Citric acid monohydrate supplier

Name
Citric acid monohydrate
EINECS 200-662-2
CAS No. 5949-29-1
Article Data5
CAS DataBase
Density 0.791 g/mL at 25 °C(lit.)
Solubility 1630 g/L (20 °C) in water
Melting Point -94 °C(lit.)
Formula C₆H₁₀O₈
Boiling Point 309.6 °C at 760 mmHg
Molecular Weight 210.141
Flash Point 155.2 °C
Transport Information UN 1090 3/PG 2
Appearance white crystals or powder
Safety 9-16-26-37/39-36/37/39-36
Risk Codes 11-36-66-67-41-36/37/38-37/38
Molecular Structure
Hazard Symbols F, Xi
Synonyms Citric acid hydrate;UNII-2968PHW8QP;Citric Acid Mono;
PSA 141.36000
LogP -1.31280

Synthetic route

: 7758-19-2
sodium chlorite

: 5949-29-1
citric acid monohydrate

Conditions

Conditions	Yield
With sodium hydroxide

: 2-(4-(3-(5-ethyl-4-oxo-7-propyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)-4-propoxyphenylsulfonyl)piperazin-1-yl)ethyl 6-(nitrooxy)hexanoate

: 5949-29-1
citric acid monohydrate

: C6H8O7*C32H46N6O9S

Conditions

Conditions	Yield
In methanol at 20℃; for 0.166667h;	98.8%

: (S)-2-(4-(3-(5-ethyl-4-oxo-7-propyl-4,5-dihydro-3H-pyrrolo[3,2-d]pyrimidin-2-yl)-4-propoxyphenylsulfonyl)piperazin-1-yl)ethyl 5,6-bis(nitrooxy)hexanoate

: 5949-29-1
citric acid monohydrate

: C6H8O7*C32H45N7O12S

Conditions

Conditions	Yield
In methanol at 20℃; for 0.166667h;	97.8%

: 56-87-1
L-lysine

: 5949-29-1
citric acid monohydrate

: L-lysine calcium citrate

Conditions

Conditions	Yield
Stage #1: citric acid monohydrate With calcium oxide In water at 20℃; Stage #2: L-lysine In water at 70 - 80℃; for 4h;	97.1%

: 74-79-3
L-arginine

: 5949-29-1
citric acid monohydrate

: L-arginine calcium citrate

Conditions

Conditions	Yield
Stage #1: citric acid monohydrate With calcium hydroxide In water at 20℃; Stage #2: L-arginine In water at 70 - 80℃; for 4h;	96%

: 3040-38-8
Acetyl-L-carnitine

: 5949-29-1
citric acid monohydrate

: acetyl L-carnitine calcium citrate

Conditions

Conditions	Yield
Stage #1: citric acid monohydrate With calcium carbonate In water at 20℃; Stage #2: Acetyl-L-carnitine In water at 70 - 80℃; for 4h;	95.8%

: 5949-29-1
citric acid monohydrate

: 20064-19-1
propionyl-L-carnitine

: propionyl L-carnitine calcium citrate

Conditions

Conditions	Yield
Stage #1: citric acid monohydrate With calcium hydroxide In water at 20℃; Stage #2: propionyl-L-carnitine In water at 70 - 80℃; for 4h;	95.3%

: 7664-41-7
ammonia

: 7722-84-1
dihydrogen peroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: 743369-26-8
zinc(II) carbonate

: Zn(2+)*4NH4(1+)*[Ti2(O2)2(H(O2CC(CH2CO2)2O)2)]2(6-)*12H2O=Zn(NH4)4([Ti2(O2)2(H(O2CC(CH2CO2)2O)2)]2)*12H2O

Conditions

Conditions	Yield
In water TiCl4 added dropwise to a water on ice bath, H2O2 and acid added, allowed to warm to room temp., carbonate added, pH adjusted to 2 (aq. ammonia); crystd. (THF/water) for several d at 4°C; elem. anal.;	94.6%

...Expand

: 7732-18-5
water

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: 1310-65-2
lithium hydroxide

: 2Li(1+)*Ti(4+)*3O2CC(CH2CO2)2O(4-)*6H(1+)*4H2O=Li2[Ti(HO2CC(CH2CO2)2OH)3]*4H2O

Conditions

Conditions	Yield
In water TiCl4 added dropwise to a water on ice bath, acid added at room temp., pH adjusted to 2 (LiOH); stored for several d at room temp.; elem. anal.;	93.7%

...Expand

: [(1R)-1-{2-[(2-fluoro-5-methylphenyl)formamido]acetamido}-3-methylbutyl]boronic acid

: 5949-29-1
citric acid monohydrate

: 2-[4-(carboxymethyl)-2-[(1R)-1-{2-[(2-fluoro-5-methylphenyl)formamido]acetamido}-3-methylbutyl]-5-oxo-1,3,2-dioxaborolan-4-yl]acetic acid

Conditions

Conditions	Yield
In ethyl acetate at 70℃; for 2h;	89.5%

: chloroauric acid

: 7664-41-7
ammonia

: 7722-84-1
dihydrogen peroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: (ammonium)7[Ti4(η2-peroxo)4(citrate(4-))2(citrate(3-))2][AuCl4]*12water

Conditions

Conditions	Yield
In water addn. of titanium chloride to water at 0°C, addn. of hydrogen peroxide and citric acid, warming to room temp., addn. of gold compd., adjusting pH to 2 by aq. ammonia; crystn. at 4°C from aq. THF, elem. anal.;	89%

...Expand

: aluminum(III) nitrate nonahydrate

: 7664-41-7
ammonia

: 5949-29-1
citric acid monohydrate

: 4NH4(1+)*[Al(C6H4O7)(C6H5O7)](4-)*2H2O=(NH4)4[Al(C6H4O7)(C6H5O7)]*2H2O

Conditions

Conditions	Yield
In water byproducts: H2O; dissolving of Al(NO3)3*9H2O and citric acid monohydrate with 1:2 molar ratio in nano-pure water; stirring at 50°C overnight, rotary evapn. to dryness, redissolving in min. amt. of H2O, adjusting of pH to 4.5 with aq. ammonia; crystn. at 4°C in abs. ethanol, filtration; elem. anal.;	88.4%

...Expand

: 7664-41-7
ammonia

: 7722-84-1
dihydrogen peroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: 534-17-8
caesium carbonate

: Cs2(NH4)6[Ti4(O2)4(citric acid(-3H))2(citric acid(-4H))2]Cl2*8H2O

Conditions

Conditions	Yield
In water TiCl4 added dropwise to H2O, cooled in an ice bath, H2O2 soln. and citric acid monohydrate added, warmed to room temp., treated with Cs2CO3, pH adjusted to 2 using NH3 soln.; crystd. from H2O/THF at 4°C for days; elem. anal.;	87.4%

...Expand

: 7664-41-7
ammonia

: 7722-84-1
dihydrogen peroxide

: 7550-45-0
titanium tetrachloride

: 554-13-2
lithium carbonate

: 5949-29-1
citric acid monohydrate

: 2Li(1+)*4NH4(1+)*[Ti2(O2)2(H(O2CC(CH2CO2)2O)2)]2(6-)*5H2O=Li2(NH4)4([Ti2(O2)2(H(O2CC(CH2CO2)2O)2)]2)*5H2O

Conditions

Conditions	Yield
In water TiCl4 added dropwise to a water on ice bath, H2O2 and acid added, allowed to warm to room temp., carbonate added, pH adjusted to 2 (aq. ammonia); crystd. (THF/water) for several d at 4°C; elem. anal.;	86.4%

...Expand

: lanthanum(III) oxide

: 7732-18-5
water

: 5949-29-1
citric acid monohydrate

: 790221-94-2, 15416-19-0
[La(citric acis(-3H))(H2O)]

Conditions

Conditions	Yield
In water High Pressure; under hydrothermal conditions; equimolar mixt. of La2O3 and citric acid in water (pH 2.2-2.5) heated at 120°C for 5 d; ppt. sepd. from hot mixt.; washed with cold water; dried under vac.; elem. anal.;	85%

...Expand

: 5949-29-1
citric acid monohydrate

: 105344-45-4
p-nitrobenzyl (4R,5S,6S)-3-<(3S,5S)-5-dimethylaminocarbonyl-1-(p-nitrobenzyloxycarbonyl)pyrrolidin-3-ylthio>-4-methyl-7-oxo-6-<(1R)-1-trimethylsilyloxoethyl>-1-azabicyclo<3.2.0>hept-2-en-2-carboxylate

: 96036-02-1
p-nitrobenzyl (4R,5S,6S)-3-<(3S,5S)-5-dimethylaminocarbonyl-1-(p-nitrobenzyloxycarbonyl)pyrrolidin-3-ylthio>-6-<(1R)-1-hydroxyethyl>-4-methyl-7-oxo-1-azabicyclo<3.2.0>hept-2-en-2-carboxylate

Conditions

Conditions	Yield
In methanol	84%
In methanol	84%

: manganese(II)carbonate

: 5949-29-1
citric acid monohydrate

: 84800-36-2, 583844-43-3
[(Mn(H2Cit)]n

Conditions

Conditions	Yield
In water High Pressure; under aerobic conditions; citric acid hydrate (2 mmol) and MnCO3 (1 mmol) dissolved in H2O, mixt. heated at 160°C in sealed teflon tube for 3 d; elem. anal.;	84%
With Ca(NO3)2 In water High Pressure; under aerobic conditions; citric acid hydrate, Ca(NO3)2, and MnCO3 (molar ratio = 8:1:4-5) dissolved in H2O, mixt. heated at 160°C in sealed teflon tube for 3 d; elem. anal.;

: 64-17-5
ethanol

: 126-45-4
silver(I) citrate

: 5949-29-1
citric acid monohydrate

: 603-35-0
triphenylphosphine

: 1370733-78-0
[(Ph3P)2Ag(H2cit)]*EtOH

Conditions

Conditions	Yield
In ethanol mixt. Ag3cit, citric acid monohydrate, PPh3 and EtOH was heated with stirring; soln. was filtered hot and allowed to cool slowly, ppt. was colledcted and washed with ice-cold EtOH; elem. anal.;	84%

...Expand

: [(1R)-1-{2-[(5-bromo-2-chlorophenyl)formamido]acetamido}-3-methylbutyl]boronic acid

: 5949-29-1
citric acid monohydrate

: 2-{2-[(1R)-1-{2-[(5-bromo-2-chlorophenyl)formamido]acetamido}-3-methylbutyl]-4-(carboxymethyl)-5-oxo-1,3,2-dioxaborolan-4-yl}acetic acid

Conditions

Conditions	Yield
In ethyl acetate at 70℃; for 1.5h;	83.1%

: [(1R)-1-(2-{[2-fluoro-5-(trifluoromethyl)phenyl]formamido}acetamido)-3-methylbutyl]boronic acid

: 5949-29-1
citric acid monohydrate

: 2-[4-(carboxymethyl)-2-[(1R)-1-(2-{[2-fluoro-5-(trifluoromethyl)phenyl]formamido}acetamido)-3-methylbutyl]-5-oxo-1,3,2-dioxaborolan-4-yl]acetic acid

Conditions

Conditions	Yield
In ethyl acetate at 70℃; for 1.5h;	82%

: 7732-18-5
water

: vanadia

: 5144-89-8
1,10-phenanthroline hydrate

: 5949-29-1
citric acid monohydrate

: [V2O3(1,10-phenanthroline)3(citric acid(-3H))]*5H2O

Conditions

Conditions	Yield
With KOH In ethanol; water V2O5 dissolved in KOH soln., mixed with an aq. soln. of citric acid monohydrate, 1,10-phenanthroline monohydrate in EtOH added, brought to pH 4.0 with a KOH soln.; crystd. for 2 wk, sepd., washed with EtOH; elem. anal.;	81%

...Expand

: 5949-29-1
citric acid monohydrate

: 74427-22-8
2,2-difluoroethyl triflate

: 1190893-07-2
1-(2,2-difluoroethyl)-7-methyl-2-oxo-1,2,3,4-tetrahydroquinoline-6-carboxylic acid ethyl ester

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide	81%

: 1072833-69-2
[(1R)-1-{2-[(2,5-difluorophenyl)formamido]acetamido}-3-methylbutyl]boronic acid

: 5949-29-1
citric acid monohydrate

: 2-[4-(carboxymethyl)-2-[(1R)-1-{2-[(2,5-difluorophenyl)formamido]acetamido}-3-methylbutyl]-5-oxo-1,3,2-dioxaborolan-4-yl]acetic acid

Conditions

Conditions	Yield
In ethyl acetate at 70℃; for 2h;	80.5%

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: potassium hydroxide

: dipotassium tricitratotitanate tetrahydrate

Conditions

Conditions	Yield
In water aq. KOH was added to an aq. soln. to pH about 2; recrystd. from hot water; elem. anal.;	80%

...Expand

: ammonium hydroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: (NH4)2[Ti(citric acid-2H)3]*3H2O

Conditions

Conditions	Yield
In water pH of aq. soln. of TiCl4 and citric acid monohydrate adjusted to 2.0 by addn. aq. ammonia, stirred for 30 min; ppt. collected and recrystd. from hot water; elem. anal.;	80%

...Expand

: ammonium hydroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: zinc(II) oxide

: [NH4]2[Zn(H2O)6][Ti(citric acid(-2H))3]2*6H2O

Conditions

Conditions	Yield
In water ZnO (5 mmol) added to aq. soln. of TiCl4 (10 mmol) and citric acid monohydrate (30 mmol); pH adjusted to 2.0 by addn. of NH4OH; elem. anal.;	80%

...Expand

: ammonium hydroxide

: 7550-45-0
titanium tetrachloride

: 5949-29-1
citric acid monohydrate

: 7439-89-6
iron

: [NH4]2[Fe(H2O)6][Ti(citric acid(-2H))3]2*6H2O

Conditions

Conditions	Yield
In water Fe (5 mmol) added to aq. soln. of TiCl4 (10 mmol) and citric acid monohydrate (30 mmol); pH adjusted to 2.0 by addn. of NH4OH; elem. anal.;	80%

...Expand

: [(1R)-1-{2-[(5-bromo-2-fluorophenyl)formamido]acetamido}-3-methylbutyl]boronic acid

: 5949-29-1
citric acid monohydrate

: 2-{2-[(1R)-1-{2-[(5-bromo-2-fluorophenyl)formamido]acetamido}-3-methylbutyl]-4-(carboxymethyl)-5-oxo-1,3,2-dioxaborolan-4-yl}acetic acid

Conditions

Conditions	Yield
In ethyl acetate at 70℃; for 0.5h;	80%

: (5-((2,5-difluorobenzyl)oxy)-1-(3,3-dimethylbutyl)-1H-pyrazol-3-yl)methylmethanesulfonate

: 5949-29-1
citric acid monohydrate

: 74-89-5
methylamine

: 1-{5-[(2,5-difluorobenzyl)oxy]-1-(3,3-dimethylbutyl)-1H-pyrazol-3-yl}-N-methylmethanamine monocitrate

Conditions

Conditions	Yield
Stage #1: (5-((2,5-difluorobenzyl)oxy)-1-(3,3-dimethylbutyl)-1H-pyrazol-3-yl)methylmethanesulfonate; methylamine In methanol; toluene at 5℃; for 1.25h; Stage #2: citric acid monohydrate In isopropyl alcohol	76.3%

...Expand

: 6156-78-1
manganese (II) acetate tetrahydrate

: 6100-05-6
tripotassium citrate monohydrate

: 5949-29-1
citric acid monohydrate

: 860812-77-7
KMn(citrate)(H2O)

Conditions

Conditions	Yield
In ethanol; water High Pressure; 2 equiv. of Mn-salt, 1.5 equiv. of K-citrate and 1.0 equiv. of citric acid were heated in alcohol/H2O at 160 °C for 3 d in a teflon-linedstainless steel autoclave; cooling, crystals were air-dried, elem. anal.;	76%

...Expand

: NH4[Ce(ethylenediaminetetraacetate)(H2O)3]*5H2O

: 5949-29-1
citric acid monohydrate

: [NH4]8[Ce2(citrate)2(ethylenediaminetetraacetate)2]*9H2O

Conditions

Conditions	Yield
With ammonium hydroxide In water a soln. of Ce-complex and citric acid in water was stirred for 0.5 h, pHwas adjusted to 5.5 by 5% NH4OH, heated at 70°C for 2 days; evapd., washed with cold water and ethanol, dried in air; elem. anal.;	76%

Citric acid monohydrate Specification

The Citric acid monohydrate, with the CAS registry number 5949-29-1, is also known as cis-Permethric acid; cis-(Dichlorovinyl)dimethylcyclopropanecarboxylic acid; cis-DL-3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid. It belongs to the product categories of Organic matters.This chemical's molecular formula is C₆H₈O₇^.H₂O and molecular weight is 210.14.What's more,Its systematic name is Citric acid monohydrate. It is white crystals or powder,Stable.Incompatible with oxidizing agents, bases, reducing agents, nitrates.

Physical properties about CIS-Cypermethric Acid are:(1)ACD/LogP: -1.721; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -6.53; (4)ACD/LogD (pH 7.4): -7.46; (5)ACD/BCF (pH 5.5): 1.00; (6)ACD/BCF (pH 7.4): 1.00; (7)ACD/KOC (pH 5.5): 1.00; (8)ACD/KOC (pH 7.4): 1.00; (9)#H bond acceptors: 7; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 6; (12)Flash Point: 155.2 °C; (13)Enthalpy of Vaporization: 63.82 kJ/mol ; (14)Boiling Point: 309.6 °C at 760 mmHg; (15)Vapour Pressure: 5.73E-05 mmHg at 25°C;

The Citric acid monohydrate is highly Flammable,risk of serious damage to eyes. It is Irritating to eyes, respiratory system and skin. Its Vapors may cause drowsiness and dizziness.When you use it, wear suitable protective clothing, gloves and eye/face protection,Keep away from sources of ignition - No smoking .In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Keep container in a well-ventilated place.

You can still convert the following datas into molecular structure:
(1)SMILES:O=C(O)CC(O)(C(=O)O)CC(=O)O.O;
(2)Std. InChI:InChI=1S/C6H8O7.H2O/c7-3(8)1-6(13,5(11)12)2-4(9)10;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);1H2;
(3)Std. InChIKey:YASYEJJMZJALEJ-UHFFFAOYSA-N.

The toxicity data of Citric acid monohydrate as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	intraperitoneal	375mg/kg (375mg/kg)		National Technical Information Service. Vol. AD-A121-876,

Product Name

Citric acid monohydrate

Synthetic route

Citric acid monohydrate Specification

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