D-Glyceraldehyde supplier | CasNO.453-17-8

Name
D-Glyceraldehyde
EINECS 207-217-1
CAS No. 453-17-8
Article Data35
CAS DataBase
Density 1.272g/cm³
Solubility
Melting Point 127-129 C
Formula C3H6 O3
Boiling Point 228°Cat760mmHg
Molecular Weight 90.0788
Flash Point 106°C
Transport Information
Appearance Orange, viscous liquid.
Safety 26-27-36/37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Glyceraldehyde,D- (8CI); Propanal, 2,3-dihydroxy-, (R)-; (+)-Glyceraldehyde;(R)-(+)-Glyceraldehyde; (R)-Glyceraldehyde; D-(+)-Glyceraldehyde;D-Glyceraldehyde; D-Glycerose; NSC 91534; Triose
PSA 57.53000
LogP -1.46150

Synthetic route

: 96-26-4
dihydroxyacetone

: 56-82-6
Glyceraldehyde

A: 453-17-8
D-Glyceraldehyde

B: 57-48-7, 87-79-6, 87-81-0, 551-68-8, 3615-39-2, 3615-56-3, 6035-50-3, 7776-48-9, 16354-64-6, 17598-81-1, 17598-82-2, 23140-52-5, 30237-26-4, 65732-90-3, 73952-10-0, 73952-11-1, 139686-85-4
L-fructose

Conditions

Conditions	Yield
With E. coli BL21 (DE3) cells harboring pETDRhaD aldolase; sodium borate buffer In water; toluene at 37℃; for 16h; pH=7.6;	A n/a B 92%

...Expand

: 591-57-1
D-glyceraldehyde-3-phosphate

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With Potato acid phosphatase (Pase) In water	85%

: 57-48-7
D-Fructose

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With lead(IV) acetate; acetic acid Erwaermen des Reaktionsprodukts mit wss.Schwefelsaeure;

: 18376-33-5
(R)-3,3-dimethoxy-propane-1,2-diol

: 453-17-8
D-Glyceraldehyde

: 56-82-6
Glyceraldehyde

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With bacterium coli
With bacterium lactis aerogenes

: 57-48-7
D-Fructose

A: 453-17-8
D-Glyceraldehyde

B: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With iron(III) chloride In water at 20℃; for 2h; Product distribution; Kinetics; Mechanism; Irradiation; anaerobic and aerobic conditions; other reagent: Fe(NO3)3; various reaction times.;

: 87-72-9, 608-45-7, 608-46-8, 608-47-9, 2460-44-8, 6748-95-4, 6763-34-4, 7261-26-9, 7283-06-9, 7283-07-0, 7296-55-1, 7296-56-2, 7296-58-4, 7296-59-5, 7296-60-8, 7296-61-9, 7296-62-0, 7322-30-7, 10257-31-5, 10257-32-6, 10257-33-7, 10257-34-8, 10257-35-9, 19982-83-3, 20242-88-0, 28697-53-2, 36562-42-2, 41546-41-2, 89299-64-9, 107655-34-5, 115794-06-4, 115794-07-5, 130550-15-1, 130606-21-2
D-Xylose

A: 453-17-8
D-Glyceraldehyde

B: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-lyxose

C: 141-46-8
Glycolaldehyde

D: 78-98-8
2-oxopropanal

Conditions

Conditions	Yield
With sulfuric acid at 250℃; under 258771 Torr; for 0.00888889h; Further byproducts given;	A 1 % Chromat. B 8 % Chromat. C 11 % Chromat. D 6 % Chromat.

...Expand

: 87-72-9, 608-45-7, 608-46-8, 608-47-9, 2460-44-8, 6748-95-4, 6763-34-4, 7261-26-9, 7283-06-9, 7283-07-0, 7296-55-1, 7296-56-2, 7296-58-4, 7296-59-5, 7296-60-8, 7296-61-9, 7296-62-0, 7322-30-7, 10257-31-5, 10257-32-6, 10257-33-7, 10257-34-8, 10257-35-9, 19982-83-3, 20242-88-0, 28697-53-2, 36562-42-2, 41546-41-2, 89299-64-9, 107655-34-5, 115794-06-4, 115794-07-5, 130550-15-1, 130606-21-2
D-Xylose

A: 10326-41-7
D-Lactic acid

B: 453-17-8
D-Glyceraldehyde

C: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-lyxose

D: 78-98-8
2-oxopropanal

Conditions

Conditions	Yield
With sulfuric acid at 250℃; under 258771 Torr; for 0.00888889h; Further byproducts given;	A 7 % Chromat. B 1 % Chromat. C 8 % Chromat. D 6 % Chromat.

...Expand

: 50-69-1
D-ribose

A: 453-17-8
D-Glyceraldehyde

B: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Irradiation;

: 50-99-7
D-glucose

A: 453-17-8
D-Glyceraldehyde

B: 10323-20-3
D-Arabinose

C: 583-50-6
D-erythrose

Conditions

Conditions	Yield
With iron(III) chloride In water at 20℃; for 3h; Product distribution; Kinetics; Mechanism; Irradiation; various reaction times.;

...Expand

: 96-26-4
dihydroxyacetone

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With trisodium arsenate; triosephosphate isomerase
With 1H-imidazole; xylose isomerase; sodium chloride; magnesium chloride In water at 25℃; pH=8; pH-value; Enzymatic reaction;

: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-lyxose

A: 98-01-1
furfural

B: 87-72-9, 608-45-7, 608-46-8, 608-47-9, 2460-44-8, 6748-95-4, 6763-34-4, 7261-26-9, 7283-06-9, 7283-07-0, 7296-55-1, 7296-56-2, 7296-58-4, 7296-59-5, 7296-60-8, 7296-61-9, 7296-62-0, 7322-30-7, 10257-31-5, 10257-32-6, 10257-33-7, 10257-34-8, 10257-35-9, 19982-83-3, 20242-88-0, 28697-53-2, 36562-42-2, 41546-41-2, 89299-64-9, 107655-34-5, 115794-06-4, 115794-07-5, 130550-15-1, 130606-21-2
D-Xylose

C: 453-17-8
D-Glyceraldehyde

D: 78-98-8
2-oxopropanal

Conditions

Conditions	Yield
With sulfuric acid at 250℃; under 258771 Torr; Further byproducts given;	A 37 % Chromat. B 2.0 % Chromat. C 1.0 % Chromat. D 5.3 % Chromat.

...Expand

: 114882-91-6
(R)-3,3-diethoxypropane-1,2-diol

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With sulfuric acid at 35℃; for 20h;

: 141650-88-6
(6R,7R,14R)-14-formyl-1,8,13,16-tetraoxodispiro<5.0.5.4>-hexadecane

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With trifluoroacetic acid for 1h; Ambient temperature;

: 153323-30-9
3-[(1R)-1,2-dihydroxyethyl]-1,5-dihydro-3H-2,4-benzodioxepine

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With hydrogen; palladium dihydroxide In methanol at 25℃; under 2585.7 Torr; for 48h;

: 15186-48-8
2,3-isopropylidene-glyceraldehyde

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With sulfuric acid In water at 45℃; for 1.5h;
With sulfuric acid
With DOWEX 50 W (H+) In tetrahydrofuran; water at 20℃; Inert atmosphere;

: 56-82-6
Glyceraldehyde

bacterium coli: bacterium coli

yeast water: yeast water

calcium dicarbonate: calcium dicarbonate

A: 453-17-8
D-Glyceraldehyde

B: 497-09-6
(S)-glyceraldehyde

Conditions

Conditions	Yield
at 37℃;

...Expand

: 56-82-6
Glyceraldehyde

bacterium lactis aerogenes: bacterium lactis aerogenes

yeast water: yeast water

calcium dicarbonate: calcium dicarbonate

A: 453-17-8
D-Glyceraldehyde

B: 497-09-6
(S)-glyceraldehyde

Conditions

Conditions	Yield
at 37℃;

...Expand

: 87-72-9, 608-45-7, 608-46-8, 608-47-9, 2460-44-8, 6748-95-4, 6763-34-4, 7261-26-9, 7283-06-9, 7283-07-0, 7296-55-1, 7296-56-2, 7296-58-4, 7296-59-5, 7296-60-8, 7296-61-9, 7296-62-0, 7322-30-7, 10257-31-5, 10257-32-6, 10257-33-7, 10257-34-8, 10257-35-9, 19982-83-3, 20242-88-0, 28697-53-2, 36562-42-2, 41546-41-2, 89299-64-9, 107655-34-5, 115794-06-4, 115794-07-5, 130550-15-1, 130606-21-2
D-Xylose

A: 98-01-1
furfural

B: 10326-41-7
D-Lactic acid

C: 453-17-8
D-Glyceraldehyde

D: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-lyxose

E: 141-46-8
Glycolaldehyde

F: 78-98-8
2-oxopropanal

G other pentose: other pentose

Conditions

Conditions	Yield
With sulfuric acid at 250℃; under 258771 Torr; for 0.00888889h; Rate constant; Product distribution; Mechanism; other reaction times, various concentrations of acid; reactions in the presence of a product (furfural); reaction with water (without acid);	A 21 % Chromat. B 7 % Chromat. C 1 % Chromat. D 8 % Chromat. E 11 % Chromat. F 6 % Chromat. G n/a

...Expand

1.2;5.6-diisopropylidene-D-mannitol: 1.2;5.6-diisopropylidene-D-mannitol

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
With lead(IV) acetate; benzene und Verseifung mit verd. H2SO4 oder Essigsaeure;
With lead(IV) acetate; acetic acid und Verseifung mit verd. H2SO4 oder Essigsaeure;

: 69-65-8
mannitol

: 7732-18-5
water

sodium periodate: sodium periodate

: 453-17-8
D-Glyceraldehyde

Conditions

Conditions	Yield
at 20℃;

...Expand

: 69-65-8
mannitol

: 7732-18-5
water

: periodic acid

A: 50-00-0
formaldehyd

B: 453-17-8
D-Glyceraldehyde

C: 10323-20-3
D-Arabinose

D: 141-46-8
Glycolaldehyde

Conditions

Conditions	Yield
at 0℃; weitere Produkt: Ameisensaeure;

...Expand

: 3416-24-8
2-amino-2-deoxyglucose

: 7732-18-5
water

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 453-17-8
D-Glyceraldehyde

C: 10323-20-3
D-Arabinose

D D-fructosazine: D-fructosazine

Conditions

Conditions	Yield
Produkt 5: Melanoidin;

...Expand

: 3416-24-8
2-amino-2-deoxyglucose

aqueous sodium phosphate: aqueous sodium phosphate

A: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

B: 453-17-8
D-Glyceraldehyde

C: 10323-20-3
D-Arabinose

D D-fructosazine: D-fructosazine

Conditions

Conditions	Yield
Produkt 5: Melanoidin;

...Expand

: 532-20-7, 613-83-2, 7261-25-8, 7687-39-0, 13221-22-2, 14795-83-6, 15761-67-8, 20074-49-1, 25545-03-3, 25545-04-4, 32445-75-3, 34436-17-4, 36441-93-7, 36468-53-8, 37110-85-3, 37388-49-1, 38029-69-5, 40461-77-6, 40461-89-0, 41546-19-4, 41546-20-7, 41546-21-8, 41546-26-3, 41546-29-6, 41546-30-9, 41546-31-0, 126872-16-0, 131064-98-7
D-lyxose

A: 98-01-1
furfural

B: 87-72-9, 608-45-7, 608-46-8, 608-47-9, 2460-44-8, 6748-95-4, 6763-34-4, 7261-26-9, 7283-06-9, 7283-07-0, 7296-55-1, 7296-56-2, 7296-58-4, 7296-59-5, 7296-60-8, 7296-61-9, 7296-62-0, 7322-30-7, 10257-31-5, 10257-32-6, 10257-33-7, 10257-34-8, 10257-35-9, 19982-83-3, 20242-88-0, 28697-53-2, 36562-42-2, 41546-41-2, 89299-64-9, 107655-34-5, 115794-06-4, 115794-07-5, 130550-15-1, 130606-21-2
D-Xylose

C: 453-17-8
D-Glyceraldehyde

D: 116-09-6
hydroxy-2-propanone

E: 78-98-8
2-oxopropanal

F other pentose: other pentose

Conditions

Conditions	Yield
With sulfuric acid at 250℃; under 258771 Torr; Rate constant; Product distribution; Mechanism;	A 37 % Chromat. B 2.0 % Chromat. C 1.0 % Chromat. D 4.5 % Chromat. E 5.3 % Chromat. F n/a

...Expand

: 91987-77-8
D-glyceraldehyde, hydrated form

A: 453-17-8
D-Glyceraldehyde

B water: water

Conditions

Conditions	Yield
In water at 20 - 80℃; Equilibrium constant; Thermodynamic data; From measured specific rotation of the equilibrium mixture of D-glyceraldehyde and its hydrate and equilibrium constant calculated specific rotation of both compounds at 436, 546 and 589 nm.;

: 533-67-5
2-Deoxy-D-ribose

A: 453-17-8
D-Glyceraldehyde

B: 75-07-0
acetaldehyde

Conditions

Conditions	Yield
With 1,4-dihydronicotinamide adenine dinucleotide; D-deoxyribose-5-phosphate aldolase; triethanolamine hydrochloride In water at 25℃; pH=7.5; Kinetics; Further Variations:; Reagents;

: 57-04-5
dihydroxyacetone phosphate

: 56-82-6
Glyceraldehyde

A: 453-17-8
D-Glyceraldehyde

B: 19456-80-5
L-fructose 1-phosphate

Conditions

Conditions	Yield
With sodium hydroxide; rhamnulose-1-phosphate aldolase; zinc(II) chloride; potassium phosphate buffer In water at 23℃; for 48h; pH=6.8;

...Expand

: 50-00-0
formaldehyd

: 141-46-8
Glycolaldehyde

A: 453-17-8
D-Glyceraldehyde

B: 497-09-6
(S)-glyceraldehyde

Conditions

Conditions	Yield
With L-proline optical yield given as %ee;

...Expand

: 453-17-8
D-Glyceraldehyde

: 530-50-7
1,1-Diphenylhydrazine

: C15H16N2O2

Conditions

Conditions	Yield
With acetic acid In methanol for 1h;	95%

: 453-17-8
D-Glyceraldehyde

: 1186-47-6
1,1-dihydroxyacetone

: D-fructose

Conditions

Conditions	Yield
With transaldolase B F178Y/R181E In water-d2 at 25℃; for 24h; Kinetics; Reagent/catalyst; Aldol reaction; Enzymatic reaction; stereoselective reaction;	94%
With his6-transaldolase B F178Y/R181E Kinetics; Reagent/catalyst; Aldol reaction; Enzymatic reaction;

: 13331-23-2
fur-2-ylboronic acid

: 453-17-8
D-Glyceraldehyde

: 3290-99-1
4-methoxybenzoic acid hydrazide

: C15H18N2O5

Conditions

Conditions	Yield
In methanol at 25℃; for 24h; Petasis Reaction; diastereoselective reaction;	94%

...Expand

: 453-17-8
D-Glyceraldehyde

: 62-31-7
dopamine hydrochloride

: 259183-94-3
(1'S)-1-(1',2'-dihydroxyethyl)-6,7-dihydroxy-1,2,3,4-tetrahydroisoquinoline

Conditions

Conditions	Yield
In methanol Heating;	93%
In methanol 1) RT, overnight, 2) reflux, 2 d;	93%

: 453-17-8
D-Glyceraldehyde

: 473-81-4, 600-19-1, 6000-40-4, 28305-26-2
D-glyceric acid

Conditions

Conditions	Yield
With sodium anthraquinone-2-sulfonate; calcium chloride In sodium hydroxide at 50℃;	92%
With water; bromine
With bromine; silver carbonate
With bromine In water for 2h;

: 453-17-8
D-Glyceraldehyde

: 123-54-6
acetylacetone

: 70107-20-9
1-(5-(hydroxymethyl)-2-methylfuran-3-yl)ethan-1-one

Conditions

Conditions	Yield
With zirconium(IV) chloride In water-d2 at 20℃; for 5h;	92%
With methanol; zinc(II) chloride

: 453-17-8
D-Glyceraldehyde

: D-Glyceraldehyde-2-phosphate

Conditions

Conditions	Yield
With amidotriphosphate sodium salt; magnesium chloride at 20℃; for 120h; pH=7.1; Substitution;	81%

: 453-17-8
D-Glyceraldehyde

: 96-26-4
dihydroxyacetone

: 57-48-7
D-Fructose

Conditions

Conditions	Yield
With D-fructose-6-phosphate aldolase of Escherichia coli Ala129Ser mutant at 25℃; for 48h; pH=7.5; NaHCO3 buffer;	81%
With transaldolase from listeria monocytogenes In aq. phosphate buffer for 8h; pH=7.5; Enzymatic reaction;	25%
With E. coli transaldolase B mutant F178Y In glycyl-glycine buffer at 25℃; pH=8.5; Enzymatic reaction; optical yield given as %de; stereoselective reaction;
With E. coli transaldolase B mutant F178Y In glycyl-glycine buffer at 30℃; pH=8.5; Kinetics; Enzymatic reaction; stereoselective reaction;

: 120-72-9
indole

: 453-17-8
D-Glyceraldehyde

: C19H18N2O2

Conditions

Conditions	Yield
With montmorillonite K10 clay (K10) at 20℃; for 0.5h;	80%

: 453-17-8
D-Glyceraldehyde

: 106-95-6
allyl bromide

: 164145-69-1
1(S)-[(2R)-1,4-dioxaspiro[4.5]decanyl]-3-buten-1-ol

Conditions

Conditions	Yield
With ammonium chloride; zinc In tetrahydrofuran at 0℃; for 6h;	78%

: 13331-23-2
fur-2-ylboronic acid

: 453-17-8
D-Glyceraldehyde

: 937-39-3
2-phenylacetylhydrazine

: C15H18N2O4

Conditions

Conditions	Yield
In methanol at 25℃; for 24h; Petasis Reaction; diastereoselective reaction;	77%

...Expand

: 453-17-8
D-Glyceraldehyde

: 116-09-6
hydroxy-2-propanone

: 119241-42-8
1-deoxy-β-D-fructopyranose

Conditions

Conditions	Yield
With E. coli transaldolase B mutant F178Y In glycyl-glycine buffer at 25℃; pH=8.5; Enzymatic reaction; stereoselective reaction;	75%

: 371-41-5
4-Fluorophenol

: 5,6-di-O-isopropylidene-(D)-mannitol

: 453-17-8
D-Glyceraldehyde

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

A: 64520-58-7
ethyl (E)-3-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate

B: 104605-97-2
(2R)-2,3-epoxy-1-(4-fluorophenoxy)propane

Conditions

Conditions	Yield
With sodium periodate; sodium sulfate In hexane; dichloromethane; sodium hydrogencarbonate; ethyl acetate	A n/a B 73%

...Expand

: 453-17-8
D-Glyceraldehyde

: S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

: S,S'-((4-(2-(bis((S)-2,3-dihydroxypropyl)amino)ethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride

Conditions

Conditions	Yield
Stage #1: D-Glyceraldehyde; S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) diethanethioate hydrochloride With sodium cyanoborohydride; acetic acid In methanol at 60℃; for 4h; Stage #2: With hydrogenchloride In water pH=3;	72%

: 453-17-8
D-Glyceraldehyde

: 75-20-7
calcium carbide

: 103-49-1
dibenzylamine

: 1510838-84-2
N,N-dibenzyl-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-prop-yn-1-amine

Conditions

Conditions	Yield
With copper(l) iodide In acetonitrile at 80℃; for 18h; Inert atmosphere;	70%

...Expand

: 996-35-0
N,N-dimethylisopropyl amine

: 453-17-8
D-Glyceraldehyde

: 380430-49-9
[4-(tert-butoxycarbonylamino)phenyl]boronic acid

: 1133434-00-0
tert-butyl 4-((1S,2S)-2,3-dihydroxy-1-isopropyl(methyl)aminopropyl)-phenylcarbamate

Conditions

Conditions	Yield
In ethanol at 20℃; for 72h;	69%

...Expand

: 453-17-8
D-Glyceraldehyde

: 116-09-6
hydroxy-2-propanone

: 32785-92-5
1-deoxy-D-frucrose

Conditions

Conditions	Yield
With D-fructose-6-phosphate aldolase of Escherichia coli Ala129Ser mutant at 25℃; for 48h; pH=7.5; NaHCO3 buffer;	68%

: 453-17-8
D-Glyceraldehyde

: 75-07-0
acetaldehyde

: 452-51-7, 13046-70-3, 29780-54-9, 36792-87-7, 36792-88-8, 113890-35-0, 113890-38-3
D-2-deoxyribose

Conditions

Conditions	Yield
With ethylenediaminetetraacetic acid In water for 48h; deoxyribose-5-phosphate aldolase (DERA), phosphate buffer, pH 7.3;	65%

: 453-17-8
D-Glyceraldehyde

: 75-20-7
calcium carbide

: 109-89-7
diethylamine

: 1510838-93-3
1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)-N,N-diethylprop-2-yn-1-amine

Conditions

Conditions	Yield
With copper(l) iodide In acetonitrile at 80℃; for 18h; Inert atmosphere;	65%

...Expand

: 453-17-8
D-Glyceraldehyde

: 312-84-5
D-Serine

: 551-84-8
xylulose

Conditions

Conditions	Yield
With magnesium(II) chloride hexahydrate; flavin adenine dinucleotide (FAD)-containing flavoenzyme from the yeast Rhodotorula gracilis; thiamine pyrophosphate; oxygen In water at 25℃; for 8h; pH=7; Enzymatic reaction;	65%

: magnesium glycerol phosphate

: 453-17-8
D-Glyceraldehyde

: 57-48-7
D-Fructose

Conditions

Conditions	Yield
Stage #1: magnesium glycerol phosphate; D-Glyceraldehyde With glycerol phosphate oxidase; recombinant D-fructose 1,6-bisphosphate aldolase from Staphylococcus carnosus; catalase In water at 20℃; for 22h; pH=7; Enzymatic reaction; Stage #2: With hydrogenchloride; acid phosphatase from sweet potato In water at 37℃; for 24h; pH=Ca. 5; Enzymatic reaction; stereoselective reaction;	60%
With FAD; Staphylococcus carnosus D-fructose 1,6-bisphosphate aldolase; Streptococcus pneumonia glycerol phosphate oxidase In water-d2 at 30℃; for 22h; pH=7; Enzymatic reaction;	56%

: 13331-23-2
fur-2-ylboronic acid

: 453-17-8
D-Glyceraldehyde

: 1354376-45-6
N’-allyl-4-methoxybenzohydrazide

: C16H22N2O3

Conditions

Conditions	Yield
In dichloromethane at 25℃; for 24h; Petasis Reaction; diastereoselective reaction;	58%

...Expand

: 453-17-8
D-Glyceraldehyde

: 1113-60-6
3-hydroxy-2-oxopropionic acid

: 669-90-9
fructonic acid

Conditions

Conditions	Yield
With recombinant aldolase B2T1L6 from Burkholderia phytofirmans; manganese(ll) chloride In aq. buffer for 20h; pH=8; Catalytic behavior; Reagent/catalyst; Aldol Addition; Green chemistry; Enzymatic reaction; stereoselective reaction;	55%

: 453-17-8
D-Glyceraldehyde

: 1258856-14-2
2-isopropoxy-5-(3-(6-methyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)-1,2,4-oxadiazol-5-yl)benzonitrile trifluoroacetate

: 1258853-82-5
(S)-5-(3-(3-(2,3-dihydroxypropyl)-6-methyl-2,3,4,5-tetrahydro-1H-benzo[d]azepin-7-yl)-1,2,4-oxadiazol-5-yl)-2-isopropoxybenzonitrile hydrochloride

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; acetic acid In dichloromethane at 20℃; for 92h; Inert atmosphere;	47%

: 453-17-8
D-Glyceraldehyde

: 1167415-61-3
2-[(1-methylethyl)oxy]-5-[3-(2,3,4,5-tetrahydro-1H-3-benzazepin-7-yl)-1,2,4-oxadiazol-5-yl]benzonitrile hydrochloride

: 1258852-98-0
5-(3-{3-[(2S)-2,3-dihydroxypropyl]-2,3,4,5-tetrahydro-1H-3-benzazepin-7-yl}-1,2,4-oxadiazol-5-yl)-2-[(1-methylethyl)oxy]benzonitrile

Conditions

Conditions	Yield
Stage #1: D-Glyceraldehyde; 2-[(1-methylethyl)oxy]-5-[3-(2,3,4,5-tetrahydro-1H-3-benzazepin-7-yl)-1,2,4-oxadiazol-5-yl]benzonitrile hydrochloride With sodium tris(acetoxy)borohydride In dichloromethane at 20℃; for 16h; Inert atmosphere; Stage #2: D-Glyceraldehyde With acetic acid In dichloromethane	46%

: 453-17-8
D-Glyceraldehyde

: 119-26-6
(2,4-dinitro-phenyl)-hydrazine

: C9H10N4O6

Conditions

Conditions	Yield
In water at 20℃; for 24h;	45%

: 453-17-8
D-Glyceraldehyde

: 1258855-37-6
2-[(1-methylethyl)oxy]-5-[3-(5-methyl-1,2,3,4-tetrahydro-6-isoquinolinyl)-1,2,4-oxadiazol-5-yl]benzonitrile hydrochloride

: (S)-5-(3-(2-(2,3-dihydroxypropyl)-5-methyl-1,2,3,4-tetrahydroisoquinolin-6-yl)-1,2,4-oxadiazol-5-yl)-2-isopropoxybenzonitrile

Conditions

Conditions	Yield
With sodium tris(acetoxy)borohydride; acetic acid In dichloromethane at 20℃; for 92h; Inert atmosphere;	44%

: 453-17-8
D-Glyceraldehyde

: 52-90-4
L-Cysteine

: 6851-62-3, 110224-40-3, 110224-41-4, 124617-03-4, 124617-05-6
2(RS)-D-glycero-(1',2'-dihydroxyethyl)thiazolidine-4(R)-carboxylic acid

Conditions

Conditions	Yield
In water	40.5%

D-Glyceraldehyde Chemical Properties

Molecular Structure:

Molecular Formula: C₃H₆O₃
Molecular Weight: 90.0779
IUPAC Name: (2R)-2,3-Dihydroxypropanal
Synonyms of Propanal,2,3-dihydroxy-, (2R)- (CAS NO.453-17-8): D-Glyceraldehyde ; EINECS 207-217-1 ; NSC 91534 ; Triose ; D-(+)-Glyceraldehyde
CAS NO: 453-17-8
Classification Code: chiral ; Carbohydrate Synthesis ; Monosaccharides ; Specialty Synthesis
Melting point: 127-129 °C
Index of Refraction: 1.454
Molar Refractivity: 19.16 cm³
Molar Volume: 70.7 cm³
Surface Tension: 53.3 dyne/cm
Density: 1.272 g/cm³
Flash Point: 106 °C
Enthalpy of Vaporization: 54.01 kJ/mol
Boiling Point: 228 °C at 760 mmHg
Vapour Pressure of Propanal,2,3-dihydroxy-, (2R)- (CAS NO.453-17-8): 0.0146 mmHg at 25°C

D-Glyceraldehyde Safety Profile

Hazard Codes of Propanal,2,3-dihydroxy-, (2R)- (CAS NO.453-17-8): Irritant Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-27-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27: Take off immediately all contaminated clothing.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 3
F: 10-23

Product Name

D-Glyceraldehyde

Synthetic route

D-Glyceraldehyde Chemical Properties

D-Glyceraldehyde Safety Profile

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