Bathophenanthroline supplier

Name
Bathophenanthroline
EINECS 216-767-1
CAS No. 1662-01-7
Article Data8
CAS DataBase
Density 1.21 g/cm³
Solubility Soluble in benzene, chloroform and dilute inorganic acid, slightly soluble in ethanol and aether, insoluble in water
Melting Point 218-220 °C(lit.)
Formula C₂₄H₁₆N₂
Boiling Point 543.108 °C at 760 mmHg
Molecular Weight 332.404
Flash Point 242.111 °C
Transport Information
Appearance white to faintly yellow crystalline powder
Safety 22-24/25-36-26
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms 1,10-Bathophenanthroline;4,7-Diphenyl-1,10-diazaphenanthrene;4,7-Diphenyl-1,10-phenanthroline;4,7-Diphenyl-o-phenanthroline;BPhen;DPA;NSC 637659;
PSA 25.78000
LogP 6.11700

Synthetic route

: 936-59-4
3-chloropropiophenone

: 95-54-5
1,2-diamino-benzene

: 1662-01-7
bathophenanthroline

Conditions

Conditions	Yield
With hydrogenchloride; hydrogen iodide In water at 100℃; for 0.333333h; Reagent/catalyst; Temperature;	76.4%

: 55484-55-4
4-phenyl-8-aminoquinoline

: 936-59-4
3-chloropropiophenone

: 1662-01-7
bathophenanthroline

Conditions

Conditions	Yield
With phosphoric acid; orthoarsenic acid

: 936-59-4
3-chloropropiophenone

: 1662-01-7
bathophenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: arsenic acid; aqueous sulfuric acid 2: SnCl2+2 H2O; ethanol 3: syrupy H3PO4; H3aso4 View Scheme

: 25771-65-7
4-phenyl-8-nitroquinoline

: 1662-01-7
bathophenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: SnCl2+2 H2O; ethanol 2: syrupy H3PO4; H3aso4 View Scheme

: 88-74-4
2-nitro-aniline

: 1662-01-7
bathophenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: arsenic acid; aqueous sulfuric acid 2: SnCl2+2 H2O; ethanol 3: syrupy H3PO4; H3aso4 View Scheme

: [Co(4,7-diphenyl-1,10-phenanthroline)2(diflunisal)][hexafluorophosphate]

A: 1662-01-7
bathophenanthroline

B: 22494-42-4
2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid

Conditions

Conditions	Yield
In aq. phosphate buffer at 37℃; for 24h; Time;

bis-(dimethyl(phenyl)silylmethyl)(cycloocta-1,5-diene)platinum(II): bis-(dimethyl(phenyl)silylmethyl)(cycloocta-1,5-diene)platinum(II)

: 1662-01-7
bathophenanthroline

: bis-(dimethyl(phenyl)silylmethyl)(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Conditions

Conditions	Yield
In toluene Ar atmosphere; stirring (60°C, 28 d); removal of excess of ligand on washing with aq. FeSO4, concn., pptn. on addn. of hexane; elem. anal.;	99%

: 14494-93-0, 23751-62-4, 106678-35-7
bis(triphenylphosphino)copper(I) nitrate

: 1662-01-7
bathophenanthroline

: 603-35-0
triphenylphosphine

: 1262033-35-1
(4,7-diphenyl-1,10-phenanthroline)bis(triphenylphosphine)copper(I) nitrate

Conditions

Conditions	Yield
In chloroform at 20℃; for 1h; Schlenk technique;	99%

...Expand

: 1662-01-7
bathophenanthroline

: 2-methyl-4,7-diphenyl-1,10-phenanthroline

Conditions

Conditions	Yield
With methyllithium In tetrahydrofuran at 0℃; for 0.25h; Inert atmosphere;	99%

: MoO2Br2(NCCH3)2

: 1662-01-7
bathophenanthroline

: ((C6H5)2C12H6N2)MoO2(Br)2

Conditions

Conditions	Yield
In tetrahydrofuran N2; stirred for 1 h; cncd., pptd. (ether), ppt. washed (diethyl ether), dried (vac.); elem. anal.;	98%

: 1662-01-7
bathophenanthroline

: 10025-73-7
chromium(III) chloride

: 1242583-98-7
[(4,7-diphenyl-1,10-phenanthroline)2CrCl2]Cl

Conditions

Conditions	Yield
With Zn In ethanol solid anhyd. CrCl3 was added to a suspn. of phenanthroline-compound in abs. ethanol, a trace amount of zinc dust was added, the mixt. was heatedto reflux for 1 h; filtered, rotary evapd.;	98%

: 1662-01-7
bathophenanthroline

: [(η5-C5H4CH2C6H4Br-4)Mo(CO)2(NCMe)2][BF4]

: [(η5-C5H4CH2C6H4Br-4)Mo(CO)2(4,7-Ph2-phen)][BF4]

Conditions

Conditions	Yield
In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;	98%

: 14104-20-2
silver tetrafluoroborate

: 1662-01-7
bathophenanthroline

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: [Ag2(4,7-diphenyl-1,10-phenanthroline)2(μ-1,3-bis(diphenylphosphino)propane)](BF4)2

Conditions

Conditions	Yield
Stage #1: silver tetrafluoroborate; 1,3-bis-(diphenylphosphino)propane In methanol; dichloromethane for 1h; Inert atmosphere; Schlenk technique; Stage #2: bathophenanthroline In methanol; dichloromethane for 1h; Inert atmosphere; Schlenk technique;	97%

...Expand

: 37366-09-9
dichloro(benzene)ruthenium(II) dimer

: 1662-01-7
bathophenanthroline

: [(BZ)(Ph2phen)RuCl]Cl

Conditions

Conditions	Yield
In methanol for 3.25h; Inert atmosphere; Reflux;	97%
In water for 0.25h; Sonication; Green chemistry;

: 1662-01-7
bathophenanthroline

: [(η5-C5H4CH2C6H4F-4)Mo(CO)2(NCMe)2][BF4]

: [(η5-C5H4CH2C6H4F-4)Mo(CO)2(4,7-Ph2-phen)][BF4]

Conditions

Conditions	Yield
In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;	97%

: 1662-01-7
bathophenanthroline

: 557-20-0
diethylzinc

: C28H26N2Zn

Conditions

Conditions	Yield
for 1h; Inert atmosphere; Schlenk technique; Glovebox;	97%

: bis(pentafluorophenyl)(1,5-cyclooctadiene)platinum(II)

: 1662-01-7
bathophenanthroline

: 852954-53-1
(4,7-diphenylphenanthroline)Pt(C6F5)2

Conditions

Conditions	Yield
recrystn. and subl.;	96%

: copper(II) choride dihydrate

: 1662-01-7
bathophenanthroline

: 22204-53-1
(2S)-2-(6-methoxy(2-naphthyl))propanoic acid

: Cu(4,7-diphenyl-1,10-phenanthroline)(naproxen)2

Conditions

Conditions	Yield
Stage #1: (2S)-2-(6-methoxy(2-naphthyl))propanoic acid With potassium hydroxide In methanol at 20℃; for 1h; Stage #2: copper(II) choride dihydrate; bathophenanthroline In methanol at 50℃; for 20h;	96%

...Expand

: 64443-05-6
tetrakis(actonitrile)copper(I) hexafluorophosphate

: 1662-01-7
bathophenanthroline

: 166330-10-5
bis[2-(diphenylphosphino)phenyl] ether

: 1421057-29-5
C60H44CuN2OP2(1+)*F6P(1-)

Conditions

Conditions	Yield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane Schlenk technique; Reflux; Stage #2: bathophenanthroline In dichloromethane at 20℃; Schlenk technique; Reflux;	95%

...Expand

: 30729-25-0, 25794-47-2, 15274-33-6, 22840-91-1, 75992-73-3, 14568-13-9
dichlorobis(dimethylsulfoxide)platinum(II)

: 1662-01-7
bathophenanthroline

: 35273-41-7
dichlorido(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Conditions

Conditions	Yield
In methanol for 3h; Reflux;	95%

: copper(II) choride dihydrate

: 60-29-7
diethyl ether

: 1662-01-7
bathophenanthroline

: 21436-03-3
(S,S)-1,2-diaminocyclohexane

: potassium perchlorate

: [copper(II)((1S,2S)-diaminocyclohexane)(4,7-diphenyl-1,10-phenanthroline)](perchlorate)2*0.5(C4H10O)

Conditions

Conditions	Yield
In ethanol; water at 60℃; for 3.5h;	94%

...Expand

: (tetra-n-butylammonium)2[Mo3S7Cl6]

: 1662-01-7
bathophenanthroline

: Mo3S7Cl4(4,7-diphenyl-1,10-phenanthroline)

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 6.5h; Reflux;	94%

: 1662-01-7
bathophenanthroline

: 917-54-4
methyllithium

: 2-methyl-4,7-diphenyl-1,10-phenanthroline

Conditions

Conditions	Yield
In diethyl ether; toluene at 0 - 20℃; for 1h; Schlenk technique; Inert atmosphere;	94%
In diethyl ether; toluene at 0℃; for 0.5h;	63%
In diethyl ether; toluene at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;	55%

: uranyl nirate hexahydrate

: 1662-01-7
bathophenanthroline

: [UVIO2(NO3)2(4,7-diphenyl-1,10-phenanthroline)]

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 0.5h;	94%

: tetrakis(acetonitrile)copper(I)tetrafluoroborate

: 1662-01-7
bathophenanthroline

: 5112-95-8
bis(diphenylphosphino)acetylene

: 71-43-2
benzene

: C100H72Cu2N4P4(2+)*2BF4(1-)*C6H6

Conditions

Conditions	Yield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; bis(diphenylphosphino)acetylene In dichloromethane; acetonitrile for 0.5h; Inert atmosphere; Stage #2: bathophenanthroline In dichloromethane; acetonitrile for 1h; Inert atmosphere; Stage #3: benzene In diethyl ether at -100.16℃;	94%

...Expand

: tetrakis(acetonitrile)copper(I)tetrafluoroborate

: 1662-01-7
bathophenanthroline

: 5112-95-8
bis(diphenylphosphino)acetylene

: [Cu2(μ-dppa)2(bathophenanthroline)2](BF4)2

Conditions

Conditions	Yield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; bis(diphenylphosphino)acetylene In dichloromethane; acetonitrile for 0.5h; Inert atmosphere; Stage #2: bathophenanthroline In dichloromethane; acetonitrile for 1h; Inert atmosphere;	94%

...Expand

: 1662-01-7
bathophenanthroline

: 3375-31-3
palladium diacetate

: 95246-09-6
(4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

Conditions

Conditions	Yield
In dichloromethane; toluene at 20℃; Inert atmosphere;	93%
In dichloromethane; toluene at 20℃; Inert atmosphere;	93%
With CH3COOH In acetone (Pd(MeCOO)2) is dissolved in acetone at room temp., after 30 min soln. is filtd. and a few drops of glacial acetic acid are added, the ligand is added as a solid to the soln.; ppt. is filtd., washed with cold acetone and dried in vac., elem. anal.;	70%

: 1662-01-7
bathophenanthroline

: 109-64-8
1,3-dibromo-propane

: 2Br(1-)*C27H22N2(2+)

Conditions

Conditions	Yield
at 130℃; for 6h; Inert atmosphere;	93%
In nitrobenzene Menschutkin reaction;
With oxygen for 0.5h; Reflux;
In toluene Reflux;

: 64-17-5
ethanol

: Eu2(Piv)6(HPiv)6*HPiv

: 1662-01-7
bathophenanthroline

: [(4,7-diphenyl-1,10-phenanthroline)2Eu2(piv)6]*2EtOH

Conditions

Conditions	Yield
In ethanol EtOH added to 4,7-Ph2-1,10-phen and Eu complex, heated at 80°C; filtered, concd.(vac.) at room temp., kept at 20°C for 24 h, washed (cold EtOH), dried (air), elem. anal.;	93%
With air at 80℃; Schlenk technique;	53%

...Expand

[{η5-C5H4(C5F4N)}Mo(CO)2(NCMe)2][BF4]: [{η5-C5H4(C5F4N)}Mo(CO)2(NCMe)2][BF4]

: 1662-01-7
bathophenanthroline

[{η5-C5H4(C5F4N)}Mo(CO)2(4,7-diphenyl-1,10-phenanthroline)][BF4]: [{η5-C5H4(C5F4N)}Mo(CO)2(4,7-diphenyl-1,10-phenanthroline)][BF4]

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 16h;	93%

: 1662-01-7
bathophenanthroline

[(η5-C5H4CH2C6H4Cl-4)Mo(CO)2(NCMe)2][BF4]: [(η5-C5H4CH2C6H4Cl-4)Mo(CO)2(NCMe)2][BF4]

: [(η5-C5H4CH2C6H4Cl-4)Mo(CO)2(4,7-Ph2-phen)][BF4]

Conditions

Conditions	Yield
In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;	93%

: 480-40-0
5,7-dihydroxy-2-phenyl-chromen-4-one

: 1662-01-7
bathophenanthroline

: C39H25CuN2O4(1+)*ClO4(1-)

Conditions

Conditions	Yield
Stage #1: copper(II) perchlorate hexahydrate; 5,7-dihydroxy-2-phenyl-chromen-4-one In methanol at 20℃; for 0.5h; Stage #2: bathophenanthroline In methanol at 20℃; for 2h;	93%

...Expand

: 36223-69-5
cis-bis{(trimethylsilyl)methyl}(1,5-cyclooctadiene)platinum(II)

: 1662-01-7
bathophenanthroline

: bis(trimethylsilylmethyl)(4,7-diphenyl-1,10-phenanthroline)platinum(II)

Conditions

Conditions	Yield
In toluene under Ar, heated to 60°C for 14 days; extn. (aq. ferrous sulphate soln.), organic phase concd., addn. of n-hexane, cooled, washed with hexane; elem. anal.;	92%

Bathophenanthroline Specification

The 1,10-Phenanthroline,4,7-diphenyl-, with the CAS registry number 1662-01-7, is also known as 1,10-Bathophenanthroline. It belongs to the product categories of Analytical Chemistry; Chelating Reagents; Electroluminescence; Functional Materials; Highly Purified Reagents; Other Categories; Phenanthrolines; Refined Products by Sublimation; White crystalline powder; Organic Amine. Its EINECS number is 216-767-1. This chemical's molecular formula is C₂₄H₁₆N₂ and molecular weight is 332.40. What's more, its systematic name is 4,7-Diphenyl-1,10-phenanthroline. Its classification codes are: (1)Enzyme Inhibitors; (2)Indicators and reagents; (3)Mutation data; (4)Uncoupling agents. This chemical is used as a determination ferrous reagent. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides.

Physical properties of 1,10-Phenanthroline,4,7-diphenyl- are: (1)ACD/LogP: 6.161; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.08; (4)ACD/LogD (pH 7.4): 6.16; (5)ACD/BCF (pH 5.5): 23389.81; (6)ACD/BCF (pH 7.4): 28283.67; (7)ACD/KOC (pH 5.5): 44172.85; (8)ACD/KOC (pH 7.4): 53415.15; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 25.78 Å²; (13)Index of Refraction: 1.71; (14)Molar Refractivity: 107.304 cm³; (15)Molar Volume: 274.682 cm³; (16)Polarizability: 42.539×10^-24cm³; (17)Surface Tension: 55.57 dyne/cm; (18)Density: 1.21 g/cm³; (19)Flash Point: 242.111 °C; (20)Enthalpy of Vaporization: 79.064 kJ/mol; (21)Boiling Point: 543.108 °C at 760 mmHg; (22)Vapour Pressure: 0 mmHg at 25°C.

Preparation of 1,10-Phenanthroline,4,7-diphenyl-: this chemical can be prepared by 2-nitrochlorobenzene and beta-Chloropropiophenone by heating. This reaction will need reagents arsenic acid, sodium hydroxide and solvent dilute sulphuric acid.

1,10-Phenanthroline,4,7-diphenyl- can be prepared by 2-nitrochlorobenzene and beta-Chloropropiophenone by heating

Uses of 1,10-Phenanthroline,4,7-diphenyl-: it can be used to produce 2,9-bis-(4-methoxy-phenyl)-4,7-diphenyl-[1,10]phenanthroline. The yield is about 80%.

1,10-Phenanthroline,4,7-diphenyl- can be used to produce 2,9-bis-(4-methoxy-phenyl)-4,7-diphenyl-[1,10]phenanthroline

When you are using this chemical, please be cautious about it as the following:
This chemcial is irritating to eyes, respiratory system and skin. It is harmful by inhalation, in contact with skin and if swallowed. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. You should not breathe dust. When using it, you must avoid contact with eyes and wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)c2ccnc3c2ccc4c3nccc4c5ccccc5
(2)Std. InChI: InChI=1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H
(3)Std. InChIKey: DHDHJYNTEFLIHY-UHFFFAOYSA-N

Product Name

Bathophenanthroline

Synthetic route

Bathophenanthroline Specification

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