Allyldiglycol supplier | CasNO.15075-50-0

Name
Allyldiglycol
EINECS 239-131-5
CAS No. 15075-50-0
Article Data23
CAS DataBase
Density 0.978 g/cm³
Solubility
Melting Point
Formula C₇H₁₄O₃
Boiling Point 213.1 °C at 760 mmHg
Molecular Weight 146.186
Flash Point 82.7 °C
Transport Information
Appearance
Safety 26
Risk Codes 36
Molecular Structure
Hazard Symbols
Synonyms Dimethyleneglycolmonoallylether;
PSA 38.69000
LogP 0.19790

Synthetic route

: 1352078-72-8
Methyl (2-allyloxy-ethoxy)-acetate

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 1h;	99%

: 106-95-6
allyl bromide

: 111-46-6
diethylene glycol

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With copper In N,N-dimethyl-formamide Heating;	92%
With sodium at 100℃; for 2h;	84%
With sodium hydroxide In tetrahydrofuran for 12h; Heating / reflux;	66%

: 106-95-6
allyl bromide

A: 15075-50-0
2-(2-allyloxyethoxy)ethanol

B: Diethylene Glycol Monoallylether Sulfate

Conditions

Conditions	Yield
In diethylene glycol	A 88% B n/a

: 107-05-1
3-chloroprop-1-ene

: 111-46-6
diethylene glycol

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With sodium hydroxide In 1,4-dioxane at 50 - 55℃; for 6h; Williamson synthesis;	82.5%
With sodium hydroxide In 1,4-dioxane at 50 - 55℃; for 6h;	82.5%
Stage #1: diethylene glycol With sodium hydroxide In 1,4-dioxane at 55℃; for 1h; Stage #2: 3-chloroprop-1-ene In 1,4-dioxane for 6h; Heating;	49.6%
With sodium hydroxide In 1,4-dioxane

: 556-56-9
allyl iodid

: 111-46-6
diethylene glycol

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran at 20℃; for 25h;	70%

: 75-21-8
oxirane

: 107-18-6
allyl alcohol

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 106-95-6
allyl bromide

sodium diethylene glycolate: sodium diethylene glycolate

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With diethylene glycol

: 107-05-1
3-chloroprop-1-ene

sodium diethylene glycolate: sodium diethylene glycolate

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With diethylene glycol

: 727986-30-3
2-(2-(2-(allyloxy)ethoxy)ethoxy)tetrahydro-2H-pyran

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water Heating;	150 g

: 111-45-5
ethylene glycol monoallyl ether

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: sodium hydride / tetrahydrofuran / 1 h / 20 °C / Reflux 1.2: 0.25 h / 0 °C 2.1: lithium aluminium tetrahydride / tetrahydrofuran / 1 h / 0 °C View Scheme

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 76-02-8
Trichloroacetyl chloride

: Trichloroacetic acid 3,6-dioxanon-8-enyl ester

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0℃; for 2h; Acylation;	99%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 98-59-9
p-toluenesulfonyl chloride

: 84183-96-0
allyl diethylene glycol toluene-p-sulfonate

Conditions

Conditions	Yield
With pyridine at -20℃; for 72h;	97.6%
Stage #1: 2-(2-allyloxyethoxy)ethanol With sodium hydroxide In tetrahydrofuran; water at 0℃; for 0.5h; Stage #2: p-toluenesulfonyl chloride In tetrahydrofuran; water at 0 - 20℃; for 1h;	33%
With dmap; triethylamine In dichloromethane

: 626-05-1
2,6-Dibromopyridine

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 2,6-bis{2-[2-(allyloxy)ethoxy]ethoxy}pyridine

Conditions

Conditions	Yield
Stage #1: 2-(2-allyloxyethoxy)ethanol With sodium hydride In N,N-dimethyl-formamide for 0.5h; Stage #2: 2,6-Dibromopyridine In N,N-dimethyl-formamide at 100℃; for 16h;	84%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 19249-03-7
triethylene glycol di-(p-toluenesulfonate)

: 136824-79-8
heptaethylene glycol bis(allyl ether)

Conditions

Conditions	Yield
With potassium hydroxide; tetrabutylammomium bromide In toluene at 100℃; for 2h;	81%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 350-46-9
4-Fluoronitrobenzene

: 374588-11-1
1-(2-(2-(allyloxy)ethoxy)ethoxy)-4-nitrobenzene

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In benzene for 4h; Heating;	66%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 372-09-8
cyanoacetic acid

: 2-(allyloxyethoxy)ethyl cyanoacetate

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In benzene Heating;	65%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 96-32-2
bromoacetic acid methyl ester

: 1352078-76-2
Methyl (2-(2-allyloxy-ethoxy)-ethoxy)-acetate

Conditions

Conditions	Yield
Stage #1: 2-(2-allyloxyethoxy)ethanol With sodium hydride In tetrahydrofuran at 20℃; for 1h; Reflux; Stage #2: bromoacetic acid methyl ester In tetrahydrofuran at 0℃; for 0.25h;	64%
With sodium hydride In tetrahydrofuran

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 1493-27-2
ortho-nitrofluorobenzene

: 188650-11-5
2-(1,4,7-trioxadec-9-enyl)nitrobenzene

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In water; benzene for 1h; Heating;	62%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 5394-63-8
2,2,6-trimethyl-4H-1,3-dioxin-4-one

: 204522-64-5
3-Oxo-butyric acid 2-(2-allyloxy-ethoxy)-ethyl ester

Conditions

Conditions	Yield
In xylene for 1.5h; Heating;	58%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 125289-14-7
3,6-dioxa-8-en-nonyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranoside

Conditions

Conditions	Yield
With mercury(II) cyanide In nitromethane; benzene Ambient temperature;	54.6%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 106-89-8
epichlorohydrin

: 198642-83-0
2-[2-(2-allyloxyethoxy)ethoxymethyl]oxirane

Conditions

Conditions	Yield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate at 0 - 5℃;	50%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 55357-38-5
choline tosylate

: C12H26NO6P

Conditions

Conditions	Yield
Stage #1: 2-(2-allyloxyethoxy)ethanol With pyridine; trichlorophosphate In dichloromethane at 0 - 20℃; for 2h; Stage #2: choline tosylate With pyridine In water at 0 - 20℃; for 30h;	50%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: C41H44N4O2(2-)*Co(2+)

: C48H56N4O4(2-)*Co(2+)

Conditions

Conditions	Yield
With tributyl-amine; 2-chloro-1-methyl-pyridinium iodide In dichloromethane for 20h; Esterification; Heating;	19%

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 920-46-7
Methacryloyl chloride

: 58985-94-7
(2-allyloxy-ethyl)-(2-methacryloyloxy-ethyl)-ether

Conditions

Conditions	Yield
With pyridine
With triethylamine at 0 - 20℃; for 3.08333h;

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 74-86-2
acetylene

: 83305-79-7
diethylene glycol vinyl allyl diether

Conditions

Conditions	Yield
With potassium hydroxide at 150℃;

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 77-47-4
hexachlorocyclopentadiene

: 19830-13-8
<1,4,5,6,7,7-Hexachlor-bicyclo<2.2.1>hepten-(5)-yl-(2)-methyl>-<2-(2-hydroxy-ethoxy)-ethyl>-ether

Conditions

Conditions	Yield
In o-xylene at 144℃;

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 638-21-1
phenylphosphane

: 144685-39-2
2-{2-[3-({3-[2-(2-Hydroxy-ethoxy)-ethoxy]-propyl}-phenyl-phosphanyl)-propoxy]-ethoxy}-ethanol

Conditions

Conditions	Yield
for 192h; Irradiation;	95 % Spectr.

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 829-85-6
diphenylphosphane

: 144685-38-1
2-[2-(3-Diphenylphosphanyl-propoxy)-ethoxy]-ethanol

Conditions

Conditions	Yield
for 192h; Irradiation;	95 % Spectr.

: 118-48-9
isatoic anhydride

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 188650-08-0
2-Amino-benzoic acid 2-(2-allyloxy-ethoxy)-ethyl ester

Conditions

Conditions	Yield
With sodium hydride 1.) benzene, reflux, 1 h, 2.) pyridine, reflux, 5 h; Yield given. Multistep reaction;

: 674-82-8
4-methyleneoxetan-2-one

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: 2-diazo-3-oxo-butyric acid 2-(2-allyloxy-ethoxy)-ethyl ester

Conditions

Conditions	Yield
Stage #1: 4-methyleneoxetan-2-one; 2-(2-allyloxyethoxy)ethanol With triethylamine In tetrahydrofuran at 0 - 20℃; Stage #2: With triethylamine; Methanesulfonyl azide In tetrahydrofuran at 0 - 20℃; Further stages.;

: 15075-50-0
2-(2-allyloxyethoxy)ethanol

: (2-{4-[2-(2-allyloxy-ethoxy)-ethoxy]-phenoxy}-ethyl)-carbamic acid tert-butyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Et3N; DMAP / CH2Cl2 2: K2CO3 / ethanol View Scheme

Allyldiglycol Specification

The Allyldiglycol, with the CAS registry number of 15075-50-0, is also known as Dimethyleneglycolmonoallylether. It belongs to the product category of Monomer. Its EINECS registry number is 239-131-5. This chemical's molecular formula is C₇H₁₄O₃ and molecular weight is 146.18. What's more, both its systematic name and IUPAC name are the same which is called 2-(2-Prop-2-enoxyethoxy)ethanol. As a chemical, it is irritating to eyes. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice.

Physical properties about the Allyldiglycol are: (1)ACD/LogP: -0.26; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.26; (4)ACD/LogD (pH 7.4): -0.26; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 17.22; (8)ACD/KOC (pH 7.4): 17.22; (9)#H bond acceptors: 3; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 27.69 Å²; (13)Index of Refraction: 1.438; (14)Molar Refractivity: 39.22 cm³; (15)Molar Volume: 149.4 cm³; (16)Surface Tension: 32.1 dyne/cm; (17)Density: 0.978 g/cm³; (18)Flash Point: 82.7 °C; (19)Enthalpy of Vaporization: 52.27 kJ/mol; (20)Boiling Point: 213.1 °C at 760 mmHg; (21)Vapour Pressure: 0.0372 mmHg at 25 °C.

Preparation: this chemical is prepared by reaction of 3-Bromo-propene with 2,2'-Oxy-bis-ethanol at heating. The reaction needs reagent Copper powder and solvent Dimethylformamide. The yield is about 92 %.

Uses: it is used to produce other chemicals. For example, it is used to produce Cyano-acetic acid 2-(2-allyloxy-ethoxy)-ethyl ester at heating. This reaction needs reagents TsOH and Cyanoacetic acid. Meanwhile, it needs solvent Benzene. The yield is about 65 %.

You can still convert the following datas into molecular structure:
(1) SMILES:O(C\C=C)CCOCCO
(2) InChI:InChI=1/C7H14O3/c1-2-4-9-6-7-10-5-3-8/h2,8H,1,3-7H2
(3) InChIKey:DIOZVWSHACHNRT-UHFFFAOYAT

Product Name

Allyldiglycol

Synthetic route

Allyldiglycol Specification

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