Butyltintrichloride supplier

Name
Butyltin trichloride
EINECS 214-263-6
CAS No. 1118-46-3
Article Data32
CAS DataBase
Density 1.693 g/mL at 25 °C(lit.)
Solubility soluble in water
Melting Point -63 °C
Formula C₄H₉Cl₃Sn
Boiling Point 226.8 °C at 760 mmHg
Molecular Weight 282.184
Flash Point 91 °C
Transport Information UN 3265 8/PG 2
Appearance Clear yellow liquid
Safety 26-27-28-36/37/39-45
Risk Codes 20/21/22-34-20/21
Molecular Structure
Hazard Symbols C
Synonyms MBTC;Butyltin trichloride (BuSnCl3);Butyltrichlorostannane;Butyltrichlorotin;Certincoat TC 100;Butyltintrichloride (6CI);NSC 67013;Trichlorobutylstannane;Trichlorobutyltin;n-Butyltin trichloride;Mono-n-butyltin trichloride;Butyltin trichloride;
PSA 0.00000
LogP 3.44180

Synthetic route

: 1461-25-2
tetra-n-butyltin(IV)

: 7646-78-8
tin(IV) chloride

A: 1118-46-3
Trichlorbutylstannan

B: 683-18-1
dibutyltin chloride

Conditions

Conditions	Yield
molar ratio of Sn(C4H9)4:SnCl4 = 1:3, 8 h, 203°C;	A 96% B n/a
molar ratio of Sn(C4H9)4:SnCl4 = 1:3, 8 h, 203°C;	A 96% B n/a
molar ratio of Sn(C4H9)4:SnCl4 = 1:2, 3 h, 100°C;

...Expand

: 683-18-1
dibutyltin chloride

: 7646-78-8
tin(IV) chloride

A: 1118-46-3
Trichlorbutylstannan

B: tin(ll) chloride

Conditions

Conditions	Yield
cis-dichlorobis(triphenylphosphine)platinum(II) In toluene stirred for 2 h at 110°C, catalyst added stirred for 12 h at 110°C; cooled to room temp., filtered, ppt. (SnCl2) washed (toluene), dried, filtrate evapd. (vac.), distilled (90°C/11 mm Hg);	A 83% B 3.7%
cis-dichlorobis(triphenylphosphine)platinum(II) In toluene stirred for 12 h at 110°C; cooled to room temp., filtered, ppt. (SnCl2) washed (toluene), dried, filtrate evapd. (vac.), distilled (90°C/11 mm Hg); elem. anal.;	A 80% B 13%
cis-dichlorobis(triphenylphosphine)platinum(II) In o-xylene stirred for 12 h at 110°C; cooled to room temp., filtered, ppt. (SnCl2) washed (toluene), dried; NMR;	A n/a B 19%

...Expand

: 7647-01-0
hydrogenchloride

: 2847-57-6
butyltriphenyltin

: 1118-46-3
Trichlorbutylstannan

Conditions

Conditions	Yield
In diethyl ether; dichloromethane at -78 - 20℃; for 12.5h;	80%
In diethyl ether; dichloromethane at -78 - 20℃; for 12.5h;	80%

: 109-69-3
n-Butyl chloride

: 1118-46-3
Trichlorbutylstannan

Conditions

Conditions	Yield
With stannous chloride; iodine; magnesium In tetrahydrofuran; toluene	55%

: 36854-57-6
2-Phenylbutyryl chloride

: 2847-57-6
butyltriphenyltin

A: 16282-16-9
1,2-diphenyl-butan-1-one

B: 1118-46-3
Trichlorbutylstannan

Conditions

Conditions	Yield
With indium In neat (no solvent) at 80℃; for 0.25h; Inert atmosphere; Sonication; regioselective reaction;	A 25% B n/a

...Expand

: 693-04-9
butyl magnesium bromide

SnCl4: SnCl4

: 1118-46-3
Trichlorbutylstannan

: 1461-25-2
tetra-n-butyltin(IV)

: 7646-78-8
tin(IV) chloride

A: 1118-46-3
Trichlorbutylstannan

B: 683-18-1
dibutyltin chloride

C: 1461-22-9
tributyltin chloride

Conditions

Conditions	Yield
With aluminium trichloride 6 h, 100°C;
200°C, 10 Torr;
molar ratio of educts = 1:1, 0-20°C;
With aluminium trichloride 6 h, 100°C;
200°C, 10 Torr;

...Expand

: 1461-25-2
tetra-n-butyltin(IV)

: 7646-78-8
tin(IV) chloride

: 1118-46-3
Trichlorbutylstannan

Conditions

Conditions	Yield
6 h, 160°C;

: 1461-25-2
tetra-n-butyltin(IV)

: 7646-78-8
tin(IV) chloride

A: 1118-46-3
Trichlorbutylstannan

B: 1461-22-9
tributyltin chloride

Conditions

Conditions	Yield
molar ratio of educts = 1:1, 0-50°C;

...Expand

: 1118-46-3
Trichlorbutylstannan

: 594-27-4
tetramethylstannane

A: 753-73-1
dimethyltin dichloride

B: 15649-24-8
butyl-methyl-tin dichloride

Conditions

Conditions	Yield
2-fold excess of C4H9SnCl3, 180°C, 2h;	A n/a B 99.4%
2-fold excess of C4H9SnCl3, 180°C, 2h;	A n/a B 99.4%

...Expand

: 1336-21-6
ammonium hydroxide

: 1118-46-3
Trichlorbutylstannan

: 497-19-8
sodium carbonate

: 2273-43-0
n-butylstannoic acid

Conditions

Conditions	Yield
In water at 60℃; for 2.5h; Temperature;	99.4%

...Expand

: 1118-46-3
Trichlorbutylstannan

: 27205-99-8
sodium O,O-diisopropyl dithiophosphate

: BuSn(S2P(OPr-i)2)2Cl

Conditions

Conditions	Yield
In benzene byproducts: sodium chloride; BuSnCl3 in benzene added to suspn. (Pr-i-O)2PS2Na in benzene (molar ratio 1:2) and mixt. refluxed for 3 h; NaCl filtered off, solvent removed under reduced pressure; elem. anal.;	99%

: 4238-71-5
1-benzylimidazole

: 1118-46-3
Trichlorbutylstannan

: 175351-02-7
[C4H9SnCl3(C6H5CH2C3H3N2)2]

Conditions

Conditions	Yield
In diethyl ether room temp.; filtration, washing (Et2O); elem. anal.;	99%

: 28170-13-0
thiobenzoic acid potassium salt

: 1118-46-3
Trichlorbutylstannan

: 869111-75-1
(butyl)Sn(Cl)2(thiobenzoate)

Conditions

Conditions	Yield
In dichloromethane byproducts: KCl; soln. of butyltin trichloride added to suspn. of potassium thiobenzoate at room temp., stirred for 1 h; ppt. filtered off, solvent evapd. under reduced pressure, dried at 0.05 Torr and 28 °C; elem. anal.;	99%

: 1118-46-3
Trichlorbutylstannan

: 27205-99-8
sodium O,O-diisopropyl dithiophosphate

: BuSn(S2P(OPr-i)2)3

Conditions

Conditions	Yield
In benzene byproducts: sodium chloride; BuSnCl3 in benzene added to suspn. (Pr-i-O)2PS2Na in benzene (molar ratio 1:3) and mixt. refluxed for 3 h; NaCl filtered off, solvent removed under reduced pressure; elem. anal.;	98%

: 74862-75-2
ammonium O,O-(2,2-dimethyltrimethylene)dithiophosphate

: 1118-46-3
Trichlorbutylstannan

: 104063-75-4
CH3(CH2)3SnCl[S2(POCH2C(CH3)2CH2O)]2

Conditions

Conditions	Yield
In benzene byproducts: NH4Cl; a soln. of monoorganotin(IV) chloride is added to a suspn. of ammonium O,O-alkylenedithiophosphate in 1:2 molar ratio (room temp.); mixt. stirred (3-4 h); filtered; solvent removed (reduced pressure); elem. anal.;	97%

: 86428-81-1
ammonium tetramethylethylene dithiophosphate

: 1118-46-3
Trichlorbutylstannan

: 104050-69-3
CH3(CH2)3Sn[S2(POC(CH3)2C(CH3)2O)]3

Conditions

Conditions	Yield
In benzene byproducts: NH4Cl; a soln. of monoorganotin(IV) chloride is added to a suspn. of ammonium O,O-alkylenedithiophosphate in 1:3 molar ratio (room temp.); mixt. stirred (3-4 h); filtered; solvent removed (reduced pressure); elem. anal.;	97%

: 67-56-1
methanol

: 1761-56-4
2-[[(2-hydroxyphenyl)imino]methyl]phenol

: 1118-46-3
Trichlorbutylstannan

: 404834-66-8
[Sn(n-Bu)Cl(2-([(2-hydroxyphenyl)imino]methyl)phenolato)(methanol)]

Conditions

Conditions	Yield
In methanol (N2); Sn compd. added to a hot ligand soln., stirred for 8 h; ppt. filtered off, washed (MeOH); elem. anal.;	96%

...Expand

: 3339-73-9
3-phthalimidopropanoic acid

: 1118-46-3
Trichlorbutylstannan

: 124-41-4
sodium methylate

: C4H9Sn(COC6H4CONCH2CH2COO)3

Conditions

Conditions	Yield
In methanol byproducts: NaCl; mixing organic compounds, refluxing for about 2 h, addn. of tin compound, refluxing for 6 h; filtn., evapn. of filtrate under reduced pressure, recrystn. (chloroform-hexane), elem. anal.;	95%

...Expand

: 616-47-7
1-methyl-1H-imidazole

: 1118-46-3
Trichlorbutylstannan

: 207740-04-3
trichlorobutylbis(1-methylimidazole)tin(IV)

Conditions

Conditions	Yield
In diethyl ether N2-atmosphere; stirring Sn-compd. with excess of ligand (room temp., pptn.); filtration (after 3 h), washing (Et2O); elem. anal.;	95%

: 288-32-4
1H-imidazole

: 1118-46-3
Trichlorbutylstannan

: 220335-19-3
trichlorobutylbis(imidazole)tin(IV)

Conditions

Conditions	Yield
In diethyl ether N2-atmosphere; stirring (room temp., 6 h); filtering, washing (Et2O), drying (vac., 20°C, 0.1 Torr); elem. anal.;	95%

: 28170-13-0
thiobenzoic acid potassium salt

: 1118-46-3
Trichlorbutylstannan

: 869111-74-0
(butyl)Sn(Cl)(thiobenzoate)2

Conditions

Conditions	Yield
In dichloromethane byproducts: KCl; soln. of butyltin trichloride added to suspn. of potassium thiobenzoate at room temp., stirred for 1 h; ppt. filtered off, solvent evapd. under reduced pressure, dried at 0.05 Torr and 28 °C, recrystd. from diethyl ether/n-hexane mixture; elem. anal.;	95%

: 1118-46-3
Trichlorbutylstannan

: 27205-99-8
sodium O,O-diisopropyl dithiophosphate

: BuSn(S2P(OPr-i)2)Cl2

Conditions

Conditions	Yield
In benzene byproducts: sodium chloride; BuSnCl3 in benzene added to suspn. (i-PrO)2PS2Na in benzene (molar ratio 1:1) and mixt. refluxed for 3 h; NaCl filtered off, solvent removed under reduced pressure; elem. anal.;	94%

: 1582766-55-9
sodium O,O'-di(3,5-dimethylphenyl)dithiophosphate

: 1118-46-3
Trichlorbutylstannan

: C40H54O4P2S4Sn

Conditions

Conditions	Yield
In toluene at 20℃; for 24h; Inert atmosphere; Schlenk technique;	94%

: 1118-46-3
Trichlorbutylstannan

: 60-24-2
2-hydroxyethanethiol

: (Sn(C4H9)(Cl)((OCH2CH2S)2Sn(C4H9))2)

Conditions

Conditions	Yield
With sodium In ethanol under Ar atm. 2-mercaptoethanol and metallic sodium were mixed in ethanol with stirring, soln. was refluxed for 1 h, soln. was cooled and BuSnCl3 was added and mixt. was refluxed for another 4 h; ppt. was filtered off in vac., washed with ethanol, stirred with water for 1 h and recrystd. from CH2Cl2; elem. anal.;	93.3%

: 1118-46-3
Trichlorbutylstannan

: 555-31-7
aluminum isopropoxide

: 845510-80-7
[(C4H9)Sn(Al(OCH(CH3)2)4)2Cl]

Conditions

Conditions	Yield
With potassium In benzene byproducts: KCl; K and Al(OCH(CH3)2)3 (2 equiv.) were reacted in isopropyl/benzene; obtained soln. was added to soln. of Sn compd. in benzene; mixt. was refluxedfor 5 h; filtered; volatiles removed (vac.); distd. at 132°C/0.15 mm; elem. anal.;	93%

: 84661-56-3
1,1'-bis(imidazolyl)methane

: 1118-46-3
Trichlorbutylstannan

: (bis(1-imidazolyl)methane)((n-Bu)SnCl3)

Conditions

Conditions	Yield
In diethyl ether; ethanol soln. of Sn compd. and ligand in Et2O/EtOH (1/1) was stirred at room temp. for 48 h under N2; filtered; dried (vac.); washed (Et2O); recrystd. (EtOH); elem. anal.;	93%

: 4702-13-0
N-phthaloylglycine

: 1118-46-3
Trichlorbutylstannan

: 124-41-4
sodium methylate

: C4H9Sn(COC6H4CONCH(H)COO)3

Conditions

Conditions	Yield
In methanol byproducts: NaCl; mixing organic compounds, refluxing for about 2 h, addn. of tin compound, refluxing for 6 h; filtn., evapn. of filtrate under reduced pressure, recrystn. (chloroform-hexane), elem. anal.;	92%

...Expand

: 1467-40-9
1,5-diphenylpentane-1,3,5-trione

: 1118-46-3
Trichlorbutylstannan

: 103238-33-1
Sn(C4H9)(C6H5C(O)CHC(O)CHC(O)C6H5)Cl(C5H5N)

Conditions

Conditions	Yield
With pyridine; sodium In isopropyl alcohol; benzene byproducts: C5H5N*HCl; exclusion of moisture; addn. of Na to solvent mixt., set aside 6 h, refluxed for 1 h, addn. of ligand in benzene followed by addn. of Sn-compd.in benzene, ppt. of NaCl; ratio 1:1:3; filtered, evapd. (vac.), recrystd. (benzene); elem. anal.;	92%

: 1118-46-3
Trichlorbutylstannan

: 23851-06-1, 23851-16-3
disodium 1,2-ethanedithiolate

: 56-34-8
tetraethylammonium chloride

: 113161-03-8
tetraethylammonium bis(ethane-1,2-dithiolato)-n-butylstannate

Conditions

Conditions	Yield
In acetone byproducts: NaCl; Et4NCl and BuSnCl3 stirred at room temp. for 0.5h under N2; dithiolate dropwise added; heated for 3h at 50 °C and stirred at room temp. overnight;; filtration; evapn.; crystn. from acetonitrile/ether at 7 °C; elem. anal.;;	91%

...Expand

: 74862-75-2
ammonium O,O-(2,2-dimethyltrimethylene)dithiophosphate

: 1118-46-3
Trichlorbutylstannan

: Sn(C4H9){S2P(OCH2C(CH3)2CH2O)}3

Conditions

Conditions	Yield
In benzene byproducts: NH4Cl; a soln. of monoorganotin(IV) chloride is added to a suspn. of ammonium O,O-alkylenedithiophosphate in 1:3 molar ratio (room temp.); mixt. stirred (3-4 h); filtered; solvent removed (reduced pressure); elem. anal.;	91%

: 1118-46-3
Trichlorbutylstannan

: 13126-82-4
silver cyclohexanecarboxylate

: bis(n-butyloxotin cyclohexanoato)-n-butyltin tricyclohexanoate dimer

Conditions

Conditions	Yield
With H2O In tetrachloromethane byproducts: AgCl, HCl; addn. of Ag-compd to a stirred soln. of n-BuSnCl3 in CCl4, 2 h reflux, filtration of AgCl, evapn., standing of oil for 3 days in a stoppered flask at 25°C; washing of crystals with 100% ethanol; more crystals by recrystn. of oil in CHCl3/hexane, CH2Cl2/hexane and diethyl ether; hydrolysis of oil with 50% ethanol gives a white powder, filtration under suction, washing with 100% ethanol, drying; elem. anal.;	91%
With H2O In chloroform byproducts: AgCl, HCl; addn. of Ag-compd to a soln. of n-BuSnCl3 in CHCl3, 2 h reflux, addn. of Na2SO4 as drying agent; filtration, evapn., dissoln. of oil in hexane, addn. of n-butylamine, 1week in the refrigerator, washing of crystals in cold hexane, drying;	90%

Yield

With H2O In tetrachloromethane byproducts: AgCl, HCl; addn. of Ag-compd to a stirred soln. of n-BuSnCl3 in CCl4, 2 h reflux, filtration of AgCl, evapn., standing of oil for 3 days in a stoppered flask at 25°C; washing of crystals with 100% ethanol; more crystals by recrystn. of oil in CHCl3/hexane, CH2Cl2/hexane and diethyl ether; hydrolysis of oil with 50% ethanol gives a white powder, filtration under suction, washing with 100% ethanol, drying; elem. anal.;

91%

With H2O In chloroform byproducts: AgCl, HCl; addn. of Ag-compd to a soln. of n-BuSnCl3 in CHCl3, 2 h reflux, addn. of Na2SO4 as drying agent; filtration, evapn., dissoln. of oil in hexane, addn. of n-butylamine, 1week in the refrigerator, washing of crystals in cold hexane, drying;

90%

: 3570-55-6
3-thiapentan-1,5-dithiol

: 1118-46-3
Trichlorbutylstannan

: 2-chloro-2-n-butyl-1,3,6-trithia-2-stannocane

Conditions

Conditions	Yield
In benzene equimolar amts., refluxing for 10 h; collection (filtration), recrystn. (CH2Cl2/hexane); elem. anal.;	91%

: 499-83-2
Pyridine-2,6-dicarboxylic acid

: 1118-46-3
Trichlorbutylstannan

: 855483-11-3
[Sn(butyl)Cl(2,6-pyridinedicarboxylato)]

Conditions

Conditions	Yield
With N(C2H5)3 In ethanol byproducts: N(C2H5)3HCl; (N2); using Schlenk techniques; addn. of NEt3 and SnBuCl3 in EtOH to soln. of 2,6-pyridinedicarboxylic acid in EtOH; stirring for 12 h; removal of solvent under reduced pressure, washing with hot water; recrystn. in mixt. of MeOH/H2O (14:1); elem. anal.;	91%

: 54216-00-1
o-hydroxyacetophenone-n-butylimine

: 1118-46-3
Trichlorbutylstannan

: trans-(n-Bu)SnCl3(N-(n-butyl)-2-hydroxyacetophenylideneimine)2

Conditions

Conditions	Yield
In hexane absence of moisture, varying educt ratio; elem. anal.;	91%

: 58308-13-7
o-hydroxyacetophenone-n-propylimine

: 1118-46-3
Trichlorbutylstannan

: trans-(n-Bu)SnCl3(N-(n-propyl)-2-hydroxyacetophenylideneimine)2

Conditions

Conditions	Yield
In hexane absence of moisture, varying educt ratio; pptn. or crystn.; elem. anal.;	91%

: 1481752-10-6
sodium O,O'-di(4-chloro-3-methylphenyl)dithiophosphate

: 1118-46-3
Trichlorbutylstannan

: C36H42Cl4O4P2S4Sn

Conditions

Conditions	Yield
In toluene at 20℃; for 24h; Inert atmosphere; Schlenk technique;	91%

: 1118-46-3
Trichlorbutylstannan

: 1191-15-7
diisobutylaluminium hydride

: 2406-65-7
n-butyltin hydride

Conditions

Conditions	Yield
In dibutyl ether reaction at 0°C;;	90%

Butyltintrichloride Consensus Reports

Reported in EPA TSCA Inventory.

Butyltintrichloride Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m³ (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m³

Butyltintrichloride Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Butyltintrichloride Specification

The Butyl trichloro stannane, with the CAS registry number 1118-46-3 and EINECS registry number 214-263-6, has the systematic name of butyl(trichloro)stannane. It is a kind of clear yellow liquid which is also moisture sensitive. And the molecular formula of the chemical is C₄H₉Cl₃Sn. What's more, it is always used as intensifier of glasses.

The physical properties of Butyl trichloro stannane are as followings: (1)ACD/LogP: 0.50; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.5; (4)ACD/LogD (pH 7.4): 0.5; (5)ACD/BCF (pH 5.5): 1.42; (6)ACD/BCF (pH 7.4): 1.42; (7)ACD/KOC (pH 5.5): 44.74; (8)ACD/KOC (pH 7.4): 44.74; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 0 Å²; (13)Flash Point: 91 °C; (14)Enthalpy of Vaporization: 44.46 kJ/mol; (15)Boiling Point: 226.8 °C at 760 mmHg; (16)Vapour Pressure: 0.12 mmHg at 25°C.

You should be cautious while dealing with this chemical. It is harmful by inhalation, in contact with skin and if swallowed, and may also cause burns. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer); In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Sn](Cl)(Cl)CCCC
(2)InChI: InChI=1/C4H9.3ClH.Sn/c1-3-4-2;;;;/h1,3-4H2,2H3;3*1H;/q;;;;+3/p-3/rC4H9Cl3Sn/c1-2-3-4-8(5,6)7/h2-4H2,1H3
(3)InChIKey: YMLFYGFCXGNERH-YHJCLRPYAB

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	2140mg/kg (2140mg/kg)		"Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1245, 1986.

Product Name

Butyltin trichloride

Synthetic route

Butyltintrichloride Consensus Reports

Butyltintrichloride Standards and Recommendations

Butyltintrichloride Analytical Methods

Butyltintrichloride Specification

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