Bisphenol A bisallyl ether supplier

Name
Bisphenol A bisallyl ether
EINECS 223-123-3
CAS No. 3739-67-1
Article Data32
CAS DataBase
Density 1.005 g/cm³
Solubility
Melting Point
Formula C₂₁H₂₄O₂
Boiling Point 430.5 °C at 760 mmHg
Molecular Weight 308.42
Flash Point 155.3 °C
Transport Information
Appearance off-yellow liquid
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Benzene,1,1'-(1-methylethylidene)bis[4-(2-propenyloxy)- (9CI);Propane,2,2-bis[p-(allyloxy)phenyl]- (6CI,7CI,8CI);2,2-Bis(4-allyloxyphenyl)propane;4,4'-Isopropylidenediphenol diallylether;Dial 2;
PSA 18.46000
LogP 5.14210

Synthetic route

: 80-05-7
BPA

: 106-95-6
allyl bromide

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With potassium carbonate In acetone for 1h; Inert atmosphere; Reflux; Stage #2: allyl bromide In acetone Reflux; Inert atmosphere;	99%

: 80-05-7
BPA

: 107-05-1
3-chloroprop-1-ene

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With potassium carbonate; sodium iodide In ethanol for 24h; Heating;	98%
With sodium hydroxide; tetra(n-butyl)ammonium hydroxide at 40℃; for 6h;	70%
With sodium hydroxide; calcium oxide In tert-butyl alcohol at 80℃; for 6h; Solvent; Reagent/catalyst; Temperature;
Stage #1: BPA With sodium hydroxide In ethanol at 78℃; for 8h; Stage #2: 3-chloroprop-1-ene at 70℃; for 6h;

: 80-05-7
BPA

: 35466-83-2
allyl methyl carbonate

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0) In tetrahydrofuran at 25℃; for 24h; Condensation;	98%
With potassium carbonate In neat (no solvent) at 85℃; for 4h; Catalytic behavior;	98%

: 80-05-7
BPA

: 591-87-7
Allyl acetate

: 603-35-0
triphenylphosphine

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With sodium hydroxide; palladium diacetate In water	95.2%

...Expand

: 80-05-7
BPA

: 107-18-6
allyl alcohol

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: allyl alcohol With carbonic acid dimethyl ester; sodium methylate at 15.5 - 23℃; for 0.216667h; Inert atmosphere; Stage #2: BPA; 5%-palladium/activated carbon; triphenylphosphine at 22 - 78℃; for 9.68h;	94.17%
With bis(η3-allyl-μ-chloropalladium(II)); silver trifluoromethanesulfonate; 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin) In toluene at 40℃; for 38h; Inert atmosphere; Schlenk technique; Molecular sieve; Green chemistry; chemoselective reaction;	77%

: 80-05-7
BPA

: 15022-08-9
diallylcarbonate

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With tetrabutylammomium bromide at 120℃; for 20h; Inert atmosphere;	77%

: 80-05-7
BPA

: 557-40-4
Allyl ether

A: 109348-07-4
2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol

B: 1745-89-7
2,2-bis(3-allyl-4-hydroxyphenyl)propane

C: 105577-85-3
C21H24O2

D: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

E: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II); silver(I) 4-methylbenzenesulfonate; toluene-4-sulfonic acid In toluene for 0.0833333h; Inert atmosphere; Stage #2: Allyl ether In toluene at 60℃; for 3h; Inert atmosphere;	A n/a B n/a C n/a D n/a E 51%

...Expand

: 80-05-7
BPA

: 107-18-6
allyl alcohol

A: 109348-07-4
2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol

B: 1745-89-7
2,2-bis(3-allyl-4-hydroxyphenyl)propane

C: 105577-85-3
C21H24O2

D: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

E: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With silver(I) 4-methylbenzenesulfonate; toluene-4-sulfonic acid In toluene for 0.0833333h; Inert atmosphere; Stage #2: allyl alcohol In toluene at 80℃; for 3h; Inert atmosphere;	A n/a B n/a C n/a D n/a E 25%

...Expand

: 80-05-7
BPA

: 557-40-4
Allyl ether

A: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

B: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With (2,2-dimethylpropane-1,3-diyl)bis(diphenylphosphane); palladium diacetate In toluene for 0.0833333h; Inert atmosphere; Stage #2: Allyl ether In toluene at 100℃; for 20h; Inert atmosphere;	A n/a B 24%

...Expand

: 80-05-7
BPA

: 591-87-7
Allyl acetate

A: 109348-07-4
2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol

B: 1745-89-7
2,2-bis(3-allyl-4-hydroxyphenyl)propane

C: 105577-85-3
C21H24O2

D: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

E: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With [RuCp(PPh3)2](OTs); silver(I) 4-methylbenzenesulfonate; toluene-4-sulfonic acid In toluene for 0.0833333h; Inert atmosphere; Stage #2: Allyl acetate In toluene at 60℃; for 3h; Inert atmosphere;	A n/a B n/a C n/a D n/a E 18%

...Expand

: 80-05-7
BPA

: 107-18-6
allyl alcohol

A: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

B: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: BPA With (2,2-dimethylpropane-1,3-diyl)bis(diphenylphosphane); palladium diacetate In toluene for 0.0833333h; Inert atmosphere; Stage #2: allyl alcohol In toluene at 100℃; for 3h; Inert atmosphere;	A n/a B 10%

...Expand

: 80-05-7
BPA

: 591-87-7
Allyl acetate

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
chloro(cyclopentadienyl)[1,2-bis(diphenylphosphinyl)ethane]ruthenium(II) at 95℃; for 4h;
chloro(cyclopentadienyl)[1,2-bis(diphenylphosphinyl)ethane]ruthenium(II) In water at 95℃; for 4h;

: 80-05-7
BPA

: 591-87-7
Allyl acetate

A: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

B: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
chloro(cyclopentadienyl)bis(triphenylphosphinyl) ruthenium(II) at 95℃; for 6h;
With crosslinked styrene polymer supported triphenylphosphine; palladium diacetate at 95℃; for 4h;
With triphenylphosphine; palladium diacetate at 95℃; for 4h;

...Expand

: 80-05-7
BPA

: 107-05-1
3-chloroprop-1-ene

A: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

B: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With potassium hydroxide In diethylene glycol dimethyl ether; water; dimethyl sulfoxide at 25 - 45℃; for 16h;

...Expand

: 80-05-7
BPA

: 35466-83-2
allyl methyl carbonate

: 15022-08-9
diallylcarbonate

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
With triphenylphosphine; 5%-palladium/activated carbon at 78℃; for 9.68333h;

...Expand

: 620-92-8
bis-(4-hydroxyphenyl)methane

: 107-05-1
3-chloroprop-1-ene

: 3739-67-1
bisphenol A diallyl ether

Conditions

Conditions	Yield
Stage #1: bis-(4-hydroxyphenyl)methane With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 6h; Stage #2: 3-chloroprop-1-ene at 85℃; for 7h;	312.8 g

: 74-93-1
methylthiol

: 3739-67-1
bisphenol A diallyl ether

: (((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis(propane-3,1-diyl))bis(methylsulfane)

Conditions

Conditions	Yield
With C38H28Au2F12FeN2O8P2S4 In 1,4-dioxane at 45℃; for 20h; Inert atmosphere; Glovebox; Sealed tube;	99%

: 3739-67-1
bisphenol A diallyl ether

: 122165-67-7
4,4'-isopropylidenediphenol dipropyl ether

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In chloroform for 3h;	98%

: 59501-41-6
4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol

: 3739-67-1
bisphenol A diallyl ether

A: 13634-08-7
C18H22O4

B: 5581-32-8
3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol

Conditions

Conditions	Yield
With potassium osmate(VI); water; 4-methylmorpholine N-oxide In tert-butyl alcohol at 25℃; for 43h; Product distribution / selectivity;	A 2.8% B 97.2%

...Expand

: 3739-67-1
bisphenol A diallyl ether

: 1745-89-7
2,2-bis(3-allyl-4-hydroxyphenyl)propane

Conditions

Conditions	Yield
at 160 - 180℃; for 4h;	95%
In various solvent(s) at 199.9 - 204.9℃; for 5h;	65%
With boron trichloride In dichloromethane Claisen rearrangement;

: 3739-67-1
bisphenol A diallyl ether

: 5581-32-8
3-[4-[1-[4-(2,3-dihydroxypropoxy)phenyl]-1-methylethyl]phenoxy]propane-1,2-diol

Conditions

Conditions	Yield
With potassium osmate(VI); water; 4-methylmorpholine N-oxide In tert-butyl alcohol at 25℃; for 18h; Product distribution / selectivity;	84%

: 3739-67-1
bisphenol A diallyl ether

A: 140896-80-6
bisphenol A monoglycidyl ether

B: 1675-54-3
diphenylolpropane diglycidyl ether

Conditions

Conditions	Yield
With tetramethyl ammoniumhydroxide; dihydrogen peroxide; acetonitrile In methanol; water at 30℃; for 4.5h; pH=11; Product distribution / selectivity;	A 55.2% B 12.6%
With dihydrogen peroxide; acetonitrile; potassium hydroxide In ethanol; water at 30℃; for 4.5h; pH=10.5; Product distribution / selectivity;	A 38.6% B 49.9%
With dihydrogen peroxide; benzonitrile; triethylamine In water at 80℃; for 25h; Conversion of starting material;	A 33% B 8%
Stage #1: bisphenol A diallyl ether; Tri-n-octylamine; sodium tungstate monohydrate; Aminomethylphosphonic acid; sulfuric acid In water; toluene at 80℃; oil bath; Stage #2: With dihydrogen peroxide In water; toluene at 85℃; for 2h; Product distribution / selectivity;

: 3739-67-1
bisphenol A diallyl ether

A: C21H22O3

B: C21H20O4

Conditions

Conditions	Yield
With Tri-n-octylamine; sodium tungstate (VI) dihydrate; phosphoric acid; dihydrogen peroxide In cyclohexane; water at 60℃; under 245 - 345 Torr; for 6h; Pressure; Dean-Stark;	A 42% B 20%

: 3739-67-1
bisphenol A diallyl ether

: 140896-80-6
bisphenol A monoglycidyl ether

Conditions

Conditions	Yield
With dihydrogen peroxide; acetonitrile; potassium hydroxide In methanol; water at 30℃; for 4.5h; pH=11.5;	25.7%

: 3739-67-1
bisphenol A diallyl ether

: C21H22O3

Conditions

Conditions	Yield
With Tri-n-octylamine; sodium tungstate (VI) dihydrate; phosphoric acid; dihydrogen peroxide In cyclohexane; water at 60℃; under 760.051 Torr; for 6h; Dean-Stark;	13%

: 3739-67-1
bisphenol A diallyl ether

: 75672-95-6
2,2-bis(3'-n-propyl-4'-hydroxyphenyl)-propane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 95 percent / 4 h / 160 - 180 °C 2: 98 percent / H2 / Pd/C / methanol / 24 h View Scheme
Multi-step reaction with 2 steps 1: 65 percent / various solvent(s) / 5 h / 199.9 - 204.9 °C 2: 87 percent / H2 / 5percent Pd-C / CHCl3 View Scheme

: 3739-67-1
bisphenol A diallyl ether

: 188244-21-5
2,2,14,14-tetramethyl-8,11,17,23-tetrapropyl-6,10,18,22-tetrahydroxycalix[4]arene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 95 percent / 4 h / 160 - 180 °C 2: 98 percent / H2 / Pd/C / methanol / 24 h 3: 22 percent / BF3*OEt2 / CH2Cl2 / 12 h / Ambient temperature View Scheme

: 3739-67-1
bisphenol A diallyl ether

: C46H58O4

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 95 percent / 4 h / 160 - 180 °C 2: 98 percent / H2 / Pd/C / methanol / 24 h 3: 22 percent / BF3*OEt2 / CH2Cl2 / 12 h / Ambient temperature 4: 12 percent / K2CO3 / dimethylformamide / 48 h / Heating View Scheme

: 3739-67-1
bisphenol A diallyl ether

: C48H60O4

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 95 percent / 4 h / 160 - 180 °C 2: 98 percent / H2 / Pd/C / methanol / 24 h 3: 22 percent / BF3*OEt2 / CH2Cl2 / 12 h / Ambient temperature 4: 61 percent / K2CO3 / dimethylformamide / 48 h / Heating View Scheme

: 3739-67-1
bisphenol A diallyl ether

: 69571-24-0
C21H24O4

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 65 percent / various solvent(s) / 5 h / 199.9 - 204.9 °C 2: m-chloroperbenzoic acid / CH2Cl2 / 12 h / 59.9 °C View Scheme

: 3739-67-1
bisphenol A diallyl ether

: 71449-73-5
2,2',6,6'-tetraallyl-4,4'-isopropylidenediphenol

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 65 percent / various solvent(s) / 5 h / 199.9 - 204.9 °C 2: 85 percent / NaOH / propan-1-ol / 30 h / Heating 3: 90 percent / 5 h / 199.9 °C View Scheme
Multi-step reaction with 3 steps 1: 1,2-dichloro-benzene / 8 h / 20 - 190 °C 2: potassium carbonate / acetone / 20 - 80 °C 3: 1,2-dichloro-benzene / 8 h / 190 °C View Scheme
Multi-step reaction with 3 steps 1.1: 4 h / 220 °C / Inert atmosphere 2.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 2.2: Reflux; Inert atmosphere 3.1: 4 h / 220 °C / Inert atmosphere View Scheme

: 3739-67-1
bisphenol A diallyl ether

: 137372-32-8
2,2'-bis(2,3-dihydroxypropyl)-4,4'-isopropylidenediphenol

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 65 percent / various solvent(s) / 5 h / 199.9 - 204.9 °C 2: m-chloroperbenzoic acid / CH2Cl2 / 12 h / 59.9 °C 3: aq. NaOH / 24 h / 99.9 °C View Scheme

: 3739-67-1
bisphenol A diallyl ether

: 26306-34-3
4,4’-(dimethylmethylene)bis[2-(2-propenyl)phenyl]diallyl ether

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 65 percent / various solvent(s) / 5 h / 199.9 - 204.9 °C 2: 85 percent / NaOH / propan-1-ol / 30 h / Heating View Scheme
Multi-step reaction with 2 steps 1: 1,2-dichloro-benzene / 8 h / 20 - 190 °C 2: potassium carbonate / acetone / 20 - 80 °C View Scheme
Multi-step reaction with 2 steps 1.1: 4 h / 220 °C / Inert atmosphere 2.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 2.2: Reflux; Inert atmosphere View Scheme

Bisphenol A bisallyl ether Specification

The Bisphenol A bisallyl ether with the cas number 3739-67-1, is also called 2,2-Bis(4-allyloxyphenyl)propane.The product can be supplied by the following suppliers: (1)Laizhou Laiyu Chemical Co., Ltd.; (2)Sichuan Huishuo Chemical Co., Ltd.; (3)Waterstone Technology, LLC.; (4)Aagile Labs Division of Tyger Scientific; (5)MOLEKULA Ltd.; (6)Nanjing Chemlin Chemical Co., Ltd..

The properties of the chemical are: (1)ACD/LogP: 6.35; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.35; (4)ACD/LogD (pH 7.4): 6.35; (5)ACD/BCF (pH 5.5): 39130.04; (6)ACD/BCF (pH 7.4): 39130.04; (7)ACD/KOC (pH 5.5): 67437.63; (8)ACD/KOC (pH 7.4): 67437.63; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 18.46 Å²; (13)Index of Refraction: 1.536; (14)Molar Refractivity: 95.74 cm³; (15)Molar Volume: 306.9 cm³; (16)Polarizability: 37.95×10^-24cm³; (17)Surface Tension: 33.8 dyne/cm; (18)Enthalpy of Vaporization: 65.94 kJ/mol; (19)Vapour Pressure: 3.25×10^-7 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O(c1ccc(cc1)C(c1ccc(OCC=C)cc1)(C)C)CC=C
(2)InChI: InChI=1/C21H24O2/c1-5-15-22-19-11-7-17(8-12-19)21(3,4)18-9-13-20(14-10-18)23-16-6-2/h5-14H,1-2,15-16H2,3-4H3

Product Name

Bisphenol A bisallyl ether

Synthetic route

Bisphenol A bisallyl ether Specification

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