1-Bromo-1-cyclohexene supplier

Name
1-Bromocyclohex-1-ene
EINECS
CAS No. 2044-08-8
Article Data32
CAS DataBase
Density 1.3901
Solubility
Melting Point
Formula C6H9 Br
Boiling Point 155.42°C (estimate)
Molecular Weight 161.041
Flash Point 58.2oC
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 1-Bromo-1-cyclohexene;1-Bromocyclohexene;
PSA 0.00000
LogP 2.83920

Synthetic route

: 28075-50-5
cyclohex-1-en-1-yl trifluoromethane sulfonate

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With tris(2,4-pentanedionato)ruthenium(III); 1,10-Phenanthroline; ethylmagnesium bromide; lithium bromide In tetrahydrofuran at 60℃; for 24h; Inert atmosphere;	91%

: 108-94-1
cyclohexanone

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; triphenylphosphine In dichloromethane at 40℃; for 24h;	75%
With triphenyl phosphite; bromine; triethylamine In dichloromethane at -60 - 20℃; for 20h; Inert atmosphere; Reflux;	67%
With 2,4,4,6-Tetrabromo-2,5-cyclohexadien-1-one; triphenylphosphine In dichloromethane for 18h; Reflux; Inert atmosphere;

: 108-93-0
cyclohexanol

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With pyridine; phosphorus tribromide In tetrahydrofuran at -10 - -5℃; for 10h; Large scale;	72%

: 636-82-8
cyclohexene-1-carboxylic acid

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
Stage #1: cyclohexene-1-carboxylic acid With bromine In dichloromethane at 20℃; for 0.5h; Stage #2: With sulfolane; dmap at 40 - 90℃;	66%

: 7429-37-0
trans-1,2-dibromocyclohexane

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With morpholine; dimethyl sulfoxide In benzene for 40h; Heating;	65%

: 5401-62-7
1,2-dibromocyclohexane

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With sodium amide; tert-butyl alcohol In tetrahydrofuran 1.) -40 deg C, 1 h, 2.) RT, 1 h;	63%
With quinoline

: 4545-18-0
N'-cyclohexylidene-4-methylbenzene-1-sulfonohydrazide

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With N-Bromosuccinimide; tetrabutylammomium bromide; potassium carbonate In 1,4-dioxane at 90℃; Inert atmosphere; regioselective reaction;	58%
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; 1,2-dibromo-1,1,2,2-tetrafluoroethane 1.) a.) hexane, -78 deg C, 2 h, b.) RT, 3 h, 2.) -78 deg C, 1 h; Yield given. Multistep reaction;

: 17170-96-6
trans-1-bromo-2-fluorocyclohexane

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With sodium amide In tetrahydrofuran; tert-butyl alcohol	47%

: 4065-81-0
cyclohexen-1-ol

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With oxalyl dichloride; Triphenylphosphine oxide; lithium bromide In chloroform at 20℃; for 7h; Appel reaction;	14%

: 10489-97-1
dibromo-cyclohexane

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With quinoline

: 6156-08-7
cyclohexanone hydrazone

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
With pyridine; bromine In chloroform

: 930-66-5
1-chlorocyclohexene

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
(i) Li, Na, Et2O, (ii) Br2, pentane; Multistep reaction;

: 75-89-8
2,2,2-trifluoroethanol

: 28075-50-5
cyclohex-1-en-1-yl trifluoromethane sulfonate

A: 2044-08-8
1-bromocyclohex-1-ene

B: 108-94-1
cyclohexanone

C: 92610-64-5
1,1-Bis(2,2,2-trifluorethoxy)cyclohexan

Conditions

Conditions	Yield
With tetraethylammonium bromide; triethylamine at 135℃; for 360h; Product distribution; Mechanism;	A 30 % Chromat. B 60 % Chromat. C 10 % Chromat.

...Expand

: 13898-96-9
(+-)-trans-1-bromo-2-chloro-cyclohexane

A: 2044-08-8
1-bromocyclohex-1-ene

B: 930-66-5
1-chlorocyclohexene

Conditions

Conditions	Yield
With potassium tert-butylate In tert-butyl alcohol at 50℃; for 120h; Yield given. Yields of byproduct given;
With sodium amide; sodium t-butanolate In tetrahydrofuran for 2h; Product distribution; Mechanism; Ambient temperature; var. NaNH2-Na(anion), var. product distributions;
With 15-crown-5; sodium amide; sodium t-butanolate In tetrahydrofuran for 0.5h; Product distribution; Mechanism; Ambient temperature;

: 7429-37-0
trans-1,2-dibromocyclohexane

A: 2044-08-8
1-bromocyclohex-1-ene

B: 110-83-8
cyclohexene

Conditions

Conditions	Yield
With sodium amide; sodium 3-methyl-pentoxide-3 In tetrahydrofuran at 25℃; Title compound not separated from byproducts;	A 69 % Chromat. B 29 % Chromat.
With sodium amide; sodium 3-methyl-pentoxide-3 In tetrahydrofuran at 25℃; Product distribution; var. complex bases;

: 17170-96-6
trans-1-bromo-2-fluorocyclohexane

A: 2044-08-8
1-bromocyclohex-1-ene

B: 2699-13-0
3-methoxycyclohexene

C: 51620-76-9
3-fluorocyclohex-1-ene

D: 1165952-91-9
cyclohexa-1,3-diene

Conditions

Conditions	Yield
With potassium tert-butylate for 3h; Product distribution; Heating; dehydrohalogenation with different equivalents of various bases at different temperatures and reaction times;

...Expand

: 108-94-1
cyclohexanone

A: 2044-08-8
1-bromocyclohex-1-ene

B: 10489-97-1
dibromo-cyclohexane

Conditions

Conditions	Yield
With phenyl(tribromomethyl)mercury(II) In benzene at 75 - 80℃; for 2h;
With phosphorus pentabromide In sulfolane at 30 - 80℃; for 6h; Inert atmosphere;

: 64-17-5
ethanol

: 19246-38-9
cis-1,2-dibromocyclohexane

sodium hydroxide: sodium hydroxide

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
at 30℃; Rate constant;
at 50℃; Rate constant;
at 20℃; Rate constant;

...Expand

: 2425-33-4, 16536-57-5, 24796-87-0, 53023-24-8, 53023-25-9, 60933-67-7
2-bromocyclocyclohexanol

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 66.6 percent / diethylaminosulfur trifluoride / CH2Cl2 / 1.5 h / -78 °C 2: 47 percent / sodamide / 2-methyl-propan-2-ol; tetrahydrofuran View Scheme

: 110-83-8
cyclohexene

palladium black: palladium black

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 86.95 percent / hydrogen fluoride, N-bromoacetamide / diethyl ether / 1.5 h / 1.) dry ice bath; 2.) room temperature overnight 2: 47 percent / sodamide / 2-methyl-propan-2-ol; tetrahydrofuran View Scheme

: 18448-47-0
methyl cyclohex-1-ene-1-carboxylate

: 2044-08-8
1-bromocyclohex-1-ene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: potassium hydroxide / dichloromethane; water / 20 °C 2.1: bromine / dichloromethane / 0.5 h / 20 °C 2.2: 40 - 90 °C View Scheme

: 2044-08-8
1-bromocyclohex-1-ene

: 73183-34-3
bis(pinacol)diborane

: 141091-37-4
2-(cyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With triphenylphosphine; bis(triphenylphosphine)palladium(II) chloride In toluene mixt. in toluene stirred at 50°C for 5 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);	99%
With bis-triphenylphosphine-palladium(II) chloride; potassium phenolate; triphenylphosphine In toluene at 50℃; for 5h; Inert atmosphere;	85%
With trans-bis(triphenylphosphine)palladium dichloride; potassium phenolate; triphenylphosphine In toluene at 50℃; for 5h; Inert atmosphere;	85%

: 2044-08-8
1-bromocyclohex-1-ene

: 259236-21-0
N1,N5-dimethoxy-N1,N5-dimethylglutaramide

: 91890-41-4
1,5-di(cyclohex-1-en-1-yl)pentane-1,5-dione

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With chloro-trimethyl-silane; magnesium; ethylene dibromide; lithium chloride In tetrahydrofuran Inert atmosphere; Reflux; Schlenk technique; Stage #2: N1,N5-dimethoxy-N1,N5-dimethylglutaramide In tetrahydrofuran; diethyl ether at 23℃; Inert atmosphere; Schlenk technique; Cooling;	99%

: 2044-08-8
1-bromocyclohex-1-ene

: 177283-77-1
(4R,5R)-N,N'-dimethoxy-N,N',2,2-tetramethyl-1,3-dioxolane-4,5-dicarboxamide

: (R,R)-(2,2-dimethyl-1,3-dioxolane-4,5-diyl)bis(cyclohex-1-en-1-ylmethanone)

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With chloro-trimethyl-silane; magnesium; ethylene dibromide; lithium chloride In tetrahydrofuran Inert atmosphere; Reflux; Schlenk technique; Stage #2: (4R,5R)-N,N'-dimethoxy-N,N',2,2-tetramethyl-1,3-dioxolane-4,5-dicarboxamide In tetrahydrofuran; diethyl ether at 23℃; Inert atmosphere; Schlenk technique; Cooling;	99%

: 2044-08-8
1-bromocyclohex-1-ene

: 201230-82-2
carbon monoxide

: 636-82-8
cyclohexene-1-carboxylic acid

Conditions

Conditions	Yield
With tetrabutylammomium bromide; dicobalt octacarbonyl In sodium hydroxide; benzene at 65℃; for 2.5h; Irradiation;	98%

: 2044-08-8
1-bromocyclohex-1-ene

: (R)-2-(4-(4-methoxyphenyl)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: (R)-1-(3-(cyclohex-1-en-1-yl)butyl)-4-methoxybenzene

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h; Inert atmosphere; Stage #2: (R)-2-(4-(4-methoxyphenyl)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran; pentane at -78 - 0℃; for 0.5h; Inert atmosphere; Stage #3: With iodine; sodium methylate In tetrahydrofuran; methanol; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;	98%

Yield

Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: (R)-2-(4-(4-methoxyphenyl)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;
Stage #3: With iodine; sodium methylate In tetrahydrofuran; methanol; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;

98%

: 2044-08-8
1-bromocyclohex-1-ene

: 683-18-1
dibutyltin chloride

: 169310-25-2
dibutylbis(cyclohexen-1-yl)stannane

Conditions

Conditions	Yield
With lithium In diethyl ether Ar atmosphere, addn. of soln. of Bu2SnCl2 to soln. of alkenyllithium (1 h), stirring (reflux, 12 h); hydrolysis (saturated aq. NH4Cl), extn. (Et2O), drying of organic phases(MgSO4), removement of solvent, fractional distillation; elem. anal.;	96%

: 2044-08-8
1-bromocyclohex-1-ene

: 1461-22-9
tributyltin chloride

: 100073-20-9
tri-n-butyl-(1-cyclohex-1-enyl)-stannane

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 1h; Inert atmosphere; Stage #2: tributyltin chloride In tetrahydrofuran; pentane at -78 - 20℃; for 18h; Inert atmosphere;	96%

: 2044-08-8
1-bromocyclohex-1-ene

: 68843-68-5
(E)-3-methyl-1-phenylbut-3-en-1-one oxime

: (S)-5-(cyclohex-1-en-1-ylmethyl)-5-methyl-3-phenyl-4,5-dihydroisoxazole

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); (R)-N-((S)-(2-(di((3R,5R,7R)-adamantan-1-yl)phosphaneyl)-4,5-dimethoxyphenyl)(phenyl)methyl)-N,2-dimethylpropane-2-sulfinamide; sodium t-butanolate In toluene at 65℃; for 12h; Inert atmosphere; Schlenk technique; enantioselective reaction;	95%

: 2044-08-8
1-bromocyclohex-1-ene

: 1071850-00-4
potassium 2-nitro-5-methoxylbenzoate

: 1609102-33-1
2-cyclohexenyl-4-methoxy-1-nitrobenzene

Conditions

Conditions	Yield
With 1,10-Phenanthroline; palladium(II) hexafluoroacetylacetonate; tri-1-napthylphosphine; copper(l) chloride In 1-methyl-pyrrolidin-2-one; 1,3,5-trimethyl-benzene at 130℃; for 16h; Inert atmosphere; regiospecific reaction;	94%

: 2044-08-8
1-bromocyclohex-1-ene

: C25H36MgMnSi3

: 108025-34-9
cyclohex-1-en-1-yldimethyl(phenyl)silane

Conditions

Conditions	Yield
In tetrahydrofuran at 0℃; for 2h;	93%

: 2044-08-8
1-bromocyclohex-1-ene

: 38604-68-1
N'-methyl-N'-phenylacetohydrazide

: 6303-88-4
9-methyl-2,3,4,9-tetrahydro-1H-carbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; N'-methyl-N'-phenylacetohydrazide With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	93%

: 2044-08-8
1-bromocyclohex-1-ene

: 1450812-50-6
N'-(4-fluorophenyl)-N'-methylacetohydrazide

: 1450812-55-1
6-fluoro-9-methyl-2,3,4,9-tetrahydro-1H-carbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; N'-(4-fluorophenyl)-N'-methylacetohydrazide With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	92%

: 2044-08-8
1-bromocyclohex-1-ene

: 63283-77-2
(E)-2-methyl-3-(thiophen-2-yl)acrylaldehyde

: 1428319-24-7
(E)-1-cyclohexenyl-2-methyl-3-(thiophen-2-yl)prop-2-en-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In diethyl ether; pentane at -78 - 20℃; for 1.25h; Stage #2: (E)-2-methyl-3-(thiophen-2-yl)acrylaldehyde In diethyl ether; pentane at -78 - 0℃; for 1h;	92%

: 2044-08-8
1-bromocyclohex-1-ene

: 15163-59-4
potassium o-nitrobenzoate

: 859219-19-5
1-cyclohexenyl-2-nitrobenzene

Conditions

Conditions	Yield
With 1,10-Phenanthroline; palladium(II) hexafluoroacetylacetonate; tri-1-napthylphosphine; copper(l) chloride In 1-methyl-pyrrolidin-2-one; 1,3,5-trimethyl-benzene at 130℃; for 16h; Reagent/catalyst; Temperature; Solvent; Inert atmosphere; regiospecific reaction;	92%

: 2044-08-8
1-bromocyclohex-1-ene

: 1191-95-3
cyclobutanone

: 70624-97-4
1-(cyclohex-1-en-1-yl)cyclobutan-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h; Inert atmosphere; Stage #2: cyclobutanone In tetrahydrofuran; pentane at -78℃; for 0.5h; Inert atmosphere;	92%

: 2044-08-8
1-bromocyclohex-1-ene

: 497-03-0
2-methylbut-2-enal

: 1428319-18-9
(E)-1-cyclohexenyl-2-methylbut-2-en-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In diethyl ether; pentane at -78 - 20℃; for 1.25h; Stage #2: 2-methylbut-2-enal In diethyl ether; pentane at -78 - 0℃; for 1h;	91%

: 2044-08-8
1-bromocyclohex-1-ene

: 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(5-{[(triisopropylsilyl)oxy]methyl}-3-thienyl)butan-1-one

: rac-4-{[tert-butyl(dimethyl)silyl]oxy}-1-(cyclohex-1-en-1-yl)-1-(5-{[(triisopropylsilyl)oxy]methyl}-3-thienyl)butan-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 1h; Stage #2: 4-{[tert-butyl(dimethyl)silyl]oxy}-1-(5-{[(triisopropylsilyl)oxy]methyl}-3-thienyl)butan-1-one With lanthanium (III) chloride bis(lithium chloride) complex In tetrahydrofuran; pentane for 1h;	91%

: 2044-08-8
1-bromocyclohex-1-ene

: C6H16N2*C5H6BrF3OZn

: (E)-2-(1-cyclohexenyl)-1-ethoxy-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 70℃; for 7h;	90%

: 2044-08-8
1-bromocyclohex-1-ene

: 59643-63-9
(2-cyclohexylidene ethenyl)-benzene

: (1-(cyclohex-1-en-1-yl)-2-cyclohexylidenevinyl)benzene

Conditions

Conditions	Yield
Stage #1: (2-cyclohexylidene ethenyl)-benzene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h; Schlenk technique; Inert atmosphere; Stage #2: 1-bromocyclohex-1-ene With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; bis(dibenzylideneacetone)-palladium(0) In toluene at 40℃; for 1h; Schlenk technique; Inert atmosphere;	90%

: 2044-08-8
1-bromocyclohex-1-ene

: 1450812-51-7
N'-(4-chlorophenyl)-N'-methylacetohydrazide

: 30451-40-2
6-chloro-9-methyl-2,3,4,9-tetrahydro-1H-carbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; N'-(4-chlorophenyl)-N'-methylacetohydrazide With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	89%

: 2044-08-8
1-bromocyclohex-1-ene

: N'-benzyl-N'-phenylacetohydrazide

: 17017-63-9
9-benzyl-2,3,4,9-tetrahydro-1H-carbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; N'-benzyl-N'-phenylacetohydrazide With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	89%

: 2044-08-8
1-bromocyclohex-1-ene

: 1450812-65-3
C11H14N2O

: 51281-98-2
N-allyl-1,2,3,4-tetrahydrocarbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; C11H14N2O With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	88%

: 2044-08-8
1-bromocyclohex-1-ene

: 3893-15-0, 93614-82-5
(E)-3-(4-methylphenyl)-2-methylacrylaldehyde

: 1428319-21-4
(E)-1-cyclohexenyl-2-methyl-3-p-tolylprop-2-en-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In diethyl ether; pentane at -78 - 20℃; for 1.25h; Stage #2: (E)-3-(4-methylphenyl)-2-methylacrylaldehyde In diethyl ether; pentane at -78 - 0℃; for 1h;	88%

: 2044-08-8
1-bromocyclohex-1-ene

: 62952-33-4
3-ethoxy-6-methylcyclohex-2-en-1-one

: 4-ethoxy-1-methyl-[1,1'-bi(cyclohexane)]-1',3-dien-2-one

Conditions

Conditions	Yield
Stage #1: 3-ethoxy-6-methylcyclohex-2-en-1-one With lithium hexamethyldisilazane In toluene at -20℃; for 0.5h; Inert atmosphere; Stage #2: 1-bromocyclohex-1-ene With chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium (II) In toluene at -20 - 20℃; for 4.16667h; Inert atmosphere; Schlenk technique;	88%

: 2044-08-8
1-bromocyclohex-1-ene

: 1338073-35-0
2-(4-(4-methoxyphenyl)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1-(3-(cyclohex-1-en-1-yl)butyl)-4-methoxybenzene

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.5h; Inert atmosphere; Stage #2: 2-(4-(4-methoxyphenyl)butan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane In tetrahydrofuran; pentane at -78 - 0℃; for 0.5h; Inert atmosphere; Stage #3: With iodine; sodium methylate In tetrahydrofuran; methanol; pentane at -78 - 0℃; for 0.5h; Inert atmosphere;	87%

: 2044-08-8
1-bromocyclohex-1-ene

: 73183-34-3
bis(pinacol)diborane

: 167773-14-0
2-(cyclohex-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With chlorotris(triphenylphosphine)cobalt(I); sodium ethanolate; 1,3-dicyclohexylimidazol-2-ylidene In tert-butyl methyl ether at 50℃; for 16h; Inert atmosphere;	87%

: 2044-08-8
1-bromocyclohex-1-ene

: 1450812-53-9
N'-(4-methoxyphenyl)-N'-methylacetohydrazide

: 3382-44-3
6-methoxy-9-methyl-2,3,4,9-tetrahydro-1H-carbazole

Conditions

Conditions	Yield
Stage #1: 1-bromocyclohex-1-ene; N'-(4-methoxyphenyl)-N'-methylacetohydrazide With copper(l) iodide; potassium carbonate; N,N-dimethylethylenediamine In toluene at 110℃; for 24h; Fischer Indole Synthesis; Schlenk technique; Inert atmosphere; Stage #2: With zinc(II) chloride In toluene at 90℃; for 1h; Fischer Indole Synthesis;	86%

: 2044-08-8
1-bromocyclohex-1-ene

: 75-56-9, 16033-71-9
methyloxirane

: 24826-68-4
1-(cyclohex-1-en-1-yl)propan-2-ol

Conditions

Conditions	Yield
With pyridine; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 4,4'-bipyridine; NiI2*3.9H2O; triethylamine hydrochloride; sodium iodide; zinc at 20℃; for 12h;	86%

: 2044-08-8
1-bromocyclohex-1-ene

: 80841-44-7
potassium 2-nitro-3-methylbenzoate

: 1609102-34-2
1-cyclohexenyl-3-methyl-2-nitrobenzene

Conditions

Conditions	Yield
With 1,10-Phenanthroline; palladium(II) hexafluoroacetylacetonate; tri-1-napthylphosphine; copper(l) chloride In 1-methyl-pyrrolidin-2-one; 1,3,5-trimethyl-benzene at 130℃; for 16h; Inert atmosphere; regiospecific reaction;	86%

1-Bromo-1-cyclohexene Specification

The 1-Bromo-1-cyclohexene, with the CAS registry number 2044-08-8.It belongs to the product Organic matters. This chemical's molecular formula is C₆H₉Br and molecular weight is 161.03. What's more, Its systematic name is 1-Bromocyclohexene.

Physical properties about 1-Bromo-1-cyclohexene are: (1)ACD/LogP: 3.076; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.08; (4)ACD/LogD (pH 7.4): 3.08; (5)ACD/BCF (pH 5.5): 128.19; (6)ACD/BCF (pH 7.4): 128.19; (7)ACD/KOC (pH 5.5): 1123.05; (8)ACD/KOC (pH 7.4): 1123.05; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 0; (12)Index of Refraction: 1.538; (13)Molar Refractivity: 35.056 cm³; (14)Molar Volume: 112.101 cm³; (15)Surface Tension: 37.5029983520508 dyne/cm; (16)Density: 1.437 g/cm³; (17)Flash Point: 58.157 °C; (18)Enthalpy of Vaporization: 38.52 kJ/mol; (19)Boiling Point: 165.211 °C at 760 mmHg; (20)Vapour Pressure: 2.48900008201599 mmHg at 25°C;

You can still convert the following datas into molecular structure:
(1)SMILES:Br\C1=C\CCCC1;
(2)Std. InChI:InChI=1S/C6H9Br/c7-6-4-2-1-3-5-6/h4H,1-3,5H2;
(3)Std. InChIKey:QBUMXSSCYUMVAW-UHFFFAOYSA-N.

Product Name

1-Bromocyclohex-1-ene

Synthetic route

1-Bromo-1-cyclohexene Specification

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