D-Glucaric acid supplier

Name
D-SACCHARIC ACID CALCIUM SALT
EINECS 201-768-1
CAS No. 87-73-0
Article Data111
CAS DataBase
Density 1.939 g/cm³
Solubility
Melting Point 125-126°
Formula C₆H₁₀O₈
Boiling Point 766.4 °C at 760 mmHg
Molecular Weight 210.141
Flash Point 431.2 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Glucaricacid, D- (8CI);Saccharic acid (6CI);D-(+)-Saccharic acid;D-Glucosaccharicacid;D-Saccharate;D-Saccharic acid;D-Tetrahydroxyadipic acid;L-Gularic acid;
PSA 155.52000
LogP -3.40080

Synthetic route

: 50-99-7
D-glucose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With 5 % platinum on carbon; oxygen In water at 80℃; under 10351 Torr; for 10h; pH=7.2; pH-value; Temperature; Pressure;	74%
With oxygen In water at 110℃; under 8517.48 Torr; for 2h;	21%
With nitric acid

: 576-42-1
D-glucaric acid monopotassium salt

A: 87-73-0
D-glucaric acid

B: 389-36-6
D-Glucaro-1,4-lacton

C: 2782-04-9
D-glucaro-6,3-lactone

Conditions

Conditions	Yield
With H(1+) resin Rexyn 100(H) In water for 3h; lactonization;	A n/a B n/a C 69.1%

...Expand

: 2280-44-6
D-Glucose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With 2.44 wt.% platinum and 2.38 wt.% aurum on carbon; oxygen In water at 90℃; under 4635.46 Torr; for 5h; Reagent/catalyst;	60%

: 50-99-7
D-glucose

A: 64-18-6
formic acid

B: 526-95-4
gluconic acid

C: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With dihydrogen peroxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In water at 60℃; for 18h;	A 7% B 35% C 17%
With oxygen; potassium hydrogen phthalate In water for 3h; pH=4.01; Catalytic behavior; Kinetics; Mechanism; Reagent/catalyst; pH-value; UV-irradiation;

...Expand

: 50-99-7
D-glucose

A: 526-95-4
gluconic acid

B: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With oxygen; sodium hydroxide In water at 60℃; under 7500.75 Torr; for 24h; Catalytic behavior; Temperature; Pressure; Reagent/catalyst; Autoclave;	A 31% B 18%
With MoO5; dihydrogen peroxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In water at 60℃; for 18h;	A 27% B 13%
With ammonium vanadate In sulfuric acid at 90℃; for 3h; Kinetics; Mechanism; Equilibrium constant; activation energy; different concentrations of H2SO4;
With oxygen; sodium nitrite In sulfolane; perchloric acid at 59.85℃; under 750.06 Torr; Kinetics; Further Variations:; Temperatures; Pressures;
With Fe-doped TiO2-supported zeolite; air In water; acetonitrile at 30℃; under 760.051 Torr; for 1.5h; Reagent/catalyst; Solvent; UV-irradiation;

: 50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5
glucose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With nitric acid in mehreren Stufen;
bei der Einw. von Aspergillus niger;
bei der Einw. der Nektarhefen Anthomyces Reukaufii oder Amphiernia rubra;

: 526-95-4
gluconic acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With nitric acid
Bildung aus subcutan injizierte d-Gluconsaeure im Organismus des Kaninchens. (Schott konnte diese Bildung nicht bestaetigen);
With UDP-glucose dehydrogenase Enzymatic reaction;
With sodium sulfate at 25℃; Electrochemical reaction;

: 20246-33-7
gluconic acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With nitric acid

: 576-37-4, 685-73-4, 1986-14-7, 1986-15-8, 2073-35-0, 3402-98-0, 6556-12-3, 6814-36-4, 14982-50-4, 15769-56-9, 21675-50-3, 21675-51-4, 21675-52-5, 21675-53-6, 27766-62-7, 28223-51-0, 28223-52-1, 39737-41-2, 70332-45-5, 84710-57-6, 102681-51-6, 108729-78-8
glucuronic acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With bromine

: 66-84-2, 1772-03-8, 2861-47-4, 4773-26-6, 5505-63-5, 20880-44-8, 25591-10-0, 28002-39-3, 91673-93-7, 91674-20-3, 91674-21-4, 92986-85-1, 95245-33-3, 113532-33-5
2-amino-hexanetetrol-(3,4,5,6)-al-(1); hydrochloride

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
Desaminierung und nachfolgende Oxydation mit Salpetersaeure;

: 57-50-1
Sucrose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With nitric acid
With nitric acid in mehreren Stufen;
With iron(II) ammonium sulfate; disodium hydrogenphosphate; phosphoglucomutase; sucrose phosphorylase; myo-inositol monophosphatase; uronate dehydrogenase; myo-inositol 1-phosphate synthase; myo-inositol oxygenase; nicotinamide adenine dinucleotide oxidase; nicotinamide adenine dinucleotide; magnesium chloride In aq. buffer at 30℃; for 12h; pH=7.5; pH-value; Temperature; Solvent; Concentration; Enzymatic reaction;

: 133-99-3, 490-37-9, 2152-98-9, 4482-75-1, 5965-66-2, 13299-27-9, 13360-52-6, 14641-93-1, 15548-43-3, 16462-44-5, 16984-36-4, 16984-38-6, 20869-27-6, 22688-72-8, 27452-49-9, 29276-55-9, 30608-12-9, 34481-13-5, 37169-60-1, 37169-64-5, 64234-01-1, 64234-02-2, 75281-88-8, 80446-85-1, 84413-57-0, 92344-56-4, 93221-87-5, 93301-77-0, 94799-29-8, 100427-98-3, 100428-00-0, 101312-82-7, 102046-24-2, 102046-25-3, 109432-00-0, 109432-02-2, 109432-04-4, 109432-08-8, 135268-49-4, 138231-26-2, 140461-59-2, 145414-22-8, 145414-26-2, 146339-75-5, 146339-76-6, 149116-55-2
Maltose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With bromine

: 63-42-3
D-(+)-lactose

A: 87-73-0
D-glucaric acid

B: 526-99-8, 1213827-87-2
meso-galactaric acid

Conditions

Conditions	Yield
With nitric acid

: 512-69-6
D-raffinose

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With nitric acid

: 6556-12-3, 489-91-8, 528-16-5, 552-12-5, 577-46-8, 643-33-4, 2240-07-5, 6294-16-2, 10133-02-5, 18402-78-3, 18968-14-4, 21179-08-8, 23018-83-9, 33599-45-0, 33599-46-1, 46171-67-9, 46171-69-1, 46172-26-3, 70021-34-0, 71031-08-8, 104195-06-4, 106499-29-0, 124817-72-7
D-glucuronic acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With dihydrogen peroxide; iron(II) sulfate at 30℃; for 1h; Product distribution; Mechanism; effect of reaction time, inhibitors (D-mannitol, thiourea, Me2SO), pH, buffers, further iron salt and complexing agents (EDTA, DTPA, ADP); experiments with a rat-liver microsomal preparation;
With sodium hydroxide; sodium perchlorate; chloroamine-T at 35℃; for 24h; Rate constant; Mechanism; Thermodynamic data; effect of reagents concentration, solvent isotope effect, Ea, ΔH(excit.), ΔS(excit.), ΔG(excit.), also in solvents; effect of reaction products: p-toluensulphonamide and chloride ions;
With dihydrogen peroxide; iron(II) sulfate at 30℃; for 3h; pH 6.0;
With sodium hydroxide; sodium perchlorate; chloramine-B In water at 35℃; Kinetics; Further Variations:; Solvents; Temperatures; ionic strength; Oxidation;

: 526-95-4
gluconic acid

A: 669-90-9
fructonic acid

B: 1986-15-8
α-L-guluronic acid

C: 87-73-0
D-glucaric acid

D: 144-62-7
oxalic acid

Conditions

Conditions	Yield
With oxygen In water at 55℃; under 750.06 Torr; Product distribution; Mechanism; further catalyst, further reagent, effect of further catalyst and reagent;

...Expand

: 13214-42-1
sodium 1-deoxy-1-<(N-acetyl-N-phenylamino)oxy>-β-D-glucopyranuronate

A: 87-73-0
D-glucaric acid

B: 62-53-3
aniline

Conditions

Conditions	Yield
With sulfuric acid In ethanol at 20℃; Mechanism; Rate constant;

: 29781-80-4
octyl alpha-D-glucopyranoside

A: 80-69-3
tartronic acid

B: 147-73-9
meso-tartaric acid

C: 87-69-4
L-Tartaric acid

D: 526-95-4
gluconic acid

E: 87-73-0
D-glucaric acid

F: 144-62-7
oxalic acid

Conditions

Conditions	Yield
With oxygen; platinum on activated charcoal In water at 49.9℃; under 300.02 Torr; Product distribution; Mechanism; initial rate of consumption, pH effect;

...Expand

: 97-30-3
methyl-alpha-D-glucopyranoside

A: 64-18-6
formic acid

B: 79-14-1
glycolic Acid

C: 23598-27-8
methyl α-D-gluco-hexodialdo-1,5-pyranoside

D: 5155-45-3
methyl α-D-glucopyranosiduronic acid

E: 488-16-4
D-erythronic acid

F: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With oxygen; platinum on activated charcoal In water at 49.9℃; under 300.02 Torr; Product distribution; Mechanism; initial rate of consumption, pH effect;

...Expand

: 6556-12-3, 489-91-8, 528-16-5, 552-12-5, 577-46-8, 643-33-4, 2240-07-5, 6294-16-2, 10133-02-5, 18402-78-3, 18968-14-4, 21179-08-8, 23018-83-9, 33599-45-0, 33599-46-1, 46171-67-9, 46171-69-1, 46172-26-3, 70021-34-0, 71031-08-8, 104195-06-4, 106499-29-0, 124817-72-7
D-glucuronic acid

A: 147-73-9
meso-tartaric acid

B: 728879-26-3
D-arabinuronic acid

C: 488-31-3, 608-54-8, 608-55-9, 6703-05-5, 10158-64-2, 20869-04-9, 33012-62-3
(2S,4S)-xylaric acid

D: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
With phosphate buffer; dihydrogen peroxide; iron(II) sulfate In water at 37℃; for 6h; pH=7.4; Product distribution; Further Variations:; Reagents; Oxidation;

...Expand

: 7732-18-5
water

: 389-36-6
D-Glucaro-1,4-lacton

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
at 18℃; Rate constant; Hydrolysis;
at 18℃; Equilibrium constant; Hydrolysis;

: 7732-18-5
water

: 2782-04-9
D-glucaro-6,3-lactone

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
at 18℃; Rate constant; Hydrolysis;
at 18℃; Equilibrium constant; Hydrolysis;

ricestarch: ricestarch

A: 87-73-0
D-glucaric acid

B: 144-62-7
oxalic acid

Conditions

Conditions	Yield
With nitric acid at 100℃;

: 7732-18-5
water

: 1219325-97-9
O2,O5-diacetyl-glucaric acid-1=>4;6=>3-dilactone

A: 87-73-0
D-glucaric acid

B: 64-19-7
acetic acid

Conditions

Conditions	Yield
Hydrolysis; O2,O5-diacetyl-glucaric acid-1=>4;6=>3-dilactone;

...Expand

: 50-99-7
D-glucose

: 7697-37-2
nitric acid

: 87-73-0
D-glucaric acid

: 526-95-4
gluconic acid

: 7697-37-2
nitric acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
at 85℃;

: 20246-33-7
gluconic acid

: 7697-37-2
nitric acid

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
das Lacton reagiert;

: 526-95-4
gluconic acid

: 10544-72-6
dinitrogen tetraoxide

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
at 25℃;

: 56-23-5
tetrachloromethane

: 526-95-4
gluconic acid

: 10544-72-6
dinitrogen tetraoxide

: 87-73-0
D-glucaric acid

Conditions

Conditions	Yield
at 25℃;

...Expand

: 67-56-1
methanol

: 87-73-0
D-glucaric acid

: 627-93-0
hexanedioic acid dimethyl ester

Conditions

Conditions	Yield
With potassium perrhenate; phosphoric acid; palladium on activated charcoal; hydrogen; pyrographite at 150℃; under 3878.71 Torr;	85%

: 87-73-0
D-glucaric acid

: 3238-40-2
furan-2,5-dicarboxylic acid

Conditions

Conditions	Yield
With benzenesulfonic acid for 0.0333333h; microwave irradiation;	58%
With toluene-4-sulfonic acid at 140℃; for 2h;	52%
With 1-butyl-3-methylimidazolium hydrogen sulfate; sulfuric acid at 120℃; for 17h; Temperature;	39 %Chromat.
With sulfolane; sulfuric acid In toluene at 100 - 130℃; Reagent/catalyst; Solvent; Temperature;

: 186581-53-3, 908094-01-9
diazomethane

: 87-73-0
D-glucaric acid

: 4041-92-3
Lg-threo-4-hydroxy-2,5-dimethoxy-hex-2c-enedioic acid-1-lactone-6-methyl ester

Conditions

Conditions	Yield
With diethyl ether

: 50-00-0
formaldehyd

: 87-73-0
D-glucaric acid

: 4,5-bis-(5-oxo-[1,3]dioxolan-4-yl)-[1,3]dioxolane

Conditions

Conditions	Yield
bei 10-20-maligem Abdampfen; -β.β'-methylene ether α.α'-bis-methylene ether ester;

: 107-85-7
1-amino-3-methylbutane

: 87-73-0
D-glucaric acid

: 13679-79-3
1-(3-methyl-butyl)-pyrrole

Conditions

Conditions	Yield
under 70 Torr; bei der Destillation;

: 50-99-7
D-glucose

: 87-73-0
D-glucaric acid

: 87-69-4
L-Tartaric acid

Conditions

Conditions	Yield
With nitric acid waehrend aus Staerke;

: 87-73-0
D-glucaric acid

: 59-88-1
phenylhydrazine hydrochloride

: 7404-38-8, 99782-61-3, 110507-66-9
idaric acid bis-(N'-phenyl-hydrazide)

Conditions

Conditions	Yield
With sodium acetate -bis-phenylhydrazide;

: 87-73-0
D-glucaric acid

A: 496-64-0
3-hydroxy-2-pyrone

B: 88-14-2
2-furanoic acid

Conditions

Conditions	Yield
With potassium pyrosulfate

: 87-73-0
D-glucaric acid

A: 4H-pyran-2,3-dione

B: 88-14-2
2-furanoic acid

Conditions

Conditions	Yield
With potassium pyrosulfate

: 87-73-0
D-glucaric acid

: 124-04-9
Adipic acid

Conditions

Conditions	Yield
With phosphorus; hydrogen iodide at 140 - 150℃; im geschlossenen Rohr;
With hydrogen iodide; hydrogen In acetic acid at 210℃; for 3h; Flow reactor;

: 87-73-0
D-glucaric acid

: 87-69-4
L-Tartaric acid

Conditions

Conditions	Yield
With permanganate(VII) ion at 0℃;
With sulfuric acid Electrolysis;
With dihydrogen peroxide

: 87-73-0
D-glucaric acid

A: 87-69-4
L-Tartaric acid

: 133-37-9
DL-tartaric acid

Conditions

Conditions	Yield
With nitric acid

: 87-73-0
D-glucaric acid

: 133-37-9
DL-tartaric acid

Conditions

Conditions	Yield
With nitric acid

: 87-73-0
D-glucaric acid

: 541-50-4
2-acetoacetic acid

Conditions

Conditions	Yield
bei der Durchblutung der ueberlebenden Leber;

: 87-73-0
D-glucaric acid

: 110-15-6
succinic acid

Conditions

Conditions	Yield
bei der Einw.von Bac.coli unter anaeroben Bedingungen;
With calcium carbonate bei der Einw.von Bact.lactis aerogenes unter anaeroben Bedingungen;

: 87-73-0
D-glucaric acid

: 4,5-bis-phenylhydrazono-L-threo-4,5-dideoxy-pentonic acid

Conditions

Conditions	Yield
Reaktion ueber mehrere Stufen;

: 87-73-0
D-glucaric acid

: 32449-92-6
D-glucurono-6,3-lactone

Conditions

Conditions	Yield
With sodium amalgam; sulfuric acid; water

: 87-73-0
D-glucaric acid

A: 389-36-6
D-Glucaro-1,4-lacton

B: 2782-04-9
D-glucaro-6,3-lactone

Conditions

Conditions	Yield
Eindampfen einer wss. Loesung unter vermindertem Druck;

: 87-73-0
D-glucaric acid

: (3-hydroxy-5-oxo-4-phenylhydrazono-tetrahydro-[2]furyl)-phenylhydrazono-acetic acid

Conditions

Conditions	Yield
With water; dihydrogen peroxide; iron man faellt mit Phenylhydrazinacetat; bis-phenylhydrazone of melting point 242 degree-244 degree;

: 87-73-0
D-glucaric acid

: 108-24-7
acetic anhydride

: 1219325-97-9
O2,O5-diacetyl-glucaric acid-1=>4;6=>3-dilactone

Conditions

Conditions	Yield
With zinc(II) chloride O2,O5-diacetyl-glucaric acid-1=>4;6=>3-dilactone;

D-Glucaric acid Specification

The D-Glucaric acid, with the CAS registry number 87-73-0, is also known as D-(+)-saccharic acid. Its EINECS registry number is 201-768-1. This chemical's molecular formula is C₆H₁₀O₈ and molecular weight is 210.14. Its IUPAC name is called (2S,3S,4S,5R)-2,3,4,5-tetrahydroxyhexanedioic acid.

Physical properties of D-Glucaric acid: (1)ACD/LogP: -1.46; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -6.12; (4)ACD/LogD (pH 7.4): -6.21; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 8; (10)#H bond donors: 6; (11)#Freely Rotating Bonds: 9; (12)Index of Refraction: 1.638; (13)Molar Refractivity: 38.94 cm³; (14)Molar Volume: 108.3 cm³; (15)Surface Tension: 137.2 dyne/cm; (16)Density: 1.939 g/cm³; (17)Flash Point: 431.2 °C; (18)Enthalpy of Vaporization: 127.27 kJ/mol; (19)Boiling Point: 766.4 °C at 760 mmHg; (20)Vapour Pressure: 4.04E-27 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C(C(C(C(=O)O)O)O)(C(C(=O)O)O)O
(2)Isomeric SMILES: [C@H]([C@@H]([C@@H](C(=O)O)O)O)([C@H](C(=O)O)O)O
(3)InChI: InChI=1S/C6H10O8/c7-1(3(9)5(11)12)2(8)4(10)6(13)14/h1-4,7-10H,(H,11,12)(H,13,14)/t1-,2-,3-,4+/m0/s1
(4)InChIKey: DSLZVSRJTYRBFB-LLEIAEIESA-N

Product Name

D-SACCHARIC ACID CALCIUM SALT

Synthetic route

D-Glucaric acid Specification

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