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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(E)-Tiglaldehyde

Cas:497-03-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Product number 35881 English Name TRANS-2-METHYL-2-BUTENAL CAS Number 497-03-0 Purity 98% Molecula

TRANS-2-METHYL-2-BUTENAL Cas no.497-03-0 98%

Cas:497-03-0

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 497-03-0 with best quality

Cas:497-03-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2-Butenal, 2-methyl-,(2E)-

Cas:497-03-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Butenal, 2-methyl-,(2E)-

Cas:497-03-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:497-03-0

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance: clear colorless to yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates

2-methyl-2-butenal

Cas:497-03-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-methyl-2-butenal

Cas:497-03-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

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TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: TRANS-2-METHYL-2-BUTENAL Synonyms: (2E)-2-Methyl-2-butenal;(E)-2-Methyl-2-butenal;(E)-2-methylbut-2-en-1-al;(E)-2-methylbut-2-enal;2,2-Dimethylacrolein;2-Butenal,2-methyl-,(2E)-;2-Butenal,2-methyl-,(E)-;2-methyl-(E)-2-but

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:1 Metric Ton

FOB Price: $20.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Tiglic Aldehyde

Cas:497-03-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Tiglic aldehyde

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec trans-2-Methyl-2-butenal 5ml

Cas:497-03-0

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

trans-2-Methyl-2-butenal

Cas:497-03-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

trans-2-Methyl-2-butenal

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Trans-2-methyl-2-butenal

Cas:497-03-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL Application:TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

TIANFUCHEM--High purity 497-03-0 TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:White to Off-White Solid Storage:Keep it in dry,shady and cool place Package:as your requirement Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by Sea

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

TRANS-2-METHYL-2-BUTENAL

Cas:497-03-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

497-03-0

Cas:497-03-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

2-Butenal, 2-methyl-,(2E)-

Cas:497-03-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

(E)-2-methyl-2-buten-1-ol
497-02-9

(E)-2-methyl-2-buten-1-ol

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With dipyridinium dichromate In dichloromethane Inert atmosphere; Molecular sieve;95%
dimethylacetylene
503-17-3

dimethylacetylene

carbon monoxide
201230-82-2

carbon monoxide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With C34H51NP2; hydrogen; palladium(II) acetylacetonate; toluene-4-sulfonic acid In tetrahydrofuran at 100℃; under 30003 Torr; for 10h; Schlenk technique; Autoclave; Inert atmosphere; stereoselective reaction;87%
With acetylacetonatodicarbonylrhodium(l); C21H10F12NOP; hydrogen In toluene at 55℃; under 3750.38 Torr; for 20h; stereoselective reaction;78%
Tiglic acid
80-59-1

Tiglic acid

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran at 0℃; for 2h;81%
With Bis(N-methylpiperazinyl) aluminum hydride In tetrahydrofuran for 6h; Heating;72%
2-methyl-3-ethoxybutanal
64197-53-1

2-methyl-3-ethoxybutanal

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II) In dichloromethane for 36h; Ambient temperature;80%
With toluene-4-sulfonic acid at 180℃;
isoprene epoxide
1838-94-4

isoprene epoxide

A

2,5-dihydro-3-methyl-furan
1708-31-2

2,5-dihydro-3-methyl-furan

B

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
tetra-n-heptylammonium iodide; tributyltin iodide In para-xylene at 119℃; for 2h; Heating / reflux;A 40.8%
B 9.2%
carbon monoxide
201230-82-2

carbon monoxide

isoprene epoxide
1838-94-4

isoprene epoxide

A

5-methyl-3,6-dihydro-pyran-2-one
60920-98-1

5-methyl-3,6-dihydro-pyran-2-one

B

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

C

isoprene
78-79-5

isoprene

Conditions
ConditionsYield
With dicobalt octacarbonyl at 85℃; under 150012 Torr;A 37%
B 13%
C 19%
isoprene epoxide
1838-94-4

isoprene epoxide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
HRh(PPh3)4 In benzene at 105℃; for 3h;35%
rhodium hydrido (PEt3)3 complex In benzene at 105℃; for 3h; sealed tube;35%
(2S,4S)-carveol
7632-16-8

(2S,4S)-carveol

(+)-trans-carveol
2102-58-1

(+)-trans-carveol

A

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

B

butene-2
107-01-7

butene-2

C

acetaldehyde
75-07-0

acetaldehyde

D

isoprene
78-79-5

isoprene

Conditions
ConditionsYield
at 560℃; under 170 Torr;
acetaldehyde
75-07-0

acetaldehyde

propionaldehyde
123-38-6

propionaldehyde

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

1-methylprop-1-enyltributyltin
86633-14-9, 86633-15-0, 859828-60-7

1-methylprop-1-enyltributyltin

A

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

B

(Z)-2-methyl-2-butenal
6038-09-1

(Z)-2-methyl-2-butenal

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at -78℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

dibutylbis(1-methyl-1-propenyl)stannane

dibutylbis(1-methyl-1-propenyl)stannane

A

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

B

(Z)-2-methyl-2-butenal
6038-09-1

(Z)-2-methyl-2-butenal

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at -78℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
hydrogenchloride
7647-01-0

hydrogenchloride

isoprene epoxide
1838-94-4

isoprene epoxide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

isoprene epoxide
1838-94-4

isoprene epoxide

diluted aqueous sulfuric acid

diluted aqueous sulfuric acid

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

ethylacrolein
922-63-4

ethylacrolein

CaCl2

CaCl2

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
und Destillation;
selenium(IV) oxide
7446-08-4

selenium(IV) oxide

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

benzene
71-43-2

benzene

A

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

B

2-methyl-2-buten-1-ol
497-02-9, 19319-26-7, 4675-87-0

2-methyl-2-buten-1-ol

C

isoprene
78-79-5

isoprene

D

bis-<2-methyl-buten-(2)-yl-(1)>-selenide

bis-<2-methyl-buten-(2)-yl-(1)>-selenide

hydrogenchloride
7647-01-0

hydrogenchloride

methanol
67-56-1

methanol

(E)-1,4-diacetoxy-2-methyl-2-butene
59054-99-8

(E)-1,4-diacetoxy-2-methyl-2-butene

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

3-hydroxy-2-methylbutanal
99506-67-9

3-hydroxy-2-methylbutanal

sulfuric acid
7664-93-9

sulfuric acid

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
Wasserdampfdestillation;
3-hydroxy-2-methylbutanal
99506-67-9

3-hydroxy-2-methylbutanal

water
7732-18-5

water

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

2-methyl-2-buten-1-ol
497-02-9, 19319-26-7, 4675-87-0

2-methyl-2-buten-1-ol

bromine
7726-95-6

bromine

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
und nachfolgendem Kochen mit Wasser;
diethyl ether
60-29-7

diethyl ether

3-hydroxy-2-methylbutanal
99506-67-9

3-hydroxy-2-methylbutanal

KOH-solution

KOH-solution

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
at 30℃;
carbon monoxide
201230-82-2

carbon monoxide

2-diphenylphosphanyl-benzoic acid 1-methyl-allyl ester

2-diphenylphosphanyl-benzoic acid 1-methyl-allyl ester

A

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

B

2-diphenylphosphanyl-benzoic acid 1,2-dimethyl-3-oxo-propyl ester

2-diphenylphosphanyl-benzoic acid 1,2-dimethyl-3-oxo-propyl ester

C

2-diphenylphosphanyl-benzoic acid 1-methyl-4-oxo-butyl ester

2-diphenylphosphanyl-benzoic acid 1-methyl-4-oxo-butyl ester

Conditions
ConditionsYield
With triphenyl phosphite; hydrogen; acetylacetonatodicarbonylrhodium(l) In toluene at 30℃; under 30002.4 Torr; for 46h; Title compound not separated from byproducts;
(E)-2-bromobut-2-ene
3017-71-8

(E)-2-bromobut-2-ene

carbon monoxide
201230-82-2

carbon monoxide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 5625.56 Torr; for 16h;98 % Chromat.
(Z)-2-Bromo-2-butene
3017-68-3

(Z)-2-Bromo-2-butene

carbon monoxide
201230-82-2

carbon monoxide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; hydrogen; catacxium A; palladium diacetate In toluene at 100℃; under 5625.56 Torr; for 16h;76 % Chromat.
1,1,3-triethoxy-2-methyl-butane
36551-27-6

1,1,3-triethoxy-2-methyl-butane

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous phosphoric acid; hydroquinone
2: toluene-4-sulfonic acid / 180 °C
View Scheme
1-acetoxyl-2-methyl-1,3-butadiene
86400-08-0

1-acetoxyl-2-methyl-1,3-butadiene

A

diacetoxy-2-methyl-1,3-butadiene

diacetoxy-2-methyl-1,3-butadiene

B

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

4-penten-3-one
1629-58-9

4-penten-3-one

acrolein
107-02-8

acrolein

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Ethyl tiglate
5837-78-5

Ethyl tiglate

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / diethyl ether / 20 °C / Inert atmosphere; Reflux
2: dipyridinium dichromate / dichloromethane / Inert atmosphere; Molecular sieve
View Scheme
With lithium aluminium tetrahydride Inert atmosphere;
formic acid
64-18-6

formic acid

dimethylacetylene
503-17-3

dimethylacetylene

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Conditions
ConditionsYield
With dicarbonylacetylacetonato rhodium (I); acetic anhydride; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 100℃; for 12h; Inert atmosphere; Sealed tube; Glovebox; Darkness; regioselective reaction;61 %Chromat.
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

trimethyl phosphonoacetate
5927-18-4

trimethyl phosphonoacetate

methyl (2E,4E)-4-methyl-2,4-hexadienoate
57258-50-1

methyl (2E,4E)-4-methyl-2,4-hexadienoate

Conditions
ConditionsYield
Stage #1: trimethyl phosphonoacetate With sodium hydride In benzene at 20℃; for 1.33333h;
Stage #2: 2-methylbut-2-enal In benzene for 0.5h; Heating;
100%
With sodium hydride 1.) THF, 2.) RT, 9 h; Multistep reaction;
With sodium hydride In benzene at 65℃; for 4h;37.82 g
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Chlorodifluoromethyl n-hexyl ketone
86340-68-3

Chlorodifluoromethyl n-hexyl ketone

(E)-5,5-difluoro-4-hydroxy-3-methyl-2-dodecen-6-one
115818-45-6

(E)-5,5-difluoro-4-hydroxy-3-methyl-2-dodecen-6-one

Conditions
ConditionsYield
With copper(l) chloride; zinc In tetrahydrofuran Heating;100%
With molecular sieve; copper(l) chloride; zinc In diethyl ether for 3h; Heating;100%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine
35019-66-0

(4S,5S)-2,2-dimethyl-4-phenyl-1,3-dioxan-5-amine

C17H23NO2

C17H23NO2

Conditions
ConditionsYield
With trifluoroacetic anhydride In benzene for 5h; Inert atmosphere; Dean-Stark; Reflux;100%
ethyl 3-pyrrolidinobut-2-enoate
2723-42-4, 54716-02-8, 70526-06-6

ethyl 3-pyrrolidinobut-2-enoate

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

5-Methyl-3-((1E,3E)-3-methyl-penta-1,3-dienyl)-isoxazole-4-carboxylic acid ethyl ester

5-Methyl-3-((1E,3E)-3-methyl-penta-1,3-dienyl)-isoxazole-4-carboxylic acid ethyl ester

Conditions
ConditionsYield
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane 1.) 0 deg C, 20 min, 2.) -78 deg C, 2 h, 3.) warm to room temperature, 10 h;99%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

(E)-3-methyl-2-(trimethylsilyloxy)pent-3-enenitrile
74149-67-0

(E)-3-methyl-2-(trimethylsilyloxy)pent-3-enenitrile

Conditions
ConditionsYield
With potassium carbonate at 20℃; for 6h; Inert atmosphere; Neat (no solvent);99%
With tetra-(n-butyl)ammonium iodide92%
With zinc(II) iodide
With zinc(II) iodide
With potassium cyanide; 18-crown-6 ether In dichloromethane
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

(1S,2R,3S,4S)-2,3-dimethylbicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

(1S,2R,3S,4S)-2,3-dimethylbicyclo[2.2.1]hept-5-ene-2-carboxaldehyde

Conditions
ConditionsYield
With (R)-3,3'-bis(2-hydroxyphenyl)-2,2'-dihydroxy-1,1'-binaphthyl-boric acid In tetrahydrofuran; dichloromethane at -78℃; for 4h;99%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

(1S,2R,3S,4R)-2,3-Dimethyl-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde

(1S,2R,3S,4R)-2,3-Dimethyl-bicyclo[2.2.1]hept-5-ene-2-carbaldehyde

Conditions
ConditionsYield
With (R)-3,3'-di(2-hydroxyphenyl)-2,2'-dihydroxy-1,1'-binaphthyl*B(OMe)3 In tetrahydrofuran; dichloromethane at -78℃; for 4h;99%
With (R)-3-(2-hydroxy-3-phenylphenyl)-2,2'-dihydroxy-1,1'-binaphthyl*3,5-bis(trifluoromethyl)benzeneboronic acid at -78℃; for 50h;90%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

benzenesulfonyl cyanide
24224-99-5

benzenesulfonyl cyanide

5-methyl-2-benzenesulfonyl-pyridine

5-methyl-2-benzenesulfonyl-pyridine

Conditions
ConditionsYield
With boric acid In toluene; butan-1-ol99%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

boric acid tributyl ester
688-74-4

boric acid tributyl ester

benzenesulfonyl cyanide
24224-99-5

benzenesulfonyl cyanide

5-methyl-2-benzenesulfonyl-pyridine

5-methyl-2-benzenesulfonyl-pyridine

Conditions
ConditionsYield
In toluene; butan-1-ol99%
In toluene; butan-1-ol99%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

N-methylaniline hydrochloride
2739-12-0

N-methylaniline hydrochloride

(E)-N-methyl-N-(2-methylbut-2-enyl)benzenamine

(E)-N-methyl-N-(2-methylbut-2-enyl)benzenamine

Conditions
ConditionsYield
Stage #1: 2-methylbut-2-enal; N-methylaniline hydrochloride In methanol at 20℃; for 1h;
Stage #2: With triethylsilane; indium(III) chloride In methanol at 20℃; for 24h;
99%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

Camphor
76-22-2

Camphor

(1S,4S)-3-((E)-1-Hydroxy-2-methyl-but-2-enyl)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

(1S,4S)-3-((E)-1-Hydroxy-2-methyl-but-2-enyl)-1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one

Conditions
ConditionsYield
98%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

1-(N-triisopropylsilyl-1H-indol-3-yl)-N,N-dimethylmethanamine
146886-51-3

1-(N-triisopropylsilyl-1H-indol-3-yl)-N,N-dimethylmethanamine

(E)-3-dimethylaminomethyl-4-(1-hydroxy-2-methyl-2-butenyl)-1-triisopropylsilyl-1H-indole
468077-81-8

(E)-3-dimethylaminomethyl-4-(1-hydroxy-2-methyl-2-butenyl)-1-triisopropylsilyl-1H-indole

Conditions
ConditionsYield
Stage #1: 1-(N-triisopropylsilyl-1H-indol-3-yl)-N,N-dimethylmethanamine With tert.-butyl lithium In diethyl ether at -78 - 0℃;
Stage #2: 2-methylbut-2-enal In diethyl ether at -78 - 20℃;
98%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

ethyl (2E,4E)-4-methylhexa-2,4-dienoate
149400-42-0, 90107-62-3

ethyl (2E,4E)-4-methylhexa-2,4-dienoate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 312h; Wittig Olefination;98%
In dichloromethane at 20℃;67%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

(E)-trimethyl(2-methylbuta-1,3-dienyloxy)silane
54623-57-3

(E)-trimethyl(2-methylbuta-1,3-dienyloxy)silane

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 5h;98%
diethoxyphosphoryl-acetic acid ethyl ester
867-13-0

diethoxyphosphoryl-acetic acid ethyl ester

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

ethyl (2E,4E)-4-methylhexa-2,4-dienoate
149400-42-0, 90107-62-3

ethyl (2E,4E)-4-methylhexa-2,4-dienoate

Conditions
ConditionsYield
Stage #1: diethoxyphosphoryl-acetic acid ethyl ester With sodium hydride In tetrahydrofuran at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 2-methylbut-2-enal In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
97%
With potassium tert-butylate In tetrahydrofuran at 20℃;90%
With sodium ethanolate In tetrahydrofuran at -20℃; for 0.5h;90.8%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

2-Iodomethyl-oxazole-4-carboxylic acid ethyl ester

2-Iodomethyl-oxazole-4-carboxylic acid ethyl ester

2-((1E,3E)-3-Methyl-penta-1,3-dienyl)-oxazole-4-carboxylic acid ethyl ester

2-((1E,3E)-3-Methyl-penta-1,3-dienyl)-oxazole-4-carboxylic acid ethyl ester

Conditions
ConditionsYield
With lithium diisopropyl amide; triethylphosphine In N,N-dimethyl-formamide Product distribution; trans/cis selectivity; var. phosphines;97%
With lithium diisopropyl amide; triethylphosphine 1.) DMF; 2.) DMF; Yield given. Multistep reaction;
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

phenyllithium
591-51-5

phenyllithium

α-(1-methyl-1-propenyl)benzenemethanol
80317-46-0

α-(1-methyl-1-propenyl)benzenemethanol

Conditions
ConditionsYield
In tetrahydrofuran at 0℃; for 4h;96%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

N-isopropyl oxazolidinone
77877-19-1

N-isopropyl oxazolidinone

(4S,2'S,3'S,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-isopropyl-2-oxazolidinone
694440-08-9

(4S,2'S,3'S,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-isopropyl-2-oxazolidinone

Conditions
ConditionsYield
Stage #1: N-isopropyl oxazolidinone With di-n-butylboryl trifluoromethanesulfonate; triethylamine In dichloromethane at -3℃; for 1h;
Stage #2: 2-methylbut-2-enal In dichloromethane at -78 - 0℃; for 2h;
Stage #3: With dihydrogen peroxide In methanol; phosphate buffer; dichloromethane at 0℃; for 1h; pH=7; Further stages.;
96%
Stage #1: N-isopropyl oxazolidinone With di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; for 0.5h;
Stage #2: 2-methylbut-2-enal In dichloromethane at -78 - 20℃; for 2h;
Stage #3: With dihydrogen peroxide In methanol; phosphate buffer; dichloromethane at 0℃; for 1h; pH=7;
94%
Stage #1: N-isopropyl oxazolidinone With di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine In diethyl ether; dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 2-methylbut-2-enal In diethyl ether; dichloromethane at -78 - 20℃; for 2h;
N-methylmaleimide
930-88-1

N-methylmaleimide

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

phenylacetyl chloride
103-80-0

phenylacetyl chloride

2,3,3a,4,7,7a-hexahydro-2,6-dimethyl-1,3-dioxo-1H-isoindol-7-yl 2-phenylacetate

2,3,3a,4,7,7a-hexahydro-2,6-dimethyl-1,3-dioxo-1H-isoindol-7-yl 2-phenylacetate

Conditions
ConditionsYield
Stage #1: 2-methylbut-2-enal; phenylacetyl chloride With potassium n-butoxide In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: N-methylmaleimide In tetrahydrofuran at 60℃; for 16h;
96%
Benzyl N-hydroxycarbamate
3426-71-9

Benzyl N-hydroxycarbamate

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

benzyl 5-hydroxy-3,4-dimethylisoxazolidin-2-carboxylate

benzyl 5-hydroxy-3,4-dimethylisoxazolidin-2-carboxylate

Conditions
ConditionsYield
With pyrrolidine In chloroform at 20℃; for 144h;96%
1-ethenylcyclohexene
931-49-7

1-ethenylcyclohexene

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

(4E)-1-cyclohexenyl-4-methylhex-4-en-1-yn-3-ol
1237836-86-0

(4E)-1-cyclohexenyl-4-methylhex-4-en-1-yn-3-ol

Conditions
ConditionsYield
Stage #1: 1-ethenylcyclohexene With n-butyllithium In diethyl ether; hexane at -78℃; Inert atmosphere;
Stage #2: 2-methylbut-2-enal In diethyl ether; hexane at -78 - 20℃; Inert atmosphere;
95%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

benzylamine
100-46-9

benzylamine

Benzyl-((E)-2-methyl-but-2-enyl)-amine
107175-79-1

Benzyl-((E)-2-methyl-but-2-enyl)-amine

Conditions
ConditionsYield
Stage #1: 2-methylbut-2-enal; benzylamine With magnesium sulfate In dichloromethane at 20℃; for 1h; Inert atmosphere;
Stage #2: With sodium tetrahydroborate In methanol at 0 - 20℃; for 16h; Inert atmosphere;
95%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

allyl bromide
106-95-6

allyl bromide

(E)-5-methyl-1,5-heptadien-4-ol
62036-50-4

(E)-5-methyl-1,5-heptadien-4-ol

Conditions
ConditionsYield
With zinc In diethyl ether at 0℃; for 6h;94%
With diethyl ether; zinc
Stage #1: allyl bromide With indium(III) chloride; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran for 0.5h;
Stage #2: 2-methylbut-2-enal In tetrahydrofuran at 25℃; for 0.5h;
91 %Chromat.
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

(4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one
77877-20-4

(4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one

(4R,5S,2'R,3'R,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-methyl-5-phenyl-2-oxazolidinone
694440-05-6

(4R,5S,2'R,3'R,4'E)-3-(2',4'-dimethyl-3'-hydroxy-1'-oxo-4'-hexenyl)-4-methyl-5-phenyl-2-oxazolidinone

Conditions
ConditionsYield
Stage #1: (4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one With di-n-butylboryl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; for 0.5h;
Stage #2: 2-methylbut-2-enal In dichloromethane at -78 - 20℃; for 2h; pH=7;
Stage #3: With dihydrogen peroxide In phosphate buffer; dichloromethane at 0℃; for 1h;
94%
Stage #1: (4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one With di-n-butylboryl trifluoromethanesulfonate; triethylamine In dichloromethane at -10 - 0℃; for 2.08333h;
Stage #2: 2-methylbut-2-enal In dichloromethane at -78 - 20℃;
89%
Stage #1: (4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one With di-n-butylboryl trifluoromethanesulfonate; triethylamine In dichloromethane at 0℃; for 1h;
Stage #2: 2-methylbut-2-enal In dichloromethane at -78 - 0℃; for 2h;
Stage #3: With dihydrogen peroxide In methanol; phosphate buffer; dichloromethane at 0℃; for 1h; pH=7; Further stages.;
88%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

mesityllithium
5806-59-7

mesityllithium

E-1-mesityl-2-methyl-2-buten-1-ol
84061-27-8

E-1-mesityl-2-methyl-2-buten-1-ol

Conditions
ConditionsYield
94%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

methyl 2-(triphenylphosphoranylidene)propionate
2605-68-7

methyl 2-(triphenylphosphoranylidene)propionate

(E,E)-methyl 2,4-dimethylhexa-2,4-dienoate
102103-76-4

(E,E)-methyl 2,4-dimethylhexa-2,4-dienoate

Conditions
ConditionsYield
In dichloromethane for 48h; Heating;94%
In dichloromethane for 48h; Heating;73%
In dichloromethane at 40℃; for 18h;70%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

phenethylmagnesium chloride
90878-19-6

phenethylmagnesium chloride

(+/-)-(E)-4-methyl-1-phenylhex-4-en-3-ol
181573-12-6

(+/-)-(E)-4-methyl-1-phenylhex-4-en-3-ol

Conditions
ConditionsYield
Stage #1: 2-methylbut-2-enal; phenethylmagnesium chloride In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere;
Stage #2: With ammonium chloride In tetrahydrofuran; water at 0℃;
94%
In tetrahydrofuran at 0 - 20℃;82%
2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

n-octyne
629-05-0

n-octyne

(E)-3-methyldodec-2-en-5-yn-4-ol
1237836-84-8

(E)-3-methyldodec-2-en-5-yn-4-ol

Conditions
ConditionsYield
Stage #1: n-octyne With n-butyllithium In diethyl ether; hexane at -78℃; Inert atmosphere;
Stage #2: 2-methylbut-2-enal In diethyl ether; hexane at -78 - 20℃; Inert atmosphere;
94%
1,3 dithiane
505-23-7

1,3 dithiane

2-methylbut-2-enal
497-03-0

2-methylbut-2-enal

(E)-1-(1,3-dithian-2-yl)-2-methylbut-2-en-1-ol
1351557-44-2

(E)-1-(1,3-dithian-2-yl)-2-methylbut-2-en-1-ol

Conditions
ConditionsYield
Stage #1: 1,3 dithiane With n-butyllithium In tetrahydrofuran; hexane at -20℃; for 1h; Inert atmosphere;
Stage #2: 2-methylbut-2-enal In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
94%

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