2,4-DINITRODIPHENYLAMINE supplier

Name
2,4-Dinitrodiphenylamine
EINECS 213-508-4
CAS No. 961-68-2
Article Data109
CAS DataBase
Density 1.446g/cm³
Solubility 1.322mg/L(25 oC)
Melting Point 159-161 °C(lit.)
Formula C₁₂H₉N₃O₄
Boiling Point 413.8 °C at 760 mmHg
Molecular Weight 259.221
Flash Point 204.1 °C
Transport Information
Appearance solid
Safety 26-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Diphenylamine,2,4-dinitro- (8CI);Acetoquinone Yellow 5JZ;C.I.10340;C.I. Disperse Yellow 14;N-(2,4-Dinitrophenyl)aniline;N-(2,4-Dinitrophenyl)benzenamine;N-Phenyl-2,4-dinitroaniline;NSC 6150;Serisol Yellow 2G;Supracet Yellow 3G;o,p-Dinitrodiphenylamine;
PSA 103.67000
LogP 4.36600

Synthetic route

: 584-48-5
2,4-dinitrobromobenzene

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With tetrabutylammomium bromide; palladium diacetate; caesium carbonate; ruphos In dimethyl sulfoxide at 100℃; for 17h; Inert atmosphere;	98%

: 70-34-8
2,4-Dinitrofluorobenzene

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran for 25h; Inert atmosphere;	97%
In dimethyl sulfoxide at 100℃; for 16h; Inert atmosphere;	85%
In methanol at 0 - 20℃; for 18h;	85.3%

: 107569-59-5
2,4-dinitrophenyl N-phenylbenzimidate

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: 65-85-0
benzoic acid

Conditions

Conditions	Yield
With sodium hydroxide In water for 4h; Ambient temperature;	A 96% B n/a

: 62-53-3
aniline

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
In neat (no solvent) at 30℃; for 0.166667h; Reagent/catalyst; Green chemistry;	95%
In dimethyl sulfoxide at 20℃; for 24h;	93%
With sodium acetate In ethanol at 78℃; for 1h;	91%

: 70-34-8
2,4-Dinitrofluorobenzene

: 85599-59-3
Cyclohexyl N-phenylsulfamate

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With sodium carbonate; N-benzyl-N,N,N-triethylammonium chloride In benzene Ambient temperature;	89%

: 98-80-6
phenylboronic acid

: 97-02-9
2,4-Dinitroanilin

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With potassium acetate In N,N-dimethyl-formamide at 20℃; for 15h;	79%

: 99-65-0
meta-dinitrobenzene

: 62-53-3
aniline

A: 51-28-5
2,4-Dinitrophenol

B: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With potassium permanganate; tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 20℃; for 1h;	A 22% B 75%

...Expand

: 591-50-4
iodobenzene

: 97-02-9
2,4-Dinitroanilin

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With CuMoO4; caesium carbonate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;	72%

: 108-86-1
bromobenzene

: 97-02-9
2,4-Dinitroanilin

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With CuMoO4; caesium carbonate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;	64%

: 99-65-0
meta-dinitrobenzene

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride In N,N-dimethyl-formamide at 20℃; for 3h; Substitution; UV-irradiation;	54%
Stage #1: aniline With n-butyllithium In tetrahydrofuran; hexane at -78 - -70℃; Inert atmosphere; Stage #2: meta-dinitrobenzene In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;

: 4746-61-6
glycolanilide

: 58333-00-9
1-(2,4-dinitrophenyl)-4-methyl-3,5-dinitropyrazole

A: 51-28-5
2,4-Dinitrophenol

B: 961-68-2
N-phenyl-2,4-dinitroaniline

C: 20916-37-4
2-(2,4-dinitrophenoxy)-N-phenylacetamide

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile for 4h; Reflux;	A Ca. 0.015 g B 25% C 52%

...Expand

: 106038-76-0
2,4-Dinitrodiphenylacetamide

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: 2876-33-7
2-nitrophenazine 10-oxide

Conditions

Conditions	Yield
With trifluoroacetic acid In benzene for 0.583333h; Irradiation;	A 80 % Turnov. B 15%
With trifluoroacetic acid In benzene Irradiation;
With trifluoroacetic acid In benzene for 0.583333h; Irradiation; also with 1,4-diazabicyclo<2.2.2>octane (DABCO); also flash photolysis;	A 80 % Turnov. B 15 % Turnov.

: 123-91-1
1,4-dioxane

: 62-53-3
aniline

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
at 45℃; Rate constant;

...Expand

: 56-23-5
tetrachloromethane

: 64-17-5
ethanol

: N-(2,4-dinitro-phenyl)-N,N'-diphenyl-urea

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
beim Verduennen Abscheidung des Produktes;
beim Ansaeuern Abscheidung des Produktes;

...Expand

: 538-51-2
benzylidene phenylamine

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With ethanol

: 64-17-5
ethanol

: 141-78-6
ethyl acetate

: 62-53-3
aniline

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
at 24℃; Rate constant;

...Expand

: 141-78-6
ethyl acetate

: 62-53-3
aniline

: 97-00-7
1-chloro-2,4-dinitro-benzene

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
at 24℃; Rate constant;

...Expand

: 584-48-5
2,4-dinitrobromobenzene

: 64-17-5
ethanol

: 100-65-2
N-Phenylhydroxylamine

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: N-(2,4-dinitro-phenyl)-N-phenyl-hydroxylamine

C: 542-11-0
aniline hydrobromide

...Expand

: 584-48-5
2,4-dinitrobromobenzene

: 64-17-5
ethanol

: 100-65-2
N-Phenylhydroxylamine

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: N-(2,4-dinitro-phenyl)-N-phenyl-hydroxylamine

C: 62-53-3
aniline

...Expand

: 584-48-5
2,4-dinitrobromobenzene

: 100-65-2
N-Phenylhydroxylamine

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
With ethanol

: 64-17-5
ethanol

: 1594-56-5
2,4-dinitro-phenyl thiocyanate

: 62-53-3
aniline

A: 2217-55-2
bis(2,4-dinitrophenyl) disulphide

B: 961-68-2
N-phenyl-2,4-dinitroaniline

C: 2253-67-0
bis-(2,4-dinitro-phenyl)-sulfide

D: 103-85-5
monophenylthiourea

...Expand

: 64-17-5
ethanol

: 6526-37-0
1-(2,4-dinitrophenyl)-3-methylpyridinium chloride

: 62-53-3
aniline

A: 108-99-6
3-Methylpyridine

B: 961-68-2
N-phenyl-2,4-dinitroaniline

C: 97-02-9
2,4-Dinitroanilin

...Expand

: 67-66-3
chloroform

: 859775-56-7
(2,4-dichloro-5-nitro-phenyl)-(2,4-dinitro-phenyl)-ether

: 62-53-3
aniline

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: 39489-77-5
2,4-dichloro-5-nitrophenol

...Expand

: 2486-07-9
2,4-dinitrophenyl phenyl ether

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

Conditions

Conditions	Yield
at 180℃;

: 2734-77-2
1-(2-naphthoxy)-2,4-dinitrobenzene

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 742-25-6
2,4-dinitrophenyl 4-methylbenzenesulfonate

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 2217-56-3
bis(2,4-dinitrophenyl) ether

: 62-53-3
aniline

A: 51-28-5
2,4-Dinitrophenol

B: 961-68-2
N-phenyl-2,4-dinitroaniline

...Expand

: 2217-56-3
bis(2,4-dinitrophenyl) ether

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 26516-42-7
1-iodo-2,6-dinitrobenzene

: 62-53-3
aniline

A: 961-68-2
N-phenyl-2,4-dinitroaniline

B: 13744-81-5
2,6-dinitro-N-phenyl-benzenamine

...Expand

: 3761-11-3
1,3-bis-(2,4-dinitro-phenoxy)-benzene

: 62-53-3
aniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 55315-12-3
2-amino-4-nitro-N1-phenylaniline

Conditions

Conditions	Yield
With sodium sulfide; water; sulfur In ethanol for 2h; Reflux;	99%
With sodium sulfide; sodium hydrogencarbonate In ethanol; water at 80℃;	81.8%
With ammonium hydroxide; ethanol; hydrogen sulfide

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 136-17-4
2,4-diaminodiphenylamine

Conditions

Conditions	Yield
With hydrazine; nickel In tetrahydrofuran; ethanol at 20℃; for 0.333333h;	87%
With hydrogenchloride; iron
With hydrogenchloride; tin

: 961-68-2
N-phenyl-2,4-dinitroaniline

A: 2784-89-6
1-anilino-4-amino-2-nitrobenzene

B: 55315-12-3
2-amino-4-nitro-N1-phenylaniline

Conditions

Conditions	Yield
With nickel; hydrazine hydrate In ethanol; 1,2-dichloro-ethane at 50 - 60℃; for 4h;	A 29% B 70%

: 64-18-6
formic acid

: 961-68-2
N-phenyl-2,4-dinitroaniline

A: 53897-95-3
1-phenylbenzimidazol-5-amine

B: 15127-88-5
5-nitro-1-phenyl-1H-benzo[d]imidazole

Conditions

Conditions	Yield
Stage #1: N-phenyl-2,4-dinitroaniline With hydrogen; palladium 10% on activated carbon In ethyl acetate for 52h; Stage #2: formic acid With hydrogenchloride In water at 78 - 80℃; for 22h; Inert atmosphere; Stage #3: With sodium hydroxide In water at 20℃; pH=12;	A 25% B 61%

...Expand

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 2835-06-5
phenylglycin

: 853791-71-6
5-nitro-1,2-diphenyl-1H-benzimidazole

Conditions

Conditions	Yield
With iron(III) chloride; potassium carbonate In toluene at 120℃; for 16h;	58%

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 84145-28-8
(+/-)-2-amino-2'-fluorophenylacetic acid

: 5-nitro-2-(2-fluorophenyl)-1-phenyl-1H-benzimidazole

Conditions

Conditions	Yield
With iron(III) chloride; potassium carbonate In toluene at 120℃; for 16h;	56%

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 2784-89-6
1-anilino-4-amino-2-nitrobenzene

Conditions

Conditions	Yield
With sulfuric acid; hydrogen; platinum on activated charcoal In acetic acid at 85℃;	45%

: 67-56-1
methanol

: 961-68-2
N-phenyl-2,4-dinitroaniline

: (2,4-dinitro-phenyl)-phenyl-aniline; compound with potassium ethanolate

Conditions

Conditions	Yield
With potassium hydroxide

: 64-67-5
diethyl sulfate

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 58133-79-2
ethyl-(2,4-dinitro-phenyl)-phenyl-amine

Conditions

Conditions	Yield
With potassium hydroxide

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 3442-62-4
2-nitrophenazine

Conditions

Conditions	Yield
at 360℃;

: 961-68-2
N-phenyl-2,4-dinitroaniline

A: 14434-10-7
(2,4-dinitro-phenyl)-(2-nitro-phenyl)-amine

B: 970-76-3
2,4-dinitro-N-(4-nitrophenyl)aniline

Conditions

Conditions	Yield
Nitrieren;
With nitric acid; acetic acid

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 2908-76-1
bis(2,4-dinitrophenyl)amine

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 80 - 90℃;
With nitric acid; acetic acid; N-nitrosodiphenylamine
With nitric acid at 40 - 90℃; mit 53prozentiger Salpetersaeure;

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 131-73-7
Dipikrylamin

Conditions

Conditions	Yield
technische Gewinnung;
With nitric acid
Nitrierung;

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 108-24-7
acetic anhydride

: 106038-76-0
2,4-Dinitrodiphenylacetamide

Conditions

Conditions	Yield
With perchloric acid
With zinc(II) chloride

: 961-68-2
N-phenyl-2,4-dinitroaniline

: 64-19-7
acetic acid

: 110-46-3
isopentyl nitrite

: 2908-76-1
bis(2,4-dinitrophenyl)amine

Conditions

Conditions	Yield
at 18℃;

...Expand

2,4-DINITRODIPHENYLAMINE Chemical Properties

Molecular Formula: C₁₂H₉N₃O₄
Formula Weight: 259.22
IUPAC Name: 2,4-Dinitro-n-phenylaniline
Synonyms: Benzenamine,2,4-dinitro-N-phenyl- ; 2,4-Dinitro-diphenylamin ; O,p-dinitrodiphenylamine ; 2,4-Dinitro-phenyl)-phenyl-amine
Melting Point: 159-161^°C(lit.)
Flash Point: 204.1 ^°C
Boiling Point: 413.8 ^°C at 760 mmHg
Density of 2,4-Dinitrodiphenylamine (961-68-2): 1.446 g/cm³
Vapour Pressure: 4.66E-07 mmHg at 25^°C
Index of Refraction: 1.693
Appearance: 2,4-Dinitrodiphenylamine (961-68-2) is a solid
Stability: 2,4-Dinitrodiphenylamine (961-68-2) is stable. Incompatible with strong bases, strong acids, strong oxidizing agents.

2,4-DINITRODIPHENYLAMINE Uses

2,4-Dinitrodiphenylamine (961-68-2) is used as an intermediate in organic synthesis.

2,4-DINITRODIPHENYLAMINE Production

Add 2, 4-dinitrochlorobenzene and aniline into water by equimolar, stirred reacting for 2 hours at the temperature of 60 °C and then again stirred reacting for 2 hours at the temperature of 90^°C. After cooling, filtration, washing and drying, we can obtain 2,4-Dinitrodiphenylamine (961-68-2).

2,4-DINITRODIPHENYLAMINE Toxicity Data With Reference

ivn-mus LD50:180 mg/kg

CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#06394 .

2,4-DINITRODIPHENYLAMINE Consensus Reports

Reported in EPA TSCA Inventory.

2,4-DINITRODIPHENYLAMINE Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic vapors of NO_x.
Safety: Safety glasses.
Hazard Codes : Xi: Irritant
Risk Statements : 36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements : 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
37/39: Wear suitable gloves and eye/face protection
WGK Germany : 3
RTECS : JJ8825000

2,4-DINITRODIPHENYLAMINE Specification

2,4-Dinitrodiphenylamine (961-68-2) is a light yellow needle crystal and it is mainly used as an intermediate in organic synthesis. It is soluble in acetone, chloroform, pyridine and hot ethanol, slightly soluble in water.

Product Name

2,4-Dinitrodiphenylamine

Synthetic route

2,4-DINITRODIPHENYLAMINE Chemical Properties

2,4-DINITRODIPHENYLAMINE Uses

2,4-DINITRODIPHENYLAMINE Production

2,4-DINITRODIPHENYLAMINE Toxicity Data With Reference

2,4-DINITRODIPHENYLAMINE Consensus Reports

2,4-DINITRODIPHENYLAMINE Safety Profile

2,4-DINITRODIPHENYLAMINE Specification

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