Product Name

  • Name

    D-(-)-ERYTHROSE

  • EINECS 209-505-2
  • CAS No. 583-50-6
  • Article Data87
  • CAS DataBase
  • Density 1.41 g/cm3
  • Solubility Fully miscible in water.
  • Melting Point <25℃
  • Formula C4H8O4
  • Boiling Point 311.1 °C at 760 mmHg
  • Molecular Weight 120.105
  • Flash Point 156.2 °C
  • Transport Information
  • Appearance clear colourless very viscous liquid
  • Safety 24/25-36-26
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 583-50-6 (D-(-)-ERYTHROSE)
  • Hazard Symbols IrritantXi
  • Synonyms Butanal,2,3,4-trihydroxy-, [R-(R*,R*)]-;Erythrose, D- (8CI);D-(-)-Erythrose;D-Erythrose;
  • PSA 77.76000
  • LogP -2.10060

Synthetic route

D-Fructose
57-48-7

D-Fructose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With sodium hydroxide; iron(III) chloride In water at 20℃; Quantum yield; Irradiation; other carbohydrate-metal ion system: D-fructose-MnCl2, D-glucose-FeCl3;74%
With perchloric acid; ammonium vanadate In water at 30℃; under 750.06 Torr; Rate constant; Mechanism; activation volume; further pressures;
meso-erythritol
909878-64-4

meso-erythritol

C

D-erythronic acid
488-16-4

D-erythronic acid

D

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
PtTl In perchloric acid; water for 4h; Product distribution; electrocatalytic reaction; also on Pt and on Pt-Pb electrode; oxidation potential varied: 0.45, 0.6, 0.8 V;A 74%
B n/a
C 22%
D n/a
platinum lead wire In perchloric acid; water for 4h; electrocatalytic reaction;A 4%
B 5%
C 33%
D 7%
Conditions
ConditionsYield
With dihydrogen peroxide; FAU(2.4); copper In water at 19.85℃; for 3.5h; pH=6.5; Product distribution; Further Variations:; Catalysts; Ruff degradation;A 63%
B 9%
2-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-4-isopropyl-2H-oxazol-5-one

2-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-4-isopropyl-2H-oxazol-5-one

A

3-methyl-2-ketobutanoic acid
759-05-7

3-methyl-2-ketobutanoic acid

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran Ambient temperature;A n/a
B 59%
D-threose
95-43-2

D-threose

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With zeolite H-USY In water at 120℃; for 3h;A 26%
B 1%

A

D-threose
95-43-2

D-threose

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With zeolite H-USY In water at 120℃; for 3h;A 5%
B 4%
With pyridine Equilibrium constant; Heating;
D-glucose
50-99-7

D-glucose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With lead(IV) acetate; acetic acid Erwaermen der erhaltenen O2,O3(oderO2,O4)-Diformyl-D-erythrose mit verd. wss. Salzsaeure;
With lead(IV) acetate
With molybdenum(VI) oxide In isopropyl alcohol at 190℃; for 2.66667h; Reagent/catalyst; Solvent;
5,5-bis-ethanesulfonyl-L-erythro-pent-4-ene-1,2,3-triol
115014-57-8

5,5-bis-ethanesulfonyl-L-erythro-pent-4-ene-1,2,3-triol

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With ammonium hydroxide
D-arabinononitrile 2,3,4,5-tetraacetate
34360-54-8

D-arabinononitrile 2,3,4,5-tetraacetate

sodium methylate
124-41-4

sodium methylate

D-erythrose
583-50-6

D-erythrose

2,4-O-ethylidene-aldehydo-D-erythrose
901783-93-5

2,4-O-ethylidene-aldehydo-D-erythrose

A

endo-2,3-O-ethylidene-β-D-erythrofuranose
29810-04-6

endo-2,3-O-ethylidene-β-D-erythrofuranose

B

exo-1,2-O-ethylidene-α-D-erythrofuranose
77489-43-1

exo-1,2-O-ethylidene-α-D-erythrofuranose

C

exo-2,3-O-ethylidene-β-D-erythrofuranose
77519-84-7

exo-2,3-O-ethylidene-β-D-erythrofuranose

D

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
sulfuric acid for 0.25h; Heating;
2,4-O-ethylidene-aldehydo-D-erythrose
901783-93-5

2,4-O-ethylidene-aldehydo-D-erythrose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
In sulfuric acid at 100℃; for 0.25h; steam distillation;11.5 g
D-Fructose
57-48-7

D-Fructose

A

D-Glyceraldehyde
453-17-8

D-Glyceraldehyde

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) chloride In water at 20℃; for 2h; Product distribution; Kinetics; Mechanism; Irradiation; anaerobic and aerobic conditions; other reagent: Fe(NO3)3; various reaction times.;
D-Fructose
57-48-7

D-Fructose

A

Adonitol
488-81-3

Adonitol

B

(S)-3,4-dihydroxy-butyraldehyde
81893-52-9

(S)-3,4-dihydroxy-butyraldehyde

C

2,3-dideoxy-3-C-hydroxymethyltetrose
81539-41-5

2,3-dideoxy-3-C-hydroxymethyltetrose

D

2-deoxy-2-C-hydroxymethyltetrose
81539-40-4, 132215-58-8

2-deoxy-2-C-hydroxymethyltetrose

E

ethylene glycol
107-21-1

ethylene glycol

F

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
In water Quantum yield; Irradiation; 254-nm photolysis in deoxigenated and oxygenated solutions;
1,2-O-isopropylidene-D-erythrose
14048-37-4

1,2-O-isopropylidene-D-erythrose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With oxonium
D-Mannose
3458-28-4

D-Mannose

A

D-Arabinose
10323-20-3

D-Arabinose

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Irradiation;
D-Arabinose
10323-20-3

D-Arabinose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Irradiation;
D-ribose
50-69-1

D-ribose

A

D-Glyceraldehyde
453-17-8

D-Glyceraldehyde

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Irradiation;
D-ribose
50-69-1

D-ribose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With cerium(IV) perchlorate In perchloric acid at 25 - 50℃; Kinetics; Product distribution; variation of the concentration;
D-glucose
50-99-7

D-glucose

A

D-Glyceraldehyde
453-17-8

D-Glyceraldehyde

B

D-Arabinose
10323-20-3

D-Arabinose

C

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Kinetics; Mechanism; Irradiation; various reaction times.;
D-erythrofuranose
210230-59-4

D-erythrofuranose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
In water-d2 at 60℃; Rate constant; Equilibrium constant; pH=4.0, acetate buffer;
With sodium acetate In water-d2 at 51℃; Rate constant; Kinetics;
exo-1,2-O-ethylidene-α-D-erythrofuranose
77489-43-1

exo-1,2-O-ethylidene-α-D-erythrofuranose

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With sulfuric acid at 96℃; for 4h; Product distribution; further erythrofuranoses;
fructopyranose
6347-01-9

fructopyranose

A

formic acid
64-18-6

formic acid

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With oxygen; iron(III) chloride In water at 20℃; for 120h; Product distribution; Quantum yield; Irradiation; variation of time; pH range between 6.8-9.0;
sodium D-gluconate
527-07-1

sodium D-gluconate

A

D-Arabinose
10323-20-3

D-Arabinose

B

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
In water at 25 - 40℃; for 12h; electrolysis; max. specific power consumption: 43 kWh kg-1; total current 17 A, pH 5.6; Yield given. Yields of byproduct given;
ammonium hydroxide

ammonium hydroxide

1,1-bis-ethanesulfonyl-D-2,5-anhydro-1-deoxy-ribitol
31818-58-3

1,1-bis-ethanesulfonyl-D-2,5-anhydro-1-deoxy-ribitol

A

bis(ethylsulfonyl)methane
1070-92-4

bis(ethylsulfonyl)methane

B

D-erythrose
583-50-6

D-erythrose

D-Fructose
57-48-7

D-Fructose

periodic acid

periodic acid

A

formaldehyd
50-00-0

formaldehyd

B

glycolic Acid
79-14-1

glycolic Acid

C

arabinoic acid
488-30-2

arabinoic acid

D

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
at 0℃; Produkt: Glyoxylsaeure;
1,1-bis-acetylamino-D-1-deoxy-erythritol

1,1-bis-acetylamino-D-1-deoxy-erythritol

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With sulfuric acid
D-arabinononitrile 2,3,4,5-tetraacetate
34360-54-8

D-arabinononitrile 2,3,4,5-tetraacetate

sulfuric acid
7664-93-9

sulfuric acid

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
beim folgenden Behandeln mit Ba(OH)2 und Ag2CO3;
calcium-D arabinonate

calcium-D arabinonate

D-erythrose
583-50-6

D-erythrose

Conditions
ConditionsYield
With iron(III) sulfate; water; barium(II) acetate Erwaermen der Reaktionsloesung mit wss.Wasserstoffperoxid;
S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

D-erythrose
583-50-6

D-erythrose

S,S'-((4-(2-(bis((2S,3R)-2,3,4-trihydroxybutyl)amino)ethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

S,S'-((4-(2-(bis((2S,3R)-2,3,4-trihydroxybutyl)amino)ethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

Conditions
ConditionsYield
Stage #1: S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride; D-erythrose With sodium cyanoborohydride; acetic acid In methanol at 55℃; for 6h;
Stage #2: With hydrogenchloride In water pH=3;
73%
{4-[4-(2-Aminoethoxy)phenyl]butyl}carbamic acid benzyl ester hydrochloride
587880-59-9

{4-[4-(2-Aminoethoxy)phenyl]butyl}carbamic acid benzyl ester hydrochloride

D-erythrose
583-50-6

D-erythrose

4-(4-Carboxymethylphenyl)butylamine

4-(4-Carboxymethylphenyl)butylamine

Conditions
ConditionsYield
With sodium cyanoborohydride; acetic acid In methanol72%
D-erythrose
583-50-6

D-erythrose

benzyl alcohol
100-51-6

benzyl alcohol

benzyl α,β-D-erythroside
82883-31-6, 82883-32-7

benzyl α,β-D-erythroside

Conditions
ConditionsYield
With hydrogenchloride; calcium sulfate for 24h;66%
methanol
67-56-1

methanol

D-erythrose
583-50-6

D-erythrose

A

D-Erythrose dimethyl acetal
74761-31-2

D-Erythrose dimethyl acetal

B

methyl β-D-erythrofuranoside
53109-84-5

methyl β-D-erythrofuranoside

C

methyl α-D-erythrofuranoside
52613-15-7

methyl α-D-erythrofuranoside

Conditions
ConditionsYield
With sulfuric acid for 30h; Ambient temperature;A 8%
B 65%
C 11%
With sulfuric acid for 30h; Ambient temperature;A 11%
B 65%
C 8%
1.3-propanedithiol
109-80-8

1.3-propanedithiol

D-erythrose
583-50-6

D-erythrose

D-erythrose propane-1,3-diyl dithioacetal
218439-29-3

D-erythrose propane-1,3-diyl dithioacetal

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran Ambient temperature;64%
With hydrogenchloride 1) 10 min., 0 deg C; 2) 30 min. at room temp.;2.88 g
acetaldehyde
75-07-0

acetaldehyde

D-erythrose
583-50-6

D-erythrose

2-deoxy-D-arabino-hexono-1,4-lactone
75754-51-7, 75754-52-8, 137873-05-3, 137873-23-5

2-deoxy-D-arabino-hexono-1,4-lactone

Conditions
ConditionsYield
With ethylenediaminetetraacetic acid In water for 48h; deoxyribose-5-phosphate aldolase (DERA), phosphate buffer, pH 7.3;62%
D-erythrose
583-50-6

D-erythrose

1,1-Diphenylhydrazine
530-50-7

1,1-Diphenylhydrazine

(2R,3S,E)-4-(2,2-diphenylhydrazono)butane-1,2,3-triol

(2R,3S,E)-4-(2,2-diphenylhydrazono)butane-1,2,3-triol

Conditions
ConditionsYield
In methanol at 20℃; for 0.75h;57%
In methanol at 20℃; for 0.75h;19%
ethane-1,2-dithiol
540-63-6

ethane-1,2-dithiol

D-erythrose
583-50-6

D-erythrose

(1R,2R)-1-[1,3]Dithiolan-2-yl-propane-1,2,3-triol
145458-89-5

(1R,2R)-1-[1,3]Dithiolan-2-yl-propane-1,2,3-triol

Conditions
ConditionsYield
With hydrogenchloride55%
nitromethane
75-52-5

nitromethane

D-erythrose
583-50-6

D-erythrose

A

1-Desoxy-1-nitro-D-arabino-pentitol
55065-39-9

1-Desoxy-1-nitro-D-arabino-pentitol

B

1-Deoxy-1-nitro-D-ribitol
130930-30-2

1-Deoxy-1-nitro-D-ribitol

Conditions
ConditionsYield
With sodium methylate In methanol for 4h;A 47%
B 28%
1,6-Hexanediamine
124-09-4

1,6-Hexanediamine

D-erythrose
583-50-6

D-erythrose

1,6-bis(1-deoxy-D-erithritol-1-ylamino)hexane

1,6-bis(1-deoxy-D-erithritol-1-ylamino)hexane

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In methanol; water at 40℃; under 6750.68 Torr; for 24h;47%
7-amino-3-(2-trifluoromethylphenyl)-2H-isoquinolin-1-one
862470-02-8

7-amino-3-(2-trifluoromethylphenyl)-2H-isoquinolin-1-one

D-erythrose
583-50-6

D-erythrose

3-(2-trifluoromethylphenyl)-7-((2S,3R)-2,3,4-trihydroxybutylamino)-2H-isoquinolin-1-one
908256-38-2

3-(2-trifluoromethylphenyl)-7-((2S,3R)-2,3,4-trihydroxybutylamino)-2H-isoquinolin-1-one

Conditions
ConditionsYield
With sodium cyanoborohydride; acetic acid In tetrahydrofuran; methanol at 0 - 20℃; for 4h;42%
D-Serine
312-84-5

D-Serine

D-erythrose
583-50-6

D-erythrose

D-Fructose
57-48-7

D-Fructose

Conditions
ConditionsYield
With magnesium(II) chloride hexahydrate; flavin adenine dinucleotide (FAD)-containing flavoenzyme from the yeast Rhodotorula gracilis; thiamine pyrophosphate; oxygen In water at 25℃; for 8h; pH=7; Enzymatic reaction;40%
D-erythrose
583-50-6

D-erythrose

B

D-threose
95-43-2

D-threose

Conditions
ConditionsYield
With zeolite H-USY In water at 120℃; for 3h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Time; Concentration;A 39%
B 2%
D-erythrose
583-50-6

D-erythrose

formic acid
64-18-6

formic acid

Conditions
ConditionsYield
With phosphovanadomolybdic acid; oxygen In water at 180℃; under 15001.5 Torr; for 3h;38%
D-erythrose
583-50-6

D-erythrose

A

D-threonic acid
20246-26-8

D-threonic acid

B

D-erythronic acid
488-16-4

D-erythronic acid

Conditions
ConditionsYield
With sodium anthraquinone-2-sulfonate; calcium chloride In sodium hydroxide at 50℃; Product distribution; further solvent, without catalyst; further D-aldoses;A 34%
B 29%
With sodium anthraquinone-2-sulfonate; calcium chloride In sodium hydroxide at 50℃;A 34%
B 29%
2-thiazolylamine
96-50-4

2-thiazolylamine

D-erythrose
583-50-6

D-erythrose

C10H14N4O3S2

C10H14N4O3S2

Conditions
ConditionsYield
In aq. buffer for 24h; pH=7;32%
C60H58N14O18S5
214044-53-8

C60H58N14O18S5

D-erythrose
583-50-6

D-erythrose

C65H66N14O21S5
1064084-29-2

C65H66N14O21S5

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 24h;20%
methanol
67-56-1

methanol

methylthiol
74-93-1

methylthiol

D-erythrose
583-50-6

D-erythrose

methyl 2-hydroxy-4-(methylthio)butanoate
52703-96-5

methyl 2-hydroxy-4-(methylthio)butanoate

Conditions
ConditionsYield
With potassium carbonate at 100℃; for 4h; Temperature;20%
sodium pyruvate
113-24-6

sodium pyruvate

D-erythrose
583-50-6

D-erythrose

Sodium; (4S,5S,6R)-4,5,6,7-tetrahydroxy-2-oxo-heptanoate

Sodium; (4S,5S,6R)-4,5,6,7-tetrahydroxy-2-oxo-heptanoate

Conditions
ConditionsYield
With potassium dihydrogenphosphate; sodium azide In water for 96h; 2-keto-3-deoxy-6-phosphogluconate aldolase from Escherichia coli;18.2%
D-erythrose
583-50-6

D-erythrose

A

5-hydroxymethyl-2-furfuraldehyde
67-47-0

5-hydroxymethyl-2-furfuraldehyde

B

3,4-Dihydroxybenzoic acid
99-50-3

3,4-Dihydroxybenzoic acid

C

1-(3,4-dihydroxyphenyl)ethan-1-one
1197-09-7

1-(3,4-dihydroxyphenyl)ethan-1-one

D

1-[5-(hydroxymethyl)furan-2-yl]ethan-1-one
55087-82-6

1-[5-(hydroxymethyl)furan-2-yl]ethan-1-one

E

3,4-dihydroxybenzaldehyde
139-85-5

3,4-dihydroxybenzaldehyde

F

3-methylbenzene-1,2-diol
488-17-5

3-methylbenzene-1,2-diol

Conditions
ConditionsYield
With acetate buffer for 45h; Product distribution; Heating;A 0.04%
B 0.03%
C 0.01%
D 0.15%
E 0.01%
F 0.03%
nitromethane
75-52-5

nitromethane

sodium methylate
124-41-4

sodium methylate

D-erythrose
583-50-6

D-erythrose

D-ribose
50-69-1

D-ribose

Conditions
ConditionsYield
With methanol Eintragen einer wss.Loesung des Reaktionsprodukts in wss.Schwefelsaeure bei -20grad;
nitromethane
75-52-5

nitromethane

D-erythrose
583-50-6

D-erythrose

1-nitro-D-erythro-pentene-(1)-triol-(3.4.5)-triacetate
29810-07-9, 68107-77-7

1-nitro-D-erythro-pentene-(1)-triol-(3.4.5)-triacetate

Conditions
ConditionsYield
With sodium methylate Behandlung mit Eisessig und mit Acetanhydrid + H2SO4 und folgendes Kochen mit NaHCO3 in Benzol;
D-erythrose
583-50-6

D-erythrose

D-erythronic acid
488-16-4

D-erythronic acid

Conditions
ConditionsYield
With perchloric acid; sodium perchlorate; chromium (VI) Kinetics; Mechanism; ΔH=40 +/-3 kJ/mol, ΔS= -119 +/-10 J/deg.mol k2=14.9 1/mol.sec;
With water; bromine
With sodium hydroxide; osmium(VIII) oxide In water at 14.85℃; Rate constant; Thermodynamic data; ΔH*, ΔS* at 303 K;
With gold(III) chloride In water at 24.85℃; pH=3.72; Activation energy; Kinetics; Further Variations:; Reagents; pH-values;
Conditions
ConditionsYield
With sodium amalgam

D-Erythrose Specification

The CAS register number of D-Erythrose is 583-50-6. It also can be called as Butanal,2,3,4-trihydroxy-, (2R,3R)- and the IUPAC name about this chemical is (2S,3S)-2,3,4-trihydroxybutanal. The molecular formula about this chemical is C4H8O4 and the molecular weight is 120.1. It belongs to the following product categories which include Carbohydrate Synthesis; Carbohydrates; Carbohydrates A to; Carbohydrates D-FBiochemicals and Reagents; Monosaccharides; MonosaccharideSpecialty Synthesis and so on.

Physical properties about D-Erythrose are: (1)ACD/LogP: -1.69; (2)ACD/LogD (pH 5.5): -1.69; (3)ACD/LogD (pH 7.4): -1.69; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.87; (7)ACD/KOC (pH 7.4): 2.87; (8)#H bond acceptors: 4; (9)#H bond donors: 3; (10)#Freely Rotating Bonds: 6; (11)Polar Surface Area: 44.76Å2; (12)Index of Refraction: 1.505; (13)Molar Refractivity: 25.28 cm3; (14)Molar Volume: 85.1 cm3; (15)Polarizability: 10.02x10-24cm3; (16)Surface Tension: 68.6 dyne/cm; (17)Enthalpy of Vaporization: 64.01 kJ/mol; (18)Boiling Point: 311.1 °C at 760 mmHg; (19)Vapour Pressure: 5.12E-05 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. When you are using it, please avoid contact with skin and eyes and wear suitable protective clothing. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C[C@H](O)[C@H](O)CO
(2)InChI: InChI=1/C4H8O4/c5-1-3(7)4(8)2-6/h1,3-4,6-8H,2H2/t3-,4+/m0/s1
(3)InChIKey: YTBSYETUWUMLBZ-IUYQGCFVBI
(4)Std. InChI: InChI=1S/C4H8O4/c5-1-3(7)4(8)2-6/h1,3-4,6-8H,2H2/t3-,4+/m0/s1
(5)Std. InChIKey: YTBSYETUWUMLBZ-IUYQGCFVSA-N

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