1,7-Octadiene supplier | CasNO.3710-30-3

Name
1,7-Octadiene
EINECS
CAS No. 3710-30-3
Article Data55
CAS DataBase
Density 0.73g/cm³
Solubility Miscible with methanol and cyclohexane. Slightly miscible with water.
Melting Point -70 °C
Formula C8H14
Boiling Point 114-121 °C(lit.)
Molecular Weight 110.199
Flash Point 9.4°C
Transport Information
Appearance CLEAR COLORLESS TO SLIGHTLY YELLOW LIQUID
Safety Mildly toxic by ingestion, inhalation and skin contact. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes.
Risk Codes 11-52/53-65
Molecular Structure
Hazard Symbols
Synonyms NSC 82324; a,w-Octadiene
PSA 0.00000
LogP 2.91880

Synthetic route

: 14122-59-9
2-(5-hexenyl)thiirane

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With hydrogen sulfide; triphenylphosphine; methyltrioxorhenium(VII) In [D3]acetonitrile for 1h; Ambient temperature;	100%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene Heating;	85%

: 5162-44-7
1-bromo-4-butene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With triethanolamine; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; [Ni(2,2′:6′,2''-terpyridine)(pyridine)(CH3CN)2](PF6)2 In acetonitrile at 23 - 28℃; for 12h; Inert atmosphere; Sealed tube; Irradiation;	98%
With diethyl ether; sodium

: 3491-26-7
octa-1,7-dien-3-yl acetate

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With formic acid; triethylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine In tetrahydrofuran for 4h; Heating;	76%

: 30460-73-2
(E)-1-acetoxy-2,7-octadiene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With formic acid; triethylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine In tetrahydrofuran for 2h; Heating;	67%
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	100 % Chromat.

: 32634-64-3
7,8-diazabicyclo<4.2.2>dec-7-ene

A: 931-88-4, 931-87-3
(Z)-Cyclooctene

B: 28282-35-1
cis-bicyclo<4.2.0>octane

C: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With 4-tert-Butylcatechol In Petroleum ether at 160 - 170℃; for 69h;	A 14% B 23% C 30%
In Petroleum ether at 160 - 170℃; for 69h; Mechanism; 4-t-butylpyrocatechol;	A 14% B 23% C 30%
In Petroleum ether at 170℃;
In Petroleum ether at 170℃; also with deuterio labelled substrate;

...Expand

: 7051-34-5
cyclopropylcarbinyl bromide

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With lanthanum; iodine In tetrahydrofuran at 67℃; for 2h;	26%
With α-picoline; manganese; trifluoroacetic acid; cobalt(II) bromide In acetonitrile at 50℃;
With triethanolamine; (4,4'-di-tert-butyl-2,2'-dipyridyl)-bis-(2-phenylpyridine(-1H))-iridium(III) hexafluorophosphate; [Ni(2,2′:6′,2''-terpyridine)(pyridine)(CH3CN)2](PF6)2 for 12h; Irradiation; Inert atmosphere;

: C36H50N2NiO(1-)*C12H24KO6(1+)

: 7051-34-5
cyclopropylcarbinyl bromide

: C36H50N2NiO

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
In tetrahydrofuran-d8 at 22℃; Inert atmosphere; Schlenk technique;	A 22% B 22%

...Expand

: 74-85-1
ethene

: 110-83-8
cyclohexene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
In hexane at 16 - 18℃; under 53203.6 Torr; Pressure; Temperature;	20.1%
at 25 - 80℃; under 30003 - 150015 Torr; for 24 - 42h; Product distribution / selectivity;

: 871-84-1
1,7-Octadiyne

A: 111-65-9
octane

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
palladium anchored polystyrene In neat (no solvent) at 25℃; under 1551.4 Torr; for 36h;	A 20% B 20%
palladium anchored polystyrene In neat (no solvent) at 25℃; under 1551.4 Torr; for 36h;	A 20% B 20%

: 106-99-0
buta-1,3-diene

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
Stage #1: buta-1,3-diene With TEMPOL; sodium methylate; palladium diacetate In 1-methyl-pyrrolidin-2-one at -5 - 75℃; under 7500.75 Torr; Inert atmosphere; Stage #2: With formic acid In 1-methyl-pyrrolidin-2-one at 80 - 90℃; under 15001.5 Torr; Product distribution / selectivity; Inert atmosphere;	A 5.5% B 94.3 %Chromat.
With formic acid; triethylamine; palladium diacetate; triphenylphosphine In DMF (N,N-dimethyl-formamide) at 90℃; under 750.075 Torr; for 1.5h; Product distribution / selectivity;

: 871-84-1
1,7-Octadiyne

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium sulfate; ammonia; sodium Reagens 4: Aether;
With ethylene dibromide; copper(I) bromide; lithium bromide; zinc In tetrahydrofuran; ethanol Heating;

: 772-60-1
cyclooctyl acetate

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 500℃; Pyrolysis;

: 34164-50-6
4-penten-1-ylmagnesium bromide

: 106-95-6
allyl bromide

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With diethyl ether

: 34164-50-6
4-penten-1-ylmagnesium bromide

: 107-05-1
3-chloroprop-1-ene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With diethyl ether

: 931-88-4, 931-87-3
(Z)-Cyclooctene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 550℃;
at 633℃; Thermodynamic data; Rate constant; further temp.; energy of activation;

: 3992-48-1
1,8-octanediyl diacetate

A: 5048-35-1
oct-7-en-1-yl acetate

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 500℃;

: 111-20-6
1,10-decanedioic acid

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With acetic anhydride; bis-triphenylphosphine-palladium(II) chloride at 250℃; under 735.5 Torr; Yield given;
Stage #1: 1,10-decanedioic acid With bis(1,5-cyclooctadiene)diiridium(I) dichloride; triphenylphosphine; potassium iodide at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Stage #2: With acetic anhydride at 160℃; for 5h; Inert atmosphere; Schlenk technique; regioselective reaction;
With formate dehydrogenase; 1200 U catalase; OleT in combination with the putidaredoxin electron-transfer system CamAB; P450 monooxygenase OleT; ammonium formate; β-nicotinamide adenine dinucleotide, disodium salt, reduced form In ethanol at 4℃; for 72h; Catalytic behavior; Enzymatic reaction;
Multi-step reaction with 2 steps 1: P450 monooxygenase OleT; OleT in combination with the putidaredoxin electron-transfer system CamAB; formate dehydrogenase; β-nicotinamide adenine dinucleotide, disodium salt, reduced form; 1200 U catalase; ammonium formate / ethanol / Enzymatic reaction 2: P450 monooxygenase OleT; OleT in combination with the putidaredoxin electron-transfer system CamAB; formate dehydrogenase; β-nicotinamide adenine dinucleotide, disodium salt, reduced form; 1200 U catalase; ammonium formate / ethanol / Enzymatic reaction View Scheme

: 278-30-8, 28282-35-1, 63296-41-3
bicyclo<4.2.0>octane

A: 74-85-1
ethene

B: 3710-30-3
1,7-Octadiene

C: 110-83-8
cyclohexene

Conditions

Conditions	Yield
In pentane Quantum yield; Irradiation;

...Expand

: 15972-89-1
(E)-1-phenoxy-2,7-octadiene

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	A 2 % Chromat. B 98 % Chromat.

: 15972-91-5
3-Phenoxy-1,7-octadien

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	A 1 % Chromat. B 99 % Chromat.

: 931-89-5
(E)-cyclooctene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 633℃; Rate constant; further temperature;

: 931-89-5
(E)-cyclooctene

A: 931-88-4, 931-87-3
(Z)-Cyclooctene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 300.1℃; Rate constant; Thermodynamic data; further temperatures; energy of activation; ΔH(exit.); ΔS(exit.);

: 931-89-5
(E)-cyclooctene

A: 931-88-4, 931-87-3
(Z)-Cyclooctene

B: 695-12-5
vinylcyclohexane

C: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 512℃; Rate constant; further temperatures;

...Expand

: 3491-26-7
octa-1,7-dien-3-yl acetate

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	A 4 % Chromat. B 96 % Chromat.

: 30460-73-2
(E)-1-acetoxy-2,7-octadiene

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	A 30 % Chromat. B 70 % Chromat.
With ammonium formate; bis-triphenylphosphine-palladium(II) chloride; triphenylphosphine In 1,4-dioxane at 100℃; for 2h; Product distribution; other catalysts, other ligands;	A 21 % Chromat. B 79 % Chromat.
With ammonium formate; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; triethyl phosphite In 1,4-dioxane for 2h; Product distribution; Heating; var. catalyst,;	A 26 % Chromat. B 74 % Chromat.

: 92747-31-4
(E)-2,7-octadienyl methyl carbonate

A: 3710-41-6
1,6-octadiene

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With ammonium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	A 1 % Chromat. B 99 % Chromat.

: 32634-64-3
7,8-diazabicyclo<4.2.2>dec-7-ene

A: 931-88-4, 931-87-3
(Z)-Cyclooctene

B: 28282-35-1
cis-bicyclo<4.2.0>octane

C: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
In cyclohexane at 170℃; Product distribution; Mechanism; var. temps; also direct and sensitised photolysis;	A 18 % Chromat. B 35 % Chromat. C 47 % Chromat.

...Expand

: 92747-32-5
(E)-8-chloro-octa-1,6-diene

: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
With sodium formate; tris(dibenzylideneacetone)dipalladium chloroform complex; tributylphosphine In 1,4-dioxane for 2h; Heating;	100 % Chromat.

: 66301-61-9
cis-8-thiabicyclo<4.3.0>nonane 8,8-dioxide

A: 106-99-0
buta-1,3-diene

B: 3710-30-3
1,7-Octadiene

C: 71-43-2
benzene

Conditions

Conditions	Yield
at 850℃; under 0.005 Torr; Product distribution; other temperature (925 deg C); flash vacuum pyrolysis of bi- and tricyclic sulfones;	A n/a B 41 % Spectr. C 2 % Spectr.

...Expand

: 931-88-4, 931-87-3
(Z)-Cyclooctene

A: 695-12-5
vinylcyclohexane

B: 3710-30-3
1,7-Octadiene

Conditions

Conditions	Yield
at 336.9 - 817.9℃; Kinetics; Thermodynamic data; activation energy;

: 3710-30-3
1,7-Octadiene

: 111-65-9
octane

Conditions

Conditions	Yield
With hydrogen; sodium triethylborohydride In tetrahydrofuran at 23℃; under 30402 Torr; for 24h; Catalytic behavior; Inert atmosphere; Schlenk technique;	100%
With [Re(NO)(η(2)-H2)Br2(PiPr3)2]; dimethylamine borane; hydrogen at 90℃; under 7500.75 Torr; for 0.2h; Autoclave;	88%
With hydrogen; sodium triethylborohydride In tetrahydrofuran at 23℃; under 30003 Torr; for 48h; Reagent/catalyst; Autoclave;	82%

: 3710-30-3
1,7-Octadiene

: 110-83-8
cyclohexene

Conditions

Conditions	Yield
With diazomethyl-trimethyl-silane; ruthenium Schiff-base In toluene at 70℃; for 1h; ring-closing metathesis;	100%
With diazomethyl-trimethyl-silane; ruthenium In toluene at 85℃; for 17h; Product distribution; Further Variations:; Catalysts;	100%
[2-((2,6-iPr2-Ph-imino)methyl)phenol][p-cymene][=CHPh]Ru2Cl3 In various solvent(s) at 70℃; for 4h; Product distribution; Further Variations:; Catalysts; Temperatures;	100%

: 6941-75-9
5-Bromoisoindoline-1,3-dione

: 3710-30-3
1,7-Octadiene

: 1620872-13-0
C24H20N2O4

Conditions

Conditions	Yield
With palladium diacetate; triethylamine; triphenylphosphine In N,N-dimethyl-formamide at 150℃; for 24h; Heck Reaction;	100%
With palladium diacetate; triethylamine; triphenylphosphine In N,N-dimethyl-formamide at 150℃; for 24h; Heck Reaction;	100%

: 766-98-3
1-ethynyl-4-fluorobenzene

: 3710-30-3
1,7-Octadiene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-(4-fluorophenyl)-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 143874-13-9
4-ethynyl-1,2-difluorobenzene

: 3710-30-3
1,7-Octadiene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-(3,4-difluorophenyl)-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 767-91-9
1-ethynyl-2-methoxybenzene

: 3710-30-3
1,7-Octadiene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-(2-methoxyphenyl)-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 705-31-7
4-trifluoromethylphenylacetylene

: 3710-30-3
1,7-Octadiene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-(4-trifluoromethylphenyl)-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 3710-30-3
1,7-Octadiene

: 536-74-3
phenylacetylene

: 130-15-4
[1,4]naphthoquinone

: 6337-31-1
2-phenyl-1,4,4a,9a-tetrahydroanthracene-9,10-dione

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 3710-30-3
1,7-Octadiene

: 768-60-5
4-methoxyphenylacetylen

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-(4-methoxyphenyl)-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	99%

...Expand

: 1438-82-0
1,1,1,3,3-pentamethyl-1,3-disiloxane

: 3710-30-3
1,7-Octadiene

: 1,8-bis(1,1,3,3,3-pentamethyl-disiloxanyl)octane

Conditions

Conditions	Yield
With cobalt pivalate; 1-adamantyl isocyanide at 80℃; for 24h; Inert atmosphere;	99%
With cobalt pivalate; [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene at 80℃; for 24h; Inert atmosphere;	60%

: 1338063-88-9
2,4-bis[2,6-bis(2,4,6-trimethylphenyl)phenyl]-1,3-diphospha-2,4-diazacyclobutane

: 3710-30-3
1,7-Octadiene

: C56H64N2P2

Conditions

Conditions	Yield
In benzene at 20℃; for 1h; Inert atmosphere;	99%

: 7648-30-8
ethyl 2,2-difluoro-2-iodoacetate

: 3710-30-3
1,7-Octadiene

: diethyl 2,2,11,11-tetrafluoro-4,9-diiodododecanedioate

Conditions

Conditions	Yield
With diethylzinc In hexane; acetonitrile at -20℃; for 16h; Schlenk technique; Inert atmosphere;	99%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 3710-30-3
1,7-Octadiene

: {((C5H5)Re(NO)(P(C6H5)3))2(CH2CH(CH2)4HCCH2)}(2+)*2BF4(1-)={((C5H5)Re(NO)(P(C6H5)3))2(CH2CH(CH2)4HCCH2)}(BF4)2

Conditions

Conditions	Yield
In chlorobenzene under N2, addn. of HBF4*OEt2 to cooled soln. of Re-compd. at -45°C, then addn. of diene to the intermediate with stirring, stirring 15 h at 100°C; soln. filtered into hexane, filtration, washing (pentane), drying, mixt. of isomers;	98%

...Expand

: 3710-30-3
1,7-Octadiene

: 536-74-3
phenylacetylene

: 2288-18-8
2-phenyl-1,3-butadiene

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; Sealed tube; Inert atmosphere;	98%

: 3710-30-3
1,7-Octadiene

: 536-74-3
phenylacetylene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-phenyl-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 20h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	98%

...Expand

: 423-39-2
1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

: 3710-30-3
1,7-Octadiene

: 13105-46-9
1,1,1,2,2,3,3,4,4,13,13,14,14,15,15,16,16,16-octadecafluoro-6,11-diiodohexadecane

Conditions

Conditions	Yield
With Sodium thiosulfate pentahydrate; 2,2'-azobis-(2,4-dimethylvaleronitrile) at 85℃; for 3h;	97.5%

: 14428-98-9, 98325-59-8, 98359-08-1
(E)-1-phenyl-N-(1-phenylethylidene)methanamine

: 3710-30-3
1,7-Octadiene

: 1-(2-octyl-phenyl)-ethanone

Conditions

Conditions	Yield
Stage #1: (E)-1-phenyl-N-(1-phenylethylidene)methanamine; 1,7-Octadiene With molecular sieve; tris(triphenylphosphine)rhodium(I) chloride In toluene at 150℃; for 2h; Stage #2: With water Acid hydrolysis; Stage #3: With hydrogen; palladium on activated charcoal	97%

: 13412-55-0
triphenylmethylacetonitrile oxide

: 3710-30-3
1,7-Octadiene

: 123622-56-0
5-(5-hexenyl)-3-(triphenylmethyl)-2-isoxazoline

Conditions

Conditions	Yield
In benzene for 48h; Heating;	96%

: 3710-30-3
1,7-Octadiene

: 2426-07-5
1,2,7,8-diepoxyoctane

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃;	95%
With 3-chloro-benzenecarboperoxoic acid at 10 - 23℃; for 16h;	95.2%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃; for 24h;	94%

(NH4)2WO4: (NH4)2WO4

: 3710-30-3
1,7-Octadiene

: 124-04-9
Adipic acid

Conditions

Conditions	Yield
With manganese dioxide; dihydrogen peroxide In 1,4-dioxane; acetic acid	95%
With manganese dioxide; dihydrogen peroxide In 1,4-dioxane	51%

: 3710-30-3
1,7-Octadiene

: 88444-81-9
3,5-bis(trifluoromethyl)phenylacetylene

: 623-91-6
diethyl Fumarate

: (trans)-diethyl 4-[3,5-bis(trifluoromethyl)phenyl]-4-cyclohexene-1,2-dicarboxylate

Conditions

Conditions	Yield
With [2-(i-PrO)-C6H4]C(H)=RuCH[(Mes)NCH2CH2N(Mes)]Cl2 In toluene at 90℃; for 30h; Diels-Alder reaction; Sealed tube; Inert atmosphere;	95%

...Expand

: C17H13Cl3O2

: 3710-30-3
1,7-Octadiene

: C19H17Cl3O2

Conditions

Conditions	Yield
With C29H31F3I2N2RuS In benzene-d6 at 80℃; for 1h;	95%

: 694-53-1
phenylsilane

: 3710-30-3
1,7-Octadiene

: 1,8-bis(phenylsilyl)octane

Conditions

Conditions	Yield
[Y(C5Me4CH2SiMe2NCMe3)(THF)] In hexane at 20℃; for 48h;	94%
With ((HBPIMes,H)FeBr2); sodium triethylborohydride at 20℃; for 24h; Inert atmosphere; Schlenk technique;	14%

: 3710-30-3
1,7-Octadiene

: 18152-31-3
(E,E)-2,6-octadiene

Conditions

Conditions	Yield
With C24H42N2PRu(1+)*F6P(1-) In [(2)H6]acetone at 20℃; for 0.166667h; stereoselective reaction;	94%

: 201230-82-2
carbon monoxide

: 3710-30-3
1,7-Octadiene

: 1188-08-5
2,7-dimethyl-octanedioic acid

Conditions

Conditions	Yield
With hydrogenchloride; oxygen; copper dichloride; palladium dichloride In tetrahydrofuran under 760 Torr; for 18h; Ambient temperature;	93%

: 100891-32-5
1,1,1-triphenyl-3,3-dimethyldisiloxane

: 3710-30-3
1,7-Octadiene

: C48H58O2Si4

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex at 70 - 90℃; for 24h;	93%
With dihydrogen hexachloroplatinate; platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 70 - 90℃; for 24.1667h;	93%

: 677-69-0
perfluoroisopropyl iodide

: 3710-30-3
1,7-Octadiene

: 143766-68-1
9,10,10,10-Tetrafluoro-7-iodo-9-trifluoromethyldec-1-ene

Conditions

Conditions	Yield
With bis(cyclopentadienyl)titanium dichloride; iron In ethanol at 55℃; for 10h; other per(poly)fluoroalkyl iodides and bromides;	92%
With bis(cyclopentadienyl)titanium dichloride; iron In ethanol at 55℃; for 10h;	92%

: 513-81-5
2,3-dimethyl-buta-1,3-diene

: 3710-30-3
1,7-Octadiene

: 1254327-45-1
C20H34

Conditions

Conditions	Yield
With cobalt(II) bromide-[1,2-bis(diphenylphosphino)ethane]; zinc(II) iodide; zinc In dichloromethane for 20h;	92%

1,7-Octadiene Chemical Properties

IUPAC Name: Octa-1,7-diene
The MF of 1,7-Octadiene (CAS NO.3710-30-3) is C₈H₁₄.

The MW of 1,7-Octadiene (CAS NO.3710-30-3) is 110.2.
Synonyms of 1,7-Octadiene (CAS NO.3710-30-3): Octa-1,7-diene ; .alpha.,.omega.-Octadiene
Product Categories: Acyclic;Alkenes;Organic Building Blocks
Apperance: clear colorless to slightly yellow liquid
Index of Refraction: 1.425
EINECS: 223-054-9
Density: 0.73 g/ml
Flash Point: 9.4 °C
Boiling Point: 115.5 °C
Melting Point: <-70 °C
Storage temp; Flammables area
BRN: 605288

1,7-Octadiene Uses

1,7-Octadiene (CAS NO.3710-30-3) is used in organic synthesis.

1,7-Octadiene Toxicity Data With Reference

1.	orl-rat LD50:14,696 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470.
2.	ihl-rat LCLo:8000 ppm/4H	AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470.
3.	skn-rbt LD50:10,519 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470.

1,7-Octadiene Consensus Reports

Reported in EPA TSCA Inventory.

1,7-Octadiene Safety Profile

Mildly toxic by ingestion, inhalation and skin contact. A very dangerous fire hazard when exposed to HEAT or flame; can react vigorously with oxidizing materials. When HEATed to decomposition it emits acrid smoke and irritating fumes.Safety information of 1,7-Octadiene (CAS NO.3710-30-3):
Hazard Codes F, Harmful Xn
Risk Statements
11 Highly Flammable
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
65 Harmful: May cause lung damage if swallowed
Safety Statements
16 Keep away from sources of ignition - No smoking
61 Avoid release to the environment. Refer to special instructions safety data sheet
62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
RIDADR UN 2309 3/PG 2
WGK Germany 1
RTECS RG5250000
F 9
HazardClass 3
PackingGroup II

Product Name

1,7-Octadiene

Synthetic route

1,7-Octadiene Chemical Properties

1,7-Octadiene Uses

1,7-Octadiene Toxicity Data With Reference

1,7-Octadiene Consensus Reports

1,7-Octadiene Safety Profile

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