Cobalt tetramethoxyphenylporphyrin supplier

Name
Cobalt tetramethoxyphenylporphyrin
EINECS -0
CAS No. 28903-71-1
Article Data19
CAS DataBase
Density
Solubility
Melting Point 241-248 °C
Formula C₄₈H₃₆CoN₄O₄
Boiling Point
Molecular Weight 791.831
Flash Point
Transport Information
Appearance Purple powder
Safety 24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Cobalt,[5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-4-1)-;Cobalt, [5,10,15,20-tetrakis(p-methoxyphenyl)porphinato(2-)]- (8CI);(5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato)cobalt;(Tetra-p-anisylporphyrin)cobalt;5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine cobalt (II);Cobalt meso-tetrakis(4-methoxyphenyl)porphyrin;Cobalt tetrakis(p-methoxyphenyl)porphyrin;Tetrakis(4-methoxyphenyl)porphyrinatocobalt;a,b,g,d-meso-Tetra(4-methoxyphenyl)porphinatocobalt;
PSA 71.50000
LogP 6.47220

Synthetic route

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: 22112-78-3
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 110℃; for 1h; Inert atmosphere;	86%
In N,N-dimethyl-formamide for 0.00555556h; Reflux;	67%
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere;
In N,N-dimethyl-formamide at 150℃; for 24h; Inert atmosphere;

: 5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 140℃; for 12h; Inert atmosphere;	59.4%
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;;	33%
In acetic acid heating of tetra4-methoxy-phenyl)-prophine and Co(II)-acetate in acetic acid;; chromatographic purification with CHCl3 as solvent; recrystallisation in a CHCl3-CH3OH-mixture;;	33%

: 5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In acetic acid porphyrin was added to boiling soln. of acetate in acetic acid, mixt. was boiled for 0.5 h and kept at room temp. for 12 h; ppt. was filtered, washed with hot water, dried in air at 70°C, chromd. (silica gel, chloroform), recrystd. from chloroform-hexane mixt.;	35%
In acetic acid mixt. of porphin, Co salt, acetic acid refluxed; cooled; filtered; ppt. washed (hot water); dried (air, 353 K); dissolvedin CHCl3; chromd. (Al2O3); eluate evapd. to min. vol.; pptd. (MeOH);

: 109-97-7
pyrrole

: 123-11-5
4-methoxy-benzaldehyde

: 7646-79-9
cobalt(II) chloride

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In propionic acid in situ synthesis on RB-carbon support;	18%

...Expand

: 5,10,15,20-meso-tetra(p-methoxyphenyl) porphyrin

: 7646-79-9
cobalt(II) chloride

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide two step procedure: absorbing of metal chloride on RB-carbon carrier followed by reaction with porphin;	18%

: 123-11-5
4-methoxy-benzaldehyde

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: propionic acid; acetic acid; trifluoroacetic acid; nitrobenzene / 4 h / 140 °C 2: N,N-dimethyl-formamide / 12 h / 140 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: propionic acid / 2.25 h / 140 °C / Inert atmosphere 2: N,N-dimethyl-formamide / 1 h / 110 °C / Inert atmosphere View Scheme
Multi-step reaction with 2 steps 1: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 2: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme

: C85H44CoF15N8O4Sn

: 80937-33-3
oxygen

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: C74H16F30N8OSn2

Conditions

Conditions	Yield
In benzene-d6 under 760.051 Torr; Irradiation;

...Expand

: 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical

: C85H44CoF15N8O4Sn

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: C37H8F15N4OSn

Conditions

Conditions	Yield
In benzene-d6 at 70℃; Thermodynamic data; Inert atmosphere; Darkness;

...Expand

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: 22112-78-3
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide Reflux;

: 104-93-8
4-Methylanisole

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: oxygen; N-hydroxyphthalimide; cobalt(II) 5,10,15,20-tetra(o-methoxyphenyl)porphyrin complex / neat (no solvent) / 8 h / 120 °C / 7500.75 Torr / Autoclave 2: propionic acid / 2 h / 145 °C / Inert atmosphere; Darkness 3: N,N-dimethyl-formamide / 24 h / 150 °C / Inert atmosphere View Scheme

: 15226-74-1, 61091-28-9, 61117-58-6
dicobalt octacarbonyl

: 22112-78-3
5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

Conditions

Conditions	Yield
With aluminum oxide; lithium hydroxide for 0.666667h; Milling; Green chemistry;

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 75-03-6
ethyl iodide

: Co(C48H36N4O4)(C2H5)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;	95%
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 300 min; detected by H-NMR (<2 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 115-18-4
2-methyl-3-buten-2-ol

: Co(C48H36N4O4)(CH2CH2C(CH3)2OH)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;	95%
With 2,2'-azobis(isobutyronitrile) In chloroform Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 360-420 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 25°C for 1800-2400 min; detected by H-NMR (>95 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: Co(C48H36N4O4)(CH3)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;	95%
With 2,2'-azobis(isobutyronitrile); methyl iodide In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile); methyl iodide In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 400 min; detected by H-NMR (5 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 201230-82-2
carbon monoxide

: 873-75-6
4-bromobenzenemethanol

: 4-bromobenzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;	94%

...Expand

: 7647-01-0
hydrogenchloride

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 7732-18-5
water

: 158671-51-3
[5,10,15,20-tetra(p-methoxy)phenylporphyrin]cobalt(III) chloride monohydrate

Conditions

Conditions	Yield
In methanol at 50℃; Inert atmosphere;	93%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 201230-82-2
carbon monoxide

: 100-51-6
benzyl alcohol

: benzyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;	93%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 201230-82-2
carbon monoxide

: 98-85-1, 13323-81-4
1-Phenylethanol

: 1-phenethyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;	92%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 565-80-0
2,4-dimethylpentan-3-one

: C52H43CoN4O5

Conditions

Conditions	Yield
With water; triphenylphosphine In acetone at 25℃; for 1.5h; Darkness; Inert atmosphere;	89%

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 64-17-5
ethanol

: 201230-82-2
carbon monoxide

: ethoxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;	87%

...Expand

: 100-48-1
pyridine-4-carbonitrile

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 67-66-3
chloroform

: C54H40CoN6O4*CHCl3

Conditions

Conditions	Yield
for 24h;	80%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 67-66-3
chloroform

: 100-97-0
hexamethylenetetramine

: [CoII(TMPP)(HMTA)]•2CHCl3

Conditions

Conditions	Yield
for 4h;	80%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 10102-43-9
nitrogen(II) oxide

: nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
In dichloromethane absence of air and moisture; bubbling NO for 20 min; vol. reduction (boiling), pptn. on MeOH addn., decantation, drying (vac.), recrystn. (PhMe/hexane=10:1); elem. anal.;	72%
With piperidine In dichloromethane absence of air and moisture; excess piperidine, bubbling NO for 20 min; bubbling N2 for 2 min, vol. reduction (boiling), pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), recrystn. (CH2Cl2/hexane=1:1);	63%
With piperidine In dichloromethane Co-compd. dissoln., soln. degassing carefully, piperidine addn., NO bubbling into soln. for 0.5 h, NO excess removal on soln. purging with N2, heating to boiling, pptn. after MeOH addn.; ppt. filtration, vac. drying;	50%

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 292638-85-8
acrylic acid methyl ester

: Co(C48H36N4O4)(CH(CH3)CO2CH3)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;	70%
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR;
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90 min; detected by H-NMR (70 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: (Et4N)2[{Ni(κ2-SPh-o-NNO-p-CF3)(NO)}2]

: nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

: trans-(Et4N)2[Ni(SPh-o-NNO-p-CF3)2]

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h; Solvent;	A 70% B n/a

...Expand

: 108-86-1
bromobenzene

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 571165-61-2
C54H41CoN4O4

Conditions

Conditions	Yield
With potassium hydroxide; tert-butyl alcohol In benzene at 150℃; for 1.5h; Inert atmosphere; Darkness;	69%

: 106-88-7
ethyloxirane

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: Co(C48H36N4O4)(CH2CH(OH)C2H5)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide excess AIBN and org. substrate, sealed tube (vac.), 333 K;	65%
With 2,2'-azobis(isobutyronitrile) In N,N-dimethyl-formamide a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, heated at 60°C for 180-240 min; detected by H-NMR (65 % yield);
With 2,2'-azobis(2,4-dimethylpentanenitrile) In N,N-dimethyl-formamide Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in DMF was sealed in an evacuated ampoule, react. at 40°C for 500-660 min; detected by H-NMR (84 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 100-200 min; detected by H-NMR (<2 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 536-74-3
phenylacetylene

: Co(C48H36N4O4)(C(C6H5)CH2)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;	60%
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 80 min; detected by H-NMR (60 % yield);

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 99685-96-8, 161105-99-3, 161106-00-9, 111138-12-6, 133318-63-5, 134053-11-5, 134931-35-4, 134931-36-5, 139703-76-7, 145633-27-8, 175414-73-0, 175414-74-1, 175414-75-2, 175519-12-7, 175519-13-8, 175519-14-9, 175519-15-0, 136376-46-0, 144906-37-6, 144906-38-7, 151767-00-9, 152882-97-8, 152882-98-9, 152882-99-0, 153062-34-1, 154171-74-1, 154171-75-2, 154333-99-0, 154334-00-6, 154397-63-4, 154460-59-0, 199456-56-9, 108739-25-9, 120329-57-9, 120329-58-0
fullerene-C60

: 445241-52-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)*C60

Conditions

Conditions	Yield
With ferrocene In toluene a soln. in toluene containing Co-complex, C60 and ferrocene at a 1:1:10 molar ratio, was evapd. under Ar; the solvent was decanted, crystals were washed with dry acetone;	60%

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: nitrolsylcobalt(II) meso-tetra(p-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With [C5H10NH2](+)[C5H10NN(O)NO](-) In dichloromethane N2-atmosphere; stirring for 30 min, then boiling; pptn. on MeOH addn., cooling to room temp., collection (filtration), washing (MeOH), drying (vac.);	60%

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 201230-82-2
carbon monoxide

: 75-65-0
tert-butyl alcohol

: tert-butyloxycarbonylcobalt meso-(4-methoxyphenyl)porphyrin

Conditions

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In toluene at 20℃; under 5320.36 Torr; for 16h; Darkness;	60%

...Expand

: 292638-84-7
styrene

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: Co(C48H36N4O4)(CH(CH3)C6H5)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform excess AIBN and org. substrate, sealed tube (vac.), 333 K;	50%
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, heated at 60°C; detected by H-NMR;
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, heated at 60°C for 90-120 min; detected by H-NMR (47 % yield);

: 7647-01-0
hydrogenchloride

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 82150-28-5
5,10,15,20-tetra(4-methoxyphenyl) porphyrinato cobalt chloride

Conditions

Conditions	Yield
With air In hydrogenchloride; methanol air flow was passed through suspn. of Co(II) complex in MeOH and concd. HCl for 10 h; ppt. was filtered, soln. was neutralized by concd. soln. of NH4OH;	47%

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 7732-18-5
water

: 84-58-2
2,3-dicyano-5,6-dichloro-p-benzoquinone

: C48H36CoN4O4(1+)*CN(1-)*H2O

Conditions

Conditions	Yield
In chloroform at 20℃; for 2h;	0.6%

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 627-27-0
homoalylic alcohol

: Co(C20N4H8(C6H4OCH3)4)(CH2(CH2)3OH)

: Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 60°C for 120-150 min; detected by H-NMR (52/28 % yield);

...Expand

: 28903-71-1
(5,10,15,20-tetrakis(p-methoxyphenyl)-21H,23H-porphyrinate)cobalt(II)

: 627-27-0
homoalylic alcohol

: Co(C20N4H8(C6H4OCH3)4)(CH(CH3)(CH2)2OH)

Conditions

Conditions	Yield
With 2,2'-azobis(2,4-dimethylpentanenitrile) In chloroform a soln. of the Co-complex, the organic substrate and the azocompd. in CHCl3 was sealed in an evacuated ampoule, react. at 40°C for 300-360 min; detected by H-NMR (>95 % yield);
With 2,2'-azobis(isobutyronitrile) In chloroform-d1 Kinetics; a soln. of the Co-complex, the organic substrate and the azocompd. in CDCl3 was sealed in an evacuated ampoule, react. at 60°C; detected by H-NMR;

Cobalt tetramethoxyphenylporphyrin Chemical Properties

Product Name: Cobalt tetramethoxyphenylporphyrin
Synonyms of Cobalt tetramethoxyphenylporphyrin (CAS NO.28903-71-1): Tetrakis(4-methoxyphenyl)-21h,23h-porphine cobalt(II) ; Tetra(4-methoxyphenyl)porphine cobalt complex ; Molybdate ionophore I ; Tmppco ; Tmopp-co ; Tetramethoxyphenylporphyrin cobalt II
CAS NO: 28903-71-1
Molecular Formula: C₄₈H₃₆CoN₄O₄
Molecular Weight: 791.757
Molecular Structure:

Melting Point: 241-248°C
ProductCategories: Porphyrins ; Biochemistry ; Classes of Metal Compounds ; Co (Cobalt) Compounds ; Transition Metal Compounds ; CobaltPhotonic and Optical Materials ; Catalysis and Inorganic Chemistry ; Chemical Synthesis ; Phthalocyanine and Porphyrin Dyes ; Porphyrines
H bond acceptors: 8
Freely Rotating Bonds: 8
Polar Surface Area of Cobalt tetramethoxyphenylporphyrin (CAS NO.28903-71-1): 69.81 Å²

Cobalt tetramethoxyphenylporphyrin Safety Profile

Safety Statements of Cobalt tetramethoxyphenylporphyrin (CAS NO.28903-71-1): 24/25
S24/25: Avoid contact with skin and eyes.
WGK Germany: 3

Product Name

Cobalt tetramethoxyphenylporphyrin

Synthetic route

Cobalt tetramethoxyphenylporphyrin Chemical Properties

Cobalt tetramethoxyphenylporphyrin Safety Profile

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