1,5-Diazocine, octahydro supplier | CasNO.5687-07-0

Product Name

Name
1,5-DIAZACYCLOOCTANE
EINECS
CAS No. 5687-07-0
Article Data15
CAS DataBase
Density 0.852
Solubility
Melting Point
Formula C6H14 N2
Boiling Point 194ºC
Molecular Weight 114.191
Flash Point 84ºC
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms (1,5)Diazocane;1,5-Diazacyclooctane; Octahydro-1,5-diazocine
PSA 24.06000
LogP 0.61700

Synthetic route

: 40422-46-6
1,5-diazabicyclooctane dihydrobromide

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
With sodium methylate In methanol at 70℃; for 0.166667h;	98%

: 67761-04-0
1,5-bis(p-toluenesulphonyl)-1,5-diazacyclooctane

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
With hydrogen bromide; phenol at 80℃; for 60h;	86%

: 503-29-7
azetidine

: 50-00-0
formaldehyd

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
at 120℃; im Rohr;

: 5397-67-1
1,5-diazabicyclo[3.3.0]octane

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
With water; nickel Hydrogenation;
With diisobutylaluminum hydride

: 35513-93-0
N1-(cyanoethyl)-1,3-propanediamine

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
With sodium; butan-1-ol

: 1,5-diazoniatricyclo<3.3.3.0>undecane bistetrafluoroborate

A: 5687-07-0
1,5-diazacyclooctane

B: 281-17-4
1,5-diazabicyclo<3.3.1>nonane

Conditions

Conditions	Yield
With tetrafluoroboric acid for 0.5h; Product distribution; Heating; t1/2; further reagent:NaOH/D2O;

N.N'-di-p-toluenesulfonyl-: N.N'-di-p-toluenesulfonyl-

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
With hydrogenchloride at 180℃;

: 64-17-5
ethanol

: 142-28-9
1,3-Dichloropropane

: 302-01-2
hydrazine

A: 504-70-1
pyrazolidine

B: 5687-07-0
1,5-diazacyclooctane

C 1.2-trimethylene-pyrazolidine: 1.2-trimethylene-pyrazolidine

: 75321-10-7
3-propyl tosylate

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) sodium hydride / 1.) DMF, 80 deg C, 2.5 h, 2.) DMF, 80 deg C, 24 h 2: 86 percent / phenol, 33percent HBr in acetic acid / 60 h / 80 °C View Scheme

: 56187-12-3
N-tosyl-bis(3-hydroxypropyl)amine

: 5687-07-0
1,5-diazacyclooctane

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 65 percent / triethylamine, 4-dimethylaminopyridine (DMAP) / CH2Cl2 / 2 h / Ambient temperature 2: 1.) sodium hydride / 1.) DMF, 80 deg C, 2.5 h, 2.) DMF, 80 deg C, 24 h 3: 86 percent / phenol, 33percent HBr in acetic acid / 60 h / 80 °C View Scheme

: 46755-00-4, 46755-01-5
{Cu(1,5-diazocane)2}(2+)

A: 5687-07-0
1,5-diazacyclooctane

B: copper(II) ion

Conditions

Conditions	Yield
In hydrogenchloride Kinetics; hydrolysis reaction in HCl/NaCl solns.; depending on H(1+) concn.; spectrophotometry (abs. max. at 595 nm);

: 46755-00-4, 46755-01-5
{Cu(1,5-diazocane)2}(2+)

A: 5687-07-0
1,5-diazacyclooctane

B: copper(II)(1,5-diazacyclooctane)(2+)

Conditions

Conditions	Yield
With acetate buffer In water Kinetics; dissociation of Cu(daco)2(2+)in the presence of acetate buffer, at 20°C, pH = 4.24 - 5.05; monitored by stopped flow spectrophotometry;
With 4-morpholineethanesulfonic acid In water Kinetics; acid dissociation of Cu(daco)2(2+) with 2-(N-morpholino)ethane and the corresponding sodium salt (1:1), at 20°C, pH = 5.81 - 6.41; monitored by stopped flow spectrophotometry;
With potassium dihydrogenphosphate In water Kinetics; dissociation of Cu(daco)2(2+)in the presence of potassium dihydrogen phosphate, at 20°C; monitored by stopped flow spectrophotometry;

: 41685-78-3
(Ni(DACO)2)(2+)

: {Ph3PhCH2P}{H2F3}

A: 5687-07-0
1,5-diazacyclooctane

B: {Ni(1,5-diazocane)}(2+)

Conditions

Conditions	Yield
In hydrogenchloride hydrolysis reaction in HCl/NaCl solns., depending on H(1+) concn.; spectrophotometry( abs. max. at 595 nm);

: copper(II)(1,5-diazacyclooctane)(2+)

A: 5687-07-0
1,5-diazacyclooctane

B: copper(II) ion

Conditions

Conditions	Yield
With perchloric acid In water Kinetics; acid dissociation of Cu(daco)(2+)with perchloric acid (pH=8.5), at 20°C; monitored by stopped flow spectrophotometry;

: 5687-07-0
1,5-diazacyclooctane

: (4S)-2-chloromethyl-4-ethyl-2-oxazoline

: (S,S)-1,5-bis(4-ethyloxazolin-2-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile Heating;	87%

: 5687-07-0
1,5-diazacyclooctane

: 221196-91-4
(S)-2-(chloromethyl)-4-isopropyl-4,5-dihydrooxazole

: (S,S)-1,5-bis(4-isopropyloxazolin-2-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile Heating;	83%

: 5687-07-0
1,5-diazacyclooctane

: 20074-80-0
5-chloro-pentanal

: 84904-88-1
7-aza-1-azoniatricyclo<5.3.3.01,6>tridecane chloride

Conditions

Conditions	Yield
With magnesium sulfate In dichloromethane	82%

: 5687-07-0
1,5-diazacyclooctane

: (4S)-2-chloromethyl-4-methyl-2-oxazoline

: (S,S)-1,5-bis(4-methyloxazolin-2-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile for 10h; Heating;	81%

: 5687-07-0
1,5-diazacyclooctane

: (4S)-2-chloromethyl-4-isobutyl-2-oxazoline

: (S,S)-1,5-bis(4-isobutyloxazolin-2-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile Heating;	79%

: 5687-07-0
1,5-diazacyclooctane

: 221196-90-3
(4S)-2-chloromethyl-4-benzyl-2-oxazoline

: (S,S)-1,5-bis(4-benzyloxazolin-2-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile Heating;	75%

: 5687-07-0
1,5-diazacyclooctane

: 6139-84-0
4-chlorobutyraldehyde

: 82407-78-1
6-aza-1-azoniatricyclo<4.3.3.01,5>dodecane chloride

Conditions

Conditions	Yield
With magnesium sulfate In dichloromethane	74%

: 5687-07-0
1,5-diazacyclooctane

: 2096-78-8
vinyldiphenylphosphine oxide

: 165273-23-4
1,5-bis(2-diphenylphosphoryethyl)-1-azonia-5-azacyclooctane

Conditions

Conditions	Yield
In benzene at 150 - 160℃; for 6h;	67%

: 303161-67-3
3-n-butoxy-5-chloropyridine

: 5687-07-0
1,5-diazacyclooctane

: 1-(5-butoxy-pyridin-3-yl)-[1,5]diazocane

Conditions

Conditions	Yield
With potassium tert-butylate In 1,2-dimethoxyethane at 20℃; for 1.5h;	63%

: 625-92-3
3,5-dibromopyridine

: 5687-07-0
1,5-diazacyclooctane

: 1-(5-bromo-pyridin-3-yl)-[1,5]diazocane

Conditions

Conditions	Yield
at 150℃; for 48h;	63%

: 5687-07-0
1,5-diazacyclooctane

: 7496-46-0
8-bromomethyl-quinoline

: N,N'-bis(quinolin-8-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium hydroxide In ethanol	60%

: 5687-07-0
1,5-diazacyclooctane

: 78667-04-6
2-chloromethyl-1-methyl-imidazol hydrochloride

: 1,5-bis(N-1-methylimidazol-2-methyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium hydroxide In ethanol	60%

: 10445-91-7
4-(Chloromethyl)pyridine

: 5687-07-0
1,5-diazacyclooctane

: 1,5-bis(pyridin-4-ylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
With potassium hydroxide In ethanol at 20℃; for 72h; pH=9;	60%

: 141-30-0
3,6-dichlorpyridazine

: 5687-07-0
1,5-diazacyclooctane

: 223795-03-7
1-(6-Chloro-3-pyridazinyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
In toluene Heating / reflux;	42%

: 5687-07-0
1,5-diazacyclooctane

: 5954-68-7
2-methyl-2-propenethiol

: 152241-93-5
N,N'-bis(2-methyl-2-mercaptopropyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
In benzene for 48h; Ambient temperature;	40.8%

: 5687-07-0
1,5-diazacyclooctane

: 50-00-0
formaldehyd

: 4559-70-0
Diphenylphosphine oxide

: 1,5-bis(diphenylphosphorylmethyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
In benzene at 150 - 160℃; for 6h;	32%

: 5687-07-0
1,5-diazacyclooctane

: 2457-47-8
3,5-dichloropyridine

: 1-(5-chloro-pyridin-3-yl)-[1,5]diazocane

Conditions

Conditions	Yield
at 150℃;	2.5%

: 372-47-4
3-Fluoropyridine

: 5687-07-0
1,5-diazacyclooctane

: 1-(3-pyridyl)-1,5-diazacyclooctane

Conditions

Conditions	Yield
In 1,4-dioxane at 160℃; for 18h;	1.5%

: 5687-07-0
1,5-diazacyclooctane

: 98-59-9
p-toluenesulfonyl chloride

: 67761-04-0
1,5-bis(p-toluenesulphonyl)-1,5-diazacyclooctane

: 5687-07-0
1,5-diazacyclooctane

: 644-97-3
Dichlorophenylphosphine

: 35661-66-6
9-phenyl-1,5-diaza-9-phospha-bicyclo[3.3.1]nonane

Conditions

Conditions	Yield
With triethylamine In diethyl ether

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