1,1,1,2-Tetrachloroethane supplier

Name
1,1,1,2-Tetrach loroethane
EINECS 211-135-1
CAS No. 630-20-6
Article Data50
CAS DataBase
Density 1.566 g/cm³
Solubility
Melting Point -70.2 °C
Formula C₂H₂Cl₄
Boiling Point 132.4 °C at 760 mmHg
Molecular Weight 167.85
Flash Point 35.5 °C
Transport Information UN 2810
Appearance colourless liquid
Safety 26-36-45-24-16-7-39
Risk Codes 22-40-41-23/25-11-20/22
Molecular Structure
Hazard Symbols Xn,T,F
Synonyms (Chloromethyl)trichloromethane;1,1,1,2-Tetrachloroethane;F 130a;HCC 130a;
PSA 0.00000
LogP 2.59540

Synthetic route

: 17341-93-4
2,2,2-Trichloroethyl chloroformate

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 5634-37-7
bis(2,2,2-trichloroethyl) carbonate

Conditions

Conditions	Yield
With hexabutylguanidinium chloride at 100℃; for 168h;	A 1% B 99%

: 71-55-6
1,1,1-trichloroethane

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 75-35-4
1,1-Dichloroethylene

C: 76-01-7
pentachloroethane

Conditions

Conditions	Yield
With chlorine at 25℃; Irradiation;	A 92.5% B 2.4% C 5.1%
With chlorine at 25℃; Irradiation;	A 89.9% B 4.7% C 5.3%

...Expand

: 71-55-6
1,1,1-trichloroethane

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 75-35-4
1,1-Dichloroethylene

Conditions

Conditions	Yield
With chlorine at 200℃; Mechanism; Irradiation; other temperature; other laser; other Cl2 flow rate; other ratio educt/Cl2;	A 61.3% B 25.9%
With chlorine at 200℃; Irradiation;	A 61.3% B 25.9%

: 60-29-7
diethyl ether

: 67-72-1
hexachloroethane

: 925-90-6
ethylmagnesium bromide

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 630-20-6
1,1,1,2-tetrachoroethane

C: 76-01-7
pentachloroethane

D: 79-34-5
1,1,2,2-tetrachloroethane

...Expand

: 60-29-7
diethyl ether

: 67-72-1
hexachloroethane

: phenylmagnesium bromide

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 630-20-6
1,1,1,2-tetrachoroethane

C: 76-01-7
pentachloroethane

D: 79-34-5
1,1,2,2-tetrachloroethane

...Expand

: 75-00-3
chloroethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
durch Chlorierung;

: 71-55-6
1,1,1-trichloroethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
durch Chlorierung im Sonnenlicht;

: 71-55-6
1,1,1-trichloroethane

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 76-01-7
pentachloroethane

C: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
Chlorierung im Sonnenlicht;

...Expand

: 75-35-4
1,1-Dichloroethylene

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With chlorine at 25 - 40℃;
With chlorine; iron at 20 - 30℃;
With nitrosylchloride at 25℃;
With chlorine; iron(III) chloride

: 75-35-4
1,1-Dichloroethylene

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 6061-04-7
1,1-dichloro-2-nitro ethylene

Conditions

Conditions	Yield
With nitrosylchloride at 25℃;

: 505-60-2
bis (2-chloroethyl) sulphide

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With chlorine at 25℃; und Zersetzen des Reaktionsprodukts in der Waerme unter vermindertem Druck;

: 57678-85-0
1,1-diiodo-ethene

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With tetrachloromethane; chlorine im Sonnenlicht;

: 79-01-6
Trichloroethylene

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With hydrogenchloride; aluminium trichloride
With hydrogenchloride; iron(III) chloride
With hydrogenchloride; aluminium trichloride at 30 - 40℃;
With pumice stone at 700℃;
With hydrogenchloride; chromium(III) oxide In gas at 249.9℃; Product distribution; Thermodynamic data; various temp.; ΔRH0; ΔRG0;

: 79-01-6
Trichloroethylene

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 21400-41-9
1,1,2,4,4-pentachloro-1,3-butadiene

C: 630-20-6
1,1,1,2-tetrachoroethane

D: 79-34-5
1,1,2,2-tetrachloroethane

Conditions

Conditions	Yield
at 200 - 250℃; under 934095 Torr; Produkt5:Pentachloraethan.Pyrolysis;

...Expand

: trichloroethoxycarbonyl chloride

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With aluminium trichloride

: 107-06-2
1,2-dichloro-ethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
durch Chlorieren;

: 60-29-7
diethyl ether

: 67-72-1
hexachloroethane

: 4294-57-9
para-methylphenylmagnesium bromide

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 630-20-6
1,1,1,2-tetrachoroethane

C: 76-01-7
pentachloroethane

D: 79-34-5
1,1,2,2-tetrachloroethane

...Expand

: 60-29-7
diethyl ether

: 67-72-1
hexachloroethane

: 703-55-9
1-naphthylmagnesiumbromide

A: 127-18-4
1,1,2,2-tetrachloroethylene

B: 630-20-6
1,1,1,2-tetrachoroethane

C: 76-01-7
pentachloroethane

D: 79-34-5
1,1,2,2-tetrachloroethane

...Expand

: 74-86-2
acetylene

A: 156-60-5
trans-1,2-dichloroethylene

B: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With chlorine; pyrographite at 40℃;
With chlorine; copper dichloride at 200 - 240℃;

: 79-34-5
1,1,2,2-tetrachloroethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With aluminium trichloride at 110℃;
With water; calcium chloride

: 79-00-5
1,1,2-trichloroethane

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 2431-52-9
1,2,2,3,4-pentachlorobutane

Conditions

Conditions	Yield
With chlorine Mechanism; Irradiation; var. temperature, concns. of Cl2, O2, laser fluence;

: 79-00-5
1,1,2-trichloroethane

A: 630-20-6
1,1,1,2-tetrachoroethane

B: 79-34-5
1,1,2,2-tetrachloroethane

Conditions

Conditions	Yield
With chlorine; 1,2-dichloro-benzene at 20℃; Product distribution; Kinetics; Mechanism; Irradiation; presence of CCl4;
With chlorine In 1,2-dichloro-benzene at -20 - 80℃; Product distribution; Mechanism; Ratio of products and rate constants; different concentrations of o-dichlorobenzene;

: 1649-08-7
1,2-dichloro-1,1-difluoroethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With hydrogenchloride; chromium(III) oxide In gas at 249.9℃; Thermodynamic data; various temp.; ΔRH0; ΔRG0;

: 7446-70-0
aluminium trichloride

: 79-34-5
1,1,2,2-tetrachloroethane

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
at 110℃;

: 7647-01-0
hydrogenchloride

: 7446-70-0
aluminium trichloride

: 79-01-6
Trichloroethylene

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
at 30 - 40℃;

...Expand

: 590-27-2
(E)-1,2-diiodoethene

: 7782-50-5
chlorine

: 630-20-6
1,1,1,2-tetrachoroethane

: 7647-01-0
hydrogenchloride

: 79-01-6
Trichloroethylene

: 7705-08-0
iron(III) chloride

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
im Dunkeln;

...Expand

CH2ClCHCl2: CH2ClCHCl2

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
durch Chlorieren;

tris-<2,2,2-trichloro-ethyl>-phosphite: tris-<2,2,2-trichloro-ethyl>-phosphite

: 630-20-6
1,1,1,2-tetrachoroethane

Conditions

Conditions	Yield
With diethyl ether; chlorine at 150℃;

: 630-20-6
1,1,1,2-tetrachoroethane

: 1067-87-4
Diethyl allylphosphonate

: (2,4,4,5-Tetrachloro-pentyl)-phosphonic acid diethyl ester

Conditions

Conditions	Yield
With 2-hydroxy-2-phenylacetophenone; iron(III) chloride In acetonitrile at 130℃;	25%

: 186581-53-3, 908094-01-9
diazomethane

: 630-20-6
1,1,1,2-tetrachoroethane

: 27865-58-3
6-acetyl-2,3-diacetoxyphenol

A: 1-(3,4-diacetoxy-2-methoxy-phenyl)-ethanone

B: 860741-89-5
1-(2,4-diacetoxy-3-methoxy-phenyl)-ethanone

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 630-20-6
1,1,1,2-tetrachoroethane

: 93395-14-3
3-acetoxy-1-hydroxy-anthraquinone

: 75299-66-0
1-methoxy-3-acetoxyanthraquinone

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 630-20-6
1,1,1,2-tetrachoroethane

: 75697-69-7
1-hydroxy-9,10-dioxo-9,10-dihydroanthracen-2-yl benzoate

A: 2-benzoyloxy-1-methoxy-anthraquinone

B: 96087-89-7
1-benzoyloxy-2-methoxy-anthraquinone

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 630-20-6
1,1,1,2-tetrachoroethane

: 2-benzoyloxy-1,7-dihydroxy-anthraquinone

A: 2-benzoyloxy-1,7-dimethoxy-anthraquinone

B: 1-benzoyloxy-2,7-dimethoxy-anthraquinone

...Expand

: 85-44-9
phthalic anhydride

: 630-20-6
1,1,1,2-tetrachoroethane

: (3,7-dimethyl-[1]naphthyl)-methyl ether

: 860595-98-8
2-(4-methoxy-2,6-dimethyl-[1]naphthoyl)-benzoic acid

Conditions

Conditions	Yield
at -15℃; sowie bei 20grad;

...Expand

: 85-44-9
phthalic anhydride

: 630-20-6
1,1,1,2-tetrachoroethane

: 541-73-1
1,3-Dichlorobenzene

: 3,3-bis-(2,4-dichloro-phenyl)-phthalide

...Expand

: 60-29-7
diethyl ether

: 630-20-6
1,1,1,2-tetrachoroethane

: 75-00-3
chloroethane

Conditions

Conditions	Yield
at 250 - 290℃; in Gegenwart von Aluminiumoxyd oder -phosphat enthaltenden Katalysatoren unter Druck;

: 812-01-1
methyl chlorosulfate

: 630-20-6
1,1,1,2-tetrachoroethane

: 3651-62-5
3-hydroxy-N-(4-methylphenyl)naphthalene-2-carboxamide

: 2-hydroxy-3-p-tolylcarbamoyl-naphthalene-1-sulfonic acid

Conditions

Conditions	Yield
at 100 - 110℃; beim nachfolgenden Erwaermen mit verd. Sodaloesung;

...Expand

: 64-17-5
ethanol

: 630-20-6
1,1,1,2-tetrachoroethane

: 75-00-3
chloroethane

Conditions

Conditions	Yield
in Gegenwart von Katalysatoren bei erhoehter Temperatur;

: 630-20-6
1,1,1,2-tetrachoroethane

: 52755-65-4
5,11-naphthacenequinone

: 858456-17-4
6,12-dichloro-6,12-dihydro-naphthacene-5,11-dione

Conditions

Conditions	Yield
Einleiten von Chlor;

: 630-20-6
1,1,1,2-tetrachoroethane

: 218-01-9
chrysene

: 408311-76-2
2-(chrysene-6-carbonyl)-benzoic acid

Conditions

Conditions	Yield
at 20 - 75℃;
at 20 - 75℃;

: 630-20-6
1,1,1,2-tetrachoroethane

: 18271-17-5
N-tosyl-1-naphthylamine

: 858005-74-0
N-(2,4-dichloro-[1]naphthyl)-toluene-4-sulfonamide

Conditions

Conditions	Yield
at 50℃; beim Chlorieren;
at 50℃; beim Chlorieren;

: 630-20-6
1,1,1,2-tetrachoroethane

: 4,6-dichloro-2-methyl-6-nitro-1-nitryloxy-cyclohexa-2,4-dienol

: 3-chloro-6-hydroxy-5-methyl-6-nitryloxy-cyclohexa-2,4-dienone

: 630-20-6
1,1,1,2-tetrachoroethane

: 861560-61-4
chloro-nitro-phenyl-acetic acid amide

: 7598-13-2
dichloro-phenyl-acetic acid amide

Conditions

Conditions	Yield
at 140℃;

: 630-20-6
1,1,1,2-tetrachoroethane

: 303755-60-4
N-[1]naphthyl-naphthalene-2-sulfonamide

: N-(4-chloro-[1]naphthyl)-naphthalene-2-sulfonamide

Conditions

Conditions	Yield
at 50℃; beim Chlorieren;

: 630-20-6
1,1,1,2-tetrachoroethane

: 858005-76-2
N-(4-chloro-[1]naphthyl)-toluene-4-sulfonamide

: 858005-74-0
N-(2,4-dichloro-[1]naphthyl)-toluene-4-sulfonamide

Conditions

Conditions	Yield
at 50℃; beim Chlorieren;
at 50℃; beim Chlorieren;

: 630-20-6
1,1,1,2-tetrachoroethane

: 108981-71-1
2-methyl-5-nitro-benzenesulfonic acid-[1]naphthylamide

: 858005-86-4
2-methyl-5-nitro-benzenesulfonic acid-(4-chloro-[1]naphthylamide)

Conditions

Conditions	Yield
at 50℃; beim Chlorieren;

: 630-20-6
1,1,1,2-tetrachoroethane

: 4,5,6-trichloro-2-methyl-6-nitro-1-nitryloxy-cyclohexa-2,4-dienol

: 2,3-dichloro-6-hydroxy-5-methyl-6-nitryloxy-cyclohexa-2,4-dienone

: 630-20-6
1,1,1,2-tetrachoroethane

: 4,5,6-tribromo-2-methyl-6-nitro-1-nitryloxy-cyclohexa-2,4-dienol

: 2,3-dibromo-6-hydroxy-5-methyl-6-nitryloxy-cyclohexa-2,4-dienone

: 630-20-6
1,1,1,2-tetrachoroethane

: 4,5-dichloro-2-methyl-6,6-dinitro-1-nitryloxy-cyclohexa-2,4-dienol

: 2,3-dichloro-6-hydroxy-5-methyl-6-nitryloxy-cyclohexa-2,4-dienone

: 630-20-6
1,1,1,2-tetrachoroethane

: 141-52-6
sodium ethanolate

: 42345-82-4
(E)-1,2-dichloro-1-ethoxy-ethene

1,1,1,2-Tetrachloroethane Consensus Reports

IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 41 ,1986,p. 87.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NTP Carcinogenesis Bioassay (gavage); Clear Evidence: mouse NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-237 ,1982. ; (gavage); No Evidence: rat NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-237 ,1982. . Reported in EPA TSCA Inventory.

1,1,1,2-Tetrachloroethane Standards and Recommendations

NIOSH REL: (1,1,1,2-Tetrachloroethane) Handle with caution

1,1,1,2-Tetrachloroethane Specification

The product name and IUPAC name of this chemical are the same which is called as 1,1,1,2-Tetrachloroethane. Its CAS registry number is 630-20-6. This chemical is also known as Ethane, 1,1,1,2-tetrachloro- which is a chlorinated hydrocarbon with the formula C₂H₂Cl₄. It belongs to the product categories of Refrigerants; Organics; Analytical Chemistry; Standard Solution of Volatile Organic Compounds for Water & Soil Analysis; Standard Solutions (VOC); T-Z; Volatiles/ Semivolatiles; Fumigants Volatiles/ Semivolatiles; Alpha Sort; Chemical Class; Chloro Pesticides; Halogenated; Insecticides; TA - TE; T-ZAlphabetic; Alphabetic. Its EINECS registry number is 211-135-1. It is used as a solvent and in the production of wood stains and varnishes.

Physical properties of 1,1,1,2-Tetrachloroethane: (1)ACD/LogP: 2.48; (2)ACD/LogD (pH 5.5): 2.48; (3)ACD/LogD (pH 7.4): 2.48; (4)ACD/BCF (pH 5.5): 45.08; (5)ACD/BCF (pH 7.4): 45.08; (6)ACD/KOC (pH 5.5): 531.53; (7)ACD/KOC (pH 7.4): 531.53; (8)Index of Refraction: 1.484; (9)Molar Refractivity: 30.67 cm³; (10)Molar Volume: 107.1 cm³; (11)Surface Tension: 34.9 dyne/cm; (12)Density: 1.566 g/cm³; (13)Flash Point: 35.5 °C; (14)Enthalpy of Vaporization: 35.47 kJ/mol; (15)Boiling Point: 132.4 °C at 760 mmHg; (16)Vapour Pressure: 10.9 mmHg at 25°C.

Preparation of 1,1,1,2-Tetrachloroethane: this chemical can be prepared by 1,1,1-trichloro-ethane. This reaction will need reagent Cl₂. The reaction temperature is 200 °C. The yield is about 61.3%.

1,1,1,2-Tetrachloroethane can be prepared by 1,1,1-trichloro-ethane

When you are using this chemical, please be cautious about it as the following:
This chemical may cause damage to health. It is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing. Finally, you must avoid contacting it with skin and eyes.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C(C(Cl)(Cl)Cl)Cl
(2)InChI: InChI=1S/C2H2Cl4/c3-1-2(4,5)6/h1H2
(3)InChIKey: QVLAWKAXOMEXPM-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	1275mg/kg (1275mg/kg)		Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 8, Pg. 371, 1966.
mouse	LD50	oral	1500mg/kg (1500mg/kg)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 35, Pg. 593, 1974.
rabbit	LC50	inhalation	2800ppm/4H (2800ppm)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 35, Pg. 593, 1974.
rabbit	LD50	skin	20gm/kg (20000mg/kg)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 35, Pg. 593, 1974.
rat	LC50	inhalation	2100ppm/4H (2100ppm)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 35, Pg. 593, 1974.
rat	LD50	oral	670mg/kg (670mg/kg)		Archives des Maladies Professionnelles de Medecine du Travail et de Securite Sociale. Vol. 35, Pg. 593, 1974.

Product Name

1,1,1,2-Tetrach loroethane

Synthetic route

1,1,1,2-Tetrachloroethane Consensus Reports

1,1,1,2-Tetrachloroethane Standards and Recommendations

1,1,1,2-Tetrachloroethane Specification

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