Product Name

  • Name

    2,6-Dichlorobenzaldehyde

  • EINECS 201-472-2
  • CAS No. 83-38-5
  • Article Data111
  • CAS DataBase
  • Density 1.4 g/cm3
  • Solubility <0.1 g/100 mL at 23 °C in water
  • Melting Point 69-71 °C(lit.)
  • Formula C7H4Cl2O
  • Boiling Point 239.2 °C at 760 mmHg
  • Molecular Weight 175.014
  • Flash Point 97.4 °C
  • Transport Information UN 3261 8/PG 2
  • Appearance white to light yellow powder
  • Safety 26-27-28-36/37/39-45-37/39
  • Risk Codes 34-36/37/38
  • Molecular Structure Molecular Structure of 83-38-5 (2,6-Dichlorobenzaldehyde)
  • Hazard Symbols CorrosiveC, IrritantXi
  • Synonyms 2,6-Dichlorobenzaldehyde
  • PSA 17.07000
  • LogP 2.80590

Synthetic route

2,6-dichlorobenzyl alcohol
15258-73-8

2,6-dichlorobenzyl alcohol

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With dmap; tetrakis(actonitrile)copper(I) hexafluorophosphate; N,N'-di-tert-butylethylenediamine; oxygen In dichloromethane at 20℃; under 760.051 Torr; for 3h; Schlenk technique; Molecular sieve; Sealed tube;99%
With tert.-butylnitrite; oxygen; acetic acid In toluene at 50℃; for 8.5h;99%
With 2,2'-azobis(isobutyronitrile); oxygen; sodium bromide In 1,4-dioxane at 70℃;94%
2,6-Dichlorobenzaldehyde N,N-dimethylhydrazone
2828-47-9

2,6-Dichlorobenzaldehyde N,N-dimethylhydrazone

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With 3-benzyl-5-(2-hydroxyethyl)-4-methyl-1,3-thiazol-3-ium chloride In chloroform at 20℃; for 1h; oxidative cleavage;98%
With chloro-trimethyl-silane; sodium iodide In water; acetonitrile for 0.0333333h; deprotection;94%
With triethylene diamine nickel thiosulfate; water In chloroform at 20℃; for 0.166667h; Hydrolysis;94%
With iron(II) sulfate In chloroform at 20℃; for 0.75h; Hydrolysis;88%
2,6-dichlorobenzaldoxime
25185-95-9

2,6-dichlorobenzaldoxime

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With Cr-MCM-41 zeolite on silica gel for 0.1h; microwave irradiation;98%
With 2,6-dicarboxypyridinium fluorochromate for 0.5h;96%
With potassium permanganate; 1-n-butyl-3-methylimidazolim bromide at 20℃; for 0.383333h; Ionic liquid; chemoselective reaction;91%
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With N-chloro-succinimide; palladium diacetate; silver trifluoroacetate; anthranilic acid; trifluoroacetic acid In 1,2-dichloro-ethane at 60℃; for 24h; Sealed tube;95%
With N-chloro-succinimide; 2-hydroxyl-5-nitro-3-(trifluoromethyl)pyridine; 4-trifluoromethylphenylamine; palladium diacetate; trifluoroacetic acid In 1,2-dichloro-ethane at 80℃; for 24h; Sealed tube;92%
1,3-Dichloro-2-chloromethyl-benzene
2014-83-7

1,3-Dichloro-2-chloromethyl-benzene

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With dihydrogen peroxide; trimethylamine In water for 2h; Reflux;94%
2-(2,6-dichlorophenyl)-1,3-dithiane

2-(2,6-dichlorophenyl)-1,3-dithiane

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; dimethyl sulfoxide In dichloromethane at 20℃; for 2.15h;91%
2,6-Dichlorbenzaldehyd-2,4-dinitrophenylhydrazon
51379-82-9

2,6-Dichlorbenzaldehyd-2,4-dinitrophenylhydrazon

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With potassium permanganate at 40℃; for 2.8h; Ionic liquid; chemoselective reaction;81%
2,6-dichlorobenzaldehyde dimethyl acetal

2,6-dichlorobenzaldehyde dimethyl acetal

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With β‐cyclodextrin In methanol; water at 50℃; for 10h;80%
1,3-dichloro-2-methoxymethylbenzene
33486-90-7

1,3-dichloro-2-methoxymethylbenzene

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With N-Bromosuccinimide In tetrachloromethane for 1h; Irradiation; Reflux;77%
2-(2,6-dichlorophenyl)-1,3-dioxolane
82073-58-3

2-(2,6-dichlorophenyl)-1,3-dioxolane

triphenylphosphine hydrobromide
6399-81-1

triphenylphosphine hydrobromide

A

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

B

2-(hydroxyethyl)triphenylphosphonium bromide
7237-34-5

2-(hydroxyethyl)triphenylphosphonium bromide

Conditions
ConditionsYield
In dichloromethane at 50℃; for 0.0833333h; Microwave irradiation; Sealed tube;A 76%
B n/a
2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone
32188-71-9

2,6-dichlorobenzaldehyde (2,6-dichlorobenzylidene)hydrazone

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In water; acetonitrile at 50℃; for 15h; Oxidation;57%
d,l-1,2-Bis(2,6-dichlorphenyl)-N,N'-diethylethylendiamin
74105-85-4

d,l-1,2-Bis(2,6-dichlorphenyl)-N,N'-diethylethylendiamin

A

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

B

4-Chlor-2-(2,6-dichlorphenyl)-1-ethylindol
74105-78-5

4-Chlor-2-(2,6-dichlorphenyl)-1-ethylindol

C

4,9-Dichlor-5,10-diethyl-4b,5,9b,10-tetrahydroindolo<3,2-b>indol
74105-79-6

4,9-Dichlor-5,10-diethyl-4b,5,9b,10-tetrahydroindolo<3,2-b>indol

Conditions
ConditionsYield
at 215℃; for 0.25h;A 4%
B 53%
C 22%
(2,6-dichlorobenzylidene)aniline
104669-26-3, 33629-92-4

(2,6-dichlorobenzylidene)aniline

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With hydrogenchloride; water In diethyl ether; toluene at 20℃; for 2h; Inert atmosphere;32%
2,6-dichloro-N,N-diethylbenzamide
10345-78-5

2,6-dichloro-N,N-diethylbenzamide

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With Schwartz's reagent In tetrahydrofuran at 20℃; for 18h;17%
2,6-dichlorobenzyl azide

2,6-dichlorobenzyl azide

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With sodium dithionite; spermwhale myoglobin (H64V,V68A) In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7; Catalytic behavior;1%
With sodium dithionite In methanol; aq. phosphate buffer at 20℃; for 24h; pH=7; Catalytic behavior; Enzymatic reaction;
2,6-dichloro-benzaldehyde-[N-(4-dimethylamino-phenyl)-oxime ]
115231-29-3

2,6-dichloro-benzaldehyde-[N-(4-dimethylamino-phenyl)-oxime ]

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With sulfuric acid
2,6-dichlorobenzalchloride
81-19-6

2,6-dichlorobenzalchloride

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With sulfuric acid anschliessenden Behandeln mit Eis;
With ethanol; silver nitrate
guanabenz
60329-03-5

guanabenz

A

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

B

aminoguanidine
79-17-4

aminoguanidine

Conditions
ConditionsYield
With hydrogenchloride In water at 37℃; for 10h; effect of pH on the reversibility;
C16H10Cl4O3

C16H10Cl4O3

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
Yield given. Multistep reaction;
N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

1,3-Dichlorobenzene
541-73-1

1,3-Dichlorobenzene

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With n-butyllithium 1.) hexane,THF, -65 to -70 deg C, 45 min, 2.) THF, -70 deg C, 45 min; Yield given. Multistep reaction;
Stage #1: 1,3-Dichlorobenzene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Inert atmosphere;
Stage #2: N,N-dimethyl-formamide at -78℃; for 0.5h; Inert atmosphere; regioselective reaction;
Stage #1: 1,3-Dichlorobenzene With lithium diisopropyl amide In 1,2-dimethoxyethane; n-heptane; ethylbenzene at -60℃; for 1h;
Stage #2: N,N-dimethyl-formamide In 1,2-dimethoxyethane; n-heptane; ethylbenzene at -60℃; for 0.5h; Cooling with ice;
1,2-di-(2,6-dichlorophenyl)-1,2-ethanediol
112792-78-6

1,2-di-(2,6-dichlorophenyl)-1,2-ethanediol

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Conditions
ConditionsYield
With 1-Benzyl-1,4-dihydronicotinamide; oxygen; meso-tetraphenylporphyrin iron(III) chloride In dichloromethane for 12h; Ambient temperature; Irradiation;20 % Chromat.
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,6-dichlorobenzaldoxime
25185-95-9

2,6-dichlorobenzaldoxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride100%
With pyridine; hydroxylamine hydrochloride at 20℃; for 0.166667h;100%
With pyridine; hydroxylamine hydrochloride at 20℃; for 0.166667h;100%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

(1E)-2,6-dichlorobenzaldehyde oxime
6575-28-6

(1E)-2,6-dichlorobenzaldehyde oxime

Conditions
ConditionsYield
With pyridine; hydroxylamine hydrochloride In ethanol100%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 80 - 90℃; for 18 - 24h;96%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 90℃; for 24h;96%
cyclohexanone
108-94-1

cyclohexanone

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

(2S,1'R)-2-[(2,6-dichlorophenyl)hydroxymethyl]cyclohexan-1-one

(2S,1'R)-2-[(2,6-dichlorophenyl)hydroxymethyl]cyclohexan-1-one

Conditions
ConditionsYield
With C18H17F6N5; 2,4-dinitrobenzoic acid In neat (no solvent) at 0℃; for 48h; Aldol Addition;100%
With C35H55N3O5; water at -20℃; for 24h; Aldol Condensation; enantioselective reaction;99%
trans-4-hydroxy-L-prolinamide derivative In water at 25℃; for 5h;95%
ethyl acetoacetate
141-97-9

ethyl acetoacetate

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2-(2,6-dichlorophenyl)-4-hydroxy-4-methyl-6-oxo-cyclohexane-1,3-dicarboxylic acid diethyl ester
371981-20-3

2-(2,6-dichlorophenyl)-4-hydroxy-4-methyl-6-oxo-cyclohexane-1,3-dicarboxylic acid diethyl ester

Conditions
ConditionsYield
With piperidine In ethanol at 20℃;100%
With piperidine In ethanol Inert atmosphere;68%
cis, trans-1,3-dimethylaminocyclohexane
2579-20-6

cis, trans-1,3-dimethylaminocyclohexane

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

C22H22Cl4N2
1217526-98-1

C22H22Cl4N2

Conditions
ConditionsYield
In methanol at 20℃; Molecular sieve;100%
In methanol at 20℃; Molecular sieve;
1,3-dimethylbarbituric acid
769-42-6

1,3-dimethylbarbituric acid

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

dimedone
126-81-8

dimedone

diethylamine
109-89-7

diethylamine

C21H22Cl2N2O5*C4H11N

C21H22Cl2N2O5*C4H11N

Conditions
ConditionsYield
In water at 20℃; Inert atmosphere;100%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

dimedone
126-81-8

dimedone

diethylamine
109-89-7

diethylamine

Diethylammonium 2-((2,6-dichlorophenyl)(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)methyl)-5,5-dimethyl-3-oxocyclohex-1-enolate

Diethylammonium 2-((2,6-dichlorophenyl)(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-en-1-yl)methyl)-5,5-dimethyl-3-oxocyclohex-1-enolate

Conditions
ConditionsYield
In water at 20℃; Inert atmosphere;100%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

ethanethiol
75-08-1

ethanethiol

C9H9ClOS
1186033-44-2

C9H9ClOS

Conditions
ConditionsYield
Stage #1: ethanethiol With sodium hydroxide In water at 20℃; for 0.5h;
Stage #2: 2,6-dichlorobenzaldehyde With tetrabutylammomium bromide In water at 82℃;
99.4%
Stage #1: ethanethiol With sodium hydroxide In water for 1h;
Stage #2: 2,6-dichlorobenzaldehyde With tetrabutylammomium bromide In water for 4h; Reflux;
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

malononitrile
109-77-3

malononitrile

2-(2,6-dichlorobenzylidene)malononitrile
2972-79-4

2-(2,6-dichlorobenzylidene)malononitrile

Conditions
ConditionsYield
In water at 20℃; for 0.166667h; Knoevenagel Condensation; Green chemistry;99%
With ZnO/Al-SBA-15 (40) In ethanol at 20℃; for 2h; Knoevenagel Condensation; Green chemistry;97%
With zirconium(IV) oxide In ethanol for 2h; Knoevenagel Condensation; Reflux;95%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,6-dichlorobenzyl alcohol
15258-73-8

2,6-dichlorobenzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0℃;99%
With sodium tetrahydroborate In ethanol at 20℃; for 2h;94%
With Triethoxysilane; C27H42FeP4S In tetrahydrofuran at 50℃; for 2h; Catalytic behavior; Schlenk technique; Green chemistry;93%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

4-acetylbenzenesulfonyl-Rink resin

4-acetylbenzenesulfonyl-Rink resin

4-[(2E)-3-(2,6-dichlorophenyl)prop-2-enoyl]benzenesulfonamide

4-[(2E)-3-(2,6-dichlorophenyl)prop-2-enoyl]benzenesulfonamide

Conditions
ConditionsYield
Stage #1: 2,6-dichlorobenzaldehyde; 4-acetylbenzenesulfonyl-Rink resin With sodium ethanolate In tetrahydrofuran; ethanol at 20℃; for 0.5h;
Stage #2: With trifluoroacetic acid In dichloromethane Further stages.;
99%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

Trimethylenediamine
109-76-2

Trimethylenediamine

N,N'-bis(2,6-dichlorobenzylidene)propane-1,3-diamine
348630-62-6

N,N'-bis(2,6-dichlorobenzylidene)propane-1,3-diamine

Conditions
ConditionsYield
In ethanol for 0.5h; Heating;99%
In benzene for 24h; Heating;72.07%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,4,5-tris(2,6-dichlorophenyl)-4,5-dihydro-1H-imidazole

2,4,5-tris(2,6-dichlorophenyl)-4,5-dihydro-1H-imidazole

Conditions
ConditionsYield
With ammonium chloride In ethanol at 20℃; for 192h;99%
3-chloro-1,1-dimethylpropylamine hydrochloride
686746-12-3

3-chloro-1,1-dimethylpropylamine hydrochloride

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

(3-chloro-1,1-dimethylpropyl)-(2,6-dichlorobenzylidene)-amine
686746-13-4

(3-chloro-1,1-dimethylpropyl)-(2,6-dichlorobenzylidene)-amine

Conditions
ConditionsYield
Stage #1: 3-chloro-1,1-dimethylpropylamine-hydrochloride With sodium hydroxide In water at 0℃; for 0.5h;
Stage #2: 2,6-dichlorobenzaldehyde In dichloromethane at 20℃; for 18h;
99%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

allyl-trimethyl-silane
762-72-1

allyl-trimethyl-silane

1,3-dichloro-2-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene
1200328-43-3

1,3-dichloro-2-[1-[(trimethylsilyl)oxy]-3-buten-1-yl]benzene

Conditions
ConditionsYield
With Montmorillonite K10 clay In dichloromethane at 0 - 20℃; for 1.08333h; Hosomi-Sakurai reaction;99%
With C76H92CoN4(1+)*F6Sb(1-) In 1,2-dichloro-ethane at 100℃; for 4h; Sealed tube;
cyclohexanone
108-94-1

cyclohexanone

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2-[hydroxy-(2,6-dichlorophenyl)-methyl]-cyclohexan-1-one

2-[hydroxy-(2,6-dichlorophenyl)-methyl]-cyclohexan-1-one

Conditions
ConditionsYield
With (S)-N-( p-dodecylphenylsulfonyl)-2-pyrrolidinecarboxamide; water In 1,2-dichloro-ethane at 20℃; for 48h; Aldol condensation; optical yield given as %ee; enantioselective reaction;99%
3-(dimethylcarbamothioyl)-1-methyl-1H-imidazol-3-ium chloride
161149-23-1

3-(dimethylcarbamothioyl)-1-methyl-1H-imidazol-3-ium chloride

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

O-(2,6-dichlorophenyl)(1-methyl-1H-imidazol-2-yl)methyl dimethylcarbamothioate
1413413-86-1

O-(2,6-dichlorophenyl)(1-methyl-1H-imidazol-2-yl)methyl dimethylcarbamothioate

Conditions
ConditionsYield
With triethylamine In N,N-dimethyl-formamide at 30℃; for 12h; Temperature; Inert atmosphere;99%
(4R,5R)-4-benzyloxycarbonylamino-5-isopropylpyrazolidin-3-one

(4R,5R)-4-benzyloxycarbonylamino-5-isopropylpyrazolidin-3-one

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

(3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

(3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

Conditions
ConditionsYield
Stage #1: (4R,5R)-4-benzyloxycarbonylamino-5-isopropylpyrazolidin-3-one; 2,6-dichlorobenzaldehyde In methanol at 20℃; for 0.0833333h;
Stage #2: With trifluoroacetic acid In methanol at 20℃; for 7h;
99%
1-ethynyl-3-methyl-benzene
766-82-5

1-ethynyl-3-methyl-benzene

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

C16H12Cl2O
1590443-25-6

C16H12Cl2O

Conditions
ConditionsYield
With 2,2,2-Trifluoroacetophenone; triphenylphosphine In water at 60℃; for 2h; Schlenk technique; Inert atmosphere; Green chemistry;99%
4-benzyloxycarbonylamino-5-isopropyl-3-pyrazolidinone

4-benzyloxycarbonylamino-5-isopropyl-3-pyrazolidinone

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

(3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

(3R,4R,Z)-4-(benzyloxycarbonylamino)-2-(2,6-dichlorobenzylidene)-3-isopropyl-5-oxopyrazolidin-2-ium-1-ide

Conditions
ConditionsYield
With trifluoroacetic acid In methanol99%
methanol
67-56-1

methanol

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,6-dichlorobenzaldehyde dimethyl acetal

2,6-dichlorobenzaldehyde dimethyl acetal

Conditions
ConditionsYield
With Eosin Y In acetonitrile at 20℃; for 12h; Schlenk technique; Inert atmosphere; Irradiation; chemoselective reaction;99%
With titanium tetrachloride; triethylamine In dichloromethane at 0 - 20℃; for 0.5h; Inert atmosphere;93%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-((2,6-dichlorobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-((2,6-dichlorobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With C34H28N6Zn In neat (no solvent) at 20℃; for 2h; Glovebox; Schlenk technique;99%
With C24H34N5PSeTi In toluene at 30℃; for 3h; Glovebox; Schlenk technique; chemoselective reaction;93%
With C45H69FeN8PSi2 In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique;
acetic anhydride
108-24-7

acetic anhydride

2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

1,1-diacetoxy-1-(2,6-dichlorophenyl)methane
24653-82-5

1,1-diacetoxy-1-(2,6-dichlorophenyl)methane

Conditions
ConditionsYield
With p-toluenesulfonic acid-paraformaldehyde copolymer at 25℃; for 0.25h; Neat (no solvent);98%
aluminium dodecatungsten phosphate at 20℃; for 0.25h;95%
With lithium trifluoromethanesulfonate at 20℃; for 19h;95%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,6-dichloro-benzonitrile
1194-65-6

2,6-dichloro-benzonitrile

Conditions
ConditionsYield
With aluminum oxide; hydroxylamine hydrochloride; methanesulfonyl chloride at 100℃; for 0.333333h;98%
With ammonia; oxygen In tert-Amyl alcohol at 40℃; under 750.075 Torr; for 24h; Green chemistry;94%
With manganese(IV) oxide; ammonia; magnesium sulfate In tetrahydrofuran; isopropyl alcohol at 20℃; for 17h;93%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

tetraethyl (aminomethylene)bis(phosphonate)
80474-99-3

tetraethyl (aminomethylene)bis(phosphonate)

[{[1-(2,6-Dichloro-phenyl)-meth-(E)-ylidene]-amino}-(diethoxy-phosphoryl)-methyl]-phosphonic acid diethyl ester

[{[1-(2,6-Dichloro-phenyl)-meth-(E)-ylidene]-amino}-(diethoxy-phosphoryl)-methyl]-phosphonic acid diethyl ester

Conditions
ConditionsYield
In diethyl ether for 2h;98%
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2,6-dichlorobenzaldoxime
3714-77-0

2,6-dichlorobenzaldoxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; titanium(IV) oxide at 80℃; for 0.166667h;98%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 0 - 20℃; for 2h;96%
With cadmium sulfate; hydroxylamine hydrochloride for 0.0833333h; Microwave irradiation; stereoselective reaction;85%
With hydroxylamine hydrochloride; potassium carbonate at 90℃; for 5h;90 % Spectr.
With aluminum oxide; methanesulfonic acid at 80℃; for 0.0833333h;95 % Spectr.
2,6-dichlorobenzaldehyde
83-38-5

2,6-dichlorobenzaldehyde

2-amino-6-hydrazino-4-pyrrolidino-5-pyrimidinecarbonitrile
308356-30-1

2-amino-6-hydrazino-4-pyrrolidino-5-pyrimidinecarbonitrile

2-Amino-4-{N'-[1-(2,6-dichloro-phenyl)-meth-(E)-ylidene]-hydrazino}-6-pyrrolidin-1-yl-pyrimidine-5-carbonitrile

2-Amino-4-{N'-[1-(2,6-dichloro-phenyl)-meth-(E)-ylidene]-hydrazino}-6-pyrrolidin-1-yl-pyrimidine-5-carbonitrile

Conditions
ConditionsYield
With acetic acid In ethanol for 1h; Heating;98%

2,6-Dichlorobenzaldehyde Chemical Properties

The Molecular Structure of 2,6-Dichlorobenzaldehyde (CAS NO.83-38-5):
 

Empirical Formula: C7H4Cl2O
Molecular Weight: 175.0121 
IUPAC Name: 2,6-dichlorobenzaldehyde 
Appearance: white to light yellow powder
Nominal Mass: 174 Da
Average Mass: 175.0121 Da
Monoisotopic Mass: 173.96392 Da 
Index of Refraction: 1.6
Molar Refractivity: 42.79 cm3
Molar Volume: 125 cm3
Surface Tension: 45.1 dyne/cm
Density: 1.4 g/cm3
Flash Point: 97.4 °C
Enthalpy of Vaporization: 47.61 kJ/mol
Boiling Point: 239.2 °C at 760 mmHg
Vapour Pressure: 0.0406 mmHg at 25°C 
Water Solubility: <0.1 g/100 mL at 23 ºC
Sensitive: Air Sensitive
Stability: Stable. Incompatible with strong oxidizing agents, strong bases. Air, light and moisture sensitive
InChI
InChI=1/C7H4Cl2O/c8-6-2-1-3-7(9)5(6)4-10/h1-4H
Smiles
c1(c(cccc1Cl)Cl)C=O 
Product Categories: Benzaldehyde;Dicloxacillin;Aldehydes;C7;Carbonyl Compounds
Synonyms: CCRIS 6014 ; EINECS 201-472-2 ; Benzaldehyde, 2,6-dichloro-   

2,6-Dichlorobenzaldehyde Uses

 2,6-Dichlorobenzaldehyde (CAS NO.83-38-5) can be used for the synthesis of dyes, intermediates of pesticide and pharmaceuticalare, also used as fungicides and herbicides and used in the manufacture of 2,6 - dichlorobenzonitrile .

2,6-Dichlorobenzaldehyde Safety Profile

Hazard Codes: IrritantXiCorrosiveC
Risk Statements: 34-36/37/38 
R34: Causes burns
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-27-28-36/37/39-45-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27: Take off immediately all contaminated clothing
S28: After contact with skin, wash immediately with plenty of soap-suds
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible)
S37/39: Wear suitable gloves and eye/face protection
RIDADR: UN 3261 8/PG 2
WGK Germany: 2
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: III
HS Code: 29130000

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