products with a reasonable price Application:api
Conditions | Yield |
---|---|
With n-butyllithium In pentane for 2.5h; Inert atmosphere; Glovebox; | 87% |
With n-butyllithium In hexane at 21℃; for 2h; | 84% |
With phenyllithium |
Conditions | Yield |
---|---|
With lithium; zinc(II) chloride; 2,5-Diphenyl-6a-thiathiophthen In tetrahydrofuran at 0℃; under 750.06 Torr; for 6h; Product distribution; | A 75% B n/a |
With lithium; 2,5-Diphenyl-6a-thiathiophthen; zinc(II) chloride In tetrahydrofuran at 0℃; under 750.06 Torr; for 6h; Yields of byproduct given; | A 75% B n/a |
Conditions | Yield |
---|---|
With lithium | |
With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 2h; |
Conditions | Yield |
---|---|
With lithium |
Conditions | Yield |
---|---|
With diethyl ether | |
Ambient temperature; |
1,1-Dilithioethan
vinyllithium
Conditions | Yield |
---|---|
With chloro-trimethyl-silane In tetrahydrofuran for 8h; Ambient temperature; Yield given; |
1,2-dilithioethane
vinyllithium
1,2-dilithioethane
A
vinyllithium
B
1,4-dilithiobutane
C
hexanediyl dilithium
Conditions | Yield |
---|---|
With lithium at -196℃; under 0.005 Torr; Mechanism; |
cis-1,2-Dilithioethylen
A
vinyllithium
B
dilithium acetylide
Conditions | Yield |
---|---|
Title compound not separated from byproducts; |
trans-1,2-Dilithioethylen
A
vinyllithium
B
dilithium acetylide
Conditions | Yield |
---|---|
Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With dilithiumethylene Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
In tetrahydrofuran; hexane at 0℃; for 0.5h; | |
In tetrahydrofuran; hexane at -78 - 20℃; for 1.08333h; | |
In pentane Inert atmosphere; | |
In hexane at 20℃; for 1h; |
Conditions | Yield |
---|---|
In diethyl ether at 0℃; for 0.5h; Inert atmosphere; |
Conditions | Yield |
---|---|
With n-butyllithium In pentane at -78℃; Inert atmosphere; |
Conditions | Yield |
---|---|
In tetrahydrofuran -78 deg C to room temp.; | 100% |
vinyllithium
2-methyl-6-methylenetricyclo<3.3.1.02,7>nonan-8-one
8-ethenyl-2-methyl-6-methylenetricyclo<3.3.1.02,7>nonan-8-ol
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 1.5h; | 100% |
vinyllithium
(4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone
Conditions | Yield |
---|---|
Stage #1: vinyllithium With copper(l) cyanide In diethyl ether at -78 - 0℃; Stage #2: (4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone In diethyl ether at -78℃; for 0.25h; Stage #3: With ammonium chloride In water | 100% |
dichloro(η(5)-1-[2-(N,N-dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentandienyl)(η(5)-pentamethylcyclopentadienyl)titanium
vinyllithium
(η(5)-1-[2-(N,N-dimethylamino)ethyl]-2,3,4,5-tetramethylcyclopentandienyl)(η(5)-pentamethylcyclopentadienyl)(2-methylidene)titanacyclobutane
Conditions | Yield |
---|---|
In tetrahydrofuran N2-atmosphere; -78°C to room temp.; evapn., extg. (hexane), filtering, evapn.; | 100% |
(2RS,4SR,5RS)-2,5-diphenyl-3,4-dimethyl-1,3,2-oxazaphospholidine-2-borane
vinyllithium
(RSp)-(N-methyl[(1RS,2SR)-(1-hydroxy-1-phenylprop-2-yl)]amino)phenyl-(vinyl)phosphine borane
Conditions | Yield |
---|---|
In tetrahydrofuran (Ar); soln. of Li compd. in THF was added dropwise to soln. of B-P compd. in THF at -78°C; mixt. was stirred at -78°C for 30 min; warmed to room temp.; H2O added; THF removed (vac.); extd. (CH2Cl2); dried (MgSO4); solvent evapd; chromd. (silica gel, toluene/EtOAc, 9/1); | 100% |
vinyllithium
(E)-4-methoxy-N-(naphthalene-1-ylmethylene)phenylamine
(4-Methoxy-phenyl)-(1-naphthalen-1-yl-allyl)-amine
Conditions | Yield |
---|---|
1-(2-methoxyphenoxy)-N,N-dimethyl-3-phenylpropan-2-amine In toluene at -42℃; | 99% |
vinyllithium
5-Methyl-5-(phenylthio)-2-hexanone
Conditions | Yield |
---|---|
In diethyl ether at -78 - -20℃; for 2.5h; | 98% |
vinyllithium
(1aR,3S,3aR,3bS,5aR,6S,8aR,8bR,10R,10aR)-6-((S)-1-Hydroxy-1-methyl-allyl)-10-methoxy-3,8a-bis-methoxymethoxy-3a,5a-dimethyl-hexadecahydro-cyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-ol
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 1h; | 97% |
vinyllithium
6-Methyl-6-(2-trimethylsilanylmethyl-allyl)-cyclohex-2-enone
(1S,6R)-6-Methyl-6-(2-trimethylsilanylmethyl-allyl)-1-vinyl-cyclohex-2-enol
Conditions | Yield |
---|---|
97% |
vinyllithium
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 0.25h; | 97% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 0.5h; | 97% |
vinyllithium
[4-(benzylideneamino)phenyl]methanol
N-(p-methoxyphenyl)-α-ethenylbenzenemethaneamine
Conditions | Yield |
---|---|
1-(2-methoxyphenoxy)-N,N-dimethyl-3-phenylpropan-2-amine In toluene at -42℃; | 96% |
vinyllithium
4-(t-butyldimethylsilyloxy)-3-methoxycyclopent-2-enone
5-(tert-Butyl-dimethyl-silanyloxy)-3-vinyl-cyclopent-2-enone
Conditions | Yield |
---|---|
In diethyl ether at -78 - -20℃; for 1h; | 96% |
vinyllithium
Acetic acid (1R,2R,4S,5R,6S,8S)-5-benzyloxy-8-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-11-methylene-10-oxo-12-oxa-tricyclo[6.3.1.01,6]dodec-4-yl ester
Acetic acid (1R,2R,4S,5R,6S,8S,11S)-11-allyl-5-benzyloxy-8-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-10-oxo-12-oxa-tricyclo[6.3.1.01,6]dodec-4-yl ester
Conditions | Yield |
---|---|
With CuCN In diethyl ether at -60℃; Addition; | 96% |
vinyllithium
6-methyl-6-(phenylthio)hept-1-en-3-ol
Conditions | Yield |
---|---|
In diethyl ether at -78 - -20℃; for 2.5h; | 96% |
vinyllithium
dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate
dimethyl (2R,3S,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-3-vinyl-piperidine-1,2-dicarboxylate
Conditions | Yield |
---|---|
Stage #1: vinyllithium With copper(l) iodide In diethyl ether at -78 - -35℃; for 0.333333h; Stage #2: dimethyl (S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5,6-dihydro-4H-pyridine-1,2-dicarboxylate In diethyl ether at -78 - -30℃; for 1h; Michael addition; Further stages.; | 96% |
2-Benzenesulfonyl-6-benzyloxy-6-methyl-7-oxa-bicyclo[2.2.1]hept-2-ene
vinyllithium
(1R,2R,5R)-3-Benzenesulfonyl-5-benzyloxy-5-methyl-2-vinyl-cyclohex-3-enol
Conditions | Yield |
---|---|
In toluene at -78℃; | 95% |
vinyllithium
2(R)-(Z)-propenyl-(3,5-dideoxy-1,2-O-isopropylidene-α-D-ribo-furano)<3,4-c>cyclohexanone
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 20℃; | 95% |
vinyllithium
Conditions | Yield |
---|---|
In toluene at -78℃; for 0.25h; | 95% |
vinyllithium
dimethyl (5R,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5-ethyl-5,6-dihydro-4H-pyridine-1,2-dicarboxylate
dimethyl (2R,3S,5R,6S)-(+)-6-(tert-butyldiphenylsilyloxymethyl)-5-ethyl-3-vinylpiperidine-1,2-dicarboxylate
Conditions | Yield |
---|---|
Stage #1: vinyllithium With copper(l) iodide In diethyl ether at -78 - -35℃; for 0.333333h; Stage #2: dimethyl (5R,6S)-(-)-6-(tert-butyldiphenylsilyloxymethyl)-5-ethyl-5,6-dihydro-4H-pyridine-1,2-dicarboxylate In diethyl ether at -78 - -20℃; for 1h; Michael addition; Further stages.; | 95% |
iron(II)(carbonyl)2(trimethylphosphine)2Br2
vinyllithium
cis,trans-Fe(CO)2(PMe3)2(CH=CH2)Br
Conditions | Yield |
---|---|
In diethyl ether under N2 atm. to soln. cis,trans,cis-Fe(CO)2(PMe3)2Br2 in Et2O soln. CH2=CHLi in Et2O was added dropwise, 10 min; soln. was washed with water, Et2O phase was dried over MgSO4, crystn. from n-hexane at -20°C; | 95% |
vinyllithium
3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone
3-ethenyl-4,4-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone
Conditions | Yield |
---|---|
Acidic aq. solution; | 95% |
Stage #1: vinyllithium; 3-methoxy-6,6-dimethyl-2-[4-(1-methylethyl)-2,3,5-trimethoxyphenylmethyl]-2-cyclohexenone Inert atmosphere; Stage #2: Inert atmosphere; Acidic conditions; | 95% |
Conditions | Yield |
---|---|
In tetrahydrofuran at -55℃; | 94% |
vinyllithium
N-phenyl-N'-((trimethylsilyl)methyl)carbodiimide
N-Phenyl-N'-trimethylsilanylmethyl-acrylamidine
Conditions | Yield |
---|---|
In tetrahydrofuran for 1h; | 94% |
vinyllithium
6,7-dihydrocyclopenta[d][1,3]dioxin-5(4H)-one
2-(hydroxymethyl)-3-vinyl-2-cyclopentenone
Conditions | Yield |
---|---|
In tetrahydrofuran at -78℃; for 0.25h; | 94% |
vinyllithium
2-[(benzyloxy)methyl]cyclohex-2-en-1-one
2-Benzyloxymethyl-1-vinyl-cyclohex-2-enol
Conditions | Yield |
---|---|
With n-butyllithium In tetrahydrofuran at -78℃; for 0.166667h; | 94% |
vinyllithium
1-<4'-(S)-tert-butyloxazolin-2'-yl>naphthalene
methyl iodide
(S)-4-tert-Butyl-2-((1S,2S)-1-methyl-2-vinyl-1,2-dihydro-naphthalen-1-yl)-4,5-dihydro-oxazole
Conditions | Yield |
---|---|
at 0℃; for 36h; | 94% |
Product distribution; Mechanism; various times and temperatures; other organolithium compounds; |
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 0℃; for 0.5h; | 94% |
In tetrahydrofuran Ring cleavage; substitution; | 94% |
vinyllithium
3-methyl-3-(phenylthio)butanal
5-methyl-5-(phenylthio)hex-1-en-3-ol
Conditions | Yield |
---|---|
In diethyl ether at -78 - -20℃; for 2.5h; | 94% |
vinyllithium
6-methyl-5-(phenylthio)hept-5-en-2-one
3,7-dimethyl-6-(phenylthio)octa-1,6-dien-3-ol
Conditions | Yield |
---|---|
In diethyl ether at -78 - -20℃; for 2.5h; | 94% |
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