Product Name

  • Name

    1-Iodobutane

  • EINECS 208-824-4
  • CAS No. 542-69-8
  • Article Data120
  • CAS DataBase
  • Density 1.622 g/cm3
  • Solubility Insoluble in water.
  • Melting Point -103 °C(lit.)
  • Formula C4H9I
  • Boiling Point 130.9 °C at 760 mmHg
  • Molecular Weight 184.02
  • Flash Point 33.3 °C
  • Transport Information UN 1993 3/PG 3
  • Appearance liquid
  • Safety 16-36-36/37/39-26
  • Risk Codes 10-20-36/37/38-20/22
  • Molecular Structure Molecular Structure of 542-69-8 (1-Iodobutane)
  • Hazard Symbols HarmfulXn
  • Synonyms Butyl iodide;1-Iodobutane Butyl iodide;1-Butyliodide;Butane,1-iodo-;1-Jodbutan [Czech];
  • PSA 0.00000
  • LogP 2.22150

Synthetic route

butan-1-ol
71-36-3

butan-1-ol

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With potassium iodide In acetonitrile at 20℃; for 0.25h;95%
With iodine; triphenylphosphine at 20℃; for 0.133333h; Ionic liquid;91%
With hydrogen iodide at 120℃; for 4h;80%
pentan-1-ol
71-41-0

pentan-1-ol

A

2-methyltetrahydrofuran
96-47-9

2-methyltetrahydrofuran

B

1-iodo-butane
542-69-8

1-iodo-butane

C

pentanal
110-62-3

pentanal

Conditions
ConditionsYield
With N-iodo-succinimide In chlorobenzene for 2h; Irradiation;A 94%
B 1%
C n/a
With N-iodo-succinimide In chlorobenzene for 2h; Product distribution; Irradiation; var. irradiat. times, temps. and light cond.;A 94%
B 1%
C n/a
dibutyl ether
142-96-1

dibutyl ether

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With hexaethylbisphosphonium bistriiodide Heating;88%
With phosphoric acid; potassium iodide
N-isobutylideneethylamine
1743-56-2

N-isobutylideneethylamine

dibutyl phosphoriodidite
59611-99-3

dibutyl phosphoriodidite

A

1-iodo-butane
542-69-8

1-iodo-butane

B

2-butoxy-1,4-diethyl-3,5-diisopropyl-1,4,2-diazaphospholidine 2-oxide

2-butoxy-1,4-diethyl-3,5-diisopropyl-1,4,2-diazaphospholidine 2-oxide

Conditions
ConditionsYield
In diethyl ether for 2h; Ambient temperature;A n/a
B 85%
1-bromo-butane
109-65-9

1-bromo-butane

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With I*2H2O In toluene at 150℃; Rate constant;80%
With I*2H2O In toluene at 150℃;80%
With sodium iodide In acetone Substitution;64%
n-Butyldiphenylsulfoniumperchlorat

n-Butyldiphenylsulfoniumperchlorat

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With potassium iodide In dichloromethane; water at 20℃; for 0.15h;78%
With potassium iodide In dichloromethane; water at 20℃; for 0.15h; Product distribution; further diphenylalkylsulfonium salts, further K salts and other nucleophiles;78%
tetra-(n-butyl)ammonium iodide
311-28-4

tetra-(n-butyl)ammonium iodide

A

1-iodo-butane
542-69-8

1-iodo-butane

B

tributyl-amine
102-82-9

tributyl-amine

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate In acetone at 320℃; Product distribution; in a gas chromatograph; other temperature; various concentration of reagent;A 77%
B n/a
tributyl-amine
102-82-9

tributyl-amine

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; sodium iodide In acetone Reflux;70%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

acetyl iodide
507-02-8

acetyl iodide

A

vinyl acetate
108-05-4

vinyl acetate

B

1-iodo-butane
542-69-8

1-iodo-butane

C

vinyliodide
593-66-8

vinyliodide

D

acetic acid butyl ester
123-86-4

acetic acid butyl ester

Conditions
ConditionsYield
In dichloromethane at 10℃;A 11.8%
B 12.8%
C 35.8%
D 39.8%
n-Butyl chloride
109-69-3

n-Butyl chloride

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With iron pentacarbonyl; iodoform In N,N-dimethyl-formamide 1.) 70-90 deg C, 1 h, 2.) 80-90, 1 h;37%
With ethylene glycol; potassium iodide
With iodine; iron pentacarbonyl at 85 - 90℃; for 1.5h; further reagent; Yield given;
n-butane
106-97-8

n-butane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

2-butyl iodide
513-48-4, 52152-71-3

2-butyl iodide

Conditions
ConditionsYield
With tert-butylhypochlorite; mercury(II) iodide In 1,1,2-Trichloro-1,2,2-trifluoroethane at 47℃; for 8h; Irradiation; Yield given;A n/a
B 35%
With tert-butylhypochlorite; mercury(II) iodide In 1,1,2-Trichloro-1,2,2-trifluoroethane at 47℃; for 8h; Irradiation;A n/a
B 35%
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

diiodomethane
75-11-6

diiodomethane

(1Z)-N-(3-ethynylphenyl)-2,2,2-trifluoroethanimidoyl chloride

(1Z)-N-(3-ethynylphenyl)-2,2,2-trifluoroethanimidoyl chloride

A

1-iodo-butane
542-69-8

1-iodo-butane

B

N,N'-[(2Z,4Z)-1,1,1,5,5,5-hexafluoro-2-penten-2-yl-4-ylidene]bis(3-ethynylaniline)

N,N'-[(2Z,4Z)-1,1,1,5,5,5-hexafluoro-2-penten-2-yl-4-ylidene]bis(3-ethynylaniline)

Conditions
ConditionsYield
Stage #1: diiodomethane; (1Z)-N-(3-ethynylphenyl)-2,2,2-trifluoroethanimidoyl chloride With methyllithium lithium bromide In tetrahydrofuran; diethyl ether at -78℃; for 0.5h;
Stage #2: n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -78℃; for 0.5h;
A 25%
B 31%
tetrahydrofuran
109-99-9

tetrahydrofuran

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With phosphoric acid; potassium iodide
dibutyl hydrogen phosphite
1809-19-4

dibutyl hydrogen phosphite

A

1-iodo-butane
542-69-8

1-iodo-butane

B

Phosphoric acid mono-n-butylester
16456-56-7

Phosphoric acid mono-n-butylester

Conditions
ConditionsYield
With hydrogen iodide
butyl para-toluenesulfonate
778-28-9

butyl para-toluenesulfonate

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With water; potassium iodide
With tetra-(n-butyl)ammonium iodide In acetone at 210℃; Product distribution; ina gas chromatograph;
butyl methyl ether
628-28-4

butyl methyl ether

chloro-acetyl iodide
191340-22-4

chloro-acetyl iodide

A

butyl chloroacetate
590-02-3

butyl chloroacetate

B

1-iodo-butane
542-69-8

1-iodo-butane

C

methyl iodide
74-88-4

methyl iodide

dibutyl ether
142-96-1

dibutyl ether

acetyl iodide
507-02-8

acetyl iodide

A

1-iodo-butane
542-69-8

1-iodo-butane

B

acetic acid butyl ester
123-86-4

acetic acid butyl ester

Conditions
ConditionsYield
at 25℃; unter Lichtausschluss;
dibutyl ether
142-96-1

dibutyl ether

butyl 2,4,6-trimethylbenzoate
70116-77-7

butyl 2,4,6-trimethylbenzoate

phenylmagnesium iodide
16002-63-4

phenylmagnesium iodide

A

1-iodo-butane
542-69-8

1-iodo-butane

B

biphenyl
92-52-4

biphenyl

C

mesitylenecarboxylic acid
480-63-7

mesitylenecarboxylic acid

Conditions
ConditionsYield
anschliessend Behandeln mit wss. Schwefelsaeure;
1-butyl-3-propyl-imidazolium; iodide
65039-16-9

1-butyl-3-propyl-imidazolium; iodide

A

1-propyl-1H-imidazole
35203-44-2

1-propyl-1H-imidazole

B

1-Butylimidazole
4316-42-1

1-Butylimidazole

C

1-iodo-butane
542-69-8

1-iodo-butane

D

1-iodo-propane
107-08-4

1-iodo-propane

Conditions
ConditionsYield
at 260 - 300℃; im Vakuum;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

ethyl iodide
75-03-6

ethyl iodide

A

1-iodo-butane
542-69-8

1-iodo-butane

B

ethyllithium
811-49-4

ethyllithium

Conditions
ConditionsYield
reversible Reaktion;
ethene
74-85-1

ethene

ethyl iodide
75-03-6

ethyl iodide

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With water; dibenzoyl peroxide at 95℃; unter hohem Druck;
3-ethyl-1-butyl-imidazolium; iodide
65039-17-0

3-ethyl-1-butyl-imidazolium; iodide

A

N-Ethylimidazole
7098-07-9

N-Ethylimidazole

B

1-Butylimidazole
4316-42-1

1-Butylimidazole

C

1-iodo-butane
542-69-8

1-iodo-butane

D

ethyl iodide
75-03-6

ethyl iodide

Conditions
ConditionsYield
at 260 - 300℃; im Vakuum;
1-bromo-butane
109-65-9

1-bromo-butane

iodo(trimethylsilyl)methane
4206-67-1

iodo(trimethylsilyl)methane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

(bromomethyl)trimethylsilane
18243-41-9

(bromomethyl)trimethylsilane

Conditions
ConditionsYield
With triisooctyl amine Equilibrium constant;
1-butylene
106-98-9

1-butylene

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With borane; iodine; sodium methylate 1.) THF, 25 deg C, 1 h, 2.) MeOH, 24 h; Yield given. Multistep reaction;
1,4-Diiodobutane
628-21-7

1,4-Diiodobutane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
With sodium hydroxide; nickel tetraaza macrocycle; water at 25℃;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With tri-n-butylstannylmethyl iodide
(Z)-2-Butene
590-18-1

(Z)-2-Butene

1-iodo-butane
542-69-8

1-iodo-butane

Conditions
ConditionsYield
With borane; iodine; sodium methylate 1.) THF, 25 deg C, 1 h, 2.) MeOH, 24 h; Yield given. Multistep reaction;
n-Butyl chloride
109-69-3

n-Butyl chloride

iodo(trimethylsilyl)methane
4206-67-1

iodo(trimethylsilyl)methane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

Conditions
ConditionsYield
With triisooctyl amine Equilibrium constant;
dibutyl ethylphosphonite
24603-81-4

dibutyl ethylphosphonite

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

A

1-iodo-butane
542-69-8

1-iodo-butane

B

butyl ethyl(heptafluoropropyl)phosphinate
77529-58-9

butyl ethyl(heptafluoropropyl)phosphinate

Conditions
ConditionsYield
In octane Rate constant; Kinetics; Thermodynamic data; E (activ.); ΔH(excit.); ΔS(excit.); ΔG(excit.);
1-iodo-butane
542-69-8

1-iodo-butane

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 25℃; for 1h; Product distribution; var. aralkyl halides, rates of reduction;100%
With sodium ammonium; ammonia
With aluminium amalgam
N-methylcyclohexylamine
626-67-5

N-methylcyclohexylamine

1-iodo-butane
542-69-8

1-iodo-butane

1-butyl-1-methylpiperidinium iodide
37971-78-1

1-butyl-1-methylpiperidinium iodide

Conditions
ConditionsYield
In chloroform at 60℃; for 6h;100%
In chloroform Heating;
1-iodo-butane
542-69-8

1-iodo-butane

potassium pyrrolide
16199-06-7

potassium pyrrolide

N-butylpyrrole
589-33-3

N-butylpyrrole

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 16h;100%
1-iodo-butane
542-69-8

1-iodo-butane

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phospha-bicyclo[3.3.3]undecane 1-sulfide
127491-67-2

2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phospha-bicyclo[3.3.3]undecane 1-sulfide

1-Butylsulfanyl-2,8,9-trimethyl-2,8,9-triaza-5-azonia-1λ5-phospha-tricyclo[3.3.3.01,5]undecane; iodide

1-Butylsulfanyl-2,8,9-trimethyl-2,8,9-triaza-5-azonia-1λ5-phospha-tricyclo[3.3.3.01,5]undecane; iodide

Conditions
ConditionsYield
In acetonitrile at 50 - 55℃; for 96h;100%
1-iodo-butane
542-69-8

1-iodo-butane

C10H21N4PS2

C10H21N4PS2

1-Butylsulfanylthiocarbonyl-2,8,9-trimethyl-2,5,8,9-tetraaza-1-phosphonia-bicyclo[3.3.3]undecane; iodide

1-Butylsulfanylthiocarbonyl-2,8,9-trimethyl-2,5,8,9-tetraaza-1-phosphonia-bicyclo[3.3.3]undecane; iodide

Conditions
ConditionsYield
In [D3]acetonitrile100%
1-iodo-butane
542-69-8

1-iodo-butane

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie
176100-94-0

O,O-diethyltrimethylsilylchloromethylphosphonate α-lithie

(1-Chloro-1-trimethylsilanyl-pentyl)-phosphonic acid diethyl ester
118512-69-9

(1-Chloro-1-trimethylsilanyl-pentyl)-phosphonic acid diethyl ester

Conditions
ConditionsYield
In tetrahydrofuran; hexane for 1h; Ambient temperature;100%
1-iodo-butane
542-69-8

1-iodo-butane

1-amino-3-methylbenzene
108-44-1

1-amino-3-methylbenzene

N-butyl-N-(3-methyl-n-propyl)-m-toluidine
74878-72-1

N-butyl-N-(3-methyl-n-propyl)-m-toluidine

Conditions
ConditionsYield
With sodium acetate at 130 - 140℃; for 4h;100%
quindoline
243-58-3

quindoline

1-iodo-butane
542-69-8

1-iodo-butane

5-Butyl-10H-indolo[3,2-b]quinolin-5-ium; iodide

5-Butyl-10H-indolo[3,2-b]quinolin-5-ium; iodide

Conditions
ConditionsYield
at 135℃; for 15h;100%
1-iodo-butane
542-69-8

1-iodo-butane

N-benzyl-N'-dodecyl-thiourea
102463-72-9

N-benzyl-N'-dodecyl-thiourea

C24H43N2S(1+)*I(1-)

C24H43N2S(1+)*I(1-)

Conditions
ConditionsYield
In methanol100%
1-iodo-butane
542-69-8

1-iodo-butane

to 2b

to 2b

C42H80N4S2(2+)*2I(1-)

C42H80N4S2(2+)*2I(1-)

Conditions
ConditionsYield
In methanol100%
1-iodo-butane
542-69-8

1-iodo-butane

Cyclobutanecarboxylic acid
3721-95-7

Cyclobutanecarboxylic acid

1-butylcyclobutane carboxylic acid
58148-13-3

1-butylcyclobutane carboxylic acid

Conditions
ConditionsYield
Stage #1: Cyclobutanecarboxylic acid With lithium diethylamide In tetrahydrofuran; n-heptane; ethylbenzene at 0 - 20℃; for 2h;
Stage #2: 1-iodo-butane In tetrahydrofuran; n-heptane; ethylbenzene at 20℃;
100%
With lithium diisopropyl amide In tetrahydrofuran at 20℃; for 12h;
Stage #1: Cyclobutanecarboxylic acid With lithium diisopropyl amide In tetrahydrofuran; hexane at -78 - 20℃; for 1h;
Stage #2: 1-iodo-butane In tetrahydrofuran at 0 - 20℃; for 12h;
1-iodo-butane
542-69-8

1-iodo-butane

4-(6-hydroxy-7-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester
634198-18-8

4-(6-hydroxy-7-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester

4-(6-butoxy-7-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester
634198-06-4

4-(6-butoxy-7-methoxy-4-quinazolinyl)-1-piperazinecarboxylic acid tert-butyl ester

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;100%
1-iodo-butane
542-69-8

1-iodo-butane

2-imidazolecarbaldehyde
10111-08-7

2-imidazolecarbaldehyde

1-n-butyl-1H-imidazole-2-carbaldehyde
169378-52-3

1-n-butyl-1H-imidazole-2-carbaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide100%
Stage #1: 2-imidazolecarbaldehyde With potassium carbonate In N,N-dimethyl-formamide
Stage #2: 1-iodo-butane
82%
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 50℃; for 6h;
With potassium carbonate In N,N-dimethyl-formamide at 80℃;
C14H18N2O2
938169-94-9

C14H18N2O2

1-iodo-butane
542-69-8

1-iodo-butane

C18H26N2O2

C18H26N2O2

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 4h; Heating;100%
1-iodo-butane
542-69-8

1-iodo-butane

(4aS,7S,7aR)-2-n-butyl-4,7-dimethyl-2,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyridin-1-one

(4aS,7S,7aR)-2-n-butyl-4,7-dimethyl-2,4a,5,6,7,7a-hexahydro-1H-cyclopenta[c]pyridin-1-one

Conditions
ConditionsYield
Stage #1: (4aS,7S,7aR)-nepetalactam With potassium hydride In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: 1-iodo-butane In tetrahydrofuran at 0 - 20℃; for 1h;
100%
Cyclopentyl bromide
137-43-9

Cyclopentyl bromide

1-iodo-butane
542-69-8

1-iodo-butane

2-butoxy-1-methoxy-4-nitro-benzene
205067-45-4

2-butoxy-1-methoxy-4-nitro-benzene

Conditions
ConditionsYield
100%
1-iodo-butane
542-69-8

1-iodo-butane

2Li(1+)*GeC4(C6H5)4(2-)=Li2GeC4(C6H5)4

2Li(1+)*GeC4(C6H5)4(2-)=Li2GeC4(C6H5)4

1,1-dibutyl-2,3,4,5-tetraphenylgermole
122951-51-3

1,1-dibutyl-2,3,4,5-tetraphenylgermole

Conditions
ConditionsYield
In not given100%
1-iodo-butane
542-69-8

1-iodo-butane

2,6-bis(1H-benzo[d]imidazol-1-yl)pyridine
1030366-99-4

2,6-bis(1H-benzo[d]imidazol-1-yl)pyridine

bis(N-butylbenzimidazolium)-2,6-pyridine diiodide

bis(N-butylbenzimidazolium)-2,6-pyridine diiodide

Conditions
ConditionsYield
at 160℃; for 30h; Inert atmosphere; Neat (no solvent); Sealed tube;100%
at 160℃; for 30h;
1-iodo-butane
542-69-8

1-iodo-butane

C10H7F7OSe
1092379-00-4

C10H7F7OSe

butyl phenyl selenide
28622-61-9

butyl phenyl selenide

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 0.25h;100%
1-vinylimidazole
1072-63-5

1-vinylimidazole

1-iodo-butane
542-69-8

1-iodo-butane

1-vinyl-3-butyl-3H-imidazol-1-ium iodide
45965-87-5

1-vinyl-3-butyl-3H-imidazol-1-ium iodide

Conditions
ConditionsYield
In toluene at 110℃; for 24h;100%
for 5h; Inert atmosphere; Reflux;96%
In tert-butyl methyl ether at 20℃; for 312h;83%
In tetrahydrofuran at 20℃; for 24h;31%
Reflux;
1-iodo-butane
542-69-8

1-iodo-butane

2-bromo-N-(4-ethylphenyl)benzamide
296273-16-0

2-bromo-N-(4-ethylphenyl)benzamide

2-bromo-N-butyl-N-(4-ethylphenyl)benzamide

2-bromo-N-butyl-N-(4-ethylphenyl)benzamide

Conditions
ConditionsYield
Stage #1: 2-bromo-N-(4-ethylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide; mineral oil at 0℃;
100%
Stage #1: 2-bromo-N-(4-ethylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide
1-iodo-butane
542-69-8

1-iodo-butane

2-bromo-N-(4-tert-butylphenyl)benzamide
852686-98-7

2-bromo-N-(4-tert-butylphenyl)benzamide

2-bromo-N-butyl-N-(4-tert-butylphenyl)benzamide

2-bromo-N-butyl-N-(4-tert-butylphenyl)benzamide

Conditions
ConditionsYield
Stage #1: 2-bromo-N-(4-tert-butylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide; mineral oil at 0℃;
100%
Stage #1: 2-bromo-N-(4-tert-butylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide
1-iodo-butane
542-69-8

1-iodo-butane

2-bromo-N-(4-methylphenyl)benzamide
136926-09-5

2-bromo-N-(4-methylphenyl)benzamide

2-bromo-N-butyl-N-p-tolylbenzamide

2-bromo-N-butyl-N-p-tolylbenzamide

Conditions
ConditionsYield
Stage #1: 2-bromo-N-(4-methylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 0.5h; Inert atmosphere;
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide; mineral oil at 0℃;
100%
Stage #1: 2-bromo-N-(4-methylphenyl)benzamide With sodium hydride In N,N-dimethyl-formamide
Stage #2: 1-iodo-butane In N,N-dimethyl-formamide
1-iodo-butane
542-69-8

1-iodo-butane

tert-butyl (3-perfluorooctyl)propoxycarbamate
1228692-98-5

tert-butyl (3-perfluorooctyl)propoxycarbamate

C20H24F17NO3
1228693-15-9

C20H24F17NO3

Conditions
ConditionsYield
With caesium carbonate In acetonitrile at 45℃; for 2h;100%
1-iodo-butane
542-69-8

1-iodo-butane

sodium 1-thio-β-D-glucopyranoside
10593-29-0

sodium 1-thio-β-D-glucopyranoside

n-butyl 1-thio-β-D-glucopyranoside
85618-17-3

n-butyl 1-thio-β-D-glucopyranoside

Conditions
ConditionsYield
In methanol at 20℃; for 1h;100%
1-iodo-butane
542-69-8

1-iodo-butane

1,3-bis(2,6-diiopropylphenyl)imidazol-2-ylidene borane
956972-12-6

1,3-bis(2,6-diiopropylphenyl)imidazol-2-ylidene borane

1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene boryl iodide
1207374-64-8

1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene boryl iodide

Conditions
ConditionsYield
In benzene byproducts: C12H26; 1 equiv of borane and 1 equiv of C4H9I were heated in C6H6 at 180°C for 72 h; filtered;100%
1-iodo-butane
542-69-8

1-iodo-butane

(E)-N-(benzimidazol-1-yl)-1-(4-methoxyphenyl)methanimine

(E)-N-(benzimidazol-1-yl)-1-(4-methoxyphenyl)methanimine

(E)-N-(3-butylbenzimidazol-3-ium-1-yl)-1-(4-methoxyphenyl)methanimine iodide

(E)-N-(3-butylbenzimidazol-3-ium-1-yl)-1-(4-methoxyphenyl)methanimine iodide

Conditions
ConditionsYield
at 100℃; for 5h;100%
for 5h; Reflux; Inert atmosphere;99%
1-iodo-butane
542-69-8

1-iodo-butane

(E)-N-(benzimidazol-1-yl)-1-(4-bromo-2-thienyl)methanimine

(E)-N-(benzimidazol-1-yl)-1-(4-bromo-2-thienyl)methanimine

(E)-1-(4-bromo-2-thienyl)-N-(3-butylbenzimidazol-3-ium-1-yl)methanimine iodide

(E)-1-(4-bromo-2-thienyl)-N-(3-butylbenzimidazol-3-ium-1-yl)methanimine iodide

Conditions
ConditionsYield
at 100℃; for 5h;100%
1-iodo-butane
542-69-8

1-iodo-butane

(E)-N-(benzimidazol-1-yl)-1-(p-tolyl)methanimine

(E)-N-(benzimidazol-1-yl)-1-(p-tolyl)methanimine

(E)-N-(3-butylbenzimidazol-3-ium-1-yl)-1-(p-tolyl)methanimine iodide

(E)-N-(3-butylbenzimidazol-3-ium-1-yl)-1-(p-tolyl)methanimine iodide

Conditions
ConditionsYield
at 100℃; for 5h;100%
1-iodo-butane
542-69-8

1-iodo-butane

N-(benzimidazol-1-yl)-1-(4-nitrophenyl)methanimine
81949-16-8

N-(benzimidazol-1-yl)-1-(4-nitrophenyl)methanimine

N-(3-butylbenzimidazol-3-ium-1-yl)-1-(4-nitrophenyl)methanimine iodide
1289374-93-1

N-(3-butylbenzimidazol-3-ium-1-yl)-1-(4-nitrophenyl)methanimine iodide

Conditions
ConditionsYield
at 100℃; for 5h;100%

1-Iodobutane Specification

1.Introduction of 1-Iodobutane

1-Iodobutane, with its CAS register No 542-69-8, is a kind of colorless or pale orange clear liquid. It has synonyms of Butyl iodide;1-Iodobutane Butyl iodide;1-Butyliodide;Butane,1-iodo- and 1-Jodbutan [Czech]. 1-Iodobutane should be stored in shady and cool warehouse and mainly used as solvent.

2.Properties of 1-Iodobutane

(1) Freely Rotating Bonds: 2 (2) Polar Surface Area: 0 Å2 (3) Index of Refraction: 1.503 (4) Molar Refractivity: 33.54 cm3
(5) Molar Volume: 113.3 cm3 (6) Polarizability: 13.3 ×10-24cm3 (7) Surface Tension: 29.9 dyne/cm (8) Density: 1.622 g/cm3
(9) Flash Point: 33.3 °C  (10) Enthalpy of Vaporization: 34.66 kJ/mol  (11) Boiling Point: 130.9 °C at 760 mmHg
(12) Vapour Pressure: 11.7 mmHg at 25°C


3.Structure descriptors of 1-Iodobutane

SMILES:ICCCC

Std. InChI:InChI=1S/C4H9I/c1-2-3-4-5/h2-4H2,1H3

Std. InChIKey:KMGBZBJJOKUPIA-UHFFFAOYSA-N


4.Safety information of   1-Iodobutane

Hazard Codes: HarmfulXn
Risk Statements: 10-20-36/37/38-20/22
R10: Flammable.
R20: Harmful by inhalation.
R36/37/38: Irritating to eyes, respiratory system and skin.
R20/22: Harmful by inhalation and if swallowed.
Safety Statements: 16-36-36/37/39-26
S16: Keep away from sources of ignition.
S36: Wear suitable protective clothing.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
RTECS: EK4400000
F: 8
HazardClass: 3
PackingGroup: III
HS Code: 29033080
 

5.Toxicity date of 1-Iodobutane

1.    

mouseLD50:101 mg/kg

    "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 30, 1982.
2.    

ratLD50:6100mg/m3/4H

    "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 756, 1969.
3.    

ratLD50:692mg/kg

    "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 30, 1982.

 

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