Product Name

  • Name

    Boronic acid, B-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-

  • EINECS
  • CAS No. 952514-79-3
  • Article Data13
  • CAS DataBase
  • Density 1.21±0.1 g/cm3(Predicted)
  • Solubility
  • Melting Point
  • Formula C19H15 B N2 O2
  • Boiling Point 572.6±60.0 °C(Predicted)
  • Molecular Weight 314.151
  • Flash Point
  • Transport Information
  • Appearance
  • Safety
  • Risk Codes
  • Molecular Structure Molecular Structure of 952514-79-3 (Boronic acid, B-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-)
  • Hazard Symbols
  • Synonyms Boronic acid, B-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]-
  • PSA 58.28000
  • LogP 2.37230

Synthetic route

triethyl borate
150-46-9

triethyl borate

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium In tetrahydrofuran; cyclohexane at -78℃; for 1h; Inert atmosphere;
Stage #2: triethyl borate In tetrahydrofuran; cyclohexane at 20℃; for 12h; Inert atmosphere;
80%
Triisopropyl borate
5419-55-6

Triisopropyl borate

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;74%
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -78 - 20℃;
58.3%
Triisopropyl borate
5419-55-6

Triisopropyl borate

water
7732-18-5

water

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: Triisopropyl borate; 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
Stage #2: water With hydrogenchloride In tetrahydrofuran; hexane
74%
hydrogenchloride
7647-01-0

hydrogenchloride

Trimethyl borate
121-43-7

Trimethyl borate

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: With n-butyllithium at -78℃; for 0.5h;
Stage #3: hydrogenchloride; Trimethyl borate Further stages;
70%
Trimethyl borate
121-43-7

Trimethyl borate

water
7732-18-5

water

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: Trimethyl borate In tetrahydrofuran for 2h;
Stage #3: water In tetrahydrofuran for 0.333333h;
65%
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: Trimethyl borate In tetrahydrofuran for 2h;
Stage #3: water With hydrogenchloride In tetrahydrofuran for 0.833333h;
60%
2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium; Trimethyl borate
Stage #2: With hydrogenchloride In water
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: thionyl chloride / 1,2-dichloro-ethane / 3 h / Reflux
2.1: 1-methyl-pyrrolidin-2-one / 20 °C
3.1: acetic acid / 12 h / Reflux
4.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
4.2: -78 - 20 °C
View Scheme
4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 1-methyl-pyrrolidin-2-one / 20 °C
2.1: acetic acid / 12 h / Reflux
3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
3.2: -78 - 20 °C
View Scheme
Multi-step reaction with 3 steps
1: triethylamine / 1-methyl-pyrrolidin-2-one / 20 °C
2: acetic acid / 12 h / Reflux
3: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: triethylamine / 1-methyl-pyrrolidin-2-one / 20 °C
2: acetic acid / 12 h / Reflux
3: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: N,N-dimethyl acetamide
2.1: acetic acid / 0.5 h / 115 °C
3.1: TEFLON / tetrahydrofuran / 0.5 h / -78 °C
3.2: 0.5 h / -78 °C
View Scheme
4-bromo-N-(2-(phenylamino)phenyl)benzamide
359427-13-7

4-bromo-N-(2-(phenylamino)phenyl)benzamide

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: acetic acid / 12 h / Reflux
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: acetic acid / 12 h / Reflux
2: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: acetic acid / 12 h / Reflux
2: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1.1: acetic acid / 0.5 h / 115 °C
2.1: TEFLON / tetrahydrofuran / 0.5 h / -78 °C
2.2: 0.5 h / -78 °C
View Scheme
4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: N,N-dimethyl-formamide / 130 °C / Molecular sieve; Inert atmosphere
2: potassium iodide / N,N-dimethyl-formamide / 80 °C
3: sodium hydroxide / N,N-dimethyl-formamide; water / 0.5 h / 20 °C
View Scheme
(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)boronic acid MIDA ester

(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)boronic acid MIDA ester

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
With sodium hydroxide In water; N,N-dimethyl-formamide at 20℃; for 0.5h;
4-formylphenylboronic acid
1072960-66-7

4-formylphenylboronic acid

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium iodide / N,N-dimethyl-formamide / 80 °C
2: sodium hydroxide / N,N-dimethyl-formamide; water / 0.5 h / 20 °C
View Scheme
N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: triethylamine / 1-methyl-pyrrolidin-2-one / 20 °C
2: acetic acid / 12 h / Reflux
3: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1: triethylamine / 1-methyl-pyrrolidin-2-one / 20 °C
2: acetic acid / 12 h / Reflux
3: n-butyllithium / tetrahydrofuran; hexane / -78 - 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 3 steps
1.1: N,N-dimethyl acetamide
2.1: acetic acid / 0.5 h / 115 °C
3.1: TEFLON / tetrahydrofuran / 0.5 h / -78 °C
3.2: 0.5 h / -78 °C
View Scheme
4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: triethylamine / tetrahydrofuran
2: n-butyllithium
View Scheme
Trimethyl borate
121-43-7

Trimethyl borate

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Stage #1: 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole With n-butyllithium
Stage #2: Trimethyl borate
Stage #3: With hydrogenchloride In water
2-bromo-1-phenyl-1H-benzo[d]imidazole

2-bromo-1-phenyl-1H-benzo[d]imidazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol; water / 10 h / 85 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; cyclohexane / 1 h / -78 °C / Inert atmosphere
2.2: 12 h / 20 °C / Inert atmosphere
View Scheme
2-bromo-1H-1,3-benzodiazole
54624-57-6

2-bromo-1H-1,3-benzodiazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: copper(l) iodide; 18-crown-6 ether; potassium carbonate / N,N-dimethyl acetamide / 12 h / 165 °C / Inert atmosphere
2.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol; water / 10 h / 85 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; cyclohexane / 1 h / -78 °C / Inert atmosphere
3.2: 12 h / 20 °C / Inert atmosphere
View Scheme
iodobenzene
591-50-4

iodobenzene

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: copper(l) iodide; 18-crown-6 ether; potassium carbonate / N,N-dimethyl acetamide / 12 h / 165 °C / Inert atmosphere
2.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / toluene; ethanol; water / 10 h / 85 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran; cyclohexane / 1 h / -78 °C / Inert atmosphere
3.2: 12 h / 20 °C / Inert atmosphere
View Scheme
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

2',7'-dibromospiro[fluorene-9,9'-thioxanthene]

2',7'-dibromospiro[fluorene-9,9'-thioxanthene]

C63H40N4S

C63H40N4S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 5h; Suzuki Coupling; Inert atmosphere; Reflux;95%
9-(2-chloroquinazolin-4-yl)-9H-carbazole
1262866-84-1

9-(2-chloroquinazolin-4-yl)-9H-carbazole

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

9-(2-(4-(1-phenyl-1H-indol-2-yl)phenyl)quinazolin-4-yl)-9H-carbazole

9-(2-(4-(1-phenyl-1H-indol-2-yl)phenyl)quinazolin-4-yl)-9H-carbazole

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In water; toluene at 100℃; for 4h; Inert atmosphere;94%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

2-amino-6-bromophenol
28165-50-6

2-amino-6-bromophenol

C25H19N3O

C25H19N3O

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate In N,N-dimethyl-formamide at 80℃; for 2h;92%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

7-(4-bromophenyl)-7H-benzofuro[2,3-b]carbazole

7-(4-bromophenyl)-7H-benzofuro[2,3-b]carbazole

FCBI

FCBI

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In ethanol; water; toluene Suzuki Coupling;91.7%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

3-bromo-2-(dibenzo[b,d]thiophen-4-yl)pyridine

3-bromo-2-(dibenzo[b,d]thiophen-4-yl)pyridine

C35H22N2S

C35H22N2S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 5h; Reflux;91%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C29H21BrN2

C29H21BrN2

C48H34N4

C48H34N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 12h; Reflux; Inert atmosphere;89%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C38H22BrN

C38H22BrN

C57H35N3

C57H35N3

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water for 5h; Reflux; Inert atmosphere;89%
3,5-bis(4-tert-butylphenyl)-1-bromobenzene
351029-50-0

3,5-bis(4-tert-butylphenyl)-1-bromobenzene

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C45H42N2

C45H42N2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere;89%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

para-bromoacetophenone
99-90-1

para-bromoacetophenone

C27H20N2O

C27H20N2O

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 80℃; for 16h; Inert atmosphere;88.5%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 20 - 80℃; for 16h; Inert atmosphere;88.5%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

2-bromo-5-chloro-1,3,4-thiadiazole

2-bromo-5-chloro-1,3,4-thiadiazole

C40H26N6S

C40H26N6S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 14h; Inert atmosphere;88%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

3-bromo-2-(dibenzo[b,d]furan-4-yl)pyridine

3-bromo-2-(dibenzo[b,d]furan-4-yl)pyridine

C36H23N3O

C36H23N3O

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 5h; Reflux;87%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C32H20BrNO

C32H20BrNO

C51H33N3O

C51H33N3O

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In tetrahydrofuran; water for 4h; Inert atmosphere; Reflux;87%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene
1361126-22-8

10-(4-Bromophenyl)-12,12-dimethyl-10,12dihydro-10-azaindeno[2,1-b]-fluorene

ICBI

ICBI

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In ethanol; water; toluene Suzuki Coupling;85.7%
(rac)-2,2'-diiodo-9,9'-spirobifluorene
790674-48-5

(rac)-2,2'-diiodo-9,9'-spirobifluorene

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C63H40N4
1274565-72-8

C63H40N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); tri-tert-butyl phosphine; sodium carbonate In toluene for 48h; Inert atmosphere; Reflux;85%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C31H20BrN
1290058-18-2

C31H20BrN

8,8-Diphenyl-6-[4-(1-phenyl-1H-benzoimidazol-2-yl)-phenyl]-8H-indolo[3,2,1-de]acridine
1290058-19-3

8,8-Diphenyl-6-[4-(1-phenyl-1H-benzoimidazol-2-yl)-phenyl]-8H-indolo[3,2,1-de]acridine

Conditions
ConditionsYield
With potassium phosphate monohydrate; tris-(o-tolyl)phosphine; palladium diacetate In 1,4-dioxane; water; toluene for 5h; Reflux;85%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C34H21BrN2

C34H21BrN2

C53H34N4

C53H34N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 5h; Inert atmosphere; Heating;85%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

6-bromobenzo[d]triphenyleno[2,3-b]thiophene

6-bromobenzo[d]triphenyleno[2,3-b]thiophene

C43H26N2S

C43H26N2S

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium hydroxide In tetrahydrofuran; water at 90℃; for 24h; Inert atmosphere;85%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C19H18F3NO5S

C19H18F3NO5S

C37H31N3O2

C37H31N3O2

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 70℃; for 8h; Inert atmosphere;84.9%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

2,7-dibromo-9,9'-spirobi[fluorene]
171408-84-7

2,7-dibromo-9,9'-spirobi[fluorene]

C63H40N4
1274565-70-6

C63H40N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); tri-tert-butyl phosphine; sodium carbonate In toluene for 48h; Inert atmosphere; Reflux;84%
9-Bromoanthracene
1564-64-3

9-Bromoanthracene

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

9-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]anthracene
944801-79-0

9-[4-(1-phenyl-1H-benzimidazol-2-yl)phenyl]anthracene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 6h; Inert atmosphere; Reflux;83%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C23H14ClN

C23H14ClN

C42H27N3

C42H27N3

Conditions
ConditionsYield
With potassium phosphate; bis(tri-t-butylphosphine)palladium(0) In 1,4-dioxane; water for 5h; Reflux;83%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

2-phenyl-6-chloroimidazo<1,2-b>pyridazine
1844-53-7

2-phenyl-6-chloroimidazo<1,2-b>pyridazine

C31H21N5

C31H21N5

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran for 10h; Reflux; Inert atmosphere;83%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C20H8Br2O4S2

C20H8Br2O4S2

C58H34N4O4S2

C58H34N4O4S2

Conditions
ConditionsYield
With bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II); sodium carbonate In toluene at 75 - 90℃; Inert atmosphere;83%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C25H17BrN2

C25H17BrN2

C44H30N4

C44H30N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 10h; Suzuki Coupling;82.9%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

12-bromo-pyrido[3',2':4,5]pyrrolo[1,2-f]phenanthridine

12-bromo-pyrido[3',2':4,5]pyrrolo[1,2-f]phenanthridine

C38H24N4

C38H24N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 24h; Reflux;82%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

3-(10-bromophenanthren-9-yl)-9-phenyl-9H-carbazole

3-(10-bromophenanthren-9-yl)-9-phenyl-9H-carbazole

9-phenyl-3-(10-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)phenanthren-9-yl)-9H-carbazole

9-phenyl-3-(10-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)phenanthren-9-yl)-9H-carbazole

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In tetrahydrofuran; water for 6h; Suzuki Coupling; Reflux; Inert atmosphere;82%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

3-bromo-9-(naphthalen-2-yl)-9H-carbazole
934545-80-9

3-bromo-9-(naphthalen-2-yl)-9H-carbazole

9-(naphthyl-2-yl)-3-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-9H carbazole
1334036-93-9

9-(naphthyl-2-yl)-3-(4-(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl)-9H carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran for 48h; Suzuki coupling; Inert atmosphere; Reflux;81.2%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

5,10-dibromo-1,2-diphenyl-1H-phenanthro[9,10-d]imidazole

5,10-dibromo-1,2-diphenyl-1H-phenanthro[9,10-d]imidazole

C65H42N6

C65H42N6

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 5h; Inert atmosphere; Reflux;81%
(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid
952514-79-3

(4-(1-phenyl-1H-benzo [d]imidazole-2-yl) phenyl)boronic acid

C48H43Br

C48H43Br

2-(4-(2,6-di-tert-butyl-10-(4-(1,2,2-triphenylvinyl)phenyl)anthracen-9-yl)phenyl)-1-phenyl-1H-benzo[d]imidazole

2-(4-(2,6-di-tert-butyl-10-(4-(1,2,2-triphenylvinyl)phenyl)anthracen-9-yl)phenyl)-1-phenyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; water; toluene at 110℃; for 12h; Suzuki Coupling; Inert atmosphere;81%

4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic acid Chemical Properties

Molecular Structure of 4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic acid (CAS No.952514-79-3):
Molecular Formula: C19H15BN2O2
Molecular Weight: 314.15
CAS No: 952514-79-3
Product Categories: Electronic Chemicals

4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic acid Specification

   4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic acid (CAS No.952514-79-3), its synonym is B-[4-(1-Phenyl-1H-benzimidazol-2-yl)phenyl]boronic acid  .

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