Aluminium sodium tetrachloride supplier

Name
SODIUM TETRACHLOROALUMINATE
EINECS 232-050-6
CAS No. 7784-16-9
Article Data22
CAS DataBase
Density 2.01 g/mL at 25 °C(lit.)
Solubility Soluble in water
Melting Point 185 °C(lit.)
Formula AlCl₄Na
Boiling Point
Molecular Weight 191.783
Flash Point
Transport Information
Appearance
Safety 22-26-27-36/37/39-45
Risk Codes 14-34
Molecular Structure
Hazard Symbols C
Synonyms Sodium tetrachloroaluminate;
PSA 0.00000
LogP 2.75800

Synthetic route

: 7647-14-5
sodium chloride

: 7784-16-9
sodium tetrachloroaluminate

Conditions

Conditions	Yield
With aluminium trichloride
With hydrogenchloride; aluminum oxide In melt melt of NaCl in graphite crucible; Al2O3 tube affected;

: 7446-70-0
aluminium trichloride

A: 7784-16-9
sodium tetrachloroaluminate

B: 7429-90-5
aluminium

Conditions

Conditions	Yield
With sodium In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;;
With Na In neat (no solvent) passing excess AlCl3 vapor over Na in a iron tube at 200-300°C;completion of the reaction by heating the mixture of Al and NaAlCl3 in pots of clay or cast iron until beginning vaporization of NaAlCl3;; removal and melting of Al balls;;

: 7429-90-5
aluminium

: 7647-14-5
sodium chloride

: 7784-16-9
sodium tetrachloroaluminate

Conditions

Conditions	Yield
In not given

: 7446-70-0
aluminium trichloride

: 7647-14-5
sodium chloride

: 7784-16-9
sodium tetrachloroaluminate

Conditions

Conditions	Yield
In neat (no solvent) drybox and vac. line techniques; fused together in an ampoule; recrystd., decanted, zone-refining;
pre-electrolysis and filtration;
In neat (no solvent, solid phase) stoich. quant. of AlCl3 and NaCl (previously fused at 1023 K) were fused together under Ar;

: 7446-70-0
aluminium trichloride

: 7784-16-9
sodium tetrachloroaluminate

Conditions

Conditions	Yield
With NaCl In melt AlCl3/NaCl melt (170-240°C), NaCl satd.;

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na2(AlO2)2(SiO2)190

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 450°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na5(AlO2)5(SiO2)187

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 375°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na24(AlO2)24(SiO2)168

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 300°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na20(AlO2)20(SiO2)172

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 350°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na26(AlO2)26(SiO2)166

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 250°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 10026-04-7, 53609-55-5
tetrachlorosilane

: NaY zeolite

A: 7784-16-9
sodium tetrachloroaluminate

B: Na32(AlO2)32(SiO2)160

Conditions

Conditions	Yield
byproducts: NaCl, AlCl3; Under N2, the dehydrated zeolite is heated in a flow of a SiCl4 and N2 mixt. for 1 h at 200°C.; Flushing for addnl. 2 h at the same temp. to remove excess SiCl4 and volatile AlCl3, cooling to room temp., washing with deionized water, ion exchange with NH4Cl; detn. of Si/Al ratio by IR, (29)Si-, (27)Al-NMR and X-ray diffraction.;

...Expand

: 7446-70-0
aluminium trichloride

: 16920-10-8
Na(1+)*NbCl6(1-)=NaNbCl6

A: 7784-16-9
sodium tetrachloroaluminate

B: 10026-12-7
niobium pentachloride

Conditions

Conditions	Yield
In not given

...Expand

: 7446-70-0
aluminium trichloride

: 16920-14-2
sodium tantalum hexachloride

A: 7784-16-9
sodium tetrachloroaluminate

B: 7721-01-9
tantalum pentachloride

...Expand

: 7446-70-0
aluminium trichloride

: 103349-41-3
sodium tri-tert-butylsilanide

A: 7784-16-9
sodium tetrachloroaluminate

B: supersilylaluminium dichloride, dimer

Conditions

Conditions	Yield
In benzene-d6 (inert conditions); heating for 1 week;

...Expand

: 7784-16-9
sodium tetrachloroaluminate

: 63580-87-0
2-(difluorochloromethyl)-6-(fluoro-dichloromethyl)-chlorobenzene

: 63430-03-5
1-trifluoromethyl-2-chloro-3-trichloromethyl-benzene

: 7784-16-9
sodium tetrachloroaluminate

: 7446-11-9
sulfur trioxide

: Na(1+)*Al(3+)*4(SO3Cl)(1-)=NaAl(SO3Cl)4

Conditions

Conditions	Yield
In liquid sulphur dioxide -15°C;

: niobium(V) oxide

: 7784-16-9
sodium tetrachloroaluminate

: 13597-20-1
niobium(V) oxide chloride

Conditions

Conditions	Yield
In gaseous matrix Kinetics; heating mixture of NaAlCl4 and Nb2O5 (annealed at 400°C, fine powdered) in stream of Ar at 350°C;;
In melt byproducts: AlOCl, NaCl; Nb2O5 and molten NaAlCl4 below 600°C;;
In neat (no solvent) 275-450°C;;

: cryolite

: 7784-16-9
sodium tetrachloroaluminate

: 7429-90-5
aluminium

Conditions

Conditions	Yield
With sodium In neat (no solvent) by bringing a mixture of powdered NaAlCl3 and Na3AlF6 with pieces of Na (ratio=10:5:2) into a warm furnace; violent reaction, mass and furnace getting white-hot, for completion of reaction further heating;; tapping, Al flows out in liquid slag; yields Al pieces of 6-8 kg;;
With Na In neat (no solvent) by bringing a mixture of powdered NaAlCl3 and Na3AlF6 with pieces of Na (ratio=10:5:2) into a warm furnace; violent reaction, mass and furnace getting white-hot, for completion of reaction further heating;; tapping, Al flows out in liquid slag; yields Al pieces of 6-8 kg;;

: 7784-16-9
sodium tetrachloroaluminate

: 7429-90-5
aluminium

Conditions

Conditions	Yield
In neat (no solvent) reduction with sodium potassium alloy;;
With sodium In neat (no solvent) by heating a mixture of NaAlCl3 and Na using CaF2 as flux;; Al castings;;
With sodium In neat (no solvent) by heating a mixture of NaAlCl3 and Na using Na3AlF6 as flux;; Al casting;;

: 7784-16-9
sodium tetrachloroaluminate

: 10049-14-6
uranium(IV) tetrafluoride

: 10026-10-5
uranium(IV) chloride

: 7784-16-9
sodium tetrachloroaluminate

: 50960-82-2
carbonylgold(I) chloride

: sodium tetrachloroaurate(III)

Conditions

Conditions	Yield
In thionyl chloride

: 7784-16-9
sodium tetrachloroaluminate

A: tetrafluoroaluminate(1-)

B: 108528-94-5
AlClF3(1-)

C: 109144-15-2
AlCl2F2(1-)

D: 109144-16-3
AlCl3F(1-)

Conditions

Conditions	Yield
With NaF In further solvent(s) byproducts: NaCl; dissolved in molten NaF at 820 ° C (ratio F:Al = 3.0); product ratio detd. by Raman spectroscopy;

...Expand

: 7784-16-9
sodium tetrachloroaluminate

A: tetrafluoroaluminate(1-)

B: 108528-94-5
AlClF3(1-)

C: 109144-15-2
AlCl2F2(1-)

D: 109144-16-3
AlCl3F(1-)

E: tetrachloroaluminate(1-)

Conditions

Conditions	Yield
With LiCl; NaF In further solvent(s) byproducts: NaCl; various amounts dissolved in 80 mol-% LiCl and 20 mol-% NaF (temp. >490 ° C);
With NaF In further solvent(s) byproducts: NaCl; dissolved in molten NaF at 820 ° C, various amounts of NaAlCl4 (ratio F:Al = 2.0 or 2.5); product ratio detd. by Raman spectroscopy;

...Expand

: 7784-16-9
sodium tetrachloroaluminate

A: 108528-94-5
AlClF3(1-)

B: 109144-15-2
AlCl2F2(1-)

C: 109144-16-3
AlCl3F(1-)

D: tetrachloroaluminate(1-)

Conditions

Conditions	Yield
With NaF In further solvent(s) byproducts: NaCl; dissolved in molten NaF at 820 ° C (ratio F:Al = 1.44); product ratio detd. by Raman spectroscopy;

...Expand

: 7784-16-9
sodium tetrachloroaluminate

A: 109144-15-2
AlCl2F2(1-)

B: 109144-16-3
AlCl3F(1-)

Conditions

Conditions	Yield
With NaCl; NaF In further solvent(s) various amounts dissolved in 60 mol-% NaCl and 40 mol-% NaF (820 ° C);

: 7784-16-9
sodium tetrachloroaluminate

A: 109144-15-2
AlCl2F2(1-)

B: 109144-16-3
AlCl3F(1-)

C: tetrachloroaluminate(1-)

Conditions

Conditions	Yield
With NaF In further solvent(s) byproducts: NaCl; dissolved in molten NaF at 820 ° C (ratio F:Al = 0.99); product ratio detd. by Raman spectroscopy;

...Expand

: 7784-16-9
sodium tetrachloroaluminate

: 7664-93-9
sulfuric acid

: sodium aluminum hydrosulfate

Conditions

Conditions	Yield
In neat (no solvent) 100% H2SO4; 100°C; several days at 80°C;
In liquid sulphur dioxide molar ratio H2SO4 : NaAlCl4 = 4:1;

Aluminium sodium tetrachloride Specification

The Aluminium sodium tetrachloride is an organic compound with the formula AlCl₄Na. The IUPAC name of this chemical is sodium tetrachloroalumanuide. With the CAS registry number 7784-16-9, the product's categories are AluminumMetal and Ceramic Science; Catalysis and Inorganic Chemistry; Chemical Synthesis; Salts; Sodium Salts. Besides, it should be stored in a closed cool and dry place.

When you are using this chemical, please be cautious about it as the following:
It reacts violently with water. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical can cause burns. When you are using it, wear suitable gloves and eye/face protection and do not breathe dust. Please take off immediately all contaminated clothing. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].Cl[Al-](Cl)(Cl)Cl
(2)InChI: InChI=1/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4/rAlCl4.Na/c2-1(3,4)5;/q-1;+1
(3)InChIKey: CMLRNXGMTZKKSR-MLBQZSPTAH
(4)Std. InChI: InChI=1S/Al.4ClH.Na/h;4*1H;/q+3;;;;;+1/p-4
(5)Std. InChIKey: CMLRNXGMTZKKSR-UHFFFAOYSA-J

Product Name

SODIUM TETRACHLOROALUMINATE

Synthetic route

Aluminium sodium tetrachloride Specification

Related Products

Hot Products