Product Name

  • Name

    3-Phenoxybenzyl alcohol

  • EINECS 237-525-1
  • CAS No. 13826-35-2
  • Article Data48
  • CAS DataBase
  • Density 1.151 g/cm3
  • Solubility insoluble in water
  • Melting Point 4-7°C
  • Formula C13H12O2
  • Boiling Point 377.8 °C at 760 mmHg
  • Molecular Weight 200.237
  • Flash Point 151.3 °C
  • Transport Information
  • Appearance colourless liquid
  • Safety 26-36/37
  • Risk Codes 22
  • Molecular Structure Molecular Structure of 13826-35-2 (3-Phenoxybenzyl alcohol)
  • Hazard Symbols HarmfulXn, IrritantXi
  • Synonyms Benzylalcohol, m-phenoxy- (7CI,8CI);(3-Phenoxyphenyl)methanol;1-Hydroxymethyl-3-phenoxybenzene;3-(Hydroxymethyl)diphenyl ether;3-Phenoxybenzenemethanol;m-Phenoxybenzyl alcohol;
  • PSA 29.46000
  • LogP 2.97120

Synthetic route

3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0 - 20℃; for 1.5h;99%
With hydrogen In methanol at 20℃; for 4.3h; chemoselective reaction;99%
With sodium tetrahydroborate In tetrahydrofuran; 1,2-dimethoxyethane for 3h; Cooling with ice;99.2%
methanolic potassium hydroxide

methanolic potassium hydroxide

3-phenoxybenzyl acetate
50789-44-1

3-phenoxybenzyl acetate

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
97.2%
2-(3-phenoxy-benzyloxy)-tetrahydro-pyran

2-(3-phenoxy-benzyloxy)-tetrahydro-pyran

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With copper dichloride In methanol at 20℃; Hydrolysis;95%
With CuCl2*2H2O In methanol at 20℃; for 1.25h;95%
3-phenoxybenzyl acetate
50789-44-1

3-phenoxybenzyl acetate

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water95%
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water90%
With sodium hydroxide In methanol; dichloromethane; water90%
3-phenoxybenzoic acid
3739-38-6

3-phenoxybenzoic acid

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
In ethanol; sulfuric acid; water electrochemical reduction;93%
Multi-step reaction with 3 steps
1: phosphorus (V)-chloride
2: toluene; palladium/barium sulfate
3: concentrated aqueous KOH / 60 °C
View Scheme
Multi-step reaction with 2 steps
1: sulfuric acid / 3 h / 60 °C
2: methanol; sodium tetrahydroborate / tetrahydrofuran / 0.5 h / Reflux
View Scheme
8-quinolinol
148-24-3

8-quinolinol

3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene93%
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene
3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

chlorobenzene
108-90-7

chlorobenzene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N1-benzyl-N2-(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere;92%
With potassium carbonate; 8-quinolinol; copper(l) chloride In various solvent(s) at 150 - 170℃; for 15h;88 % Chromat.
With potassium carbonate; 8-quinolinol; copper(l) chloride In dimethyl sulfoxide at 150 - 170℃; for 15h; Product distribution; solvents varied;58 % Chromat.
bromobenzene
108-86-1

bromobenzene

3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; N,N’-bis(2-phenylphenyl)oxalic acid In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;92%
3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

A

triethylene glucol monomethyl ether
112-35-6

triethylene glucol monomethyl ether

B

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
A n/a
B 87%
(3-Bromophenyl)methanol
15852-73-0

(3-Bromophenyl)methanol

phenol
108-95-2

phenol

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With sodium dodecyl-sulfate; potassium carbonate In water at 80℃; under 760.051 Torr; for 10h; Ullmann Condensation; Green chemistry; chemoselective reaction;84%
3-phenoxybenzoic acid
3739-38-6

3-phenoxybenzoic acid

trifluoroborane diethyl ether
109-63-7

trifluoroborane diethyl ether

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With mercury In tetrahydrofuran; diethyl ether; water83%
With mercury In tetrahydrofuran
3-Hydroxybenzyl alcohol
620-24-6

3-Hydroxybenzyl alcohol

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
75%
74%
74%
71%
71%
3-phenoxybenzyl (1RS)-cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
61949-76-6

3-phenoxybenzyl (1RS)-cis-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

A

3-phenoxybenzyl chloride
53874-66-1

3-phenoxybenzyl chloride

cis-permethrinic acid
59042-49-8

cis-permethrinic acid

C

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzyl (1RS)-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

3-phenoxybenzyl (1RS)-trans-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate

Conditions
ConditionsYield
With potassium chlorate at 210℃; for 0.25h; Product distribution; Further Variations:; Reagents; Solvents; reaction time;A 3.7%
B 0.9%
C 3.3%
D n/a
3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

A

3-phenoxybenzoic acid
3739-38-6

3-phenoxybenzoic acid

B

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With potassium hydroxide at 60℃;
With formaldehyd In water at 70℃; for 24h; Product distribution; effect of the presence and amount of PEG-200, other temperatures, reaction times; other cationic surfactants;
3-phenoxytoluene
3586-14-9

3-phenoxytoluene

A

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

B

3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

Conditions
ConditionsYield
With oxygen; titanium(IV) oxide In acetonitrile Product distribution; Irradiation; var. solvents;
3-phenoxytoluene
3586-14-9

3-phenoxytoluene

A

3-phenoxybenzoic acid
3739-38-6

3-phenoxybenzoic acid

B

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

C

3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

Conditions
ConditionsYield
With oxygen; titanium(IV) oxide In acetonitrile Product distribution; Irradiation; var. times, and conc. reag.;
C13H12O2*C5H5N*Br3H

C13H12O2*C5H5N*Br3H

A

pyridinium hydrobromide perbromide
39416-48-3

pyridinium hydrobromide perbromide

B

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
In acetic acid at 19.9℃; Equilibrium constant; Thermodynamic data; ΔH, ΔS, ΔG, var. temp.;
Conditions
ConditionsYield
With sodium phosphate buffer; Aspergillus niger ZD11 pyrethroid hydrolase In acetonitrile at 30℃; pH=6.8; Enzyme kinetics;
With sodium phosphate buffer; Klebsiella sp. ZD112 pyrethroid-hydrolyzing esterase In acetonitrile at 30℃; pH=7.0; Enzyme kinetics;
Conditions
ConditionsYield
With sodium phosphate buffer; Aspergillus niger ZD11 pyrethroid hydrolase In acetonitrile at 30℃; pH=6.8; Enzyme kinetics;
With sodium phosphate buffer; Klebsiella sp. ZD112 pyrethroid-hydrolyzing esterase In acetonitrile at 30℃; pH=7.0; Enzyme kinetics;
alpha-cyano-3-phenoxybenzyl acetate
61066-87-3

alpha-cyano-3-phenoxybenzyl acetate

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With pig liver esterase; 1,4-dihydronicotinamide adenine dinucleotide; horse liver alcohol dehydrogenase In phosphate buffer; acetonitrile pH=7;
3-phenoxytoluene
3586-14-9

3-phenoxytoluene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 110 g / Co(OAc)2, KBr, O2 / acetic acid / 15 h / 175 °C / 7500.6 Torr
2: 93 percent / H2O; ethanol; aq. H2SO4 / electrochemical reduction
View Scheme
Multi-step reaction with 4 steps
1: potassium permanganate; aqueous sodium carbonate
2: phosphorus (V)-chloride
3: toluene; palladium/barium sulfate
4: concentrated aqueous KOH / 60 °C
View Scheme
bromobenzene
108-86-1

bromobenzene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: copper-powder / 160 - 190 °C
2: potassium permanganate; aqueous sodium carbonate
3: phosphorus (V)-chloride
4: toluene; palladium/barium sulfate
5: concentrated aqueous KOH / 60 °C
View Scheme
iodobenzene
591-50-4

iodobenzene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: copper-powder / 160 - 190 °C
2: potassium permanganate; aqueous sodium carbonate
3: phosphorus (V)-chloride
4: toluene; palladium/barium sulfate
5: concentrated aqueous KOH / 60 °C
View Scheme
3-phenoxy-benzoyl chloride
3586-15-0

3-phenoxy-benzoyl chloride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene; palladium/barium sulfate
2: concentrated aqueous KOH / 60 °C
View Scheme
3-phenoxybenzonitrile
50789-45-2

3-phenoxybenzonitrile

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: ethanolic KOH-solution
2: phosphorus (V)-chloride
3: toluene; palladium/barium sulfate
4: concentrated aqueous KOH / 60 °C
View Scheme
Multi-step reaction with 2 steps
1: SnCl2; HCl; diethyl ether / Erwaermen des Reaktionsprodukts mit Wasser
2: concentrated aqueous KOH / 60 °C
View Scheme
3-phenoxyaniline
3586-12-7

3-phenoxyaniline

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: sodium nitrite; aqueous hydrochloric acid / Eintragen in die mit Natriumcarbonat neutralisierten Diazoniumsalz-Loesung in eine aus Kupfer(II)-sulfat, Natriumcyanid und Wasser hergestellte Loesung
2: ethanolic KOH-solution
3: phosphorus (V)-chloride
4: toluene; palladium/barium sulfate
5: concentrated aqueous KOH / 60 °C
View Scheme
Multi-step reaction with 3 steps
1: sodium nitrite; aqueous hydrochloric acid / Eintragen in die mit Natriumcarbonat neutralisierten Diazoniumsalz-Loesung in eine aus Kupfer(II)-sulfat, Natriumcyanid und Wasser hergestellte Loesung
2: SnCl2; HCl; diethyl ether / Erwaermen des Reaktionsprodukts mit Wasser
3: concentrated aqueous KOH / 60 °C
View Scheme
phenol
108-95-2

phenol

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: sodium methylate; copper-powder / 190 °C
2: phosphorus (V)-chloride
3: toluene; palladium/barium sulfate
4: concentrated aqueous KOH / 60 °C
View Scheme
3-phenoxytoluene
3586-14-9

3-phenoxytoluene

3-phenoxy-6-chlorotoluene
52322-81-3

3-phenoxy-6-chlorotoluene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

Conditions
ConditionsYield
With sodium borohydrid; acetic acid In ethanol
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

(1R,2R,5S,6R)-Tricyclo[4.3.1.12,5]undecane-1-carbonyl chloride

(1R,2R,5S,6R)-Tricyclo[4.3.1.12,5]undecane-1-carbonyl chloride

m-phenoxybenzyl tricyclo<4.3.1.12,5>undecane-1-carboxylate

m-phenoxybenzyl tricyclo<4.3.1.12,5>undecane-1-carboxylate

Conditions
ConditionsYield
With pyridine In benzene for 21h; Heating;100%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-Phenoxybenzaldehyde
39515-51-0

3-Phenoxybenzaldehyde

Conditions
ConditionsYield
With iodosylbenzene; Cl-CH2-PS supported 5-amino-1,10-phenanthroline-Ru In acetonitrile at 60℃; for 2h;100%
With hydrogenchloride; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium nitrite In dichloromethane; water at 20℃; under 760.051 Torr; for 11h; in air;99%
With dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; copper diacetate In neat (no solvent) at 25℃; for 24h; Green chemistry;99%
acetic anhydride
108-24-7

acetic anhydride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzyl acetate
50789-44-1

3-phenoxybenzyl acetate

Conditions
ConditionsYield
With pyridine; dmap at 0 - 20℃;100%
With thalium(III) chloride tetrahydrate at 20℃; for 0.05h;99%
With silica-bonded N-propyl sulfamic acid at 20℃; for 0.5h; chemoselective reaction;90%
With pyridine at 20℃; for 12h;86%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzonitrile
50789-45-2

3-phenoxybenzonitrile

Conditions
ConditionsYield
With ammonia; oxygen In tert-Amyl alcohol; water at 100℃; under 3750.38 Torr; for 10h; Autoclave; High pressure;98.3%
With copper(II) perchlorate hexahydrate; trimethylsilylazide; 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,2-dichloro-ethane at 60℃; for 10h;95%
With copper(II) choride dihydrate; ammonium formate; potassium carbonate In neat (no solvent) at 135℃; under 760.051 Torr; for 24h; Sealed tube; Schlenk technique; Green chemistry;80%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzyl chloride
53874-66-1

3-phenoxybenzyl chloride

Conditions
ConditionsYield
With thionyl chloride In chloroform Heating / reflux;98%
With thionyl chloride In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃; for 12h;95%
With tetrachloromethane; triphenylphosphine for 5.66667h; Heating / reflux;94%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

trimethyl(3-phenoxybenzyloxy)silane

trimethyl(3-phenoxybenzyloxy)silane

Conditions
ConditionsYield
With Nafion SAC-13 at 20℃; for 0.0833333h;98%
With sulfuric acid In dichloromethane at 20℃; for 8.5h;91%
With asymmetric salen type di-Schiff base-based zinc complex supported on Fe3O4 nanoparticles at 20℃; for 0.216667h;91%
With cross-linked poly((30percent)4-vinylpyridine/(70percent)styrene) copolymer-supported bismuth(III) triflate In dichloromethane at 20℃; for 0.166667h;88%
morpholine
110-91-8

morpholine

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

4-(3-phenoxybenzyl)morpholine
415925-18-7

4-(3-phenoxybenzyl)morpholine

Conditions
ConditionsYield
With NiCuFeO(x) In 5,5-dimethyl-1,3-cyclohexadiene for 24h; Inert atmosphere; Sealed tube; Reflux;98%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

thiophenol
108-98-5

thiophenol

((3-phenoxyphenyl)methylene)bis(phenylsulfane)

((3-phenoxyphenyl)methylene)bis(phenylsulfane)

Conditions
ConditionsYield
With 9-(2-mesityl)-10-methylacridinium perchlorate In acetonitrile at 30 - 35℃; for 24h; Schlenk technique; Irradiation;98%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

aniline
62-53-3

aniline

N-phenyl-m-phenoxybenzylamine

N-phenyl-m-phenoxybenzylamine

Conditions
ConditionsYield
With cesiumhydroxide monohydrate; oxygen In 1,3,5-trimethyl-benzene at 140℃; for 24h;97%
With xanth-9-one; potassium hydroxide In toluene at 150℃; for 8h; Inert atmosphere;97%
With zinc(II) nitrate hexahydrate; potassium tert-butylate In toluene at 140℃; for 36h; Sealed tube; Inert atmosphere; Schlenk technique;85%
With iron(III) oxide; potassium hydroxide In toluene at 135℃; for 24h; Inert atmosphere; Sealed tube;84%
9H-fluorene
86-73-7

9H-fluorene

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

9-(3-phenoxybenzyl)-9H-fluorene

9-(3-phenoxybenzyl)-9H-fluorene

Conditions
ConditionsYield
With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate In toluene at 120℃; for 18h; Inert atmosphere; Sealed tube;97%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

3-phenoxybenzyl bromide
51632-16-7

3-phenoxybenzyl bromide

Conditions
ConditionsYield
With hydrogen bromide In benzene96%
With phosphorus tribromide In dichloromethane at 0℃; for 1h;95%
With 1H-imidazole; bromine; triphenylphosphine In dichloromethane at 0 - 22℃; Inert atmosphere;86%
tetra-n-butylphosphonium chloride
2304-30-5

tetra-n-butylphosphonium chloride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

4-(2,2-dichloroethenyl)dihydro-5,5-dimethyl-2(3H)-furanone
63142-59-6

4-(2,2-dichloroethenyl)dihydro-5,5-dimethyl-2(3H)-furanone

permethrin
52645-53-1

permethrin

Conditions
ConditionsYield
With potassium hydroxide; thionyl chloride In ice-water; toluene; benzene95%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

tert-butyl 3-phenoxybenzoperoxoate
1329121-85-8

tert-butyl 3-phenoxybenzoperoxoate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In water at 20℃; for 16h; Solvent;95%
cis,trans methyl 2,2-dimethyl-3-(2',2'-dichlorovinyl)-cyclopropanecarboxylate
61898-95-1

cis,trans methyl 2,2-dimethyl-3-(2',2'-dichlorovinyl)-cyclopropanecarboxylate

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

A

(3-phenoxyphenyl)methyl 2,2-dimethyl-3-(2-chloroethynyl)cyclopropanecarboxylate

(3-phenoxyphenyl)methyl 2,2-dimethyl-3-(2-chloroethynyl)cyclopropanecarboxylate

B

permethrin
52645-53-1

permethrin

Conditions
ConditionsYield
With lithium methanolate In methanol; xylene at 100 - 145℃; for 12h; Heating / reflux;A 0.1%
B 94%
With sodium methylate In methanolA 1.1%
B 81%
succinic acid anhydride
108-30-5

succinic acid anhydride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

4-oxo-4-(3-phenoxybenzyloxy)butanoic acid
940867-23-2

4-oxo-4-(3-phenoxybenzyloxy)butanoic acid

Conditions
ConditionsYield
In dichloromethane at 20℃;94%
methyl 3-(2-hydroxyphenyl)propionate
20349-89-7

methyl 3-(2-hydroxyphenyl)propionate

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

C23H22O4

C23H22O4

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In toluene at 70℃; for 3h;94%
With triphenylphosphine; diethylazodicarboxylate In toluene at 70℃; for 3h;94%
With triphenylphosphine; diethylazodicarboxylate
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

methyl 3-phenoxybenzoate
50789-43-0

methyl 3-phenoxybenzoate

Conditions
ConditionsYield
Stage #1: tert.-butylhydroperoxide; 3-Phenoxybenzyl alcohol In water; dimethyl sulfoxide
Stage #2: In water; dimethyl sulfoxide at 100℃; for 20h; Sealed tube;
94%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

(2-bromo-5-phenoxyphenyl)methanol

(2-bromo-5-phenoxyphenyl)methanol

Conditions
ConditionsYield
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In dichloromethane at 35 - 40℃; for 2h; Reagent/catalyst; Temperature; Solvent;93.7%
With 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In dichloromethane at 35℃; for 2h; Inert atmosphere; regioselective reaction;92%
1-Adamantanecarbonyl chloride
2094-72-6

1-Adamantanecarbonyl chloride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

m-phenoxybenzyl adamantane-1-carboxylate

m-phenoxybenzyl adamantane-1-carboxylate

Conditions
ConditionsYield
With pyridine In benzene for 66h; Ambient temperature;93%
permethric acid chloride
52314-67-7

permethric acid chloride

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

permethrin
52645-53-1

permethrin

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; N,N,N,N,-tetramethylethylenediamine; potassium carbonate In potassium hydroxide at 20 - 25℃; for 1.5h; pH=11.5; Schotten-Baumann-type reaction;93%
With 1-methyl-1H-imidazole; N,N,N,N,-tetramethylethylenediamine; potassium carbonate In acetonitrile at 0 - 25℃; for 2h;92%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

dimethyl sulfate
77-78-1

dimethyl sulfate

1-(methoxymethyl)-3-phenoxybenzene

1-(methoxymethyl)-3-phenoxybenzene

Conditions
ConditionsYield
With sodium hydride In diethylene glycol dimethyl ether; Petroleum ether at 55 - 90℃; for 2.5h;92%
C15H10O6
1426427-33-9

C15H10O6

3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

C28H20O7
1426427-37-3

C28H20O7

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 0 - 25℃; for 2h; Mitsunobu Displacement;92%
3-Phenoxybenzyl alcohol
13826-35-2

3-Phenoxybenzyl alcohol

anthranilic acid amide
28144-70-9

anthranilic acid amide

2-(3-phenoxyphenyl)-3,4-dihydroquinazolin-4-one
688309-06-0

2-(3-phenoxyphenyl)-3,4-dihydroquinazolin-4-one

Conditions
ConditionsYield
With tert.-butylhydroperoxide In dimethyl sulfoxide at 110℃; for 12h;92%
With potassium hydroxide In toluene at 90℃; for 20h;82%

3-Phenoxybenzyl alcohol Chemical Properties

IUPAC Name: 3-Phenoxybenzyl alcohol
The MF of 3-Phenoxybenzyl alcohol (13826-35-2) is C13H12O2.

                           
The MW of 3-Phenoxybenzyl alcohol (13826-35-2) is 200.23.
Synonyms of 3-Phenoxybenzyl alcohol (13826-35-2): (3-Phenoxyphenyl)methanol ; Benzenemethanol, 3-phenoxy- ; 3-(Hydroxymethyl)diphenyl ether 
Product Categories: Benzhydrols,Benzyl & Special Alcohols;Alcohols;Oxygen Compounds
Form: colourless liquid
Index of Refraction: 1.595  
EINECS: 237-525-1
Density: 1.151 g/ml 
Flash Point: 151.3 °C 
Boiling Point: 377.8 °C
Melting Point: 4-7 °C
Water Solubility: Insoluble
BRN: 475312
Stability: Stable

3-Phenoxybenzyl alcohol Uses

  3-Phenoxybenzyl alcohol (13826-35-2) is permethrin, phenothrin and permethrin and other pesticides in the middle of ether, pharmaceutical intermediates.

3-Phenoxybenzyl alcohol Toxicity Data With Reference

1.    

orl-rat LD50:3 g/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47.
2.    

orl-mus LD50:2040 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47.
3.    

ipr-mus LD50:575 mg/kg

    JAFCAU    Journal of Agricultural and Food Chemistry. 25 (1977),9.

3-Phenoxybenzyl alcohol Consensus Reports

Reported in EPA TSCA Inventory.

3-Phenoxybenzyl alcohol Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 3-Phenoxybenzyl alcohol (13826-35-2):
Hazard Codes  Xn,Xi
Risk Statements 
22  Harmful if swallowed
Safety Statements 
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37  Wear suitable protective clothing and gloves
WGK Germany  3
RTECS  DP0775400
Hazard Note  Irritant

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