1-Bromotridecane supplier | CasNO.765-09-3

Name
1-Bromotridecane
EINECS 212-138-0
CAS No. 765-09-3
Article Data24
CAS DataBase
Density 1.03
Solubility
Melting Point 4-7 °C(lit.)
Formula C13H27 Br
Boiling Point 148-150 °C10 mm Hg(lit.)
Molecular Weight 263.261
Flash Point 110 ºC
Transport Information
Appearance light yellow liquid
Safety Poison by intravenous route. When heated to decomposition it emits toxic vapors of Br⁻.
Risk Codes R22;R37/38;R41
Molecular Structure
Hazard Symbols
Synonyms 1-Bromo-n-tridecane;1-Bromotridecane; NSC 87870; Tridecyl bromide; n-Tridecyl bromide
PSA 0.00000
LogP 5.69230

Synthetic route

: 544-63-8
n-tetradecanoic acid

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With bromine; mercury(II) oxide In tetrachloromethane for 1.5h; Heating;	92%
With [bis(acetoxy)iodo]benzene; bromine In various solvent(s) for 22h; bromodecarboxylation; Heating; irradiation;	79%
(i) TlOEt, (ii) Br2; Multistep reaction;
With bromine; thallium (I) ethoxide 1.) hexane, 2.) reflux, 3 h; Yield given. Multistep reaction;
Multi-step reaction with 2 steps 1: oxalyl dichloride; N,N-dimethyl-formamide 2: dmap; Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt / 4 h / Reflux View Scheme

: 112-70-9
tridecan-1-ol

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With carbon tetrabromide In dichloromethane at -30 - 20℃;	88%
With hydrogen bromide at 100℃;
With hydrogen bromide

: 68975-76-8
formaldehyde ditridecylacetal

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With phosphorus pentabromide; benzene

: 2437-56-1
1-tridecene

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With hydrogen bromide; dihydrogen peroxide

1-benzamino-tridecane: 1-benzamino-tridecane

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With phosphorus pentabromide

: 2437-56-1
1-tridecene

: 10035-10-6, 12258-64-9
hydrogen bromide

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
in Gegenwart von Peroxyden;

: 68975-76-8
formaldehyde ditridecylacetal

: 7789-69-7
phosphorus pentabromide

: 71-43-2
benzene

: 765-09-3
1-bromotridecane

...Expand

mercury (II)-salt of/the/ myristic acid: mercury (II)-salt of/the/ myristic acid

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With tetrachloromethane; bromine

silver salt of/the/ myristic acid: silver salt of/the/ myristic acid

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With bromine
With tetrachloromethane; bromine
With bromine

silver-salt of/the/ myristic acid: silver-salt of/the/ myristic acid

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With Trichloroethylene; bromine

: 112-64-1
tetradecanoyl chloride

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
With dmap; Bromotrichloromethane; 2-mercaptopyridine-1-oxide sodium salt for 4h; Hunsdiecker-Borodin reaction; Reflux;

: 112-44-7
undecylaldehyde

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: dichloromethane / 20 °C 2: 10% Pd/C; hydrogen / ethanol / 20 °C 3: lithium aluminium tetrahydride / diethyl ether / 0 - 20 °C 4: carbon tetrabromide / dichloromethane / -30 - 20 °C View Scheme

: 671787-02-3
(E)-Tridec-2-enoic acid ethyl ester

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 10% Pd/C; hydrogen / ethanol / 20 °C 2: lithium aluminium tetrahydride / diethyl ether / 0 - 20 °C 3: carbon tetrabromide / dichloromethane / -30 - 20 °C View Scheme

: 28267-29-0
ethyl tridecanoate

: 765-09-3
1-bromotridecane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: lithium aluminium tetrahydride / diethyl ether / 0 - 20 °C 2: carbon tetrabromide / dichloromethane / -30 - 20 °C View Scheme

: 765-09-3
1-bromotridecane

: 6089-04-9
3-(tetrahydropyran-2'-yloxy)propyne

: 119290-95-8
2-(hexadec-2-yn-1-yloxy)tetrahydro-2H-pyran

Conditions

Conditions	Yield
With n-butyllithium at -30℃; for 1h;	100%
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Stage #2: 1-bromotridecane In tetrahydrofuran at 20℃; for 21h;	76%
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: 1-bromotridecane With N,N,N,N,N,N-hexamethylphosphoric triamide In tetrahydrofuran; hexane at -78℃; for 24h;	60%
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium 1.) THF; Multistep reaction;
Stage #1: 3-(tetrahydropyran-2'-yloxy)propyne With n-butyllithium In tetrahydrofuran; hexane at 0℃; Stage #2: 1-bromotridecane In tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; hexane at 40℃; for 24h;

: 765-09-3
1-bromotridecane

: 17356-08-0
thiourea

: BrH*C14H30N2S

Conditions

Conditions	Yield
In ethanol for 18h; Reflux;	100%
In ethanol for 12h; Reflux;

: 765-09-3
1-bromotridecane

: 6195-80-8
2,4-bis(benzyloxy)phenol

: 2,4-dibenzyloxy-1-tridecyloxybenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 50℃;	100%

: 50541-93-0
4-amino-1-benzylpiperidine

: 765-09-3
1-bromotridecane

: (1-benzyl-4-piperidinyl)tridecylamine

Conditions

Conditions	Yield
With triethylamine In acetonitrile for 3h; Heating;	99%

: 765-09-3
1-bromotridecane

: 33329-35-0
N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethylpropane-1,3-diamine

: C54H117N4(3+)*3Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 24h; Reflux;	99%

: 765-09-3
1-bromotridecane

: 2,4-di-(azetidin-1-yl)-6-methylpyrimidine

: 2,4-di-(azetidin-1-yl)-6-tetradecylpyrimidine

Conditions

Conditions	Yield
Stage #1: 2,4-di-(azetidin-1-yl)-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.25h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere;	98%
Stage #1: 2,4-di-(azetidin-1-yl)-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Inert atmosphere;	98%

: 765-09-3
1-bromotridecane

: 70277-75-7
lithium acetylide

: 765-13-9
pentadec-1-yne

Conditions

Conditions	Yield
With ethylenediamine In dimethyl sulfoxide at 0 - 20℃;	97.9%
In dimethyl sulfoxide at 20℃; for 1h;	91%

: 765-09-3
1-bromotridecane

: 40501-41-5
methyl 4'-hydroxy-4-biphenylcarboxylate

: 1439362-30-7
4'-tridecyloxy-biphenyl-4-carboxylic acid methyl ester

Conditions

Conditions	Yield
Stage #1: methyl 4'-hydroxy-4-biphenylcarboxylate With potassium carbonate; caesium carbonate In acetone for 0.0833333h; Inert atmosphere; Stage #2: 1-bromotridecane In acetone for 72h; Inert atmosphere; Reflux;	97.3%

: 765-09-3
1-bromotridecane

: 1666-13-3
diphenyl diselenide

: Phenyl 1-tridecyl selenide

Conditions

Conditions	Yield
Stage #1: diphenyl diselenide With sodium tetrahydroborate In tetrahydrofuran; ethanol Reduction; Stage #2: 1-bromotridecane In tetrahydrofuran; ethanol at 60℃; Substitution;	97%

: 765-09-3
1-bromotridecane

: 611-10-9
2-ethoxycarbonyl-1-cyclopentanone

: 1428444-37-4
ethyl 2-oxo-1-n-tridecylcyclopentanecarboxylate

Conditions

Conditions	Yield
Stage #1: 2-ethoxycarbonyl-1-cyclopentanone With potassium carbonate; potassium iodide In acetone for 0.166667h; Stage #2: 1-bromotridecane In acetone at 62℃; for 20h;	97%

: 883196-20-1
3-(3,4-trihydroxyphenyl)propionic acid methyl ester

: 765-09-3
1-bromotridecane

: 1342314-02-6
3-(3,4,5-tris-tridecyloxyphenyl)propionic acid methyl ester

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 75℃; for 8h; Inert atmosphere;	96%

: 765-09-3
1-bromotridecane

: 75-04-7
ethylamine

: N-ethyltridecan-1-amine

Conditions

Conditions	Yield
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;	96%

: 765-09-3
1-bromotridecane

: 16691-43-3
5-amino-3-mercapto-4H-[1,2,4]triazole

: 183793-94-4
5-Tridecylsulfanyl-4H-[1,2,4]triazol-3-ylamine

Conditions

Conditions	Yield
With triethylamine In acetonitrile for 2h; Heating;	95%

: 765-09-3
1-bromotridecane

: 20541-49-5
bis(p-chlorophenyl) diselenide

: 4-Chlorophenyl 1-tridecyl selenide

Conditions

Conditions	Yield
Stage #1: bis(p-chlorophenyl) diselenide With sodium tetrahydroborate In tetrahydrofuran; ethanol Reduction; Stage #2: 1-bromotridecane In tetrahydrofuran; ethanol at 60℃; Substitution;	95%

: 765-09-3
1-bromotridecane

: 4-(azetidin-1-yl)-2-cyclobutanoxy-6-methylpyrimidine

: 4-(azetidin-1-yl)-2-cyclobutanoxy-6-tetradecylpyrimidine

Conditions

Conditions	Yield
Stage #1: 4-(azetidin-1-yl)-2-cyclobutanoxy-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.25h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere;	95%
Stage #1: 4-(azetidin-1-yl)-2-cyclobutanoxy-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Inert atmosphere;	95%

: 765-09-3
1-bromotridecane

: 100-46-9
benzylamine

: N-benzyltridecan-1-amine

Conditions

Conditions	Yield
In tetrahydrofuran at 0 - 20℃; Inert atmosphere;	94%

: 17252-51-6
1,3-di(4-pyridyl)propane

: 765-09-3
1-bromotridecane

: C39H68N2(2+)*2Br(1-)

Conditions

Conditions	Yield
In acetonitrile Reflux;	93%
In acetonitrile Reflux;	93%

: 765-09-3
1-bromotridecane

: 93367-10-3
(2S,3S)-3,4-epoxy-1,2-di-O-isopropylidenebutane-1,2-diol

: 1344994-22-4
(S)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)pentadecan-1-ol

Conditions

Conditions	Yield
Stage #1: 1-bromotridecane With magnesium In tetrahydrofuran Stage #2: With copper(l) cyanide In tetrahydrofuran at -20℃; for 0.5h; Stage #3: (2S,3S)-3,4-epoxy-1,2-di-O-isopropylidenebutane-1,2-diol regioselective reaction; Further stages;	92%

: 765-09-3
1-bromotridecane

: 22323-78-0
(1R,2R)-1,2-bis((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethane-1,2-diol

: 3,4-O-di-tridecyl-1,2:5,6-di-O-isopropylidene-D-mannitol

Conditions

Conditions	Yield
Stage #1: (1R,2R)-1,2-bis((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethane-1,2-diol With sodium hydride In N,N-dimethyl-formamide for 0.5h; Cooling with ice; Stage #2: 1-bromotridecane In N,N-dimethyl-formamide at 20℃; for 4h;	92%

: 765-09-3
1-bromotridecane

: 2,4-dicyclobutanoxy-6-methylpyrimidine

: 2,4-dicyclobutanoxy-6-tetradecylpyrimidine

Conditions

Conditions	Yield
Stage #1: 2,4-dicyclobutanoxy-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.25h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere;	92%
Stage #1: 2,4-dicyclobutanoxy-6-methylpyrimidine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: 1-bromotridecane In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Inert atmosphere;	92%

: 4792-15-8
Pentaethylene glycol

: 765-09-3
1-bromotridecane

: tridecyl pentaethylene glycol ether

Conditions

Conditions	Yield
With sodium hydride In water at 66℃; for 12h; Temperature; Solvent; Cooling with ice;	91.1%

: 765-09-3
1-bromotridecane

: 1633-78-9
6-mercapto-1-hexanol

: 6-(tridecylthio)hexan-1-ol

Conditions

Conditions	Yield
Stage #1: 6-mercapto-1-hexanol With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide at 20℃; for 0.333333h; Stage #2: 1-bromotridecane In N,N-dimethyl-formamide at 65℃; for 3h;	91%

: 765-09-3
1-bromotridecane

: 603-35-0
triphenylphosphine

: 13266-02-9
n-tridecyltriphenylphosphonium bromide

Conditions

Conditions	Yield
In acetonitrile for 24h; Heating;	90%
In toluene for 26h; Inert atmosphere; Reflux;	85%
In toluene Reflux;	85%

: 104-19-8
N-methyl-N'-(2-dimethylaminoethyl)piperazine

: 765-09-3
1-bromotridecane

: C35H75N3(2+)*2Br(1-)

Conditions

Conditions	Yield
In acetonitrile Reflux;	90%
In acetonitrile Reflux;	90%

: 765-09-3
1-bromotridecane

: 3414-94-6
3-phenyl-4,5-dihydro-1H-1,2,4-triazole-5-thione

: 3-phenyl-5-tridecylsulfanyl-1H-[1,2,4]triazole

Conditions

Conditions	Yield
With tetrabutylammomium bromide; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 24h;	89%

: 765-09-3
1-bromotridecane

: 105-53-3
diethyl malonate

: 41240-46-4
diethyl 2-tridecylmalonate

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran; N,N-dimethyl-formamide at 0 - 60℃; for 18h;	88%
With sodium hydride In tetrahydrofuran at 0 - 70℃; for 18.6667h; Inert atmosphere;	75%
(i) Na, (ii) /BRN= 1739992/; Multistep reaction;

: 765-09-3
1-bromotridecane

: 1333499-12-9
tris(tert-butyldimethylsilyloxy)tris(methoxymethoxy)dehydrobenzo[12]annulene

: C69H102O9

Conditions

Conditions	Yield
With cesium fluoride In N,N-dimethyl-formamide at 70℃; for 5.5h; Inert atmosphere; Schlenk technique;	88%

: 765-09-3
1-bromotridecane

: 169238-10-2
(4R,5R)-5-benzyloxy-4-ethynyl-2,2-dimethyl-1,3-dioxane

: 161459-67-2
(4R,5R)-5-benzyloxy-4-(pentadec-1-ynyl)-2,2-dimethyl-1,3-dioxane

Conditions

Conditions	Yield
With n-butyllithium	87%
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 10.5h; Alkylation;	87%

1-Bromotridecane Chemical Properties

Chemical Name: 1-Bromotridecane
IUPAC NAME: 1-Bromotridecane
CAS No.: 765-09-3
EINECS: 212-138-0
RTECS: YD3100000
Molecular Formula: C₁₃H₂₇Br
Molecular Weight: 263.26 g/mol
Melting Point: 4-7 °C(lit.)
Density: 1.027 g/cm³
Flash Point: 120.4 °C
Boiling Point: 292.3 °C at 760 mmHg
Following is the structure of 1-Bromotridecane (CAS No.765-09-3):

Product Categories about 1-Bromotridecane (CAS No.765-09-3) are Alkyl Bromides ; Monofunctional & alpha,omega-Bifunctional Alkanes ; Monofunctional Alkanes
The chemical synonymous of 1-Bromotridecane (CAS No.765-09-3) are 1-Bromo-Tridecan ; N-Tridecyl-1-Bromide ; Tridecane,1-Bromo- ; 1-Bromotridecane ; Tridecyl Bromide ; N-Tridecyl Bromide ; 1-Bromotridecane,99%

1-Bromotridecane Toxicity Data With Reference

ivn-mus LD50:180 mg/kg

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#03504 .

1-Bromotridecane Consensus Reports

Reported in EPA TSCA Inventory.

1-Bromotridecane Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic vapors of Br⁻.
Hazard Codes: Harmful Xn
Risk Statements about 1-Bromotridecane (CAS No.765-09-3):
R22:Harmful if swallowed.
R41:Risk of serious damage to the eyes.
R37/38:Irritating to respiratory system and skin.
Safety Statements about 1-Bromotridecane (CAS No.765-09-3):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S39:Wear eye / face protection.
Attention:
1. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Avoid ingestion and inhalation. Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation.

Product Name

1-Bromotridecane

Synthetic route

1-Bromotridecane Chemical Properties

1-Bromotridecane Toxicity Data With Reference

1-Bromotridecane Consensus Reports

1-Bromotridecane Safety Profile

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