Product Name

  • Name

    1-PIPERONYLPIPERAZINE

  • EINECS 250-968-5
  • CAS No. 32231-06-4
  • Article Data15
  • CAS DataBase
  • Density 1.203 g/cm3
  • Solubility Slightly soluble in water
  • Melting Point 36-40 °C(lit.)
  • Formula C12H16N2O2
  • Boiling Point 330.5 °C at 760 mmHg
  • Molecular Weight 220.271
  • Flash Point 158.4 °C
  • Transport Information
  • Appearance white to yellow or yellow-brownish cryst. solid
  • Safety 26-37/39
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 32231-06-4 (1-PIPERONYLPIPERAZINE)
  • Hazard Symbols IrritantXi
  • Synonyms Piperazine,1-piperonyl- (7CI,8CI);1-(1,3-Benzodioxolan-5-ylmethyl)piperazine;1-(3,4-Methylenedioxybenzyl)piperazine;1-(4-Piperonyl)piperazine;1-(Benzo[1,3]dioxol-5-ylmethyl)piperazine;1-(Benzodioxol-5-ylmethyl)piperazine;1-[(2H-1,3-Benzodioxol-5-yl)methyl]piperazine;1-[(Benzo[d][1,3]dioxol-5-yl)methyl]piperazine;4-(4-Piperonyl)piperazine;4-[(Benzodioxol-5-yl)methyl]piperazine;5-(Piperazinomethyl)-1,3-benzodioxole;N-Piperonylpiperazine;N-[(1,3-Benzodioxol-5-yl)methyl]piperazine;1-(3,4-Methylenedioxyphenylmethyl)piperazine;
  • PSA 33.73000
  • LogP 1.08720

Synthetic route

piperazine
110-85-0

piperazine

piperonol
495-76-1

piperonol

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

Conditions
ConditionsYield
In o-xylene at 150℃; for 30h; Inert atmosphere; Sealed tube;81%
With aluminum (III) chloride; water In acetonitrile at 20℃; Irradiation;41%
1-(1,3-benzodioxol-5-ylmethyl)-4-[(2-nitrophenyl)methyl]piperazine

1-(1,3-benzodioxol-5-ylmethyl)-4-[(2-nitrophenyl)methyl]piperazine

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

Conditions
ConditionsYield
With hydrazine In 1,4-dioxane; water Inert atmosphere; UV-irradiation;80%
piperazine
110-85-0

piperazine

piperonal
120-57-0

piperonal

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

Conditions
ConditionsYield
With palladium 10% on activated carbon; hydrogen In tert-butyl methyl ether at 13 - 18℃; High pressure;78%
piperazine
110-85-0

piperazine

5-(chloromethyl)-1,3-benzodioxole
20850-43-5

5-(chloromethyl)-1,3-benzodioxole

piperazine dihydrochloride
142-64-3

piperazine dihydrochloride

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

Conditions
ConditionsYield
Stage #1: piperazine; piperazine dihydrochloride In ethanol at 65℃; for 1h;
Stage #2: 5-(chloromethyl)-1,3-benzodioxole In ethanol at 78℃; for 2h;
...Expand
benzyl 4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazine-1-carboxylate

benzyl 4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazine-1-carboxylate

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

Conditions
ConditionsYield
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 2h;
4-chloro-6-dimethylamino-3-methylisoxazolo[5,4-d]pyrimidine
724428-97-1

4-chloro-6-dimethylamino-3-methylisoxazolo[5,4-d]pyrimidine

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

6-dimethylamino-3-methyl-4-(3,4-methylenedioxybenzylpiperazino)isoxazolo[5,4-d]pyrimidine

6-dimethylamino-3-methyl-4-(3,4-methylenedioxybenzylpiperazino)isoxazolo[5,4-d]pyrimidine

Conditions
ConditionsYield
In tetrahydrofuran Heating;99%
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

tert-butyl 4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazine-1-carboxylate
1233143-33-3

tert-butyl 4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazine-1-carboxylate

Conditions
ConditionsYield
With triethylamine In methanol at 20℃; for 1.5h; Inert atmosphere;99%
p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-tosylpiperazine
305859-64-7

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-tosylpiperazine

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 4.5h; Inert atmosphere;99%
carbon dioxide
124-38-9

carbon dioxide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

C13H16N2O3

C13H16N2O3

Conditions
ConditionsYield
With hydrogen In methanol at 120℃; under 30003 Torr; for 24h; Autoclave;99%
dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

tetramethyl 2,2'-(1,4-piperazindiyl)dimaleate
24726-53-2

tetramethyl 2,2'-(1,4-piperazindiyl)dimaleate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 1h;98%
2-chloropyrimidine
1722-12-9

2-chloropyrimidine

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

piribedil
3605-01-4

piribedil

Conditions
ConditionsYield
With C50H61Cl2N3Pd; potassium tert-butylate In 1,4-dioxane at 100℃; for 2h;98%
With C48H55ClN2Pd; sodium t-butanolate In 1,2-dimethoxyethane at 20℃; for 16h; Inert atmosphere; Sealed tube;98%
With potassium carbonate In tetrahydrofuran for 2h; Reflux;44%
4,6-dichloro-2,8-bis(dimethylamino)-5-phenyl-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
259654-07-4

4,6-dichloro-2,8-bis(dimethylamino)-5-phenyl-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

6-chloro-2,8-bis(dimethylamino)-5-phenyl-4-(4-piperonylpiperazino)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
259654-13-2

6-chloro-2,8-bis(dimethylamino)-5-phenyl-4-(4-piperonylpiperazino)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine

Conditions
ConditionsYield
In tetrahydrofuran Substitution; Heating;95%
p-tolylsulfinyl amide
6873-55-8

p-tolylsulfinyl amide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

C19H22N2O3S

C19H22N2O3S

Conditions
ConditionsYield
With europium(III) trifluoromethanesulfonate In acetonitrile at 50℃; for 24h; Inert atmosphere; Schlenk technique;95%
acetic anhydride
108-24-7

acetic anhydride

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

1-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)ethanone

1-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)ethanone

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 13h; Inert atmosphere;94%
(3αS,5αS,9βS)-5α,9-dimethyl-3-methylene-3α,5,5α,9β-tetrahydronaphtho[1,2-β]furan-2,8(3H,4H)-dione
66726-11-2

(3αS,5αS,9βS)-5α,9-dimethyl-3-methylene-3α,5,5α,9β-tetrahydronaphtho[1,2-β]furan-2,8(3H,4H)-dione

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

(3aS,5aS,9bS)-3-(4-benzo[1,3]dioxol-5-ylmethylpiperazin-1-ylmethyl)-5a,9-dimethyl-3a,5,5a,9b-tetrahydro-3H,4H-naphtho[1,2-b]furan-2,8-dione
1217269-74-3

(3aS,5aS,9bS)-3-(4-benzo[1,3]dioxol-5-ylmethylpiperazin-1-ylmethyl)-5a,9-dimethyl-3a,5,5a,9b-tetrahydro-3H,4H-naphtho[1,2-b]furan-2,8-dione

Conditions
ConditionsYield
In methanol at 20℃; Michael reaction; stereospecific reaction;94%
acrylonitrile
107-13-1

acrylonitrile

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

3-[4-[(benzo[1,3]dioxol-5-yl)methyl]piperazin-1-yl]propionitrile
385371-21-1

3-[4-[(benzo[1,3]dioxol-5-yl)methyl]piperazin-1-yl]propionitrile

Conditions
ConditionsYield
With triethylammonium acetate at 25℃; for 0.0166667h; Aza-Michael reaction; chemoselective reaction;93%
With multi-walled carbon nanotubes-triethylammonium hydrogen phosphate composite at 25℃; for 0.0166667h; Michael Addition; Green chemistry;93%
With single-walled carbon nanotube-triethylammonium hydrogen phosphate ionic liquid at 25℃; for 0.0166667h;94 %Chromat.
1-benzyl-1H-pyrrole-2,5-dione
1631-26-1

1-benzyl-1H-pyrrole-2,5-dione

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

3-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-1-benzylpyrrolidine-2,5-dione

3-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-1-benzylpyrrolidine-2,5-dione

Conditions
ConditionsYield
With triethylamine; lithium chloride In tetrahydrofuran at 23℃; for 1.5h; chemoselective reaction;93%
6-(2-bromoacetyl)-3-methylbenzo[d]oxazol-2(3H)-one
79851-85-7

6-(2-bromoacetyl)-3-methylbenzo[d]oxazol-2(3H)-one

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

6-[2-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-yl)-acetyl]-3-methyl-3H-benzooxazol-2-one

6-[2-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-yl)-acetyl]-3-methyl-3H-benzooxazol-2-one

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane for 8h; Ambient temperature;92%
6-benzoyl-2(3H)-benzoxazolone
54903-12-7

6-benzoyl-2(3H)-benzoxazolone

formaldehyd
50-00-0

formaldehyd

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

3-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-ylmethyl)-6-benzoyl-3H-benzooxazol-2-one

3-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-ylmethyl)-6-benzoyl-3H-benzooxazol-2-one

Conditions
ConditionsYield
In methanol for 1h; Heating;92%
...Expand
formaldehyd
50-00-0

formaldehyd

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-methylpiperazine
55500-12-4

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-methylpiperazine

Conditions
ConditionsYield
Stage #1: formaldehyd; 1-Piperonylpiperazine With sodium tris(acetoxy)borohydride; triethylamine In dichloromethane; water at 20℃; for 16.5h;
Stage #2: With sodium hydrogencarbonate In dichloromethane; water		92%
Cholesteryl chloroformate
7144-08-3

Cholesteryl chloroformate

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

cholest-5-en-3-yl 4-(1,3-benzodioxol-5-ylmethyl)-1-piperazinecarboxylate
1120327-24-3

cholest-5-en-3-yl 4-(1,3-benzodioxol-5-ylmethyl)-1-piperazinecarboxylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;92%
2,6-Dichloropyrimidine
3934-20-1

2,6-Dichloropyrimidine

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

piribedil
3605-01-4

piribedil

Conditions
ConditionsYield
With C34H52BrN3OPd In 1,4-dioxane at 90℃; for 3h; Inert atmosphere; Schlenk technique;92%
benzyl bromide
100-39-0

benzyl bromide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-benzylpiperazine
414876-23-6

1-(benzo[d][1,3]dioxol-5-ylmethyl)-4-benzylpiperazine

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 18.5h; Inert atmosphere;91%
2-Benzoxazolinone
59-49-4

2-Benzoxazolinone

formaldehyd
50-00-0

formaldehyd

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

3-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-ylmethyl)-3H-benzooxazol-2-one

3-(4-Benzo[1,3]dioxol-5-ylmethyl-piperazin-1-ylmethyl)-3H-benzooxazol-2-one

Conditions
ConditionsYield
In methanol for 1h; Heating;90%
...Expand
3-(4-chlorobutyl)-1,2,3-benzotriazin-4(3H)-one
158659-66-6

3-(4-chlorobutyl)-1,2,3-benzotriazin-4(3H)-one

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

3-[4-(4-benzo[1,3]dioxol-5-ylmethyl-piperazin-1-yl)-butyl]-3H-benzo[d][1,2,3]triazin-4-one; hydrochloride

3-[4-(4-benzo[1,3]dioxol-5-ylmethyl-piperazin-1-yl)-butyl]-3H-benzo[d][1,2,3]triazin-4-one; hydrochloride

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 80 - 120℃; for 1.16667h; microwave irradiation;90%
2-chloro-N-(4,5-dihydro-1-methyl-[1,2,4]-triazolo[4,3-a]quinolin-7-yl)acet-amide
1064703-56-5

2-chloro-N-(4,5-dihydro-1-methyl-[1,2,4]-triazolo[4,3-a]quinolin-7-yl)acet-amide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

C25H28N6O3
1064703-58-7

C25H28N6O3

Conditions
ConditionsYield
With sodium carbonate In methanol for 10h; Reflux;90%
7-chloro-1-(2,4-difluorophenyl)-1,4-dihydro-8-methyl-6-nitro-4-oxoquinolone-3-carboxylic acid
1146300-32-4

7-chloro-1-(2,4-difluorophenyl)-1,4-dihydro-8-methyl-6-nitro-4-oxoquinolone-3-carboxylic acid

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

7-(4-((benzo[d][1,3]dioxol-5-yl)methyl)piperazin-1-yl)-1-(2,4-difluorophenyl)-1,4-dihydro-8-methyl-6-nitro-4-oxoquinoline-3-carboxylic acid
1146300-53-9

7-(4-((benzo[d][1,3]dioxol-5-yl)methyl)piperazin-1-yl)-1-(2,4-difluorophenyl)-1,4-dihydro-8-methyl-6-nitro-4-oxoquinoline-3-carboxylic acid

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide Microwave irradiation;90%
6-(bromomethyl)-5-chloro-2-(thiophen-2-yl)-7,8-dihydroquinoline

6-(bromomethyl)-5-chloro-2-(thiophen-2-yl)-7,8-dihydroquinoline

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

6-((4-(benzo[d] [1,3]dioxol-5-ylmethyl)piperazinyl)methyl)-5-chloro-2-(thiophen-2-yl)-7,8-dihydroquinoline

6-((4-(benzo[d] [1,3]dioxol-5-ylmethyl)piperazinyl)methyl)-5-chloro-2-(thiophen-2-yl)-7,8-dihydroquinoline

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; for 12h;90%
1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

thioctic acid-N-hydroxysuccinimide ester
40846-94-4

thioctic acid-N-hydroxysuccinimide ester

1-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-5-(1,2-dithiolan-3-yl)pentan-1-one

1-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-5-(1,2-dithiolan-3-yl)pentan-1-one

Conditions
ConditionsYield
In dichloromethane at 20℃; for 5h; Inert atmosphere;89%
4-Fluoronitrobenzene
350-46-9

4-Fluoronitrobenzene

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

1-benzo[1,3]dioxol-5-ylmethyl-4-(4-nitro-phenyl)-piperazine

1-benzo[1,3]dioxol-5-ylmethyl-4-(4-nitro-phenyl)-piperazine

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃;89%
N-(3-chloropropyl)isonicotinamide

N-(3-chloropropyl)isonicotinamide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

N-(3-(4-(piperonyl)piperazin-1-yl)propyl)isonicotinamide

N-(3-(4-(piperonyl)piperazin-1-yl)propyl)isonicotinamide

Conditions
ConditionsYield
Stage #1: N-(3-chloropropyl)isonicotinamide With sodium iodide In acetonitrile at 70℃; for 0.5h;
Stage #2: 1-Piperonylpiperazine With potassium carbonate In acetonitrile at 70℃; for 24h;		89%
(R,2E,4E)-6-((tert-butyldimethylsilyl)oxy)-7-(3,4-dimethoxyphenyl)hepta-2,4-dienoic acid
1448848-29-0

(R,2E,4E)-6-((tert-butyldimethylsilyl)oxy)-7-(3,4-dimethoxyphenyl)hepta-2,4-dienoic acid

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

(R,2E,4E)-1-(4-(benzo[1,3]dioxol-5-ylmethyl)piperazin-1-yl)-6-((tert-butyldimethylsilyl)oxy)-7-(3,4-dimethoxyphenyl)-hepta-2,4-dien-1-one

(R,2E,4E)-1-(4-(benzo[1,3]dioxol-5-ylmethyl)piperazin-1-yl)-6-((tert-butyldimethylsilyl)oxy)-7-(3,4-dimethoxyphenyl)-hepta-2,4-dien-1-one

Conditions
ConditionsYield
Stage #1: (R,2E,4E)-6-((tert-butyldimethylsilyl)oxy)-7-(3,4-dimethoxyphenyl)hepta-2,4-dienoic acid With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0 - 20℃; Inert atmosphere;
Stage #2: 1-Piperonylpiperazine In N,N-dimethyl-formamide at 20℃; Inert atmosphere;		89%
1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

2-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)pyrazine

2-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)pyrazine

Conditions
ConditionsYield
With iodine; sodium acetate In acetonitrile at 70℃;89%
2-chloro-N-(4-sulfamoylbenzyl)acetamide
101167-02-6

2-chloro-N-(4-sulfamoylbenzyl)acetamide

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

2-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-N-(4-sulfamoylbenzyl)acetamide

2-(4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)-N-(4-sulfamoylbenzyl)acetamide

Conditions
ConditionsYield
With sodium carbonate In N,N-dimethyl-formamide at 100 - 120℃; Reflux;89%
formaldehyd
50-00-0

formaldehyd

propargyl ether mycophenolate

propargyl ether mycophenolate

1-Piperonylpiperazine
32231-06-4

1-Piperonylpiperazine

mycophenoyl methyl ester-7-(butynyloxy-N-(piperonylpiperazine))

mycophenoyl methyl ester-7-(butynyloxy-N-(piperonylpiperazine))

Conditions
ConditionsYield
With copper(l) iodide In 1,4-dioxane at 120℃; for 1h;89%
...Expand

1-PIPERONYLPIPERAZINE Chemical Properties

IUPAC Name: 1-(1,3-benzodioxol-5-ylmethyl)piperazine
The MF of 1-PIPERONYLPIPERAZINE(32231-06-4): C12H16N2O2
The MW of 1-PIPERONYLPIPERAZINE(32231-06-4): 220.27
EINECS: 250-968-5
mp: 36-40 °C(lit.)
bp: 147-149 °C at 2 mm Hg(lit.)
Fp: >230 °F
Density: 1.203 g/cm3 
Index of Refraction: 1.577 
Appearance: Crystalline mass.
Solubility in water: Very soluble
Categories: Pharmaceutical Raw Materials;Heterocycles;API intermediates;Building Blocks;Heterocyclic Building Blocks;Piperazines
Synonyms: 3,4-METHYLENEDIOXY-1-(N-PIPERAZINYL)-BENZENE;1-PIPERONYLPIPERAZINE;1-[(1,3-BENZODIOXOL-5-YL)METHYL]PIPERAZINE;1-BENZO[1,3]DIOXOL-5-YLMETHYL-PIPERAZINE;1-(3,4-METHYLENEDIOXYBENZYL)PIPERAZINE;1-(3,4-METHYLENDIOXYBENZYL)PIPERAZINE;AKOS BBS-00006443;AKOS B020126
The Structure of 1-PIPERONYLPIPERAZINE(32231-06-4):

1-PIPERONYLPIPERAZINE Toxicity Data With Reference

1. mouse LD50 intraperitoneal 50mg/kg (50mg/kg)
   European Journal of Medicinal Chemistry--Chimie Therapeutique. Vol. 9, Pg. 555, 1974.

1-PIPERONYLPIPERAZINE Safety Profile

Hazard Codes: Xi
Risk Statements: 36/37/38
36/37/38:  Irritating to eyes, respiratory system and skin 
Safety Statements: 26-37/39
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
37/39:  Wear suitable gloves and eye/face protection 
RIDADR: 3259
WGK Germany: 3
RTECS: TM1550000
Hazard Note: Irritant
HazardClass: 8
PackingGroup: II

1-PIPERONYLPIPERAZINE Specification

1. First Aid Measures
Ingestion:
Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.
Inhalation:
Remove from exposure to fresh air immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes:
If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.
2. Handling and Storage
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

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